Enrichment Of Heavy Metals Research Articles

Health Risk Assessment of Heavy Metals in Shallow Groundwater of Coal-Poultry Farming Districts.

This study aimed to assess the heavy metal (Mn, Ni, Cu, Zn, Sr, Cd, Pb, and Cr) pollution characteristics, sources, and human health risks in shallow groundwater in the impact zones of urban and rural semi-intensive poultry farms in Suzhou City. Ordinary kriging interpolation showed that poultry farming contributed substantially to the pollution of shallow groundwater by Mn, Zn, and Cu. Positive matrix factorization was applied to identify the sources of heavy metals, and the health risks were assessed based on the hazard index and carcinogenic risks of the various sources. Heavy metal enrichment was closely related to anthropogenic activities. In addition, four sources were identified: poultry manure (29.33%), natural source (27.94%), industrial activities (22.29%), and poultry wastewater (20.48%). The main exposure route of carcinogenic and non-carcinogenic risks to adults and children was oral ingestion. The non-carcinogenic risk of oral ingestion in children was higher than that in adults; the carcinogenic risk was higher in adults than in children. Poultry manure (42.0%) was considered the largest contributor to non-carcinogenic risk, followed by poultry wastewater (21%), industrial activities (20%), and natural sources (17%). Industrial activity (44%) was the primary contributor to carcinogenic risk, followed by poultry wastewater (25%), poultry manure (19%), and natural sources (12%).

Heavy metal background levels and pollution temporal trend assessment within the marine sediments facing a brownfield area (Gulf of Pozzuoli, Southern Italy)

In this study, site-specific natural background levels (NBLs) were determined for 18 elements (Al, As, Be, Cd, Co, Cu, Cr, Fe, Hg, K, Mn, Mo, Ni, Pb, Tl, U, V, and Zn) in two sediment cores collected offshore the Bagnoli-Coroglio brownfield site (Gulf of Pozzuoli, southern Italy) to accurately assess the degree of contamination and the historical trends in Heavy Metals (HMs) enrichment. This objective was pursued taking in account the high temporal and spatial variability of the geochemical properties of the area due to the local geothermal activity. Moreover, the temporal variation of Polycyclic Aromatic Hydrocarbons (PAHs) was investigated.226Ra was used as an extraordinary marker to confirm 210Pb dating. It especially allowed defining the geochronological framework of the sediment core closer the brownfield up to around 1500, providing compelling support to correlate the investigated elements’ occurrences with natural geogenic dynamic. Sediment samples were accurately dated and analyzed for chemical and particle size composition. The contamination factor (Cf) and the pollution load index (PLI) showed very high enrichment of Cd, Cu, Hg, Pb, and Zn. The contamination profiles of HMs and PAHs follow the same pattern in both sediment cores, increasing from deep to upper layers. The highest contamination levels for HMs and PAHs were observed between 10 and 30 cm, corresponding to the periods of most intense industrial activity. Decreasing trends of pollutants were observed in the surface layers (0–10 cm), probably affected by a natural attenuation process due to the cessation of industrial activities.

Spread and driving factors of antibiotic resistance genes in soil-plant system in long-term manured greenhouse under lead (Pb) stress

Livestock manure is often used as fertilizer in greenhouses, resulting in simultaneous enrichment of heavy metals and antibiotic resistance genes (ARGs) in soils. The soil-plant system is a non-negligible way to spread ARGs; however, the effects of lead (Pb) on the spread of ARGs and their driving factors in the greenhouse soil-plant system remain unclear. In this present study, the occurrence of ARGs in greenhouse soils and their spread into plants under Pb stress were studied. Overall, Pb promoted the accumulation of ARGs in root endophytes at 10, 50, and 100 mg/kg as well as in soils at 10 and 200 mg/kg, but reduced the total relative abundance of ARGs in leaf endophytes. Particularly, Pb increased the mobile genetic elements (MGEs) relative abundance and endophytic bacterial community diversity in roots, consistent with the change in the total relative abundance of ARGs. Network analysis revealed that bacterial community and MGEs may jointly affect the migration of ARGs in the soil-plant system of greenhouses. Overall, this study extended our knowledge of how Pb can promote the transmission of ARGs to plant roots from greenhouse soils receiving long-term manure applications, which must be considered when assessing the risk of ARGs to public health.

A new method for identifying potential hazardous areas of heavy metal pollution in sediments

The combined effect of pollution source discharge and sediment adsorption leads to the rapid enrichment of heavy metals and other pollutants in lake sediments, which poses a serious threat to the lake ecosystem. Accurately identifying the risk areas of heavy metals in sediments is the key to lake sediment pollution control. Taking Taihu Lake as the study area, combined with the ecological risk status of heavy metals in sediments, the spatial clustering characteristics of pollution sources and the clustering information of sediment attributes, a potential toxic risk area identification method based on sediment source aggregation class (SLISA-SCA) was established. Through the source analysis of heavy metals in sediments, heavy metals such as Cr, Mn, Cu and Zn in Taihu Lake sediments were identified to have originated from natural sources and were subsequently disturbed by human activities to a certain extent. Cd was found to be strongly affected by human activities, and almost all Taihu Lake sediments were affected to varying degrees. In addition, the anthropogenic sources of heavy metals show high concentration clustering characteristics in the lake bay. By K-means cluster analysis of sediment attributes, three significant differences were obtained, which were determined as potential high pollution risk areas, potential medium risk areas and potential low risk areas, and the proportions were 5.6%, 27.6% and 66.8%, respectively. The SLISA-SCA model established in this study, from the perspective of source sinks, comprehensively considers the risks caused by pollution sources and sediment attributes to sediments and divides Taihu Lake into five different risk control areas (high-risk control area, potential high-risk control area, potential risk control area, potential low-risk control area and low-risk control area). This study identified areas with different levels of heavy metal pollution in Taihu Lake sediments, proposes corresponding treatment measures, and provides a scientific and systematic method and technology for the pollution management of other river and lake sediments in the world.

Pollution Characteristics and Human Health Risk Assessment of Heavy Metals in Street Dust from a Typical Industrial Zone in Wuhan City, Central China.

This study aimed to assess the pollution levels, sources, and human health risks of heavy metals in street dust from a typical industrial district in Wuhan City, Central China. In total, 47 street dust samples were collected from the major traffic arteries and streets around Wuhan Iron and Steel (Group) Company (WISC) in Qingshan District, Wuhan. The concentrations of heavy metals (Cr, Mn, Ni, Zn, Fe, Cu, and Cd) in street dust were determined by atomic absorption spectroscopy. Results indicated that the mean concentrations of Zn (249.71 mg/kg), Cu (51.15 mg/kg), and Cd (0.86 mg/kg) in street dust were higher than their corresponding soil background values in Hubei Province. Heavy metal enrichment is closely related to urban transportation and industrial production. The pollution level of heavy metals in street dust was assessed using the geo-accumulation method (Igeo) and potential ecological risk assessment (PERI). Based on the Igeo value, Cr, Mn, Fe, and Ni showed no pollution, Zn and Cu showed light to moderate contamination, and Cd showed moderate contamination. The PERI values of heavy metals in street dust ranged between 76.70 and 7027.28, which represents a medium to high potential ecological risk. Principal component analysis showed that the sources of heavy metals in street dust were mainly influenced by anthropogenic activities. Among the studied metals, Cu, Cr, Zn, Fe, and Mn mainly come from industrial processes, while Ni and Cd come from traffic exhaust. The non-carcinogenic risk indexes of heavy metals for children and adults are ranked as Cr > Cu > Ni > Cd > Zn. The health risks to children through the different exposure pathways are higher than those for adults. Hand-to-mouth intake is the riskiest exposure pathway for non-carcinogenic risk. In addition, Cr, Ni, and Cd do not pose a carcinogenic risk for the residents.

Geochemical characteristics of heavy metals of bedrock, soil, and tea in a metamorphic rock area of Guizhou Province, China.

Through field surveys, sampling, and laboratory experiments, the content, enrichment, and migration characteristics of heavy metals in the rock-soil-tea system in the Guizhou metamorphic rock area were analyzed herein. The results show that the As and Hg contents in metamorphic sandstone in the study area are higher than those in slate, while the Mn, Zn, Pb, and Ni contents in slate are higher. The content of heavy metals in the sandstone of the Jialu formation of the Xiajiang group in Neoproterozoic is the highest, and that of the slate of the Fanzhao formation is the lowest. The content of As in the rock samples in the study area is higher than that in the Epicontinental crust, while Cd is found to be deficient. The heavy metals at some soil points exceed the standard, but this does not affect the growth and development of tea. The content of heavy metals in most tea is lower than the safety limit standards, and the THQ value is less than 1, indicating that the heavy metals in tea in Guizhou metamorphic rock areas pose no concern for human health. In the metamorphic rock distribution areas of Guizhou, tea does not enrich As, Cr, Hg, and Pb in soil, but enriches Mn, Cu, Ni, and Zn to varying degrees, with the enrichment of Mn being the strongest.

Sources, transfers and the fate of heavy metals in soil-wheat systems: The case of lead (Pb)/zinc (Zn) smelting region

Heavy metals (HMs) from smelters pose severe challenges to the environmental soil quality of surrounding farmlands, and threaten human health through the food chain. This study explored the environmental effects of smelting activities on farmland soil, and additionally assessed the enrichment, transfer and health risk of HMs in soil-wheat systems. Multiple characterization results were combined to demonstrate that HMs from smelter waste were transferred to the surrounding soil. It was determined that the enrichment of HMs in soil-wheat systems is mainly controlled by the total HM concentration and pH in soil. Furthermore, the priority pollutant in soil-wheat systems was found to be Cd, and Cd affected the transfer of Cu, Mn and Pb from soil to wheat roots. Interestingly, the -OH stretching, C-H stretching, N-H amide and C-O bending were involved in detoxifying HMs in wheat. The mean values of non-carcinogenic and carcinogenic risks by consuming wheat grain were 9.1, 1.4E-02 (adults) and 11.3, 3.3E-03 (children), respectively, indicating a noteworthy health risk. This study highlighted the critical issues arising from Pb/Zn smelting activities on agricultural soils. Notwithstanding, to ensure food security, the affected regions could opt to follow up on the type of crops grown.

Experiment and mechanism study on enrichment of heavy metals during MSW pyrolysis by modified kaolin.

Experiment and mechanism studies on the enrichment of Pb, Cd, Zn, As, and Cr by modified kaolin were investigated during MSW (municipal solid waste) pyrolysis at 450 ~ 650°C. The results showed that γAlOK(micro- and nano-γAl2O3 by hydrothermal method modified kaolin) was relatively selective for the solid phase enrichment of Cr and As, while CaHPK (CaHPO4 impregnated modified kaolinite) was more advantageous for the adsorption of Pb and Zn, which might be related to the thermal stability of γAl2O3 and the thermal conversion of CaHPO4. Compared with the original kaolin, the adsorption and retention capacity of γAlOK for As was improved by 20 ~ 30%. Moreover, the retention rate of modified kaolin for Cd decreased from 66.75 to 30.30% at 450 ~ 650 ℃, and the effect of temperature on the volatilization of Cd was always greater than the active components on the surface of modified kaolin. In the fluidized bed experiment, the physical mixing of different modified kaolin achieves complementary advantages on the retention capacity of heavy metals. In addition, the ∆E between Ca2P2O7 and PbCl2 is smaller than that of γAl2O3 at 500 ~ 650°C, i.e., their electron transfer induction is stronger, and therefore more favorable for electron transfer and stable chemical bond formation.

Evaluation and Source Analysis of Heavy Metal Pollution in Sediments of the Yellow River Basin Based on Monte Carlo Simulation and PMF Model

As sediment is an essential component of rivers, the enrichment of heavy metals in sediment presents a serious threat to the aquatic environment. Many industrial cities are located along the Yellow River, and heavy metal pollution is a prominent problem in these areas. Thus, the study of heavy metal pollution in sediments of the Yellow River basin is of vital significance to the safety of the Yellow River basin ecosystem. In this study, we collected data on the concentrations of heavy metals (Pb, Cd, Cr, As, Zn, Cu, Ni, and Hg) in the sediments of the Yellow River basin from 2000 to 2020. We first analyzed the spatial distribution characteristics of heavy metals based on descriptive statistics and geostatistics and then used the Monte Carlo method to evaluate the probability of the ground accumulation index(Igeo), potential ecological risk, and toxicity units. Finally, the number of pollution sources and their contribution rates were determined by combining the positive definite matrix factor (PMF) decomposition model and Pearson correlation analysis. It was found that the mean values of ω(Pb), ω(As), ω(Zn), ω(Ni), ω(Cu), ω(Hg), ω(Cr), and ω(Cd) in the Yellow River basin sediments were 26.92, 11.78, 87.17, 31.13, 24.96, 0.07, 73.36, and 0.58 mg·kg-1, which exceeded the mean soil background values in the Yellow River basin provinces by 1.27, 1.08, 1.26, 1.05, 1.09, 2.32, 1.14, and 5.95 times, respectively, among which Cd exceeded the standard by the largest factor and should be taken seriously. The Igeo was ranked as Cd>Hg>Cr>Cu>Pb>Zn>As>Ni, and Cd and Hg showed medium-severe pollution. The proportions of heavy ecological risk in sediments in the upper, middle, and lower reaches of the Yellow River basin were 18.6%, 15.7%, and 7.1%, respectively, with a decreasing trend. Heavy metals in the sediments of the Yellow River basin were in a low-toxicity state. The PMF-Pearson correlation analysis showed that the four sources of heavy metals in the Yellow River basin sediments were mining sources (42.2%), natural activities (38.3%), agricultural activities (11.6%), and electroplating wastewater (7.9%). The results of this study can provide a basis for developing relevant pollution prevention and control measures in the Yellow River basin.

Selenium Application Decreases the Enrichment and Human Exposure Risk of Cadmium in the Leaf of Jute (Corchorus capsularis L.) Planted in Uncontaminated Purple Soil

The effects of soil selenium (Se) application on the enrichment and human exposure risk of heavy metals in the jute (Corchorus capsularis L.) leaf have attracted extensive attention. The jute was planted with or without soil Se addition for 265 days. The jute leaf was harvested seven times during the experiment to determine the content of lead (Pb), cadmium (Cd), and Se. The results showed that the enrichment ability ranked Cd > Se > Pb. Cd in the jute leaf exceeded the average pollutant limit in GB2762-2017 by 1.37 times without Se application. The Se application is conducive to an increase of Se by 88.11–202.79%, contrarily reducing Cd by 35.40–38.32% and Pb by 9.58–26.57%. In general, the risk quotients (HQ) of Cd and Pb were decreased and less than 1 with Se treatment. Thus, the human exposure risk of Cd and Pb is negligible when ingesting the jute leaf via diet. It is suggested that Se can be applied to inhibit the enrichment of Cd and Pb in the jute production process to reduce the potential exposure risk of Cd and Pb to the human body and increase economic and nutritional values by raising Se levels in the jute leaf.

Holocene evolution of the shelf mud deposits in the north-western South China Sea

Marine mud deposits contain rich information on past interactions between riverine sediment fluxes and marine processes. Massive mud deposits attached to a major river from South China, the Pearl River, are distributed on the north-western shelf of the South China Sea. This study examines the evolution history using cores penetrating through Holocene strata and deciphers its response to the river system, sea-level change, monsoon variations, human activities, etc. Geochemical and sedimentological data constrained by robust radiocarbon data show the difference in the evolution of mud deposits in shallow waters and on the middle shelf. Muddy wedges in shallow waters along the coast have formed since 7 ka BP, when modern current systems were established during the middle Holocene sea-level highstand. However, wide-spread muddy deposits in the middle shelf initiated after 3 ka BP which are associated with enhanced sediment fluxes and strengthened winter monsoon. Human activities on recent millennia have play a significant role in influencing the mud deposition on the north-west shelf of the South China Sea, as evidenced by the enrichment of heavy metals in marine sediments.

Geochemical Speciation, Risk Assessment, and Sources Identification of Heavy Metals in Mangrove Surface Sediments from the Nanliu River Estuary of the Beibu Gulf, China

To better understand heavy metal pollution and the potential ecological risk of mangrove sediments in the Nanliu River estuary, the speciation and distribution characteristics of heavy metals Fe, Mn, Zn, Co, Ni, Cd, Cr, Cu, and Pb in 13 surface sediments in the study area were determined and analyzed using a modified four-step BCR extraction method, and the ecological risk of heavy metals was assessed using the Geo-accumulation Index (Igeo), Potential Ecological Risk Index (RI), Risk Assessment Code (RAC), Pollution Load Index (PLI), Individual contamination factors (ICF) and Global contamination factor (GCF) methods, and source analyses were performed using correlation analysis and cluster analysis. The results showed that the heavy metal was in the order of Fe > Mn > Cu > Zn > Cr > Pb > Co > Ni > Cd. Except for Fe, Zn, Ni, Cr, Pb, and Co, the average heavy metal content of Mn, Cd, and Cu all exceeded the environmental background value; the Fe, Zn, Co, Ni, Cr, Cu, and Pd are mainly in the residual speciation, while Mn and Cd are mainly weak acid extraction and oxidation, respectively, both of which are predominantly in unstable speciation and are easily released into the environment. Mn and Cd pose a substantial ecological risk, while Cu and Pb present a moderate risk and require precaution. The source analysis results indicate that Fe, Mn, Zn, Ni, Cr, and Pb are most likely to originate from natural sources and the transportation industry, Co and Cu are likely to be mainly from ship manufacturing industrial activities, and Cd is likely to be mainly from agriculture and aquaculture. The GCF and PLI results show that places with high heavy metal enrichment and ecological risk are primarily located in areas with high industrial, agricultural, or human activity impacts.

Geochemical fingerprinting and magnetic susceptibility to unravel the heterogeneous composition of urban soils

The typically high heterogeneity of urban soil properties challenges their characterization and interpretation. The objective of this study was to investigate if proximally sensed volume-specific magnetic susceptibility and/or geochemical soil properties can uncover differences in anthropogenic, lithogenic and pedological contributions in, and between, urban soils. We also tested if volume-specific magnetic susceptibility can predict heavy metal enrichment. Data on 29 soil properties of 103 soil horizons from 16 soils from Ghent, Belgium, were analyzed by factor analysis. A correlation analysis, and in-depth analysis of five contrasting urban soils supplemented insights gained from the factor analysis.The factor analysis extracted four factors: 29.2 % of the soil property variability was attributed to fossil fuel combustion and industrial processes, with high (>0.80) loadings for S, organic carbon, magnetic susceptibility, and Zn. Furthermore, 26.0 % of the variability was linked to parent material differences, with high loadings (>0.80) for K, Rb and Ti. In absence of geogenic carbonates, increased soil alkalinity due to anthropogenic input of CaCO3 explained 17.0 % of the variability. Lastly, 4.7 % of the variability resulted from variable Zr contents by local geology. Elemental analysis by XRF, possibly combined with magnetic susceptibility measurements, helped to explain lateral or vertical differences related to (1) the nature of anthropogenic influence, for instance burning (e.g., by the S and Zn content) or the incorporation of building rubble (e.g., by the Ca content); (2) the particle size distribution (e.g., by the K, Rb or Ti content); (3) lithology (e.g., by the Zr content); or (4) pedology, such as organic matter build-up (e.g., by the S content) or leaching of alkalis (e.g., by the Ca content). Even though artifacts and soil translocation were common in the studied soils, volume-specific soil magnetic susceptibility measured on fine earth predicted the total heavy metal pollution loading index well (Pearson correlation = 0.85).

Environmental and Health Risks Posed by Heavy Metal Contamination of Groundwater in the Sunan Coal Mine, China.

Groundwater is often used for domestic and irrigation purposes, even in mining areas. Mine drainage, rainfall, and infiltration cause heavy metal enrichment, adversely affecting the groundwater and harming human health. In this study, water samples (October 2021) in the Suzhou southern coal mining area were analyzed for the heavy metals As, Cr, Cu, Fe, Mn, Pb, and Zn to determine potential effects of heavy metal contamination on environmental quality and human health. It was found that 22% and 31% of the sampling sites had “excellent” and “good” water quality, respectively. Excessive concentrations of Fe and Mn were detected in 47% and 72% of the samples, respectively. The non-carcinogenic health risk values of As, Cr, Cu, Fe, Mn, Pb, and Zn were below the negligible levels of health risk set by various environmental agencies. Content ranking was as follows: Fe > Mn > Cr > Cu > Pb > Zn > As, with Fe accounting for 43%. All sampling points exceeded the maximum acceptable level of Cr recommended by the agencies. Chromium, the major carcinogenic factor in the study area, contributed to 95.45% of the total health risk. Therefore, the authorities in this region must closely monitor three heavy metal elements—Fe, Mn, and Cr.

Source Apportionment and Health Risk Assessment of Heavy Metals in Endemic Tree Species in Southern China: A Case Study of Cinnamomum camphora (L.) Presl.

As a developed economic region in China, the problem of heavy metals (HMs) pollution in the Yangtze River Delta has become increasingly prominent. As an important evergreen broad-leaved tree species in southern China, the camphor tree cannot only be used as a street tree but also its various tissues and organs can be used as raw materials for Chinese herbal medicine. In order to explore whether heavy metal contamination in the region threatens the safety of camphor trees as pharmaceutical raw materials, we collected the bark and leaves of the tree most commonly used for pharmaceuticals in Yixing City. Based on the determination of HMs content, the health risks after human intake are evaluated, the sources and contributions of HMs are analyzed, and then the health risks of pollution sources are spatially visualized. The results showed that under the influence of human activities, the camphor trees in the study area had obvious enrichment of HMs, and the over-standard rate of Pb in the bark was as high as 90%. The non-carcinogenic risks of bark and leaves are acceptable, but the carcinogenic risks are not acceptable. The bark had the highest average carcinogenic risk, approaching six times the threshold. The results of Pb isotope ratio analysis showed that the average contribution rate of industrial activities to HMs in camphor trees in the study area was the highest, reaching 49.70%, followed by fossil fuel burning (37.14%) and the contribution of natural sources was the smallest, only 13.16%. The locations of the high-risk areas caused by the three pollution sources in the study area are basically similar, mainly concentrated in the northwest, northeast, and southeast, which are consistent with the distribution of industries and resources in the study area. This study can provide a reference for the precise prevention of HMs pollution of camphor and the safe selection of its pharmaceutical materials.

Water quality assessment using synchrotron-based TXRF.

The pollutants released from pharmaceutical, steel, paper, and battery industries into water cause stress on the natural ecosystems, may mix with soil and water, enter into human food chain, and hence cause irreparable damage to the biotic system. Hence, the appropriate monitoring of water along with determination of heavy metals is very important for human beings. In present paper, total reflection X-ray fluorescence (TXRF) spectrometry technique is employed to determine the level of different contaminants in the water samples gathered from the various sites of an identified industrial area. Experimentation is carried out at Raja Ramanna Centre for Advanced Technology (RRCAT), Indore-India by using TXRF, which is one the advance techniques of element determination up to ppb levels. The elemental concentration of Cl, K, Ca, Fe, Cu, Zn, Ga, Br, Sr, As, Pb, and Ni is quantified and compared with the limits established by the WHO (World Health Organization) and BIS (Bureau of Indian Standard) guidelines regarding drinking water use. The levels of the Pb, Fe, As, Ni, Cr, Co, and Mn exceeded the values suggested by WHO and BIS at some locations/sites. To better understand the situation, water quality parameters such as Water Quality Index (WQI), Heavy metal Pollution Index (HPI), Contamination Index (CI), Metal Enrichment Index (MEI), and Heavy Metal Evaluation Index (HEI) have also been assessed for all the sites close to industrial hub. Among all sites except at A3 and A6, WQI is found to be much greater than WHO and BIS established limit. Level of arsenic in the water at A1 location was found 73 ppb. However, lead metal in water was found to be very high at all the six studied locations, and at A1 location, it is found extremely high 2613 ppb. Therefore, water at A1 and A2 sites is found to be unfit for drinking. PRACTITIONER POINTS: Total reflection X-ray fluorescence (TXRF) spectrometry technique is employed to determine the level of different contaminants in the water samples The elemental concentration of Cl, K, Ca, Fe, Cu, Zn, Ga, Br, Sr, As, Pb, and Ni is quantified and compared with the limits prescribed by the WHO Water Quality Index (WQI), Heavy metal Pollution Index (HPI), Contamination Index (CI), Metal Enrichment Index (MEI), and Heavy Metal Enrichment Index (MEI) have also been assessed for all the sites Water at some sites is found unfit for drinking purpose. Based on the observations, some remedial measures are suggested to reduce the level of water contaminants up to desired levels.

Influence of heavy metals on Saunders's Gull (Saundersilarus saundersi) reproduction in the Yellow River Estuary: risk assessment and bioaccumulation.

The heavy metal migration in the food chain exerted significant influence on the survival and reproduction of wetland birds and then disturbed and threatened the balance and health of the estuary ecosystem. In this study, the concentration of heavy metals (Cu, Cr, Fe, Mn, Cd, Ni, and Pb) in surface sediment of the Yellow River Estuary (YRE), the food sources of Saunders's Gull (Saundersilarus saundersi) nestlings, and the egg structure of birds were analyzed to determine the bioaccumulation and reproductive influence on wetland bird. The results indicated higher mean concentrations of sediment heavy metals than their corresponding background values in 2019, with the exception of Fe. Notably, the metal Cd exceeded geochemical background value by 1561.5% in 2018 and 1353.9% in 2019, resulting in severe contamination associated with Cd in the YRE (with geo-accumulation indexes of 3.44 and 3.23). Biomagnification factor (BMF) of heavy metals demonstrated that the concentrations of Cr, Ni, and Cu decreased with the trophic level rising while Cd, Mn, Pb, and Fe denoted bio-amplification in the food chain. The residual indexes showed that the food resources of Saunders's Gull were polluted by Cr, Pb, and Cu. Additionally, a higher enrichment of heavy metals was observed in the eggshell membrane. Metal concentrations had significant influences on the reproduction of Saunders's Gull, except for Cd, among which Ni, Pb, Cu, and Fe may have contributed to the reproductive success of birds, whereas the hatching failure of birds may be caused by Cr and Mn. It is of great importance to monitor the contamination of the wetland ecosystem and provide effective management and protection of the wildlife in the YRE.

Optimizing textile dyeing wastewater for tomato irrigation through physiochemical, plant nutrient uses and pollution load index of irrigated soil

Reuse of wastewater for vegetable cultivation is becoming popular in order to augment the inadequate irrigation supplies and meet the growing demands of ground water for agriculture and industries production in different regions of the world. This study was investigated to optimize different stages of textile dyeing wastewater (TDW) for irrigation focusing on their effect on growth, yield and physiochemical attributes of tomato, plant nutrient use, heavy metals enrichment and pollution load of the irrigated soil. Textile wastewater were collected from the seven stages of (second wash after scouring and bleaching T2; enzyme treated water T3; second wash after bath drain T4; neutralization treatment T5; second wash after soaping T6; fixing treatment water T7; mixed effluent T8) of a dyeing process for physiochemical characterization and evaluation their irrigation feasibility for tomato cultivation in compare with the ground water (T1). The pot experiment consists of eight irrigation treatments was laid out following a completely randomized block design with three replications. Results showed the presence of plant nutrients and heavy metals in all the studied samples where T8 (mixed effluent) exceeded the limit of agricultural standard for almost all physiological parameters such as TDS, TSS, EC, BOD, COD affording the highest value. T8 also delivered the highest Cl- and heavy metals like Cd, Ni, Cr followed by T4 < T7. As a consequence, these provided comparatively higher enrichment factor (EF), pollution load index (PLI) and sodium absorption ratio (SAR) to transform fresh soil into the category of severe and slightly to moderate saline. Therefore, the yield and physiochemical attributes of tomato were dramatically reduced with T8 and T4 treatment. On the other hand, T2, T3 and T6 treatment had significant positive impact on growth and yield of tomato due to having higher N, P, K, S and lower heavy metals (Cu, Zn, Fe, Pb, Cd, Ni, Cr) than the recommended guideline. These features were contributed to cause minimum EF and PLI in the soil irrigated with T2, T3 and T6 stages of TDW. Correlation matrix demonstrated that EF and PLI of heavy metals (except Cd, Ni) were negatively related to yield, while positively related to SAR and fruit abortion. Although T6 (2nd wash after soaping) performed better in respect to growth, yield, yield attributes and nutrient use efficiency, principal component analysis revealed that T2 (2nd wash after scouring and bleaching) and T3 (enzyme treated water) were also belong to the same group of T6 and T1 (ground water). Thus, it may be suggested that T2, T3 and T6 stages of textile dyeing wastewater could be used profitably without ETP for vegetable cultivation and would effectively supplement not only the nutrient requirement of the crop but may also act as the alternate source of irrigation water. Although, further research is needed to sort out the health risk assessment through the heavy metals’ accumulation in the plant parts after irrigation with different stages of textile dyeing wastewater.

Ecological risk assessment and sources identification of heavy metals in surface sediments of a river–reservoir system

Heavy metal contamination of river water and sediments is a global issue affecting ecological health. To reveal heavy metals' ecological risks and biological toxicity in the middle and lower Han River (MLHR), sediment samples collected in this area were analyzed based on a modified ecological risk assessment method (NIRI) and a biological toxicity assessment method. Also, Spearman correlation analysis and Positive Matrix Factorization (PMF) methods were applied to identify the potential sources of heavy metals. The results indicated that the heavy metal content significantly exceeded the background concentrations in Hubei Province. The average potential risk of heavy metals at sampling sites was: Cd > Hg > As > Pb > Cu > Zn. Consequently, high biological toxicity occurred along the MLHR due to the heavy metal enrichment. River damming and water diversion significantly enhanced the hydrologic regime variations and ecological risk in the MLHR. Moreover, two possible pollution sources of the MLHR were identified: one is a combined source of traffic pollution, agricultural pollution, and partial industrial pollution consisting of five heavy metals, Pb, Hg, Zn, Cu, and As, the other is an industrial pollution source dominated by Cd and As. This study provides insights into sediment heavy metal pollution management and ecological risk control in the MLHR and similar rivers worldwide.

Assessment of the Enrichment of Heavy Metals in Coal and Its Combustion Residues.

Coal-fired thermal power plants remain one of the main sources of electricity generation in Turkey. Combustion of coal creates coal ash and slag, which are often stored in landfills located near residential and agricultural fields, increasing the potential for high environmental contamination and health risks. This study investigates the content and enrichment factor (EF) of heavy metals in pulverized lignite coal and its combustion residues from the Kangal lignite coal-fired thermal power plant situated in the Central Anatolian Region of Turkey. The concentration of heavy metals (Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Sr, Zr, Cd, Hg, and Pb) in lignite coal, slag, and fly ash samples were analyzed using an energy dispersive X-ray fluorescence technique. The concentration of Fe is highest while Hg concentration is lowest in the samples. The concentrations of heavy metals are higher in slag and fly ash samples than in lignite coal. Average values of EF (related to Earth’s crust average) revealed that extreme enrichment has been shown by arsenic and mercury in lignite coal and fly ash samples while very high enrichment has been shown in slag samples.