With the rapid development of micro-energy power systems, the performance of micro-combustors as key components is in urgent need of further improvement. Aimed at enhancing combustion performance, a hollow hemispherical bluff body was used to analyze the methane combustion process. In this paper, we exploited the detailed reaction mechanism of methane/air with a laminar finite-rate model; the numerical analysis of methane combustion in the micro-combustor was carried out by Ansys Fluent software. The combustion, flow and thermal characteristics of the micro-combustor embedded with a hollow hemisphere bluff body (MCEHB) and the micro combustor embedded with a slotted hollow hemisphere bluff body (MCESHB) are compared, and the effect of slot width ratio on the combustion characteristics and thermal performance is discussed in detail. The results showed that the bluff body slotting treatment is not only beneficial to improving the velocity and temperature distribution behind the bluff body but also can improve the conversion rate of methane, especially at high inlet velocities. However, the conversion rate of methane is also affected by the slot width. When the slot width ratio below 0.5, the slot width corresponding to the peak methane conversion increased with the inlet velocity. Moreover, the bluff body slotting treatment can improve the wall temperature distribution, meanwhile expanding the high temperature area at the inner wall, thereby reducing the wall temperature fluctuation in the rear part of the micro-combustor. In addition, the optimal slot width ratio B increases with the inlet velocity. Since the inlet velocity is lower than 0.5 m/s, the optimal slot width ratio B is in the range of 0.3–0.375. However, as the inlet velocity exceeds 0.5 m/s, the optimal slot width ratio B moves to the range of 0.375–0.553. Furthermore, both large and small slot widths bring obvious temperature fluctuations to the micro combustor; the uneven wall temperature distribution phenomenon is detrimental to working performance. Therefore, the slot width ratio B of 0.375 only brings slight temperature fluctuations, indicating this is an optimal slot width ratio that should be chosen. This work has reference value for optimizing the design of the bluff body structure and improving the combustion performance of methane in the micro combustor.