Over-exploitation of fossil-based energy sources is majorly responsible for greenhouse gas emissions which causes global warming and climate change. To mitigate these challenges renewable energy sources, especially solar thermal technologies, can play a decisive role. United Nations also proposes steps to attenuate the adverse effects of fossil-based energy and climate change through Sustainable Development Goals (SDG7 and SDG8). Solar thermal technologies have seen a huge capacity expansion around the globe in previous decades because of their inherent advantages. However, solar energy faces crucial limitations of fluctuating intensity and time-dependent availability. This decreases solar thermal system performance and makes solar thermal technologies time-dependent. To overcome these challenges, integrating phase change material (PCM) in solar thermal technologies makes a sustainable approach to enhance the efficacy, productivity, and utilization rate of solar thermal technologies. In this manuscript, the sustainable approach of integrating PCM in solar thermal technologies was reviewed. This includes literature on PCMs which covers classification, properties, importance, and limitation. Comprehensive data on the integration of PCM with solar thermal technologies such as solar water heating, solar desalination, solar cooking, solar dryers, solar PV/T, solar ponds, solar chimneys, and solar power plants were reported explicitly in terms of the type of PCM, efficiency and their productivity. In addition, the effect of PCMs integration in solar thermal technologies was analyzed in terms of mitigation of CO2 emissions and economic analysis at different locations around the World.