Heavy Mineral Fraction Research Articles

Dynamic collapse and regrowth of the Antarctic Ice Sheet in the Weddell Sea sector during the middle Miocene: A novel multi-proxy sedimentary provenance approach using in-situ87Rb/87Sr dating of detrital K-feldspar

The latest generation of Antarctic paleo-ice sheet models, incorporating bedrock paleo-topography, reconstruct the development of substantial ice-sheet embayments during the Mid-Miocene Climate Optimum, a warm period between ∼17–15 Ma ago. Here, we test these models using ice-rafted debris (IRD) recovered from the central Weddell Sea (Ocean Drilling Program Site 113–694). These IRD are entrained by the ice-sheet expanding into the embayment during the cooling associated with the subsequent Mid-Miocene Climate Transition and ultimately delivered to the deep marine sink by iceberg armadas during higher-frequency instability events. Due to the near-absence of heavy minerals in these volumetrically small samples, we utilise the novel in-situ K-feldspar 87Rb/87Sr provenance technique by laser-ablation inductively coupled mass spectrometer equipped with a mass-filtered reaction cell. We combine these single-grain ages with in-situ Pb-isotope analysis, as well as 40Ar/39Ar dating of a subset of grains. Results identify the Antarctic Peninsula and southern Dronning Maud Land as key sediment sources, including grains sourced from within the Recovery subglacial basin. These findings support ice sheet instability consistent with reconstructions of major ice sheet embayments formed by climatic conditions analogous to those predicted by modern anthropogenic warming trajectories. Additionally, in-situ87Rb/87Sr and Pb-isotope analysis of detrital K-feldspar provide a high-throughput alternative to conventional single grain U-Pb or 40Ar/39Ar analysis, especially in small samples where the heavy mineral fraction is limited or absent.

Pollution sources and metallic elements mobility recorded by heavy minerals in soils affected by Cu-smelting (Legnica, SW Poland)

Abstract Heavy mineral particles are widely used in Earth science studies to show sediment provenance and weathering conditions. Such particles are particularly useful in polluted soils surrounding mining and smelting facilities because heavy minerals are common by-products of these activities and may accumulate in the soils. As such, the particles are suitable indicators of metallic element carriers and their stability in the soil environment. In this study, we analyze heavy mineral particles in two soils surrounding the active copper smelter (Legnica, SW, Poland). We show that particles associated with different smelting activities dominate the heavy mineral fraction. We note the general absence of sulfides in the fraction indicating that these minerals might have been entirely dissolved, but timing of this dissolution is uncertain (before or after deposition within soils). Currently, the carriers of potentially toxic elements are mainly secondary Fe oxides. Studies aiming at better estimation of the proportion of metallic elements contained in heavy mineral particles are needed to fully use the potential of these phases in polluted soil studies. We estimate that Pb contained in Pb-rich silicate glass constitutes <0.5% of the total Pb budget and Pb contained in secondary Fe oxides is over 1% of the total budget, but these are minimal estimates.

Longshore Sediment Transport in Lake Ladoga Based on Analyses of the Heavy Mineral Fraction of Sand in Coastal Sediments

Abstract—In order to identify the directions of transport of coastal sediments of Lake Ladoga, heavy mineral fraction was extracted from sand samples collected on all types of its shores. The mineral composition, size and roundness of particles − features characterising the degree of reworking of coastal sediments − were assessed under a microscopic analysis. We identified 4 clusters with similar degrees of reworking of the source material, which, based on the results of the factor analysis, were ranked by relative transport distance from insignificant to very significant. The maximum number of samples with small transport distances was found on the northern shores of the lake, which can be explained by the location of bedrock shores − the main sources of clastic material in the lake. Samples with maximum transport distances are relatively evenly distributed along all shores of the lake. The analysis of the results showed that on all shore reaches there is a transport of heavy fraction of bottom sediments in a certain direction: on the southern shore – to the west, on the western shore – to the north, on the northern shore – to the east and on the eastern shore – to the south-east. This allows us to conclude that there is a long-term trend of coastal sediment transport along the shores of Lake Ladoga in a clockwise direction.

Size-dependent distribution of metal(loid)s in recent marine sediments of the Adriatic sea

This paper investigates occurrence of metal(loid)s, and size-dependent changes in their concentration in recent marine sediments from coastal and open-sea environments in the eastern Adriatic. Size fractionation of sediments was performed after removal of organic matter (OM), and the individual fractions, comprising particles below 8 μm, 4 μm, 2 μm, 1 μm and 0.45 μm, were analysed using HR ICP-MS. The concentrations of most elements increased with decreasing particle size, as a result of accumulation of clay minerals and Fe and Mn (oxyhydr)oxides. A decrease in concentrations was observed for Ba, Sr, Ti and U, due to lowering of the carbonate content and presence in the coarse-grained and heavy mineral fraction. The highest element concentrations were determined in the fraction comprising particles below 1 μm. Occasionally, depending on the sedimentological environment and/or the element in question, the peak concentrations occurred in the <2 μm or <0.45 μm fraction. The lowest size-dependent enrichment was observed for elements associated with aluminosilicates (Al, Be, Cs, Co, Fe, K, Li, Rb). A different size-dependent behaviour of the elements was observed between deep-sea areas and shallow environments under greater coastal influence, mainly due to differences in sediment sorting, and between the northern and central vs. southern Adriatic due to the different catchment geologies. The Fe and Mn (oxyhydr)oxides, abundant in the deep-sea sediments, played an important role in the geochemical cycle of As, Cd, Co, Mo, Sb and V.

Occurrence and transformation behaviour of silicon-bearing minerals during high silicon coal combustion from Yunnan Province, China

To understand the mineralogical characteristics and transformation behaviours of silicon-bearing minerals during coal combustion, seven typical high silicon (high-Si) coals and two high-Si fly ashes generated from high-Si coal-fired power plants were chosen. The coals were first treated by a method of low temperature ashing and the float-sink test for heavy minerals separation. Subsequently, low temperature ashes (LTA), light mineral fractions (LM), heavy mineral fractions (HM), and fly ashes from coal-fired power plants were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) combined with energy spectrum analysis (EDX), X-ray fluorescence spectrometry (XRF), and simultaneous thermogravimetry and differential scanning calorimetry (TG-DSC).The results show that The mineral compositions in the LTA and LM are almost the same and majorly composed of quartz, kaolinite, calcite, dolomite, daphnite, chlorite-serpentine, pyrite, and anatase. The mineral compositions identified in the HM are clearly different from those in the LTA and LM. Pyrite, fluorapatite, anatase, siderite, dolomite and a plenty of silicate minerals including quartz, clinochlore, daphnite, chlorite, and chamosite are found in the HM. Chlorite is a quite common mineral in the HM with different shapes, including schistose, long tetragonal prism, cylindrical, block-shaped, and near-spherical, can be identified. The minerals identified in the fly ashes from the high-Si coal-fired power plants include quartz, mullite, and hematite. The mullite in the fly ashes is derived from the transformations of quartz, kaolinite, and chlorite in the coals. The quartz in the fly ash is mainly derived from the unchanged quartz in coal and a secondary origin from the SiO2-Al2O3 phase transformation. The high-Si fly ash with the size fraction of 38.5–74 μm contains the highest SiO2 content.

Evidence and mineralogical and physico-chemical properties of chernozem and chernozem-like soils in Croatia

The aim was to determine possible local differences between the parent materials of recent leoss-derived soils in eastern Croatia (Dalj, Zmajevac). Furthermore, it highlights the existence of chernozem and chernozem-like soils in Croatia and describes their basic physical, chemical and mineral properties. For this purpose, two soil profiles (P-3 and P-6) south of the Dalj settlement and one soil profile (P-10) near the Zmajevac settlement were excavated. The investigation included a detailed pedological analysis, a modal analysis of the heavy and light mineral fraction and a mineralogical analysis of bulk samples (the &lt; 2 mm fraction) and the fraction &lt; 2 μm. By comparing the obtained results with the criteria of the Croatian Soil Classification and the World Reference Base for Soil Resources, the soil profiles P-3 and P-6 can be defined as Chernozem on Loess or Hortic Calcic chernozem (Epiloamic, Endosiltic, Aric, Humic). The systematic unit for profile P-10 was defined as Rendzina according to the Croatian Soil Classification or Calcic Chernozem (Siltic) according to the WRB. Based on the results of the pedological analysis of the soil profile horizons, a gradual degradation of the chernozem was observed as a result of anthropogenic influence, but also due to recent climate change. The degradation is particularly evident in the form of a reduction in organic matter and the relocation of carbonates from the surface to deeper zones. Due to the increasing degree of weathering caused by recent climate changes, some differences in the mineralogical composition of the studied soils were also observed. The progressive degradation of the chernozem due to the effects of recent weathering processes is indicated mainly by the presence of goethite in the fraction &lt; 2 μm as a weathering product of iron minerals (magnetite, pyroxenes…). Although the parent material of all three profiles is loess sediments, the reason why the soil material of profile P-10 has not developed a chernic horizon is the constant contribution of aeolian material and a short period of exposure to pedogenetic processes.

Tracing Oligocene−Miocene source-to-sink systems in the deep Levant Basin: A sandstone provenance study

The Levant Basin in the Eastern Mediterranean contains an ∼3-km-thick, predominantly siliciclastic section of Oligocene−Miocene age, which hosts large hydrocarbon reservoirs (“Tamar Sands Play”). Here, we present a provenance study of Oligocene−Miocene sandstones based on detrital zircon U-Pb-Hf and heavy mineral assemblages. Samples were retrieved from four boreholes across the Levant Basin: Myra-1, Dolphin-1, Leviathan-1, and Karish North-1. Our investigations revealed that the sediments are dominated by Neoproterozoic and older Precambrian zircons with variable Hf isotopic composition, indicating that they were mainly reworked from Paleozoic−Mesozoic sandstones of African-Arabian provenance, with minor derivation from the Neoproterozoic basement of the Arabian-Nubian Shield. Variations in the proportions of pre−900 Ma zircons were encountered in various levels of the siliciclastic section. These zircons were markedly enriched (44%−57%) in the Rupelian and Aquitanian−Burdigalian intervals, accompanied by abundant detrital apatite peloids in the heavy mineral fraction, and relatively sparse (21%−38%) in the Chattian−Aquitanian and Langhian−Tortonian intervals, alongside scarce Mesozoic−Cenozoic zircons. These findings allow us to associate the deep-basin detrital record with two sedimentary transport systems that reached the Levant Basin from both NE Africa and Arabia simultaneously until the late Miocene, when sediment transport from Arabia ceased. While Rupelian and Aquitanian−Burdigalian sediments, including the main section of the “Tamar Sands,” were derived mainly from Arabian sources via the Levant continental margin, Chattian−Aquitanian and Langhian−Tortonian sediments were primarily sourced from NE Africa via the Nile Delta. Detrital contribution from the Eurasian side of the Eastern Mediterranean was not identified, suggesting that sand originating in the Arabia-Eurasia collision belt did not reach the Levant Basin.

A tropical soil (Lixisol) identified in the northernmost part of the Mediterranean (Istria, Croatia)

Terra rossa soils on the Istrian peninsula are generally considered polygenetic relict soils. They overlie and mark the youngest subaerial unconformity in the northwestern part of the Adriatic Carbonate Platform and are susceptible to erosional and redepositional processes. Terra rossa soils represent a valuable archive of information that can be used to understand present and past soil formation processes in the context of climate variability and landscape dynamics, especially in low-lying parts of the karst landscape where thicker deposits are typically found. We studied a 3 m thick terra rossa profile in a karst depression on the northernmost part of the southwestern Istrian planation surface and analysed the micromorphology, physical/chemical properties, geochemistry, bulk and clay mineralogy, and composition of heavy and light mineral fractions. The profile shows several signs of colluviation and polygenesis with clay distribution along the profile, clearly indicating lithic discontinuities. Kaolinisation, along with iron oxide formation, is the dominant process in the studied profile. Ferralitisation and lessivage processes were diagnosed throughout the profile, with intense clay translocation occurring despite the extremely stable soil microaggregates. In accordance with the WRB system, the profile is classified as Rhodic Lixisol (Clayic, Aric, Cutanic). This implies that some terra rossa soils, previously classified as e.g. Cambisols or Luvisols, might actually be Lixisols or other (sub-)tropical soils (e.g. Nitisols), in which relict properties are preserved in the present climate. The finding of a Lixisol in the study area indicates the old age of the surface of the karst depression and provides the first data on the burial history of the southwestern Istrian planation surface. We suggest the older Quaternary interglacials, the mid-Piacenzian Warm Period (Pliocene) and the Miocene Climatic Optimum as favourable periods for the formation of the studied soil.

RETRACTED: A tropical soil (Ferralsol) identified in the northernmost part of the Mediterranean (Istria, Croatia)

Terra rossa soils on the Istrian peninsula are generally considered polygenetic relict soils. They overlie and mark the youngest subaerial unconformity in the northwestern part of the Adriatic Carbonate Platform and are susceptible to erosional and redepositional processes. Terra rossa soils represent a valuable archive of information that can be used to understand present and past soil formation processes in the context of climate variability and landscape dynamics, especially in low-lying parts of the karst landscape where thicker deposits are typically found. We studied a 3 m thick terra rossa profile in a karst depression on the northernmost part of the southwestern Istrian planation surface and analysed the micromorphology, physical/chemical properties, geochemistry, bulk and clay mineralogy, and composition of heavy and light mineral fractions. The profile shows several signs of colluviation and polygenesis with clay distribution along the profile, clearly indicating lithic discontinuities. Kaolinization, along with iron oxide formation, is the dominant process in the studied profile. Ferralitization and lessivage processes were diagnosed throughout the profile, with intense clay translocation occurring despite the extremely stable soil microaggregates. In accordance with the WRB system, the profile is classified as Lixic Rhodic Ferralsol (Clayic, Aric). This implies that some terra rossa soils, previously classified as e.g. Cambisols or Luvisols, might actually be Ferralsols or other tropical soils (e.g. Lixisols), in which relict properties are preserved in the present climate. The finding of a Ferralsol in the study area indicates the old age of the surface of the karst depression and provides the first data on the burial history of the southwestern Istrian planation surface. We suggest the older Quaternary interglacials, the mid-Piacenzian Warm Period (Pliocene) and the Miocene Climatic Optimum as favourable periods for the formation of the studied soil.

Mineral composition of Laky tailings dam, Central Rhodopes, Bulgaria

Quartz, calcite, feldspars, kaolinite, mica (biotite or sericite), and chlorite were determined as predominant minerals. Dolomite, amphibole, and johansenite are presented in smaller quantities. Epidote, hypogene hematite, rarely silver nugget, garnet, rhodonite, and wollastonite are also observed. Pyrite and chalcopyrite, less often sphalerite and galena are the main ore minerals. The distribution of minerals is relatively homogeneous in the samples taken from the main area, although stratification is observed in depth, with alternating layers rich in sulfides and those composed mainly of quartz. All cases of enrichment with heavy mineral fractions are associated with washing with seasonal processes and no permanent mineral distribution can be established. The results suggested that only quartz and feldspar minerals could be of interest for practical use.

GEOCHEMICAL AND MAGNETIC CHARACTERISTICS OF PLACER GOLD DEPOSITS FROM CENTRAL KALIMANTAN, INDONESIA

Massive tailings have resulted from the extensive use of placer deposits in Central Kalimantan, Indonesia, by artisanal and small-scale gold mining (ASGM) activities. Recently, the placer deposits and their tailings have been exploited for heavy minerals. In this study, geochemical and magnetic analyses were carried out on these deposits to identify the prospect of REE (rare earth element) exploration in the materials already collected by ASGM activities. Samples were collected from ten different locations. For each location, two different fractions were prepared for analyses, i.e. the heavy mineral (HM) fraction and the panned (M60) fraction. All HM and M60 samples were subjected to magnetic susceptibility measurements, but only representative samples were subjected to x-ray fluorescence (XRF) measurements (for Si, Ti, Fe, Zr, and Al) and to inductively coupled plasma-emission spectroscopy (ICP-OES) measurements (for Eu, Tb, Dy, and Sc). The results showed that the concentrations of major elements (Ti, Fe, Zr, and Al) vary significantly from deposits along one river to another, while the concentration of Si is rather similar. Compared to M60 samples, the HM samples have higher concentrations of Ti, Fe, Zr, Al, and Sc, implying that the sluice-box separation enhances the concentration of valuable minerals. Magnetic susceptibility is found to be correlated with Fe and Sc concentrations, confirming the potential use of magnetic measurements as a complementary tool for Fe and Sc exploitation in placer deposits. It is believed that both the source rocks and the sedimentary settings of these deposits determine whether certain elements (Sc, Fe, and Zr) are present or absent in Central Kalimantan placer deposits. The prospect of exploring and exploiting Sc in these placer deposits might augment the ASGM activities in Central Kalimantan.

Elemental Associations in Stream and Alluvial Sediments of the Savinja and Voglajna Rivers (Slovenia, EU) as a Result of Natural Processes and Anthropogenic Activities

Stream and alluvial sediments of the Savinja and Voglajna rivers were sampled, and sediment fractions &lt;0.063 and 0.063–0.125 mm were analyzed on the content of 60 of the main and trace elements. The objective was to determine elemental associations and identify possible sources of these associations. Differences of Al/Ti oxides ratio (9.7–26) can be attributed to the variations in the source rocks, while the K/Al oxides ratio indicates erosional or depositional river regime and variation in source rocks. One anthropogenic and three natural associations of elements were identified. The anthropogenic association (Ag, In, Sb, Cu, As, Zn, Pb, Cd, Bi, Mo and Sn) is linked to historic Zn smelting in the Celje area, and the subsequent erosion of the material from inadequately managed pyrometallurgical waste deposit. The second association (Li, Sc, Al, V, Cs and Ga) is linked to clay minerals, the third one (Mg, Ca and Te) to carbonate rocks, and the fourth one (Hf, Zr) to the heavy mineral fraction.

Soils and spoils: mineralogy and geochemistry of mining and processing wastes from lead and zinc mining at the Gratz Mine, Owen County, Kentucky.

Mineralogical and geochemical features of mining and processing wastes collected in Owen County, part of the Central Kentucky Lead-Zinc district, were investigated. The Gratz mine, abandoned in the 1940s, is on a dairy farm. Aside from discerning the nature of mining refuse at the site, the investigation was part of the University of Kentucky College of Pharmacy's mission to explore unusual environments in the search for unique microbiological communities. Four samples of a soil-plus-spoils mix were collected from spoil piles and two samples, the sluice and coarse samples, were closely associated with the site of the ore processing. Optical petrology (polarized reflected-light, oil-immersion optics at a final magnification of 500 ×), X-ray diffraction, X-ray fluorescence, inductively coupled plasma mass spectrometry, field emission scanning electron microscopy (FE-SEM), and high-resolution transmission electron microscope (HR-TEM) with selected area electron diffraction (SAED) and/or microbeam diffraction (MBD), scanning transmission electron microscopy (STEM), and energy-dispersive X-ray spectrometer (EDS) analyses were employed to characterize the samples. Calcite is the main mineral in most samples, followed by near equal amounts of quartz and dolomite. Sphalerite and galena are the principal sulfides and barite is the dominant sulfate. Geochemistry of major elements reflected the mineralogy, whereas trace elements showed different groupings between the minerals. Scandium, Cu, Ga, Ge, Cd, and Sb were found predominantly associated with Zn and Pb and sulfide minerals; Bi, Hf, In, Sn, and Zr with heavy mineral fraction; while the remaining trace elements, including the rare earths, were mostly distributed among other present phases, i.e., oxyhalides, oxides, silicates, and carbonaceous material. The data were used to illustrate the processes and conditions that control the sulfide-mineral oxidation and its potential for the environmental release of associated reaction products. The wastes represent a potential source of environmentally disruptive concentrations of Zn, Pb, and other sulfide-associated elements. The high share of carbonates suggests near-neutral conditions in deposited wastes, restricting sulfide weathering and further limiting the oxidant activity of Fe. The low-Fe content and its predominant presence in highly resistant hematite also constrain sulfide weathering. Consequently, the spoils have a low potential for generation of acidity and release of heavy metal(loid)s in the surrounding environment.

Mercury Anomaly in Oligocene–Miocene Maykop Group Sediments (Caucasus Continental Collision Zone): Mercury Hosts, Distribution, and Sources

The Oligocene–Miocene Maykop Group sediments, mainly composed of illite–smectite, store mercury in strongly variable concentrations from 10 to 920 μg/kg. Extremely high Hg levels (98–920 μg/kg) coupled with abnormal mercury-to-total organic carbon (TOC) ratios (Hg/TOC = 109 to 3000 μg/kg/wt%; TOC = 0.2 wt% to 1.2 wt%) were measured in the Middle Maykop marine shales that were deposited in the deepwater Indol–Kuban Basin under anoxic conditions. The Middle Maykop shales contain up to 70% of total mercury in sulfide form. In heavy mineral fractions, abundant Hg-bearing pyrite (with up to 4810 µg/kg Hg in hand-picked concentrates) is accompanied by sporadic cinnabar. Relative to the Middle Maykop sediments, the Upper Maykop shales have much lower Hg concentrations and Hg/TOC ratios: 10 to 63 μg/kg (34 μg/kg on average) and 7.7 to 137 μg/kg/wt% (39 μg/kg/wt% on average), respectively. Mercury sequestration is inferred to occur mostly by binding in sulfide hosts in the Middle Maykop anoxic deep-sea sediments and in organic matter, Fe3+-(oxy)hydroxides, and clay particles in the Upper Maykop shales which were deposited in a more oxygenated environment. Mercury inputs to the marine shales during Maykopian sedimentation were possibly associated with local Oligocene–Lower Miocene volcanic activity in the Caucasus Continental Collision Zone. At the same time, the mode of Hg binding in sediments was controlled by redox conditions which changed from anoxic to disoxic and suboxic at the Middle-to-Upper Maykop transition.

Characterization of storm surge deposits along the shore of the Gulf of Gdańsk (Baltic Sea) applying heavy mineral analysis

Recent studies along the southern Baltic Sea coast have revealed sedimentary records of catastrophic storm surges that significantly exceed the magnitude of storms documented by instrumental measurements. The present study aimed to apply heavy mineral analysis for storm surge deposits along coasts of Gulf of Gdańsk (southern Baltic), as well as for contemporary marine, beach, dune and coastal plain sediments, to test the applicability of the method and to provide new insights into the depositional processes and sediment sources of the storm deposits. The transparent, 0.125–0.25 mm heavy mineral fraction (>2.85 g/cm3) in 118 sediment samples was investigated, and the results were subjected to multivariate statistical analyses (cluster, PCA, LDA). Storm deposits showed higher concentrations of heavy minerals comprising enrichment in garnet, zircon, and rutile. General heavy mineral assemblage depended on regional provenance and primary sediment sources. However, flooding regime (overwash or inundation) played a key role in selective hydrodynamic sorting of grains and mineralogical composition of storm deposits. Interpretation of deposits formed in inundation regime was more certain than deposits formed in overwash regime. In the latter case, deposits showed more similarities to adjacent mineral provinces. Statistical analyses proofed that heavy minerals together with other sedimentological descriptors may be a promising proxy for recognition of deposits related to defined sedimentary environment or identification of particular sedimentological process, e.g. event layers resulted from storm surges.

Vliv diagenetických procesů na asociaci těžkých minerálů v pískovcích z lokality Slivotín (ždánická jednotka, flyšové pásmo Vnějších Západních Karpat, Česká republika)

An electron microprobe study of polished sections prepared from a sample of fine-grained sandstone from the locality Slivotín (Ždánice-Hustopeče Formation, Ždánice Unit, Flysch Belt of the Outer Western Carpathians, Czech Republic) allowed to yield in addition to data on chemical composition also the detailed information on in situ textural relationships of individual minerals. During our study, emphasis was given to accessory phases belonging to the translucent heavy mineral fraction. The detrital garnet (Alm36-82Grs2-45Prp2-22Sps0-15) was extensively dissolved and replaced by calcite cement from its margins and along the cracks. Detrital fluorapatite was dissolved in a similar way, however, dissolution episode was followed by growth of authigenic rims composed of carbonate-fluorapatite. Other observed heavy minerals (zircon, chrome spinel, TiO2 phase, monazite, tourmaline) probably remained unaltered by diagenetic processes. The chemical composition of chrome spinels varies mostly between magnesiochromite and chromite, whereas spinel is very rare. The chemical composition of garnets and chrome spinels is comparable with published data from Czech, Polish and Slovak parts of the Flysch Belt of the Western Carpathians, and indicates the primary source of detrital material in rocks of deeper parts of orogen, characterized especially by the presence of catazonal metamorphites and almost lacking volcanic rocks. Redeposition of heavy minerals from older sediments cannot also be ruled out. The pronounced diagenetic alteration of garnet, if not very scarce in the area of Flysch Belt, could help to explain the earlier observations of wide fluctuations of contents of garnet in heavy mineral concentrates.

Minerály těžké frakce arkózových pískovců z Tismic u Českého Brodu (perm blanické brázdy, Česká republika)

The heavy mineral concentrate originating from Permian freshwater sandstones/arkoses from the Tismice site (northern part of the Blanice Furrow, Bohemian Massif, Czech Republic) was studied in terms of mineral composition and chemical composition of selected phases. Ilmenite, to various degree altered to a TiO2 phase and/or unidentified non-stoichiometric Fe-Ti (hydro)oxides, is the predominating constituent of heavy mineral fraction. Garnet, tourmaline, apatite and baryte are subordinate components. Garnet (with commonly etched “drusy” surface) belongs exclusively to almandine (Alm45-91Prp4-27Sps1-32Grs0-17Adr0-5). Tourmaline has variable chemical composition, but oxy-dravite prevails. Accessory phases include biotite, REE-rich goyazite (Goy45-59Flo29-43Cra11-17Gor0-1), zircon, pyrite, limonite, gahnite (Ghn57-68Hrc21-32Spl7-10Mgt1-2Gal1), staurolite, xenotime and monazite. Baryte and goyazite were likely formed during diagenesis of the host sediments or during later hydrothermal activity. Detrital garnet and tourmaline were probably sourced from the granulites, mica schists and migmatites of the Malín segment of the neighbouring Kutná Hora Crystalline Complex (KHCC). Surprisingly, amphibolites or serpentinites, frequently present in areas of the KHCC more proximal to the Permian sedimentary basin, did not contribute their garnets. We suggest that these areas were not exposed to erosion during the Permian period. Spectacular etching of surface of garnets and pervasive alteration of ilmenite were associated with burial diagenesis of the host sediments.

TiO2–Zr–Th–Y–rare‐earth elements ore deposit in unconsolidated fine‐grained sediments from Tongo Gandima in the Bétaré Oya Gold district, Eastern Cameroon

Tongo Gandima is an area located in the southeastern part of the Bétaré Oya Gold district (Eastern Cameroon). Geochemical investigations on rare metals (TiO2, Th, Y, and rare‐earth elements [REE]) were carried out on sample types (source rocks, unconsolidated fine‐grained sediments, and concentrated sediments) using X‐ray diffraction (XRD), X‐ray fluorescence (XRF), inductively coupled plasma‐mass spectrometry (ICP‐MS), and scanning electron microscope equipped with EDAX spectrometer (SEM‐EDS) methods. In this study, five layers of river terraces were selected (organic matter layer, clayey layer, fine sandy layer, coarse sandy layer, and gravel layer). One of them, the gravel layer, is mineralized. TiO2, Zr, and REE are more enriched in monzonites than in granites. Unconsolidated sediments derive mainly from the erosion of weathered materials developed on monzonites and granites. The mineral assemblage of fine‐grained sediments from the gravel layer is muscovite, kaolinite, quartz, rutile, smectite, and others, and the average concentrations in Th, Zr, and Y are high. Fifty concentrated fractions from the same samples were analysed separately and their mineralogy is smectite, kaolinite, gibbsite, muscovite, quartz, rutile, anatase, zircon, titanomagnetite, and ilmenite. The heavy mineral fractions are opaque minerals, biotite, zircon, rutile, tourmaline, garnet, diopside, zoisite, and kyanite. TiO2, Zr, Th, Y, and REE contents are high. The REE oxides (REO) total grade ranges from 0.0088 to 15.66 wt%, marked by LREO‐abundance, especially in La2O3, Ce2O3, Pr2O3, and Nd2O3. The Tongo Gandima REO deposit was classified as LREO‐dominated type. The chondrite‐normalized REE patterns exhibit strong negative Eu anomalies; their V‐shaped patterns are typical of ore varieties. The abundant TiO2, Zr, Y, Th, and REE might have been influenced by surface processes (peneplanation and chemical weathering) and variations in sediment grain size. SEM‐EDS data reveal that apatite with Ce‐ and La‐dominant, monazite‐(Ce), and Ce‐Mn‐bearing ilmenite are rare metal‐bearing minerals. This study demonstrates that the economic importance of the alluvial‐fluvial placers from Tongo Gandima results from their high Ti, Zr, Th, Y, and REE contents.

Study of Heavy Minerals from the Vjosa and Mati river delta sediments in Albania

This research is focused on the determination of the heavy minerals (HM) load of the Vjosa and Mati river delta deposits along the Albanian coastline and it is based on X-ray Diffractometry. The Albanian coastline consists of sandy beaches at the north (Adriatic coastline) and rocky escarpments at the south (Ionian coastline). Several layers of heavy mineral deposits, up to 50 cm thick, with heavy mineral fraction up to 95% and 88% of total sample for Vjosa and Mati sediments respectively, are identified. The layers enriched in heavy minerals from Vjosa delta deposits are almost black in colour, while at Mati delta these layers are dark green coloured. Separation of the heavy from the light fraction was performed, in order to compare the different fractions between the two studied delta areas. The accumulation of HM occurs mainly in the fraction of 125-250 µm in the sediments of both deltas. The HM dominate in the magnetic field of 0.4-0.8 A/m. XRD analysis results show a great variety of minerals present in the delta samples which can be attributed to the wide variety of geological zones and lithologies that are intersected by the Vjosa and Mati rivers, respectively. In the 63-425 μm fraction rich in heavy minerals of both delta systems considerable amounts of magnetite (up to 39.4% in Vjosa samples), chromite (up to 20.2% in Vjosa samples), garnet (up to 13.6% in Vjosa samples), ilmenite (up to 8.3% in Mati samples), rutile (up to 4.7% in Mati samples), hematite (up to 2.2% in Mati samples), and zircon (up to 2.1% in Vjosa samples) are observed. Rock forming minerals such as pyroxene, amphibole, and epidote compose significant percentages of this fraction. In addition, the presence of gold grains in Vjosa delta sediments is remarkable. Both catchment areas consist to a great extent of similar formations such as the Mirdita Ophiolite Zone and the Pindos Ophiolite complex, providing thus a similar HM fingerprint at both delta areas. Minerals that occur in higher abundances reflect the extensive presence in the drained areas of related parent rocks which are rich in these minerals and which are often more vulnerable to weathering. The samples of Vjosa river delta show high percentage of carbonate constituents, which is related to the presence of carbonate rocks of the Ionian and Kruja tectonic zones within which the hydrographic network of the Vjosa River has been developed. The samples of Mati river delta show lower abundance of carbonate minerals, reflecting the limited presence of carbonate rocks at the Kruja Zone, which occur in the catchment area of the river near its mouth.

The Cyclops Ophiolite as a Source of High-Cr Spinels from Marine Sediments on the Jayapura Regency Coast (New Guinea, Indonesia)

The first detailed mineralogy, geochemistry and origin of heavy minerals in marine sediments along the Jayapura Regency coast on the Indonesian part of New Guinea Island are reported as part of a larger set of investigations conducted since 2009. In these sediments, the following heavy minerals were identified: high-Al and high-Cr spinels, chromian andradite, Mg-olivine, magnetite, mixture of iron (III) oxyhydroxides (limonite) and minerals from serpentine-group minerals (lizardite, antigorite). The heavy mineral fraction of marine sediments contains increased concentrations of metals, including W (up to 257.72 ppm) and Ag (up to 1330.29 ppb) as well as minor amounts of Ni (7.1–3560.9 ppm) and Cr (68.0–5816.0 ppm). The present state of geological knowledge suggests that there are no known prospects for rich Ti, Ni, Co, Cr, Au deposits along the examined part of the Jayapura coast. However, the average content of Ag and W is high enough to provide an impulse for suggested further deposit research. The source of marine sediments is Cyclops ophiolite, which contains a typical ophiolite sequence. Cyclops Mountain rocks have undergone intense chemical weathering processes and the resulting eroded material has been deposited on the narrow continental shelf. The chemical composition of chromian spinels indicates that their source is depleted peridotites from the SSZ (supra-subduction zone) environment of the Cyclops ophiolite. A detailed geochemical examination indicates that the evolution of parental melt of these rocks evolved towards magma with geochemical parameters similar to mid-ocean ridge basalt (MORB).