Sample Height Research Articles

Performance of geocell reinforced rubber sand mixtures under undrained triaxial test

Large quantities of scrap tires are produced by the automobile industry each year, which causes disposal challenges and impacts the environment. However, scrap tires exhibit various properties, including tensile strength, abrasion resistance, durability, thermal conductivity, elasticity, and more. Due to their versatile characteristics, these scrap tires can be utilized as construction materials for various civil engineering works to reduce their negative environmental effects and conserve natural resources. This study aims to understand the shear strength behaviours exhibited by geocell-reinforced mixtures of rubber and sand through the unconsolidated undrained triaxial test. Various parameters, including rubber sizes (425 μm to 12 mm), rubber contents (10% to 40% by volume), confining pressures (50 to 300 kPa), and geocell heights (0.2H to 0.8H, where H is the height of triaxial sample), were systematically examined to understand their impact on shear strength characteristics. The experimental findings reveal that deviatoric stress is enhanced with increasing confining pressure and rubber sizes. The maximum benefits of the rubber-sand mixture were observed at 30% rubber content. Geocell-reinforced rubber sand mixture has a higher shear strength with respect to the unreinforced mixture. Furthermore, the energy absorption capacity of the geocell-reinforced rubber sand mixtures was much better as compared to either the clean sand or rubber-sand mixture. The findings of this research demonstrate that geocellreinforced rubber sand mixtures are suitable for various geotechnical engineering works.

Effect of Heat Input on Microstructure and Microhardness in WAAM

Experiments were carried out for WAAM of samples using electric arc and additive material in the form of solid wire grade G3Si1. The layers were built-up with one transition each. Metallographic macro- and microsections were made from the obtained samples. The macro- sections are used to determine the locations of microhardness measurements. The microsections were used to measure the microhardness and to illustrate the microstructure. The analysis of the obtained results shows that the heat input and the interlayer temperature are of crucial importance for the obtained mechanical characteristics of the built-up samples. The microstructure of the obtained layers varies along the height of the built-up samples thus witnessing for the thermal treatment occurring in each layer except the last one as a result of applying the subsequent layers.

Analysis of the nanostructure evolution of soot in n-heptane/iso-octane with 2,5-dimethylfuran addition: A combined experimental study and ReaxFF MD simulations

The soot formation of n-heptane/iso-octane doped 2,5-dimethylfuran (DMF) with different ratios was experimentally investigated through laminar diffusion flame and numerically simulated by using the pyrolysis simulations method of reactive force field molecular dynamics (ReaxFF MD). The results showed that the laminar diffusion flame height of n-heptane/iso-octane increased with increasing DMF doping ratio. At a consistent sampling height, the primary soot particle sampling numbers collected were first decreasing and then increasing, and the size of the primary soot particle was first increasing and then decreasing accompanied by the DMF doping ratio increasing. Furthermore, the transmission electron microscope (TEM) analysis provided that DMF initially inhibited and subsequently promoted the primary soot particle growth in the n-heptane/iso-octane flame. The core-shell ratio increased and then decreased with the increase of the DMF doping ratio, which indicated that the maturity of soot decreased and then increased. In n-heptane/iso-octane doped with DMF ReaxFF MD pyrolysis simulation, it was divided into three stages 0–0.5 ns (the first stage), 0.5–3 ns (the second stage), and 3–4.5 ns (the third stage). Fuel decomposed in the first stage and reacted violently in the second stage. The soot precursors continued to react, molecule size kept to increase, and the polycyclic aromatic hydrocarbons (PAHs) continued to grow. In the third stage, the carbon number of the largest molecules were slowly increasing, and the development of soot entered mature stage, where the H/C ratio was slowly decreasing. Through ReaxFF MD simulations, it was found that the maturity of soot exhibited decreasing and then increasing trend with the increase of DMF doping ratio. The graphene-like structures were mainly concentrated around the H/C ratio of 0.297 region.

On-Target Deposition from Two Engine-Powered Sprayers in Medium-Foliage-Density Citrus Canopies

Spray penetration into citrus canopies is critical for adequate coverage and deposition to ensure effective pest control. However, mismatch of air assistance to target canopy characteristics can lead to unintended spraying losses through overpenetration. To evaluate the effect of air assistance on on-target deposition, two sprayers (surrogates for airflow rates) were used to apply a fluorescent tracer dye solution @ a target concentration of 300 ppm to 16 medium-foliage-density tree blocks in a commercial mandarin orchard. The complete factorial experiment in three replications, also designed for validating a model-based spray decision support tool, comprised two forward travel speeds (1.6 and 4.8 km/h), two disc-core nozzles (TeeJet® D3-25 and D6-45), and either one or two nozzle rows to obtain a wide range of application rates (496 to 9719 L/ha). Dye deposition significantly decreased with canopy depth (p =< 0.001) by nearly seven times across the 3.4 m wide canopies but was not significant over 1.2 to 2.2 m sampling height (p = 0.867). Deposition obtained with the low-airflow-rate sprayer was significantly greater (p =< 0.001) than that obtained with the high-airflow-rate sprayer over the dose range likely due to too much air pushing out spray droplets. This study underscores the importance of matching the air assistance of orchard sprayers to the target canopy.

Assessing porosity limit in freeze‐cast sintered lithium titanate (Li4Ti5O12) materials

AbstractThis study aims to assess the lower limit of porosity that can be achieved in freeze‐cast sintered lithium titanate (LTO) materials while maintaining the characteristic pore directionality. LTO materials were fabricated with solid loading varying in the range of 30–37 vol.%. Sucrose and cationic dispersant were used to vary viscosity and total solute concentration in the aqueous LTO suspensions. Two series of suspension compositions were selected for freeze‐casting. In one series, aqueous suspensions were prepared by mixing deionized (DI) water, sucrose, and LTO powder, while in the other series, aqueous suspensions were prepared by mixing DI water, sucrose, cationic dispersant (1‐hexadecyl)trimethylammonium bromide (CTAB), and LTO powder. With increasing solid loading from 30 to 37 vol.%, porosity in the sintered materials decreased from about 50 to 36 vol.%. LTO materials fabricated from suspensions containing sucrose exhibited well‐developed characteristic freeze‐cast microstructure. Unexpectedly, LTO materials fabricated from suspensions containing sucrose and dispersant exhibited cellular pore morphology irrespective of the solid loading. Sample height had an impact on microstructure evolution in the transition zone and zone length. With the increasing solid loading from 30 to 37 vol.%, the compressive strength of sintered LTO materials having the characteristic freeze‐cast microstructure increased from about 110 to 240 MPa.

Small data reliability analysis in concrete three-point bending tests: A Weibull mixture model approach based on Weibull fracture theory

Due to the high costs and time-consuming nature of experiments, data from concrete three-point bending tests are usually limited. Additionally, the performance of concrete is influenced by various factors such as mix composition and sample preparation methods, leading to significant variability in test results. This poses a major challenge for the reliability analysis of small data from repeated tests. In reliability analysis, statistical models are particularly important as they allow for the prediction of performance and failure probabilities based on existing data. However, traditional statistical methods require a large number of similar samples for data processing and may need specific adjustments due to the diversity of practical applications. To address these issues, this study proposes a mixture model that combines domain knowledge of concrete with Weibull fracture theory and uses the Clustering-Circular Block Bootstrap method for sample augmentation. By analyzing real data obtained from concrete three-point bending tests, we accurately estimated the failure probability of concrete. Additionally, the study uses Gaussian process regression with a spectral mixture kernel function to fit the threshold fracture strength of concrete and estimate failure probabilities. The results show that the proposed method can accurately fit small datasets, with a RMSE of 0.320 and a MAPE of 0.100. The nominal bending strength range at a 5% failure probability is 2.0 MPa to 6.5 MPa, depending on the sample height and pre-crack length. Statistical learning demonstrates that the proposed method excels in fitting small datasets, providing a solid framework for predicting concrete strength and reliability.

Programmable Crowding and Tunable Phases in a Binary Mixture of Colloidal Particles under Light-Driven Thermal Convection.

We employ photothermally driven self-assembly of colloidal particles to design microscopic structures with programmable size and tunable order. The experimental system is based on a binary mixture of "plasmonic heater" gold nanoparticles and "assembly building block" microparticles. Photothermal heating of the gold nanoparticles under visible light causes a natural convection flow that efficiently assembles the microscale building block particles (diameter 1-10 μm) into a monolayer. We identify the onset of active Brownian motion of colloidal particles under this convective flow by varying the conditions of light intensity, gold nanoparticle concentration, and sample height. We realize a crowded assembly of microparticles around the center of illumination and show that the size of the particle crowd can be programmed using patterned light illumination. In a binary mixture of gold nanoparticles and polystyrene microparticles, we demonstrate the formation of rapid and large-scale crystalline monolayers, covering an area of 0.88 mm2 within 10 min. We find that the structural order of the assembly can be tuned by varying the surface charge of the nanoparticles and the size of the microparticles, giving rise to the formation of different phases-colloidal crystals, crowds, and gels. Using Monte Carlo simulations, we explain how the phases emerge from the interplay between hydrodynamic and electrostatic interactions, as well as the assembly kinetics. Our study demonstrates the promise of self-assembly with programmable shapes and structural order under nonequilibrium conditions using an accessible setup comprising only binary mixtures and LED light.

Scab intensity in pecan trees in relation to hedge-pruning methods.

Pecan is a valuable nut crop cultivated in the southeastern US. Among the major yield-limiting factors in the region is scab, caused by the plant pathogenic fungus Venturia effusa. Managing scab in tall trees (15 to 25+ m) in pecan orchards is challenging due to the limitations of getting sufficient spray coverage throughout the canopy. We explored the effects of hedge-pruning on scab in three orchards: 14 m tall cv. Desirable trees winter hedge-pruned on alternate sides to 11 m (site 1), 18 m tall cv. Stuart trees hedge-pruned on both sides simultaneously to 11 m (site 2), and 15 m tall cv. Caddo trees winter hedge-pruned in winter vs. summer to 11 m (site 3). At site 1 and 2 hedge-pruned trees were compared to non-pruned control trees. All trees received recommended fungicide applications to control scab via air-blast sprayer. Disease incidence and/or severity was assessed at different sample heights on shoots, foliage and fruit during three seasons (2020, 2021, and 2022). At site 1 the hedge pruned trees often had significantly or numerically more severe scab on foliage and fruit compared to the control trees, although the differences were mostly small. The frequency of mature fruit with scab severity <10% was greatest on control trees in 2021 and 2022. At site 2, there were few differences between hedge-pruned and control trees (on fruit, scab severity was either significantly less on hedge-pruned trees, or not different to the control), but the frequency of mature fruit with scab severity <10% was consistently greatest on hedge-pruned trees. At site 3, scab intensity was low, and there were no significant differences in scab severity between winter- and summer-pruning treatments. At sites 1 and 2 there was generally more severe scab at greater sample heights compared to low in the canopy. At site 3 there was little effect of height on disease. The benefit of hedge-pruning likely increases with tree height in scab-susceptible cultivars. If a tree is >~15 m tall, a greater proportion of the fruit will be within reach of efficacious spray coverage from air-blast sprayers.

Atomic Force Microscopy of Transfer Film Development

Atomic force microscopy (AFM) provides the opportunity to perform fundamental and mechanistic observations of complex, dynamic, and transient systems and ultimately link material microstructure and its evolution during tribological interactions. This investigation focuses on the evolution of a dynamic fluoropolymer tribofilm formed during sliding of polytetrafluoroethylene (PTFE) mixed with 5 wt% alpha-phase alumina particles against 304L stainless steel. Sliding was periodically interrupted for AFM topography scans. The average film roughness, the average friction coefficient, and polymer wear rate based on sample height recession were recorded as a function of increasing sliding cycles. Topographical maps suggested tribofilm nucleates in grooves of the steel countersample, spreads, and develops into a uniform film through sliding. Prominent nanoscale features were visible around 10,000 sliding cycles and thereafter. Scanning electron microscopy and energy-dispersive X-ray spectroscopy showed good correlations between these features and aluminum-rich domains, suggesting the presence of alumina particles on the surface.

Effect of shear rate and saturation on shear strength of mineral and anthropogenic soil

The aim of the study was to determine the shear strength of mineral and anthropogenic soil of similar grain size as a function of the applied shear rate and water saturation. Stability calculations using the finite element method of the road embankment model were also carried out to demonstrate the variation in factor of safety values depending on the adopted values of the angle of internal friction and cohesion. The tests were carried out in a direct shear apparatus in a 100 x 100 mm box with a sample height of 20.5 mm. The samples were formed directly in the apparatus box at optimum moisture content until a compaction index of IS = 1.00 was obtained. Tests were carried out under conditions without and with water saturation at shear rates of 0.01, 0.05, 0.1, 0.5 and 1.0 mm•min–1 until 18% horizontal displacement was achieved. The results showed that the effect of shear rate on the strength parameters was not unequivocal and was much smaller than the changes caused by saturation of samples. An increase in shear rate resulted in small changes in the angle of internal friction with a tendency towards a decrease. In contrast, cohesion varied over a much larger range with increasing shear rate, with an apparent initial decrease and subsequent increase. The saturation of the samples resulted in a decrease in the angle of internal friction of the cohesive soil and an increase for the ash-slag mixture. The cohesion of both soils decreased. The results obtained from the road embankment model stability calculations confirmed that soil saturation had a greater influence on the factor of safety values obtained than the shear rate.

Seasonal and height dynamics of volatile organic compounds in rubber plantation: Impacts on ozone and secondary organic aerosol formation

Rubber trees emit a range of volatile organic compounds (VOCs), including isoprene, monoterpenes, and sesquiterpenes, as part of their natural metabolism. These VOCs can significantly influence air quality through photochemical reactions that produce ozone and secondary organic aerosols (SOAs). This study examines the impact of VOCs detected in a rubber tree plantation in Northeastern Thailand on air quality, highlighting their role in atmospheric reactions that lead to the formation of ozone and SOAs. VOCs were collected at varying heights and seasons using Tenax-TA tubes paired with an atmospheric sampler pump and identified by gas chromatography–mass spectrometry. In total, 100 VOCs were identified, including alkanes, alkenes, terpenes, aromatics, and oxygenated VOCs. Principal Coordinate Analysis (PCoA) revealed distinct seasonal VOC profiles, with hydrocarbons, peaking in summer and terpenes in the rainy season. The Linear Mixed-Effects (LME) model indicates that VOC concentrations are more influenced by seasonal changes than by sampling heights. Secondary organic aerosol potential (SOAP) and ozone formation potential (OFP) of selected VOC species were also determined. The total SOAP ranged from 67.24 μg/m3 in summer to 17.87 μg/m3 in winter, while the total OFP ranged from 377.87 μg/m3 in summer to 139.39 μg/m3 in winter. Additionally, positive matrix factorization (PMF) analysis identified four main VOC sources: gasoline combustion (18.3 %), microbial activity (38.6 %), monoterpene emissions during latex production (15.0 %), and industrial sources (28.1 %). These findings provide essential information for managing air pollution in rubber tree plantations. By adopting focused air quality management strategies, plantation operators can mitigate the adverse effects of VOCs, promoting a healthier and more sustainable future.

Occurrence of a “forever chemical” in the atmosphere above pristine Amazon Forest

Per- and polyfluoroalkyl substances (PFAS), often referred to as “forever chemicals”, are a class of man-made, extremely stable chemicals, which are widely used in industrial and commercial applications. Exposure to some PFAS is now known to be detrimental to human health. By virtue of PFAS long residence times, they are widely detected in the environment, including remote locations such as the Arctics, where the origin of the PFAS is poorly understood. It has been suggested that PFAS may be transported through contaminated waters, leading to accumulation in coastal areas, where they can be aerosolised via sea spray, thereby extending their geographical distribution far beyond their original source regions.The aim of this work is to investigate, for the first time, whether “forever chemicals” could be transported to areas considered to be pristine, far from coastal sites. This study was performed at the Amazonian Tall Tower Observatory (ATTO), a unique remote site situated in the middle of the Amazon rainforest, where a restricted PFAS, perfluorooctanoic acid (PFOA), was observed with concentrations reaching up to 2 pg/m3. A clear trend of increasing concentration with sampling height was observed and air masses from the south over Manaus had the highest concentrations. Atmospheric lifetime estimations, removal mechanisms supported by measurements at two heights (320 and 42 m above the rainforest), and concentration spikes indicated a long-range transport of PFOA to pristine Amazon rainforest. Potential sources, including industrial activities in urban areas, were explored, and historical fire management practices considered.This research presents the first measurements of PFAS in the atmosphere of Amazon rainforest. Remarkably, even in this remote natural environment, appreciable levels of PFAS can be detected. This study provides valuable insights into the long-range transport of the anthropogenic “forever chemical” into a remote natural ecosystem and should raise awareness of potential environmental implications.

Multi-scale microstructural construction in ultralight graphene aerogels enables super elasticity and unprecedented durability for impact protection materials

Ultralight graphene aerogels have gained extensive recognition in the impact protection field. However, attaining both elasticity and durability at low material density is challenging due to their intrinsic conflicts. Inspired by the mantis ootheca, we present a simultaneous improvement in the elasticity, durability, and density restrictions of ultralight graphene aerogels via constructing a multiscale honeycomb microstructure (MHM) within the graphene skeleton. This approach enables resulting graphene aerogel to achieve a strength per unit volume of 284.6 cm3 mg−1, the ability to recover its shape within 10 ms after an impact at 3.569 m/s, and maintain 97.2 % of its sample height after 20,000 cycles at 90 % strain. The operand analyses and calculation results reveal that the MHM structure facilitates this aerogel’s dual-stage stress transfer pathway. Initially, the macroscale honeycomb structure (millimeter-scale) of the graphene aerogels bear and transmit stress to the surrounding regions, followed by the microscale honeycomb structure (micron-scale) deformation to convert stress kinetic energy into elastic potential energy. This two-stage stress transition mechanism of the MHM structure can effectively mitigate excessive local stress and suppress strain localization, thus providing remarkable elasticity and durability. Ultimately, the obtained graphene aerogel demonstrates promising applications as a fall height detection device and impact protective material.

Soft soil foundation treatment of hydraulic fill site based on vibration boosting drainage consolidation method

Reclamation from the sea is a method of expanding urban area, but it also faces the problem of difficult treatment of soft soil foundation by hydraulic reclamation. Therefore, a soft soil consolidation method that combines vibration pressure boosting drainage and piled-load static pressure stacking is now proposed. To verify the effectiveness of this method, a consolidation test based on soft soil samples was designed and conducted in the study. The test results showed that when the sampling height was 240mm, the overall moisture content of the consolidated soil sample was the highest, 44.3%, and the consolidation effect was the worst. When the sampling height was 140mm, the overall moisture content obtained from the test was the lowest, 43.1%, and the consolidation effect was the best. The displacement of corner 2 and center point at the intersection of the preceding and following periods was greater, with values of 37.1 mm and 39.2 mm, respectively. At this point, the displacement of corner 1 was significantly smaller, at 30.9 mm. In the later loading stage, the slope of the vertical displacement curve significantly increased. When the experimental time reached 7000 min, the mixed method designed in this study had a drainage rate of 0.53 ml/min, which was significantly higher than other traditional methods. The experiment outcomes indicated that the method designed in this study had certain application potential for improving the consolidation effect of soft soil foundation in hydraulic fill sites.

Comparative analysis of thrombin generation platforms for patients with coagulation factor deficiencies: A comprehensive assessment

IntroductionThrombin generation assays (TGAs) assess the overall functionality of the hemostatic system and thereby provide a reflection of the hemostatic capacity of patients with disorders in this system. Currently, four (semi-)automated TGA platforms are available: the Calibrated Automated Thrombogram, Nijmegen Hemostasis Assay, ST Genesia and Ceveron s100. In this study, we compared their performance for detecting patients with congenital single coagulation factor deficiencies. Materials and methodsPooled patient samples, healthy control samples and normal pooled plasma were tested on all four platforms, using the available reagents that vary in tissue factor and phospholipid concentrations. The TGA parameters selected for analysis were peak height and thrombin potential. Results were normalized by using the calculated mean of healthy controls and a correction for between-run variation. Outcomes were presented as relative values, with the mean of healthy controls standardized to 100 %. ResultsAcross all platforms and reagents used, thrombin potentials and peak heights of samples with coagulation factor deficiencies were lower than those of healthy controls. Reagents designed for bleeding tendencies yielded the lowest values on all platforms (relative median peak height 19–32 %, relative median thrombin potential 19–45 %). Samples representing more severe coagulation factor deficiencies generally exhibited lower relative peak heights and thrombin potentials. ConclusionsThrombin generation assays prove effective in differentiating single coagulation factor deficient samples from healthy controls, with modest discrepancies observed between the platforms. Reagents designed for assessing bleeding tendencies, featuring the lowest tissue factor and phospholipid concentrations, emerged as the most suitable option for detecting coagulation factor deficiencies.

Investigation of structural, optical, electrical, thermoelectric and optoelectronic properties of undoped ZnO, Sb-doped ZnO and Sb–B co-doped ZnO thin films

Pure ZnO (Zinc oxide), 1 % Sb (antimony) doped ZnO (Zn0.99Sb0.01O), and 1 % Sb–1% B (boron) co-doped ZnO (Zn0.98Sb0.01B0.01O) solutions were prepared using the sol-gel method. These solutions were deposited as thin films on glass and Si (silicon) substrates via dip coating and spraying methods. In this study, doping ZnO with low amounts of Sb and B provided the conversion of the n-type semiconductor ZnO into a p-type semiconductor. The produced thin films were pure and had wurtzite ZnO polycrystalline structure. The nanodot morphology of ZnO turned into a mixture of nanodot and nanorod structures with only Sb doping. Moreover, the band gap energy of ZnO decreased from 3.26 eV to 3.24 eV with Sb doping and to 3.23 eV with Sb and B co-doping, accompanied by a decrease in optical transmittance depending on film thickness. All samples exhibited diode characteristics. According to the created Au/ZnO–Zn0.99Sb0.01O – Zn0.98Sb0.01B0.01O/Si diodes, it was understood that the ideality factor, barrier height, and serial resistance of ZnO material decreased with doping. Especially, the ideality factor, barrier height, and serial resistance of the ZnO sample decreased from 4.95, 6.80 eV, and 1.42 × 105Ω to 4.35, 6.25 eV, and 2.60 × 103Ω, respectively, with Sb and B co-doping. The photovoltaic performance of 1 % Sb-doped thin film increased 100 times compared to pure ZnO, reaching the efficiency from 0.006 to 0.600. However, the most suitable material for use as a photodiode was found to be the 1 % Sb–1% B co-doped sample. While the leakage current of this sample is around −8.0 × 10−5 A at −3 V under 100 mW/cm2 light, it is 9.5 × 10−8 A at −3 V in the dark. Furthermore, the 1 % Sb-doped thin film exhibited the best performance as a thermoelectric material at 600 K, achieving a figure of merit (ZT) of 0.00052. Overall, co-doping with Sb and B enhanced the optical, electrical, and structural (more homogeneous and less surface roughness) properties of ZnO, while improving its optoelectronic functionality such as photodiode. On the other hand, thermoelectric and solar cell properties of ZnO were enhanced with only 1 % Sb doping. A hybrid energy system containing thermoelectric and solar cells was produced cheaply and simply for wide application areas with this study. Moreover, with such a low doping amount, p-type material production was achieved, and important physical properties of the ZnO material were improved.

Momentum Fourier ptychographic topography

Reflective Fourier Ptychographic Microscopy (FPM) has demonstrated the potential as a technology for semiconductor metrology and inspection applications, offering both a wide field-of-view (FOV) and high resolution with nanoscale height reconstruction accuracy. However, to enhance resolution, the wavelength of the illumination source has been shortened to the ultraviolet (UV) range, leading to a significant decrease in height calculation accuracy due to low signal-to-noise issues. Additionally, the time-consuming aspect persists as a challenge. To address these issues, we introduce Momentum Fourier Ptychographic Topography (MFPT). MFPT can overcome the problem of getting trapped in local minima due to noise, and it does not require an iterative process of total variant regularization, allowing for significant computational time savings. Using UV illumination with MFPT, we measure a United States Air Force (USAF) 1951 target and two step-height samples, providing evidence that MFPT is robust to noise and accurately reconstructs nanoscale height. As a result, utilizing UV illumination with MFPT allows us to achieve a resolution of 173 nm, and we can rapidly and accurately calculate the height of step-height samples with nominal heights of 30 nm and 70 nm.

The Infiltration characteristics of expansive soil subjected to drying-wetting cycles under surchage

This study investigates the infiltration characteristics of expansive soil subjected to drying-wetting cycles under surcharge. Infiltration tests are conducted on undisturbed expansive soil over four drying-wetting cycles. Additionally, the permeability coefficient under loading is determined prior to any drying–wetting cycles. Within the context of this study, the sample heights after drying and after wetting are monitored to determinethe natural swelling and shrinkage deformations. Experimental results show that the infiltration rate decreases asthe presssure increases. The sample’s swelling–shrinkage deformation decreases with each progressive drying–wetting cycle, whereas the infiltration rate consistently increases. The infiltration curve under the drying–wetting cycle can be divided into three stages according to the infiltration characteristics, which is significantly different from the infiltration curve of the sample without the drying–wetting cycle. Moreover, the proposed model can fit the infiltration curves well, and its fitting parameters are described using dimensionless pressure and the number of drying-wetting cycles.The drying of the expansive soil produces cracksthat are advantageous for infiltration. Additionally, the microscopic connection between aggregates reflects changes in the internal structure of the soil during successive drying–wetting cycles. As the number of drying–wetting cycle increases, small particles aggregate into large aggregates, and the contact relationship between the aggregate changes from face–face to point-point contact, reducing the swelling potential and increasing the porosity and infiltration capacity of the soil.

Assessing canopy height measurements from ICESat-2 and GEDI orbiting LiDAR across six different biomes with G-LiHT LiDAR

The height of woody plants is a defining characteristic of forest and shrubland ecosystems because height responds to climate, soil and disturbance history. Orbiting LiDAR instruments, Ice, Cloud and land Elevation Satellite-2 (ICESat-2) and Global Ecosystem Dynamics Investigation LiDAR (GEDI), can provide near-global datasets of plant height at plot-level resolution. We evaluate canopy height measurements from ICESat-2 and GEDI with high resolution airborne LiDAR in six study sites in different biomes from dryland shrub to tall forests, with mean canopy height across sites of 0.5–40 m. ICESat-2 and GEDI provide reliable estimates for the relative height with RMSE and mean absolute error (MAE) of 7.49 and 4.64 m (all measurements ICESat-2) and 6.52 and 4.08 m (all measurements GEDI) for 98th percentile relative heights. Both datasets slightly overestimate the height of short shrubs (1–2 m at 5 m reference height), underestimate that of tall trees (by 6–7 m at 40 m reference height) and are highly biased (>3 m) for reference height <5 m, perhaps because of the difficulty of distinguishing canopy from ground signals. Both ICESat-2 and GEDI height estimates were only weakly sensitive to canopy cover and terrain slope (R 2 < 0.06) and had lower error for night compared to day samples (ICESat-2 RMSE night: 5.57 m, day: 6.82 m; GEDI RMSE night: 5.94 m, day: 7.03 m). For GEDI, the day versus night differences varied with differences in mean sample heights for the day and night samples and had little effect on bias. Accuracy of ICESat-2 and GEDI canopy heights varies among biomes, and the highest MAE was observed in the tallest, densest forest (GEDI: 7.85 m; ICESat-2: 7.84 m (night) and 12.83 m (day)). Improvements in canopy height estimation would come from better discrimination of canopy photons from background noise for ICESat-2 and improvements in the algorithm for decomposing ground and canopy returns for GEDI. Both would benefit from methods to distinguish outlier samples.

Temporal Variations in Urban Air Pollution during a 2021 Field Campaign: A Case Study of Ethylene, Benzene, Toluene, and Ozone Levels in Southern Romania

This study focused on quantifying the gas concentrations of ethylene, benzene, toluene, and ozone within an urban area in the southern region of Romania. The gas sampling campaign, conducted between March and August 2021, took place in three different locations from the point of view of the architectural structure, and the sampling height was 1.5 m. Sampling occurred on weekdays (Monday through Friday) during daylight hours, with subsequent concentration analysis employing descriptive statistics, diurnal cycles, and seasonal assessments. A highly sensitive and selective detector, employing laser photoacoustic spectroscopy, was utilized to monitor pollutants. The average concentrations (±Standard Deviation) were determined as follows: ethylene at 116.82 ± 82.37 parts per billion (ppb), benzene at 1.13 ± 0.32 ppb, toluene at 5.48 ± 3.27 ppb, and ozone at 154.75 ± 68.02 ppb, with peak levels observed during the summer months. Diurnal patterns were observable for ethylene, benzene, and toluene, exhibiting higher concentrations during the early hours of the day followed by a decrease towards the evening. In contrast, ozone concentrations peaked in the evening compared to the early part of the day. Thus, perceptible effects were demonstrated on gas concentrations as a result of the influence of meteorological variables. Moreover, the high toluene/benzene ratio indicated traffic and industrial emissions as primary sources of these pollutants. Of the four gases monitored, benzene and ozone exceeded regulatory limits, particularly during the summer season, highlighting concerns regarding air quality in the studied urban environment.