Homologous gases are difficult to be detected due to their similar chemical properties, especially for metal oxide semiconductor gas sensors whose selectivity has always been a significant challenge. Dynamic temperature modulation method with periodically changing operating temperature was used to detect alcohol homologous gases. However, there are still problems with the deviceization of heating control circuits. In this paper, dynamic temperature modulated method which needs a simple heating circuit is used to distinguish alcohol homologous gases in combination with oxygen vacancy modulation of ZnO gas sensors. Ethyl alcohol, n-propyl alcohol, isopropyl alcohol and n-butyl alcohol were measured by ZnO gas sensors with different oxygen vacancies content ratios under rectangular wave with a voltage range of 2–6 V. It was found that the greatest difference among the response curves when the material calcined at 600°C which has the largest oxygen vacancies content ratio. Finally, the recognition of the four homologue gases measured by ZnO-600 sensor was achieved by dynamic time warping and the recognition accuracy is 99.33 %.