Double enantioselection occurs in the case of hydrolysis of (1S,2R,5S,6R)-2-bromo-3-butanoyloxy-6-hexanoyloxybicyclo[3.2.0]heptane (13), allowing us to obtain the corresponding bromodiol (−)-(14) and epoxyalcohol (−)-(15) of high optical purity.
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