A zircon encapsulated carbon black (C@ZrSiO4) pigment with high color rendering was synthesized via facile non-aqueous acetic acid (NAA) assisted sol-gel method using carbon-containing precursors (zirconium n-propoxide and tetraethoxysilane) as in-situ carbon sources. The effects of the NAA amount and heat treatment temperature on the structure and properties of the synthesized encapsulation pigments were characterized by XRD, FT-IR, FE-SEM, HR-TEM, EDS, XPS and CIELAB colorimeter, respectively. The results showed that the C@ZrSiO4 encapsulated pigments heating at 1000 °C for 2 h in N2 atmosphere presented a dense and stable encapsulation structure as well as deep dark hue when the mole ratio of NAA and Zr (NAA/Zr) was 3:1, and the chromaticity values were L* = 21.20, a* = 0.56, b* = −0.09 and Cab = 0.57, respectively, which were contributed to the high homogeneity at atomic level in ZrSiO4 sol and the tight bonding between carbon black carbonized by carbon containing group and zircon matrix. In addition, the pigment exhibited excellent chemical stability, thermal stability and tinctorial strength when it was used in water, acid, alkali, organic solvents and ceramic glaze. Especially, these pigments improved the utilization of raw materials and avoided the use of heavy metals or transition metals as coloring agent, which was an environment-friendly black ceramic pigment.