The distribution of intensities of K.L n K α satellites is nearly binomial, with parameter p l , the mean L shell vacancy probability per electron. The chemical environment of an atom produces a shift, Δp l ,of p l from its value for an isolated target atom. Δp l tends to increase as p l increases, so for greatest chemical sensitivity one wants p l as large as possible. p l increases with Z p but, because it must remain ⩽1, p l must saturate for large Z p . Thus, little additional sensitivity is gained, for a given target and impact speed, by using heavy-ion projectiles of charge greater than some moderate value. We have made theoretical calculations of p l to provide information on the rate of this saturation. Whereas all earlier calculations have employed a single-particle model and a simple collision approximation, we use the Hartree-Fock independent Fermi particle model, which contains Pauli correlations, and refined coupled-channels collision theory. Because of a tendency toward random phases in the scattering amplitudes, the intensity distribution is nearly binomial in most cases, but has the possibility of deviating strongly when one or two channels are dominant. We show, as a typical example, p l as a function of Z p and E/ A for isolated Ar targets, where the tendency toward saturation appears for F 9+ and even for C 6+.
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