Hexamethylene Diisocyanate Research Articles

Card-bisphenol based bio-silica reinforced poly(urethane-co-benzoxazine) foam for an electrical insulation

Agricultural waste by-products such as cashew nut shell liquid and rice husk ash were utilized for the syntheses of card-bisphenol (C) and precipitated bio-silica (S), respectively. A hydroxyl terminated card-bisphenol based benzoxazine resin (CHB) was synthesized and then converted it into soft-foam namely benzoxazine-co-urethane pre-polymer (CHB-UF) by polymerizing with hexamethylene diisocyanate (HMDI) in the absence of any catalysts or foaming agents. Subsequent thermal ring opening polymerization of CHB-UF at 200 °C provides poly(benzoxazine-co-urethane) hard-foam (PCHB-UF) with little shrinkage. Similarly, different weight ratios of precipitated bio-silica (0–15 wt%) reinforced bio-based PCHB-UF hard-foam composites (PCHB-UFS) were prepared to utilize them for high-k dielectrics and hydrophobic applications. The foam microstructure was ascertained through the field emission scanning electron microscopy (FE-SEM). The reinforcement of bio-silica into the CHB-UF foam increases the value of dielectric constant according to the increase in weight percentage concentration, which might be due to the reduction in volume of voids. The neat PCHB-UF possesses the value of dielectric constant of 7.04 with lower value of dielectric loss of 0.01. Similarly, the values of dielectric constant and dielectric loss of 15 wt% bio-silica reinforced composites (PCHB-UFS15) are 10.1 and 0.08 respectively. The PCHB-UFS15 has shown hydrophobic nature with the value of water contact angle of 135°. Data obtained from different studies suggest that the bio-foam composites obtained from sustainable sources can be considered as an efficient dielectric materials used for electronics insulation.

Thermoplastic polyurethane/POSS nanohybrids: Synthesis, morphology, and biological properties.

Recent studies show good osteoinductive properties of polyurethanes modified with polyhedral oligomeric silsesquioxanes (POSS). In this work, three types of POSS; propanediolisobutyl-POSS (PHI-POSS), disilanolisobutyl-POSS (DSI-POSS), and octahydroxybutyl-POSS (OCTA-POSS) were chemically incorporated into linear polyurethane based on an aliphatic isocyanate, hexamethylene diisocyanate (HDI), to obtain new nanohybrid PU-POSS materials. The full conversion of POSS was confirmed by Fourier transform infrared spectroscopy (FTIR-ATR) spectra of the model reactions with pure HDI. The materials obtained were investigated by FTIR, SEM-EDS, and DSC. The DSC studies showed the thermoplasticity of the obtained materials and apparently good recovery. 30-day immersion in SBF (simulated body fluid) revealed an increase in the rate of deposition of hydroxyapatite (HAp) for the highest POSS loadings, resulting in thick layers of hydroxyapatite (~60-40 μm), and the Ca/P ratio 1.67 (even 1.785). The structure and properties of the inorganic layer depend on the type of POSS, the number of hard segments, and those containing POSS, which can be tailored by changing the HDI/poly(tetramethylene glycol) (PTMG) ratio. Furthermore, the obtained composites revealed good biocompatibility, as confirmed by cytotoxicity tests conducted on two cell lines; normal human dermal fibroblasts (NHDF) and primary human osteoblasts (HOB). Adherent cells seeded on the tested materials showed viability even after a 48-h incubation. After this time, the population of viable, and proliferating cells exceeded 90%. Bioimaging studies have shown the fibroblast and osteoblast cells were well attached to the surface of the tested materials.

Synthesis and Characteristic Valuation of a Thermoplastic Polyurethane Electrode Binder for In-Mold Coating.

A polyurethane series (PHEI-PU) was prepared via a one-shot bulk polymerization method using hexamethylene diisocyanate (HDI), polycarbonate diol (PCD), and isosorbide derivatives (ISBD) as chain extenders. The mechanical properties were evaluated using a universal testing machine (UTM), and the thermal properties were evaluated using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The PHEI-PU series exhibited excellent mechanical properties with an average tensile strength of 44.71 MPa and an elongation at break of 190%. To verify the applicability of different proportions of PU as an electrode binder, PU and Ag flakes were mixed (30/70 wt%) and coated on PCT substrates, the electrodes were evaluated by four-point probe before and after 50% elongation, and the dispersion was evaluated by scanning electron microscopy (SEM). The electrical resistance change rate of PHEI-PU series was less than 20%, and a coating layer with well-dispersed silver flakes was confirmed even after stretching. Therefore, it exhibited excellent physical properties, heat resistance, and electrical resistance change rate, confirming its applicability as an electrode binder for in-mold coating.

Preparation of Ceramic Fiber Threads with Enhanced Abrasion Resistance Performance.

Ceramic fiber thread is one of the key components in flexible external thermal insulation blankets, and it has been applied in various fields as a flexible ceramic fibrous material with excellent deformability and high-temperature resistance. However, ceramic fiber threads are often subjected to reciprocating friction motion at specific bending angles, making them highly susceptible to abrade and fracture. Enhancing the abrasion resistance performance of ceramic fiber threads under bending conditions is the future trend and remains a significant challenge. Hence, we design and construct a novel polyurethane-modified coating on the ceramic fiber threads to improve their abrasion resistance performance. The effects of the types and concentrations of modifiers on the microstructure, abrasion resistance property, and tensile property of ceramic fiber threads are systematically investigated. The ceramic fiber threads, after modification with hexamethylene diisocyanate waterborne polyurethane (HDI-WPU) with a concentration of 3%, exhibit excellent abrasion resistance properties. The number of friction cycles at fracture of the modified ceramic fiber thread is more than three times, and the tensile strength is more than one and a half times, that of the original ceramic fiber thread, demonstrating the great potential of the HDI-WPU modifier for enhancing the abrasion resistance performance of ceramic fiber threads.

Stratification of polyisocyanate in two-component waterborne polyurethane films

The coatings industry continually seeks advancements in waterborne two-component polyurethane (2 K WBPU) systems, given their potential for environmentally friendly applications and superior film properties. This study explores the mechanistic aspects of film formation in 2 K WBPU coatings formulated with an acrylic polyol and a polyisocyanate (PIC) derived from a trimer of hexamethylene diisocyanate (HDI-trimer). To enhance water dispersibility—a key parameter in industrial applications—the HDI-trimer is modified with a short polyethylene glycol, producing a hydrophilically modified PIC (hmPIC). While prior studies identified hmPIC as an effective reactive plasticizer for the polyol, the common practice of adding unmodified HDI-trimer (uPIC) to hmPIC for moisture sensitivity reduction necessitates a deeper understanding of film properties. Using fluorescence resonance energy transfer (FRET) and confocal fluorescence microscopy, we investigated the effects of blending uPIC with hmPIC on coalescence, phase separation, and film stratification in 2 K WBPU systems. Notably, environmental factors like relative humidity were found to influence film stratification significantly. This finding has critical implications for coating performance, such as durability and water resistance. A novel method was also introduced to monitor water permeation within stratified films, offering a valuable tool for optimizing film properties in real-world applications. This study underscores the importance of strategic component interactions in polymer coatings, suggesting that controlled film stratification can significantly enhance film performance in industrial settings.

Magnolol-based sustainable, high-strength, shape-memory, transparency, and UV-shielding thermosetting polyurethane networks

Growing environmental concerns have driven the rapid development of sustainable, renewable, biomass-based polymers. Herein, magnolol-based polyurethanes (PU) were synthesized by polyaddition with hexamethylene diisocyanate (HDI) and methylene diphenyl diisocyanate (MDI), respectively. The biomass-based polyurethanes had high molecular weight (up to 26600 g/mol) and a glass transition temperature (Tg) higher than room temperature (Tg > 50 °C). And then thermosetting films were prepared by thiol-ene photo-click reaction. The obtained magnolol-based PU networks (MPUN) shown Young’s modulus of 2.1 GPa and tensile strength of 57 MPa. Shape memory behaviors could be observed in these MPUN. The MPUN could be proceed into various shapes, and then quickly returned to initial states after being heated to 80 °C. More importantly, the MPUN are transparent, yet could shield 99 % of the UVB and UVC irradiation. This study demonstrates a powerful strategy for developing high performance and multifunctional biomass-based polymeric networks from lignin-based renewable products.

Controlling the Synthesis of Polyurea Microcapsules and the Encapsulation of Active Diisocyanate Compounds.

The encapsulation of active components is currently used as common methodology for the insertion of additional functions like self-healing properties on a polymeric matrix. Among the different approaches, polyurea microcapsules are used in different applications. The design of polyurea microcapsules (MCs) containing active diisocyanate compounds, namely isophorone diisocyanate (IPDI) or hexamethylene diisocyanate (HDI), is explored in the present work. The polyurea shell of MCs is formed through the interfacial polymerization of oil-in-water emulsions between the highly active methylene diphenyl diisocyanate (MDI) and diethylenetriamine (DETA), while the cores of MCs contain, apart from IPDI or HDI, a liquid Novolac resin. The hydroxyl functionalities of the resin were either unprotected (Novolac resin), partially protected (Benzyl Novolac resin) or fully protected (Acetyl Novolac resin). It has been found that the formation of MCs is controlled by the MDI/DETA ratio, while the shape and size of MCs depends on the homogenization rate applied for emulsification. The encapsulated active compound, as determined through the titration of isocyanate (NCO) groups, was found to decrease with the hydroxyl functionality content of the Novolac resin used, indicating a reaction between NCO and the hydroxyl groups. Through the thorough investigation of the organic phase, the rapid reaction (within a few minutes) of MDI with the unprotected Novolac resin was revealed, while a gradual decrease in the NCO groups (within two months) has been observed through the evolution of the Attenuated Total Reflectance-Fourier-Transform Infrared (ATR-FTIR) spectroscopy and titration, due to the reaction of these groups with the hydroxyl functionalities of unprotected and partially protected Novolac resin. Over longer times (above two months), the reaction of the remaining NCO groups with humidity was evidenced, especially when the fully protected Acetyl Novolac resin was used. HDI was found to be more susceptible to reactions, as compared with IPDI.

Development of a hyperbranched oxazolidinone dynamic omniphobic liquid-like coating with high hardness and flexibility

Dynamic omniphobic liquid-like anti-fouling coatings have a wide range of applications. However, designing dynamic omniphobic liquid coatings that are highly hard, flexible, and low-cost remains a challenge. In this study, low-cost hyperbranched epoxy resin (HEBP), hexamethylene diisocyanate trimer (HDIT), and mono-hydroxyl-terminated poly(dimethysilxane) (HO-PDMS) were used as polymer matrix. Through a copolymerization reaction, a highly cross-linked rigid oxazolidinone structure (OX) and liquid-like molecular coating were obtained. Meanwhile, this unique design endowed the coating with ultra-high hardness (8H), exceptional flexibility, extremely high transparency, and dynamic omniphobic anti-fouling properties. Moreover, the layer can withstand cycles of friction or bending and exhibits excellent chemical barrier properties. Overall, this coating can be easily prepared on a large scale and has broad application prospects in different fields such as solar panels, outdoor public facilities, and flexible display screens.

Effect of incorporation of star‐shaped polycaprolactone on structure‐properties relationship of chitosan‐based networks via urethane/urea linkage

AbstractA chitosan‐based network was fabricated using hexamethylene diisocyanate as a crosslinking agent. The effect was investigated of incorporating star‐shaped polycaprolactone (stPCL) into chitosan‐based networks (CS/stPCL), where the stPCL content varied from 10 to 50 wt%. Quantitative analyses of the urethane/urea linkages and of the stPCL content in the networks were determined based on curve fitting and Soxhlet extraction, respectively. The optimum weight ratio was 80:20 for CS and stPCL (80CS20stPCL), with the highest urethane/urea linkages and stPCL content in the network (30.73%). The compressive testing and rheological analysis indicated that incorporating stPCL enhanced the compressive strength and rheological properties of the chitosan‐based network. In addition, the 3‐(4,5‐dimethylthiazol‐2‐yl)‐2,5‐diphenyl‐2H‐tetrazolium bromide assay of the CS/stPCL network had a cell viability percentage greater than 70%. The CS/stPCL network promoted the formation of an apatite layer on the surface, indicating that the CS/stPCL network could be a promising candidate for tissue engineering.

Design and development of graphene oxide/shape memory nanocomposite based on hexamethylene diisocyanate mixing segment

AbstractShape memory polymers are remarkable materials renowned for their distinctive ability to fix and recover their original shape in response to specific stimuli. However, the lower shape fixity (SF) of conventional thermally triggered shape memory polyurethane (SMPU) has limited its broad application potential. This study investigates the transformative influence of graphene oxide (GO) nanofillers when incorporated into a linear diisocyanate‐based mixing segment SMPU (SMPU‐GO). The lower SF issue of SMPU is ingeniously addressed by leveraging the interactive properties of GO with the 4,4′‐methylene bis‐phenyl diisocyanate hard segment and the introduction of additional physical cross‐links via hexamethylene diisocyanate mixing segment. At 1 wt.% GO incorporation, the modulus increased by 178%, an 8% increase in tensile strength, while the elasticity was maintained. Excellent improvement in SF and shape recovery (SR) was attained at 1 wt.% GO incorporated SMPU, and the SMPU nanocomposite showed the highest SF (65%) and SR (100%) at 70°C temperature and 50% strain.

Olive industry liquid waste from trash to metal adsorbent for wastewater purification

The development of biobased polymeric materials for wastewater purification has become a demand due to the growing need for water free of hazardous metal ions for safe purposes. The organic components of the OLLW including carbohydrates, phenolics, aromatic acids and others are cost-effective and sustainable choices for this application. This work focuses on a method for turning the organic components of liquid waste from the olive industry (OILW) into a foam-based value-added polymer that has several metal ion binding sites. The process of making the target polymers involved reacting the components of the OILW with hexamethylene diisocyante and 1,4-phnyelene diisocynate to create the polymeric materials LHMIDIC and LPDIC that are in foam forms with urethane linkages, respectively. The adsorption competence of the polymeric foams toward Pb(II) was evaluated as a function of various parameters including adsorbent dose, pH, temperature, initial ion concentration and time. The optimum parameters values that led to a quantitative removal of Pb(II) were identified. The obtained thermodynamic parameters showed that the adsorption by the two foams was spontaneous at room temperature. The isothermal and kinetic values showed that the adsorption by synthesized foams follows a second order kinetic and obeys the Langmuir isothermal model. The foams showed a high tendency for removing multi metal ions present in a real sample of wastewater. The original nature of the starting material used in making the foam, cost and the obtained results showed the potential of using the foam in a large-scale plants of wastewater purification.Graphical

Adiabatic thermal runaway and safety relief design for hexamethylene diisocyanate reaction system

Runaway reaction may occur for hexamethylene-diisocyanate (HDI) with two active NCO groups during the reactions or storage and transportation when run into device failure, operation error and other unexpected environments, which would damage equipment or even cause explosions. Adiabatic experiments for HDI using Vent Sizing Package 2 (VSP2) is conducted and temperature and pressure changes over time, as well as the maximum temperature rise rate and maximum pressure rise rate, are obtained. The results show that the initial exothermic temperature of the system is 50°C, and the maximum temperature is 232°C and the heat of reaction is 414.7 kJ/kg, so the severity level of HDI is classified as "medium" according to the assessment criteria for the severity of a runaway reaction. The relief type of the reaction system is determined to be a gas system by analysis of the pressure change curve during heating and cooling processes, along with the temperature at the point of loss of control, and calculated by the DIERS method and Leung's correction method through Python programming, which is applied to determine the required safety relief device for an industrial scenarios, and the minimum relief area is calculated to be 0.0028m2 and 0.0019m2, respectively. The study verifies the higher reliability of the safety relief design for runaway reactions based on VSP2 experimental data.

Development of quaternary ammonium based acrylic copolymer antimicrobial coatings for polyurethane tracheoesophageal voice prostheses.

Tracheoesophageal voice prostheses (TEPs) are soft polymeric devices used to restore the voices of patients who have undergone total laryngectomy (TL). TEPs are implanted on the tracheoesophageal wall and come in direct contact with food, fluid and air. The environment of an implant is a budding ground for growth of microbes, leading to biofilm formation on the TEP surfaces. Biofilm formation is the leading cause of TEP failure because the biofilm affects its functioning by clogging the air passage over several weeks to a few months. Short useful lifespan of TEPs is a concern for patients undergoing total laryngectomy. To increase the useful lifespan of TEPs, it is imperative to prevent biofilm formation. This problem is addressed in the present study by developing a cationic crosslinked antimicrobial coating that prevents biofilm formation through contact killing. An acrylate-based tetracopolymer poly(methyl methacrylate [MMA]-co-nbutyl acrylate [BA]-co-dimethylaminoethyl methacrylate [DMAEMA]-co-2 hydroxyethyl methacrylate [HEMA]) was synthesized by free radical polymerization and was crosslinked by hexamethylene diisocyanate (THDI) trimer through urethane linkages. The crosslinked tetracopolymer coatings were subjected to quaternary ammonium formation through N-alkylation with iodooctane. Different variants of coatings were synthesized and the tetracopolymer with 22.5% MMA, 22.5% BA, 20% HEMA and 35% DMAEMA showed desirable results. The developed coatings were characterized and tested for safety as well as mechanical and antimicrobial efficacy. The final results showed that the developed coatings exhibited good cytocompatibility, haemocompatibility, mechanical properties and antimicrobial properties for 180 days against E. coli, S. aureus and C. albicans.

Functionalisation of lignin with urethane linkages and their strengthening effect on PLA composites

Lignin was functionalised by crosslinking with hexamethylene diisocyanate (HDI) through the heterogenous reaction in the solvent dimethyl sulfoxide for preferential improvement in the mechanical properties of composites. The successful synthesis of lignin modified with HDI was confirmed by the instrumental analyses, e.g., FTIR, XPS, and FESEM. The incorporation of optimum crosslinked lignin in polylactic acid (PLA) matrix was systematically evaluated on the basis of their thermal stability, mechanical property, glass transition temperature (Tg), water contact angle, water absorption, and water permeability. The results displayed that incorporation of fillers had prominent effects on tensile tear strength, which could improve tensile strength up to 231 % and elongation at break up to 53 % due to the good interface compatibility between PLA and modified lignin. Further, with the inclusion of fillers, PLA composites exhibited higher crystallinity in comparison to neat PLA.

Triple‐chain segments regulation enable shape memory and photo deformation of smart polyimide

AbstractIntegration of controllable deformation with excellent thermal stability, mechanical, and insulation properties can greatly expand the versatility of smart polyimides (PIs). However, the unique molecular structure of PI makes it difficult for its molecular chain to move, which is not conducive to the reversible transformation of highly stable PI under environmental conditions. In this study, a PI film integrating shape memory and photo deformation is prepared by constructing a chemical network with PI oligomer as the hard, hexamethylene diisocyanate (HDI) as the soft, and azobenzene as the functional chain segment. The PI films still have a high glass transition temperature Tg ~ 225°C, a high Young's modulus E ~ 3.5 GPa, and a good breakdown strength Eb ~ 176 kV/mm. Moreover, as the network point of the chemical network, the trifunctional crosslinking agent makes the PI produce the shape memory effect induced by light and heat. UV light can drive crosslinked photoresponsivity PI film to have special shape transformation under specific conditions, using azobenzene as photoresponsivity group. This study provides a new idea for the preparation of multifunctional PI, which makes it potentially applicable in the field of smart electric and electronic engineering.

Synthesis of a Reactive Cationic/Nonionic Waterborne Polyurethane Dye Fixative and Its Application Performance on Viscose Fiber Fabrics.

A series of cationic waterborne polyurethane (CWPU) emulsions was synthesized with isophorone diisocyanate (IPDI) and hexamethylene diisocyanate (HDI) as hard segments; polyol (N210) and polyethylene glycol (PEG-2000) as soft segments; N-methyldiethanolamine (MDEA) as a hydrophilic chain extender; and trimethylolpropane (TMP) as a crosslinker. Then, the effects of the R-value, MDEA content, and TMP content on the properties of the CWPU emulsion, film, and fabric treatment were investigated. The results indicated that when the R-value was 3.0, the MEDA content accounted for 4.0% of the solid and the TMP content accounted for 1.0% of the solid. CWPU has excellent storage stability. Applying it to the fixing treatment of the viscose fiber fabrics can effectively improve the color fastness to rubbing, elasticity, surface smoothness, and anti-static properties.

Mechanically stable superhydrophobic coating of crosslinked polymer composite with self-healing ability

Sustainable superhydrophobicity is of significance for practical application of superhydrophobic coatings. We fabricated a mechanically stable superhydrophobic coating with self-healing performance by spray-coating a composite suspension of poly(vinyl butyral)-hexamethylene diisocyanate and octadecylamine (PVB-HDI/ODA) on various substrates. In the as-obtained composite, PVB-HDI formed 3D self-crosslinked polymer networks which not only impart the coating with high mechanical stability but also provide strong bonding force between the coating and the substrate, and ODA formed pedal-like structures which roughened the coating surface with low surface energy. Consequently, the coating possessed superhydrophobicity with a water contact angle up to 163.9° and a sliding angle lower to 1.0°. Notably, the as-obtained coating sustained its water repellency even after being exposed to various mechanical and chemical treatments. Moreover, the coating exhibited a self-healing ability in superhydrophobicity against O2 plasma etching. Such mechanical and chemical stabilities with self-healing ability are favourable to the superhydrophobic coating to prolong the lifespan for practical applications.

Tuning physical properties of polyurethane hard segments through extender chain length variation and doping of pentaerythritol and their effect on in vitro protein adsorption

AbstractThis study explores the synthesis and characterization of polyurethanes (PUs) derived from hexamethylene diisocyanate (HDI) and 1,n‐alkane diols with varying chain lengths (n = 4, 6, and 10). Additionally, pentaerythritol (PE) is introduced as a dopant in PU6 at different weight percentages (25%, 50%, 75%, and 1:1%w/w). The research encompasses a comprehensive analysis of PU properties, including morphology, crystallinity, surface area, porosity, thermal behavior, rheological properties, and electrical conductivity. Of particular interest is the evaluation of protein adsorption capabilities employing bovine serum albumin (BSA) and fibrinogen proteins in in vitro tests. The study emphasizes the crucial role played by the chain length between isocyanate and diol groups and the nature and strength of hydrogen bonds among chains in shaping the polymer's properties, especially crystallinity and biocompatibility. Among the synthesized PUs, PU6 emerges as the top performer in terms of crystallinity and biocompatibility. Furthermore, the addition of PE is found to act as a plasticizer, reducing the glass transition temperature (Tg) from 75°C to 31°C. Electrochemical Impedance Spectroscopy shows that doping influences charge transfer processes, rendering the material semi‐conducting, as evidenced by decreased conductance when adding silver nanoparticles to PU6. Notably, protein adsorption studies reveal that undoped PU6 displays superior protein resistance compared to its doped counterpart, with fibrinogen exhibiting a higher adsorption affinity than BSA. The study discusses a plausible mechanism underlying protein adsorption.

Production of Polyurethane Elastomers from Ximenia americana L (Wild Olive) Seed Oil and Diisocyanates

Seed oils readily undergo derivatization by alcoholysis to yield biodegradable polyols and Ximenia americana plant from the family of Olacaeae has oily seeds. Hence, the objective of this paper is to assess the production of polyurethane elastomers from Ximenia americana L (Wild Olive) Seed Oil with diisocyanates, namely, hexamethylene diisocyanate (HDI), toluene diisocyanate (TDI) and 4,4’-methylene diphenyl diisocyanate (MDI) respectively using standard procedure and characterized by Fourier-Transform Infrared Spectroscopy (FTIR), Instron Tensile Testing Machine and Thermogravimetric Analyzer (TGA). The tensile strength and tensile modulus for HDI-based polyurethane elastomers, 5.83±0.15 and 3.95±0.07 MPa respectively are higher than the corresponding ones for TDI- and MDI-based polymers. This is consistent with the highest crosslink density (γ) of 5.05×10-3 for HDI-based polymer with corresponding average molecular weight between crosslinks (Mc) of 197.87 gmol-1 The polyurethane elastomers are stable up to 250-265oC with order of stability: HDPU-1.50>MDPU-1.50>TDPU-1.50. The results showed that diol from Ximenia americana seed oil is effective for production of polyurethane elastomers with properties which are comparable to ones of the non-oil-based polymers.

Enhanced adhesion property of epoxy resin composites through dual reinforcement mechanisms

The study of methods to enhance the properties of composite materials for various application areas is an enduring topic. In this paper, a high-performance filler was prepared by grafting hexamethylene diisocyanate (HDI) and amino-terminated butadiene nitrile rubber (ATBN) onto graphene oxide (GO). Epoxy resin (EP) was selected as the object of feasibility verification, and the EP composite material was prepared. It is worth noting that both physical and chemical bonding mechanisms were utilized to significantly improve the adhesion properties, mechanical properties, and thermal stability of the EP composite material. The T-peel strength reached as high as 16.4 N/mm, which is a 469 % increase compared to pure EP. This paper provides a new and more efficient approach to the modification of composite materials with superior results.