Analysis Of Heavy Metals Research Articles

Optimization of carbon-based thin film microextraction supports for simultaneous detection of heavy metals using LIBS

One of the most versatile and effective methods to improve LIBS analysis of liquids is Thin Film Microextraction (TFME).This approach generally uses carbon-based adsorbent films to extract analytes from a liquid sample and bind them into a solid matrix, which is ideal for LIBS. In a previous work, we demonstrated the feasibility of TFME supports based on graphene prepared by Pulsed Laser Ablation in Liquid (PLAL) for LIBS analysis.In this paper, we optimized the preparation of such supports for the analysis of heavy metals in aqueous samples (i.e. chromium, lead and nickel), by analyzing both standard solutions and real samples. The feasibility of coupling TFME with NELIBS approach was also exploited. The procedure was applied to the analysis of both mineral water and well water samples.We obtained a standardized procedure for the extraction of three analytes (Pb, Cr and Ni) and estimated LOD values in spiked mineral water of the order of 0.6 mg/L for LIBS and 0.2 mg/L for NELIBS.

Changes in sedimentary environments in Shihwa Lake, Korea

Shihwa Lake was an artificial freshwater lake formed in 1994 by constructing a 12.7-km-long seawall, but it became a seawater lake in 1997. The water quality of Shihwa Lake had not been recovered despite the seawater exchange through the drain gate. This may adversely affect not only the water but also the bottom sediment environment of the lake. To determine the possible reasons for the environmental deterioration, water and core samples from three points in the lake were collected. And the parameters, such as the water temperature, salinity, dissolved oxygen (DO), particle distribution, total carbon (TC) and total nitrogen (TN), C/N ratio, and radioactive strength, were measured to estimate the water and sediment quality. In addition, we investigated changes in the sedimentation environment based on heavy-metal analysis, stable-isotope analysis of the core sample, and numerical analysis of sand transport. The core-sample analysis revealed a change in the sedimentation process on a time basis (before, during, and after the construction of the seawall). As a result, the sedimentation rate was approximately 4 cm/year during the seawall construction and 2 cm/year after the construction near the center of the lake. Furthermore, we established that the trends in these calculated sedimentation rates, determined using the radioactive strength method, align consistently with the results obtained from simulations and ultrasonic-wave observations. Finally, we evaluated the effects of a tidal power plant on the exchange of seawater and sedimentation processes.

Evaluation of physicochemical parameters and heavy metal concentrations in shrimp (<i>Penaeus monodon</i>), sediment and surrounding water of the Mangrove Swamps, Rivers State, Nigeria

The study focused on the evaluation of the physiochemical and heavy metal concentration in shrimp (P. monodon), sediments and surface water of Ikpukulu, Kalio, and Ogoloma swamps in Okrika Local Government Area, Rivers State, Nigeria. The following parameters were examined: temperature, potential hydrogen, electrical conductivity, salinity, dissolved oxygen, biochemical oxygen demand, total dissolved oxygen, temperature, and the content of heavy metals (Cd, Cu, and Cr) in surface water, sediments, and shrimp. The pH values (p > 0.05) did not significantly differ amongst the stations. The three sampling station readings of pH were below WHO and FEPA (standards). The temperature data from the three stations did not show any significant differences (p > 0.05), but when compared to the standards, all of the readings were much lower. Result from Ogoloma showed that it had lowest electrical conductivity ratings of the three stations, although overall, the values were higher than the norms. At Kalio, the highest Total Dissolved Solids value (9348.6 ± 67 mg/L) was recorded. When compared to the standards, the salinity values of the three stations were noticeably higher. For Biological oxygen demand, there was no significant (p>0.05) difference between the three stations, but comparing the values to the standards they were all significantly (p>0.05) lower. Heavy metal analysis showed that in the sediment, Copper concentration at Ogoloma was significantly (p>0.05) higher among the three metals in the three stations. Copper and chromium concentrations in the three stations were much higher than the standard. Among the three metals found in the water at the three stations, copper had the highest quantities; the content of copper in Ogoloma was noticeably greater than the standard. Of the threelocations, Ogoloma exhibited a noticeably greater concentration of copper for Shrimp. Thefindings highlight the necessity for preventative action by pointing to an increase in heavy metalconcentrations in the Mangrove swamp area.

Preconcentrating extractive polymeric network in paper-based sensing of copper

The concept of using an extractive polymeric sensing network on a paper-based substrate for the pretreatment of samples in the colorimetric analysis of heavy metals is demonstrated with the determination of Cu2+ in aqueous samples. The newly developed paper-based device combines the advantages of both liquid–liquid extraction-based separation and the analytical capabilities of microfluidic paper-based analytical devices (μPADs). The preconcentrating extractive polymeric network composed of 53.5 wt% poly(vinyl chloride) (PVC), 45 wt% extractant (di-(2-ethylhexyl)phosphoric acid (D2EHPA)) and 1.5 wt% dye (1-(2′-pyridylazo)-2-naphthol (PAN)), coated on filter paper, shows good water-wicking properties, allowing the transmission of high sample volumes. This results in significant analyte preconcentration. The extractant (D2EHPA) selectively binds Fe3+ and Zn2+ which otherwise will compete with Cu2+ in its colour reaction with PAN at the chosen pH of 3.0. The device’s capacity to process higher sample volumes resulting in higher sensitivity is increased by the integration of several filter paper absorption layers. The optimized device is characterized by a limit of detection (LOD) for tap and environmental waters of 3.4 and 9.6 µg/L, respectively; stability of 51 days if stored in a refrigerator; and total analysis time (from sample insertion to colour detection) of less than 5 min.

Spatial variability and source analysis of soil heavy metals: A case study of the key planting area of special agricultural products in Cangxi County, China.

Heavy metal pollution in farmland soil represents a considerable risk to ecosystems and human health, constituting a global concern. Focusing on a key area for the cultivation of special agricultural products in Cangxi County, we collected 228 surface soil samples. We analyzed the concentration, spatial distribution, and pollution levels of six heavy metals (Cr, Cu, Pb, Ni, Zn, and Hg) in the soil. Moreover, we investigated the sources and contribution rates of these heavy metals using Principal Component Analysis/Absolute Principal Component Scores (PCA/APCS) and Positive Matrix Factorization (PMF) models. Our findings indicate that none of the six metals exceeded the pollution thresholds for farmland soils. However, the mean concentrations of Cr and Ni surpassed the background levels of Sichuan Province. A moderate spatial correlation existed between Pb and Ni, attributable to both natural and anthropogenic factors, whereas Zn, Cu, Hg, and Cr displayed a strong spatial correlation, mainly due to natural factors. The spatial patterns of Cr, Cu, Zn, Pb, and Ni were similar, with higher concentrations in the northern and eastern regions and lower concentrations centrally. Hg's spatial distribution differed, exhibiting a broader range of lower values. The single pollution index evaluation showed that Cr and Ni were low pollution, and the other elements were no pollution. The average value of comprehensive pollution index is 0.994, and the degree of pollution is close to light pollution. Predominantly, higher pollution levels in the northern and eastern regions, lower around reservoirs. The PCA/APCS model identified two main pollution sources: agricultural traffic mixed source (65.2%) and natural parent source (17.2%). The PMF model delineated three sources: agricultural activities (32.59%), transportation (30.64%), and natural parent sources (36.77%). Comparatively, the PMF model proved more accurate and reliable, yielding findings more aligned with the study area's actual conditions.

Influencing Factors, Risk Assessment, and Source Identification of Heavy Metals in Purple Soil in the Eastern Region of Guang’an City, Sichuan Province, China

Soil heavy metal contamination poses a significant threat to both environmental health and ecological safety. To investigate the influencing factors, ecological hazards, and sources analysis of heavy metals in purple soil, 27 sets of soil samples were collected from varying genetic horizons within Guang’an City, and the contents of As, Cd, Cu, Cr, Hg, Ni, Pb, and Zn were analyzed. The results indicated higher concentrations of heavy metals in soil A horizon, compared to that of C horizon. The relevance analysis indicated that the soil’s heavy metals were strongly correlated with the soil’s physicochemical properties. The enrichment factor, pollution load index, and potential risk index highlighted slightly to severely polluted levels of soil Cd and Hg, which significantly contribute to the ecological hazards posed by soil heavy metals. The potential source of heavy metals analyzed using the APCS-MLR model identified both anthropogenic inputs and natural sources as primary contributors to heavy metal presence in soils. The Cu, Cr, Ni, Pb, and Zn contents in the samples from different genetic horizons were chiefly influenced by natural sources, such as soil matrix erosion and weathering, while the concentrations of Cd and Hg were largely affected by anthropogenic activities, specifically coal combustion and agriculture. Conversely, the As content was found to be influenced by a combination of both factors. Anthropogenic activities greatly impacted soil heavy metals at various depths within the study area, thereby underscoring the importance of monitoring these heavy metals. The findings gained from this research can give a scientific basis for the potential utilization of purple soil.

Analysis of the heavy metals and Escherichia coli contamination of liquid organic fertilizers in the local market, Sri Lanka

Commercially available liquid organic fertilizers have gained popularity in agriculture due to their convenience and perceived environmental benefits. However, these fertilizers are susceptible to various contaminations, including heavy metals such as lead (Pb) and cadmium (Cd), as well as bacterial contaminants like Escherichia coli (E. coli). Monitoring these contaminants helps to identify potential health risks to consumers, prevent soil and water pollution, and maintain the quality of agricultural products. Therefore, this study involved a comprehensive analysis of Pb and Cd heavy metals and E. coli bacterial contaminants in two widely used liquid organic fertilizers in the local market. The samples were digested using an open-vessel acid digestion followed by the flame atomic absorption spectroscopic (FAAS) analysis. The limit of detection (LOD), limit of quantification (LOQ), matrix effect, and spike recovery were determined. The Pb concentration of one fertilizer was 3.45 (± 0.07) mg/kg with 92% recovery whereas the other was 2.87 (± 0.08) mg/kg with 91% recovery. In contrast, the Cd concentration was 0.09 (± 0.01) mg/kg and 0.11 (± 0.01) mg/kg with percentage recoveries of 93% and 90% for two fertilizers respectively. The Pb content exceeded the maximum permissible limit of 1.0 mg/kg set by the Sri Lanka Standard (SLS 1702:2121), while Cd levels remained within the limit of 0.5 mg/kg. Polymerase chain reaction (PCR) coupled with gel electrophoresis confirmed the presence of the pathogenic O157:H7 E. coli strain in both fertilizers. Thus, the results of this study confirmed the lead (Pb) and Escherichia coli contamination in liquid organic fertilizers in the local market of Sri Lanka.

Analysis of nutrient loads, heavy metals and physicochemical properties of wastewater, wetland grass, and papaya samples: Gondar Malt factory, Ethiopia with global implication

Robust attention was brought to researchers due to deterioration of wastewater quality of lakes and reservoirs as major global concerns by industrial release. The uncontrolled releases of effluents impose serious impacts for both aquatic and terrestrial environments. In the current study, many parameters like nutrient loads, heavy metals and physicochemical properties of wastewater, wetland grass, and papaya samples were analysed. The investigated nutrients, alkalinity, and total hardness in fresh water samples were within the allowable limits except for phosphate in fresh wastewater and alkalinity in wastewater. The detected levels of heavy metals (mg/L) in wastewater samples were:- Cd (0.386–0.905), Cr (ND-0.074), Cu (0.064–0.096), Mn (0.184–1.528), Fe (0.167–4.636), Zn (0.175–0.333), and Pb (0.044–0.892) (mg/L). The studied metals in the wastewater sample, except Cd, Fe, and Pb were lower than the allowable limit. The level of heavy metals in the grass and papaya samples ranged from Cd (37.14–147.62), Cr (ND-8.82), Cu (3.14–8.33), Mn (2.89–85.46), Fe(5.0–65.15), Zn (3.44–36.84), and Pb (ND-60.36) (mg/kg). The detected metals were below the permissible limits, except Cd, Cr, and Pb. The findings of the physicochemical characteristics in wastewater samples were computed: pH (6.61–8.54), temperatures (21.63–26.57 °C), TDS (205.9–1896 mg/L), EC (359.9–3226.67 μs/cm), BOD (12.0–732.67 mg/L), COD (3.67–1691.33 mg/L). Except for temperature and pH, all levels in the wastewater were above the recommended limit for wastewater discharge by USEPA.

Appraisal of groundwater quality and hydrochemistry in three regions of Ghana: Implications for drinking purposes

Groundwater is the most relied upon source of water for rural areas and small communities with no access to national water systems. The Community Water and Sanitation Agency (CWSA) in Ghana is an institution that facilitates the provision of water and sanitation services to small towns and communities, hence it has engineered several boreholes all over the country. However, some of these boreholes have quality challenges. Hence this study was carried out to assess the quality and hydrochemical controls of such boreholes in the Ashanti, Upper East and Central Regions of Ghana. A total of 45 boreholes were sampled across these areas and subjected to physicochemical, microbial, and heavy metal analysis. Analysis of the groundwater in the Ashanti Region indicates that its quality is negatively impacted by its iron, manganese, and arsenic content. Same was observed for the Central Region. While in the Upper East Region, total hardness, fluoride, nitrate, and arsenic are the parameters that impact the groundwater quality greatly. Water quality index was used to assess the suitability of the groundwater for domestic purposes and based on this index, 80 % of the water samples were classified as either having an excellent or good quality, while about 7 % were classified as unsuitable for domestic purposes, across all regions. The suitability of the groundwater for irrigational purposes was assessed using sodium adsorption ratio (SAR), percentage sodium (% Na), and Kelly's index (KI). Based on SAR and % Na, all the water samples were suitable for irrigation, while 9 % were unsuitable based on KI. This study provides a comprehensive information on some of the CWSA boreholes with quality challenges. This kind of information is critical and useful when considering what options and treatment technologies would be suitable to address the challenges that these boreholes have.

A GIS-based analysis of heavy metals around Otukpo rice mill in Benue state

Heavy metals are primarily sourced from natural pedo-geochemical backgrounds and anthropogenic occurrences like composting, sewage sludge, aerosol deposition, and waste animal manure. The study aims to determine the heavy metals within the rice mill in Otukpo to understand the spatial distribution with the objectives to examine the heavy metals within the identified activity areas in the Otukpo rice mill, to determine the spatial distribution of heavy metals within the study area and to compare heavy metal values with the acceptable limits. Soil samples were collected from ten locations at Otukpo Rice Mill to analyze heavy metal concentrations. The samples were collected using sterile bottles and a stainless trowel, and the soil samples were analyzed for the concentrations of Cadmium, Copper, Lead, Nickel, Zinc, Mercury, Iron, Arsenic, and Chromium using the Atomic Absorption Spectrophotometry method. The result was analyzed using interpolation to see the variation of the Heavy metals within the various activity areas. The result of the study reveals that Iron has the highest concentration at the Entrance point and lowest at the Generator house with a range value of 3.92 – 1.12mg/kg respectively. The highest concentration of Zinc was recorded at the Mechanic workshop while the lowest is at the Drying point with a range value of 0.135 – 0.872mg/kg respectively. The Husk dumpsite recorded the highest concentration of Copper (0.666mg/kg) with the Drying point recording the least (0.088 mg/kg). The study reveals uneven concentrations and highlights the effectiveness of the Geographic Information System in mapping heavy metal concentrations.

TOXICITY OF LITHIUM BATTERY WASTE ON SELECTED INVERTEBRATES

Electronic waste poses a major menace to ecosystems owing to the toxic properties of materials used for the manufacture of electronic goods. In this present study, the toxicity of lithium battery waste on invertebrates, snails (Archachatina marginata) and earthworms (Apporrectodeal longa) were evaluated using appropriate concentrations of toxicant. The physicochemical and heavy metal analysis of the toxicant was carried out according to the method of APHA (2008). The standard protocol obtained from the Organization for Economic Cooperation and Development (OECD) and the protocol obtained from the International Organization for Standardization (ISO) were adopted for the 14-day exposure to varying concentrations of the toxicant (0.3125, 0.625, 1.25, 2.5 and 5.0 mg/kg) for earthworm and (3.125,6.25, 12.5, 25 and 50 mg/kg) for snail respectively. The pH, Electrical conductivity. Total dissolved solids, Lithium, cadmium and mercury results of the toxicant were (2.6, 13500, 8640, 36.60, 2.03 and 10.48mg/L) respectively. The result also shows an increased in the mortality of test organisms with increase in toxicant concentration. LC50, LOEC, NOEC, TUc and TUa with exposure time for snails and earthworms were (1.05, 0.86,0.77,94.88, 129.87 mg/kg) and (0.68, 0.41,0.31, 147.06, 322.58.mg/kg), respectively. The study established that the toxicant (lithium battery) is considered a high risk to animals, plants and the environment as it adversely affects soil invertebrates which bring about soil fertility if not properly disposed of.

Analysis of the heavy metals and Escherichia coli contamination of liquid organic fertilizers in the local market, Sri Lanka

Commercially available liquid organic fertilizers have gained popularity in agriculture due to their convenience and perceived environmental benefits. However, these fertilizers are susceptible to various contaminations, including heavy metals such as lead (Pb) and cadmium (Cd), as well as bacterial contaminants like Escherichia coli (E. coli). Monitoring these contaminants helps to identify potential health risks to consumers, prevent soil and water pollution, and maintain the quality of agricultural products. Therefore, this study involved a comprehensive analysis of Pb and Cd heavy metals and E. coli bacterial contaminants in two widely used liquid organic fertilizers in the local market. The samples were digested using an open-vessel acid digestion followed by the flame atomic absorption spectroscopic (FAAS) analysis. The limit of detection (LOD), limit of quantification (LOQ), matrix effect, and spike recovery were determined. The Pb concentration of one fertilizer was 3.45 (± 0.07) mg/kg with 92% recovery whereas the other was 2.87 (± 0.08) mg/kg with 91% recovery. In contrast, the Cd concentration was 0.09 (± 0.01) mg/kg and 0.11 (± 0.01) mg/kg with percentage recoveries of 93% and 90% for two fertilizers respectively. The Pb content exceeded the maximum permissible limit of 1.0 mg/kg set by the Sri Lanka Standard (SLS 1702:2121), while Cd levels remained within the limit of 0.5 mg/kg. Polymerase chain reaction (PCR) coupled with gel electrophoresis confirmed the presence of the pathogenic O157:H7 E. coli strain in both fertilizers. Thus, the results of this study confirmed the lead (Pb) and Escherichia coli contamination in liquid organic fertilizers in the local market of Sri Lanka.

Evaluation of physiochemical, heavy metals, and bacteriological parameters of celery and its irrigation water within Sulaymaniyah city of Iraq.

This study rigorously assesses the physicochemical, heavy metal concentrations, and bacteriological parameters of celery and its irrigation water across three rural areas of Sulaymaniyah city, Iraq. The investigation revealed that irrigation water's pH ranged significantly from 6.9 to 8.9. Notably, phosphate concentrations (PO43-) exceeded permissible levels in Tanjaro and Kanaswra across all seasons, with the highest recorded concentration being 10.4mg L-1 during autumn in Kanaswra. Conversely, sulfate (SO42-) and sodium (Na+) concentrations remained within standard limits, with SO42- peaking at 115.1mg L-1 in Tanjaro during summer. Celery samples reflected high Na+ concentrations in some seasons, with values exceeding 570mg·kg in Kanaswra during summer. Heavy metal analysis indicated remarkably low levels in irrigation water, yet celery samples from Tanjaro and Aziz Awa exhibited Pb concentrations above the safety threshold of 0.3mg·kg in all seasons. Furthermore, bacterial contamination, including total aerobic count and coliform in both water and celery, surpassed standard limits, highlighting significant health risks. This study underscores the imperative need for stringent water treatment processes to mitigate contamination and safeguard agricultural productivity and human health.

Comparative Analysis of Heavy Metal's Toxicity in Plants Physiology and its Remediation

Comparative Analysis of Heavy Metal's Toxicity in Plants Physiology and its Remediation

Analysis of heavy metals in Ictalurus punctatus (channel catfish), Perca flavescens (yellow perch), and Aplodinotus grunniens (freshwater drum) in a Coastal Lake Michigan Watershed

Studies on metals in Great Lakes fish have focused typically on mercury (Hg), with less attention on other contaminants. Few studies exist on fish from drowned river mouths supplying the Great Lakes. This paper reports on metals in 3 common species, Ictalurus punctatus (channel catfish), Perca flavescens (yellow perch), and Aplodinotus grunniens (freshwater drum, a.k.a. sheep head) sampled from a coastal lake in West Michigan, USA. 135 fish were taken with pole and line methods from 6 different locations from July 2019–July 2021. Flank tissues were processed and analyzed by ICP-OES techniques for antimony (Sb), arsenic (As), barium (Ba), cadmium (Cd), cerium (Ce), chromium (Cr), copper (Cu), iron (Fe), lead (Pb), magnesium (Mg), manganese (Mn), nickel (Ni), selenium (Se), and zinc (Zn). Eight metals detected at quantifiable levels were Ba, Cr, Cu, Fe, Mg, Mn, Se, and Zn. Mg levels were the highest for all sites and all fish, with averages ranging from 300-1400 ppm (mg/kg of wet tissue). Zn concentrations ranged 11–21 ppm, Fe 4–14 ppm, Se 1–5 ppm, Mn about 0.4–1 ppm, and Cu below 1 ppm. Cr was only quantifiable in 34 % of the fish at <1 ppm, and Ba was detectable in 20 % of the fish, from approximately 0.1 to 4 ppm. Results were examined for statistically-significant differences between species and sites. Comparison of 3 species from one site showed sheep head had lower levels of all metals, except Fe, which were indistinguishable from perch. Cu was higher in catfish than perch, and Mn and Ba concentrations were lower in sheep head by 10× and 100×, respectively, when compared to other species. Zn, Mg, Fe, and Mn concentrations were different in perch from different sites; and, sheep head contained different concentrations of Se, Zn, Fe, Mn, Cr, Cu, and Ba between sites.

Safety of Tap Water in Terms of Changes in Physical, Chemical, and Biological Stability

Monitoring the quality of tap water in the distribution system and the ability to estimate the risk of losing its sanitary safety is an important aspect of managing the collective water supply system. During monitoring, the physical, chemical, and biological stability of water was assessed, which is the main determinant ensuring the appropriate quality of water for consumers. The physicochemical and microbiological quality of water was analyzed for two distribution systems (DSs), including the analysis of heavy metals (Zn, Fe, Mn, Cr, Ni, Cu, Cd, Pb). The tests carried out showed that in both distribution systems, the water supplied to consumers met the guidelines for water intended for human consumption. It can be considered that the risk of uncontrolled changes in water quality in DSs with an average water production of &lt;10,000 m3/d and the length of water pipelines &lt; 150 km is very low. The water introduced into the system differed in the place of water intake and water purification technology, which influenced the final water quality. In DS(II), higher values were recorded for hardness, conductivity, calcium, alkalinity, nitrates, and DOC. It was found that the content of heavy metals during water transport to the consumer increased in the case of DS(I) for Zn, Ni, Cu, Cd, and Pb, and in the case of DS(II) for Fe, Mn, Ni, Cu, Cd, and Pb. The observed differences resulted from the different quality of the intake water as well as from different materials used to build internal installations and their age and technical condition. The analyzed tap water was characterized by physical and chemical stability. However, the water did not meet the guidelines for water biostability due to the increased content of biogenic substances.

Determination Of Heavy Metals and Radon Concentration in Soil and Water Samples from Wadi-B Jere Oil Exploration Sites in Maiduguri, Northeast Nigeria

Radon gas and heavy metals are two significant risk factors that can cause lung cancer. Wadi B, a locality in Jere local government of Borno state, is an area where oil exploration is underway. There is a potential health risk of contamination of the drinking water and soil samples in the area. To investigate radon concentration and heavy metal contamination, several samples of water from wells and boreholes, as well as soil samples, were collected for analysis. The analysis was conducted using liquid scintillation (LSC) and atomic absorption spectrometry. The result of radioactivity analysis using LSC shows that water samples have varying levels of radon concentration ranging from 17.77 Bql-1 to 22.50Bql-1 which exceeded the maximum contaminant levels of 11.1Bq/L set by the USEPA 1999 and the world average value of 10Bq/L set by the World Health Organisation (WHO 2004). The mean annual effective cancer risk of radon intake varied across sampling points, ranging from 0.164, 0.246, 0.287 to 0.130, 0.218, and 0.227 for adults, children, and infants, respectively, with mean values of 0.146, 0.219, and 0.255. The mean values of excess lifetime cancer risk (ELCR) associated with radon inhalation and ingestion for adults, children, and infants were 0.0005110, 0.0007660, and 0.0008930, respectively. Moreover, elevated conductivity and total dissolved solids in water samples suggest potential contamination, exceeding the recommended limits set by the World Health Organization. On the other hand, Heavy metals analysis shows a mean value of ELCR 0.125009 for adults and 0.000063 for infants. Results showed that heavy metal concentrations in soil samples exceeded permissible limits for all metals except chromium and lead, with the order of concentration being Cr &lt; Cd &lt; Pb &lt; Cu &lt; Zn. These findings underscore the need for ongoing monitoring and remediation efforts to mitigate environmental and health risks in Wadi B

Analysis of heavy metals in barley dust and health risk assessment in Malt Factory, Ethiopia

ABSTRACT The recent rapid industrialisation in Ethiopia has become a critical concern from pollution of the environment, including contamination by heavy metals. The purpose of this study was to determine heavy metals in barley dust and evaluate the health risks associated with workers in Gondar Malt Factory, Ethiopia. For this, the concentrations of some potentially toxic heavy metals (Cu, Ni, Cd, Cr, Pb, Zn and Fe) were determined in samples from four different production lines (barley receiving, aspiration, grading, and final product dispatch lines). Prior to metal analysis by flame atomic absorption spectroscopy, a 1 g barley dust was subjected to an optimised wet digestion procedure using 8 mL HNO3, 4 mL HClO4 heated for 4 h at 250°C. The average concentration (mg/kg) of the metals was found to be in the range of 3.3‒4.8 Cu, 4.7‒9 Cd, 9.5‒11.5 Pb, 3063‒3463 Fe, 17.7‒24.7 Ni and 148‒180 Zn. Chromium was below the detection limit of the method in all the samples. The results showed that the barley dust contained significant concentration of the heavy metals. However, the study has found the absence of non-carcinogenic risk, from the analysed heavy metals in the barley dust, through both dermal contact and inhalation routes of exposure. Similarly, no carcinogenic risk was associated with the analysed heavy metals in the barley dust, except for Pb. Hence, proper management control system needs to be implemented to minimise chronic health risks from exposure to Pb.

Pollution and health risk assessment of co-existing microplastics and heavy metals in urban dust of Riyadh city, Saudi Arabia

Microplastics (MPs) and heavy metals have recently attracted much attention due to their widespread distribution in the environment. Co-occurrence of MPs and heavy metals in dust poses potential health risks for humans. The objectives of this study were to investigate pollution and health risk factors associated with co-occurring MPs and heavy metals in urban dust. Here, 20 dust samples (both indoor and outdoor environments) were collected from different places in Riyadh, Saudi Arabia using sweeping method. The MPs were separated from dust samples via density separation using ZnCl2 Microscopic techniques were used to investigate MPs while inductively coupled plasma optical emission spectrometry was used heavy metals analyses in the collected samples. The results of the study showed that all the collected dust samples were contaminated with MPs of different shapes, sizes, and colors. Fragment-shaped MPs were the most dominant, followed by granules, fibers, and lines, while the majority of the MP particles were red and black. Furthermore, the size distribution analyses demonstrated that particles above 1,000 µm were abundant. Also, the number of MPs was in the range of 20 particles g-1 to 1,052 particles g-1. Human exposure estimations showed that toddlers could inhale more MPs (0.86 MPs particles kg-1 day-1 and 312.93 particles kg-1 year-1) than children, teenagers, and adults. In addition, the concentrations of heavy metals varied from one site to another, however, the average concentrations were lower than their corresponding values in the guidelines (except for Zn). The integrated potential ecological risk in dust samples was characterized as a low-risk criterion. The enrichment factor for Zn in dust samples at all sites was more than 2, indicating a major contamination concern and anthropogenic sources responsible for the existence of Zn. The estimated hazard quotient indicates that children and adults are saved from the adverse effects of dust inhalation in the studied area. These findings could serve as a preliminary step for efficient pollution management and environmental quality maintenance in Riyadh.

Perennial Baki™ Bean Safety for Human Consumption: Evidence from an Analysis of Heavy Metals, Folate, Canavanine, Mycotoxins, Microorganisms and Pesticides.

Global food production relies on annual grain crops. The reliability and productivity of these crops are threatened by adaptations to climate change and unsustainable rates of soil loss associated with their cultivation. Perennial grain crops, which do not require planting every year, have been proposed as a transformative solution to these challenges. Perennial grain crops typically rely on wild species as direct domesticates or as sources of perenniality in hybridization with annual grains. Onobrychis spp. (sainfoins) are a genus of perennial legumes domesticated as ancient forages. Baki™ bean is the tradename for pulses derived from sainfoins, with ongoing domestication underway to extend demonstrated benefits to sustainable agriculture. This study contributes to a growing body of evidence characterizing the nutritional quality of Baki™ bean. Through two studies, we investigated the safety of Baki™ bean for human consumption. We quantified heavy metals, folate, and canavanine for samples from commercial seed producers, and we quantified levels of mycotoxins, microorganisms, and pesticides in samples from a single year and seed producer, representing different varieties and production locations. The investigated analytes were not detectable or occurred at levels that do not pose a significant safety risk. Overall, this study supports the safety of Baki™ bean for human consumption as a novel pulse crop.