Heat-treated Samples Research Articles

Effect of heat treatment on the microstructure of medium burn-up U-Mo monolithic fuel foils

Using scanning electron microscopy (SEM), this study evaluates the microstructure evolution of uranium-molybdenum (U-Mo) fuel foils made with and without heat treatment at medium burn-up (of approximately 5 × 1021 f/cm3). The impact of annealing treatments on critical microstructural properties of the U-Mo fuel foils, including porosity, grain structure, Mo homogeneity, and fuel interaction with the Zr interlayer, was examined using large area lift outs (LALOs). The heat-treated specimens presented less grain refining at these burnups when compared to the non-heat-treated specimens. Grain refinement was associated with porosities and fission products precipitation. These observations may indicate that heat treatment can influence fuel swelling during irradiation. Chemical inhomogeneity (Mo banding) was found to persist in the non-heat-treated samples but was not present in the heat-treated samples. Thus, heat-treated U-Mo foils allow for more predictable fuel behavior under irradiation with respect to non-heat-treated foils. The U-Mo and Zr interaction layer appears to be thicker and more continuous in the heat-treated sample which has been associated with stronger interface integrity during irradiation, as observed in previous studies. These observations may indicate an overall improved performance of heat-treated fuel foil in a reactor, which needs to be confirmed with higher burnup samples. The effect of local burn-up on grain size/refinement and porosities in each LALO specimen, sampled from different positions in the fuel foil, was difficult to analyze due to the large standard deviation of these parameters. Finally, evidence of grain refinement by polygonization may be present in these specimens.

Simultaneous enhancement of mechanical and functional properties by heat-treatment in CuAlNi shape memory alloys fabricated by laser powder bed fusion

Laser powder bed fusion (LPBF) is a promising manufacturing method for fabricating Cu-based shape memory alloys (SMAs), but further performance improvement is needed to ensure service stability and broaden the engineering applications. To achieve simultaneous enhancement of mechanical and functional properties of CuAlNi ternary SMAs fabricated via the LPBF process, this study conducts isochronous and isothermal quenching treatments to tailor the microstructure. The heat-treated specimens with a high quenching temperature and long soaking time exhibited high ultimate tensile strength of 696 ± 10 MPa, large ductility of 8.9 ± 0.2%, and excellent recoverable strain under 2% pre-strain with a shape recovery rate of 100%, which were considerably superior than those of as-built specimens (ultimate tensile strength of 612 ± 10 MPa, elongation of 2.6 ± 0.1%, and 1.26% recoverable strain). This is attributed to the element homogenization during heat treatment, release of residual stress, and coordinated martensite network boundary. However, no significant strain platform of martensite reorientation or detwinning was found in the tensile deformation of the as-built and heat-treated samples, due to localized strain concentration in the parent grain. The microstructural evolution under different quenching treatments and the underlying mechanisms for the improvement of mechanical and functional properties are discussed in detail. This work not only reveals the unique functional response of LPBF fabricated Cu-based SMAs, but also provides a simple and effective method to improve their performance.

Numerical fracture toughness evaluation of SS316L CT specimens using an Elastic Plastic Fracture Mechanics (EPFM) approach

In this study, fracture toughness was determined using an elastic-plastic fracture mechanics approach via numerical simulation. The material chosen for study is austenitic stainless steel 316L, which is extensively used in the nuclear industry for core internal structures. Three different SS316L conditions were considered for the analysis, including welded and post-weld heat-treated conditions aged at 300 °C for 10,000 hours (over-aged) and at 400 °C for 5,000 hours (peak-aged). A compact tension (CT) specimen of standard dimensions, which was taken from ASTM E1820–01, was used to perform the analysis. The J-integral value that is obtained for those three conditions was compared with the base material, which was taken from the open literature. It was found that theJ-integral values of SS 316L for welded conditions were lower than the base material. Also, J-integral values of SS 316L for the two post-weld heat-treated conditions were found to be greater than the weldments but less than the base material. It can also be noted that the values obtained for the SS316L weldments and the post-weld heat-treated sample aged at 335 °C for 10,000 hours were notably similar.

Experimental and Computational Study of Microhardness Evolution in the HAZ for Al–Cu–Li Alloys

The Laser Beam Welding (LBW) of aluminum alloys has attracted significant interest from industrial sectors, including the shipbuilding, automotive and aeronautics industries, as it expects to contribute to significant cost reduction associated with the production of high-quality welds. To comprehend the behavior of welded structures in regard to their damage tolerance, the application of fracture mechanics serves as the instrumental tool. However, the methods employed overlook the changes in the microstructure within the Heat-Affected Zone (HAZ), which leads to the degradation of the mechanical properties of the material. The purpose of this study is to simulate microhardness evolution in the HAZ of AA2198-T351 LBW. The material represents the latest generation of Al-Cu-Li alloys, which exhibit improved mechanical properties, enhanced damage tolerance behavior, lower density and better corrosion and fatigue crack growth resistance than conventional Al-Cu alloys. In this work, the microhardness profile of LBW AA2198 was measured, and subsequently, through isothermal heat treatments on samples, the microhardness values of the HAZ were replicated. The conditions of the heat treatments (T, t) were selected in line with the thermal cycles that each area of the HAZ experienced during welding. ThermoCalc and DICTRA were employed in order to identify the strengthening precipitates and their evolution (dissolution and coarsening) during the weld thermal cycle. The microstructure of the heat-treated samples was studied employing LOM and TEM, and the strengthening precipitates and their characteristics (volume fraction and size) were defined and correlated to the calculations and the experimental conditions employed during welding. The main conclusion of this study is that it is feasible to imitate the microstructure evolution within the HAZ through the implementation of isothermal heat treatments. This implies that it is possible to fabricate samples for fatigue crack growth tests, enabling the experimental examination of the damage tolerance behavior in welded structures.

Magnetization reversal and coercivity mechanism in ferrimagnetic M-type hexaferrite by controlling phase evolution

The correlation of phase evolution (annealing at different temperatures) with magnetic properties like magnetization reversal, coercivity mechanism, and energy product in M-type hexaferrite by substituting Sr in place of Ba has been reported in the present article. The Ba1-xSrxFe12O19 (x = 0.0, 0.5, & 1.0) have been prepared by the sol–gel auto-combustion method followed by annealing at different temperatures from 800 °C to 1200 °C. The structural and magnetic properties have been characterized by X-ray diffraction, Field emission scanning electron microscopy, Raman spectroscopy, and Vibrating sample magnetometer. The Rietveld refinement confirms contraction in unit cell parameters by replacing Sr in place of Ba and lattice expansion with increasing annealing temperature. There is no significant effect of substitution on magnetic properties found rather heat treatment affects greatly. The transition from a single domain to multidomain particles and their contribution to initial magnetization curves are analyzed. The differential susceptibility (dM/dH) calculated from room temperature magnetization confirms the existence of a pinning effect during magnetization reversal for samples heat treated below 1200 °C. Secondary phases or grain boundaries are believed to act like pinning centers. This work opens insight into the domain wall motion by microstructure engineering. The coercivity is tuned to 6.09 kOe by controlling the annealing temperature for the Ba1-xSrxFe12O19 (x = 1.0) sample. The maximum energy product (BH)max in the range of 0.94–1.27 MGOe has been achieved.

Improving the mechanical properties of laser powder bed fused AlSi10Mg alloys by eliminating the inevitable micro-voids via hot forging

PurposeThe metallic alloys and their components fabricated via laser powder bed fusion (LPBF) suffer from the microvoids formed inevitably due to the extreme solidification rate during fabrication, which are impossible to be removed by heat treatment. This paper aims to remove those microvoids in as-built AlSi10Mg alloys by hot forging and enhance their mechanical properties.Design/methodology/approachAlSi10Mg samples were built using prealloyed powder with a set of optimized LPBF parameters, viz. 350 W of laser power, 1,170 mm/s of scan speed, 50 µm of layer thickness and 0.24 mm of hatch spacing. As-built samples were preheated to 430°C followed by immediate pressing with two different thickness reductions of 10% and 35%. The effect of hot forging on the microstructure was analyzed by means of X-ray diffraction, scanning electron microscopy, electron backscattered diffraction and transmission electron microscopy. Tensile tests were performed to reveal the effect of hot forging on the mechanical properties.FindingsBy using hot forging, the large number of microvoids in both as-built and post heat-treated samples were mostly healed. Moreover, the Si particles were finer in forged condition (∼150 nm) compared with those in heat-treated condition (∼300 nm). Tensile tests showed that compared with heat treatment, the hot forging process could noticeably increase tensile strength at no expense of ductility. Consequently, the toughness (integration of tensile stress and strain) of forged alloy increased by ∼86% and ∼24% compared with as-built and heat-treated alloys, respectively.Originality/valueHot forging can effectively remove the inevitable microvoids in metals fabricated via LPBF, which is beneficial to the mechanical properties. These findings are inspiring for the evolution of the LPBF technique to eliminate the microvoids and boost the mechanical properties of metals fabricated via LPBF.

Low-Cost Arduino Reverse Transcriptase Loop-Mediated Isothermal Amplification (RT-LAMP) for Sensitive Nucleic Acid Detection.

This work presents a low-cost transcription loop-mediated isothermal amplification (RT-LAMP) instrument for nucleic acid detection, employing an Arduino Nano microcontroller. The cooling system includes customized printed circuit boards (PCBs) that serve as electrical resistors and incorporate fans. An aluminum block is designed to accommodate eight vials. The system also includes two PCB heaters-one for sample heating and the other for vial lid heating to prevent condensation. The color detection system comprises a TCS3200 color 8-sensor array coupled to one side of the aluminum heater body and a white 8-LED array coupled to the other side, controlled by two Multiplexer/Demultiplexer devices. LED light passes through the sample, reaching the color sensor and conveying color information crucial for detection. The top board is maintained at 110 ± 2 °C, while the bottom board is held at 65 ± 0.5 °C throughout the RT-LAMP assay. Validation tests successfully demonstrated the efficacy of the colorimetric RT-LAMP reactions using SARS-CoV-2 RNA amplification as a sample viability test, achieving 100% sensitivity and 97.3% specificity with 66 clinical samples. Our instrument offers a cost-effective (USD 100) solution with automated result interpretation and superior sensitivity compared to visual inspection. While the prototype was tested with SARS-CoV-2 RNA samples, its versatility extends to detecting other pathogens using alternative primers, showcasing its potential for broader applications in biosensing.

In Situ Mapping of Phase Evolutions in Rapidly Heated Zr-Based Bulk Metallic Glass with Oxygen Impurities.

Metallic glasses exhibit unique mechanical properties. For metallic glass composites (MGC), composed of dispersed nanocrystalline phases in an amorphous matrix, these properties can be enhanced or deteriorated depending on the volume fraction and size distribution of the crystalline phases. Understanding the evolution of crystalline phases during devitrification of bulk metallic glasses upon heating is key to realizing the production of these composites. Here, results are presented from a combination of in situ small- and wide-angle X-ray scattering (SAXS and WAXS) measurements during heating of Zr-based metallic glass samples at rates ranging from 102 to 104 Ks-1 with a time resolution of 4ms. By combining a detailed analysis of scattering experiments with numerical simulations, for the first time, it is shown how the amount of oxygen impurities in the samples influences the early stages of devitrification and changes the dominant nucleation mechanism from homogeneous to heterogeneous. During melting, the oxygen rich phase becomes the dominant crystalline phase whereas the main phases dissolve. The approach used in this study is well suited for investigation of rapid phase evolution during devitrification, which is important for the development of MGC.

Carbon fractions in wood for estimating embodied carbon in the built environment

Determining wood carbon (C) fractions (CFs)—or the concentration of elemental C in wood on a per unit mass basis—in harvested wood products (HWP) is vital for accurately accounting embodied C in the built environment. Most estimates of embodied C assume that all wood-based building material is comprised of 50 % C on a per mass basis: an erroneous assumption that emerges from the literature on tree- and forest-scale C estimation, which has been shown to lead to substantial errors in C accounting. Here, we use published wood CF data from live trees, alongside laboratory analyses of sawn lumber, to quantify generalizable wood CFs for HWPs. Wood CFs in lumber average 51.7 %, deviating significantly from a 50 % default wood CF, as well as from CFs in live wood globally (which average 47.6 % across all species, and 47.1 % in tree species not typically employed in construction). Additionally, the volatile CF in lumber—i.e., the quantity of C lost upon heating of wood samples, but often overlooked in C accounting—is lower than the volatile CF in live wood, but significantly >0 % suggesting that industrial lumber drying processes remove some, but not all, of volatile C-based compounds. Our results demonstrate that empirically-supported wood CFs for construction material can correct meaningful systematic biases when estimating C storage in the built environment.

A new approach to determining the specific heat using the Arduino® platform and Newton’s law of cooling

This article describes a new approach for determining the specific heat of solid and liquid samples in an educational laboratory setting. The experiment employed automated data collection, using Arduino® to record temperatures as the system cooled. Samples of water, ethyl alcohol, lead, and aluminium were analysed by exchanging heat with preheated water in a non-insulated container. To identify the moments when the samples attained thermal equilibrium with the reference liquid, we employed the cooling curve adjusted using Newton’s law of cooling. This correction allowed us to uncover the exact points of equilibrium with enhanced accuracy. The results, both for solid and liquid samples, indicated the effectiveness of the method, due to its reasonable proximity to the expected values (e% < 10). This approach goes beyond the conventional calorimeter, proving its viability in testing various samples and thus enhancing research on the thermal properties of different materials.

Optical properties and luminescence behavior of Tb3+-Doped SiO2–Al2O3–BaO–BaF2 oxyfluoride glasses and glass ceramics

In this study, oxyfluoride glasses with chemical composition of 45SiO2–15Al2O3–10BaO–30BaF2-xTbF3 (x = 0.2, 0.4 and 0.6 (mole ratios)) were prepared through the conventional melt-quenching method. Raman and FTIR spectra as well as molar volume calculations proved the creation of more non-bridging oxygens (NBOs) in presence of more TbF3 content. Accordingly, absorption edge in UV–Vis spectra showed a slight red-shift to longer wavelengths. The glass with 0.4 mol ratios of TbF3, exhibited the highest photoluminescence emission and its green-to-blue intensity ratio was 0.66. Therefore, this sample was chosen and heat treated at 630, 650 and 675 °C to prepare glass ceramic samples. For the sample heat treated at 650 °C, photoluminescence intensity increased and green-to-blue intensity ratio reached 0.69. Also, lifetimes of green and blue emissions increased from 3.35 ms to 3.67 ms and from 2.95 ms to 3.10 ms, respectively, when the base glass heat treated at 650 °C. Formation of BaF2 nanocrystals in glass ceramics moved the UV–Vis absorption edge to longer wavelengths significantly. Increment of the weak and dangling bonds in crystallized samples reduced Fermi energy, indirect and direct optical band gap energies from 3.792 eV to 3.301 eV, from 3.522 eV to 3.093 eV and from 4.095 eV to 3.582 eV respectively, which led to higher semiconducting behaviors.

Heat treatment protocol for additively manufactured nitinol shape memory alloys in biomedical applications

Additive manufacturing (AM) is getting significant attention in realizing customizable nitinol (NiTi) devices for biomedical applications. However, due to the change in composition and constituent phases occurring during printing and the microstructural inhomogeneity in the printed parts, obtaining a desired set of phase transformation behaviors and superelastic properties is a major challenge. In this work, laser powder bed fusion (LPBF) was used to fabricate NiTi at a very low laser energy density (35 J/mm3) on a titanium base plate while keeping these behaviors and properties within desirable ranges without any structural defects such as crack and delamination. Our measurements showed that the as-printed NiTi exhibited distinct one-step phase transformation with the austenite finish (Af) temperature of 2.1 °C. To increase the Af temperature to 30.2 °C (within the recommended range of Af temperature for biomedical applications), a heat treatment protocol was developed, which includes a solution cycle (at 900 °C for 1 h) followed by an aging cycle (at 450 °C for 30 min). The heat treatment protocol enabled us to attain the homogenized microstructure while creating ultrafine metastable Ni-rich precipitate, Ni4Ti3, which facilitated the desirable phase transformation behavior with the increased Af temperature. The heat-treated sample showed narrower and sharper two-step martensitic phase transformation with the formation of intermediate R-phase. The presence of both Ni4Ti3 and the R-phase was confirmed by the transmission electron microscopic (TEM) analysis. In the superelasticity test at the body temperature, these samples, starting from the 2nd cycle, demonstrated a recovery ratio of more than 90% and a recoverable strain of more than 6.5%. After 10th cycles, the stable recoverable strain was 6.52% with a recovery ratio of 96%, which is the highest superelasticity reported for the LPBF processed NiTi to the best of our knowledge. After the initial deformation process, we expect these NiTi samples to attain near full superelasticity during service. The micro-hardness study also showed that the hardness of the heat-treated samples is less affected by the cyclic loading. Therefore, this paper presents a viable heat treatment protocol, which provides an important processing roadmap in making NiTi implants by AM while maintaining excellent functional properties of NiTi for biomedical applications.

Heat-Affected Zone Microstructural Study via Coupled Numerical/Physical Simulation in Welded Superduplex Stainless Steels

Superduplex stainless steels (SDSS) are known for their combination of good mechanical properties and excellent corrosion resistance, enabled by the microstructural balance between austenite and ferrite and an amount of alloying elements. Their application in welded components is, however, limited by the possibility of the precipitation of intermetallic phases and microstructural misbalance, which might hinder their properties, especially in the heat-affected zone (HAZ). This work introduces a methodology that relies simultaneously on physical and numerical simulations to study the HAZ in a UNS S32750 SDSS. Dimensions of the fusion zone and thermal cycles were calibrated for a numerical model using preliminary welding trials. Numerically simulated cycles for each heat input (HI) were physically reproduced in a Gleeble® simulator, and the heat-treated samples were characterized and compared with real specimens welded using the same parameters. Thermal curves resulting from the numerical simulations were successfully replicated by the Gleeble®, indicating adequate application of the desired HI. The hardness and microstructural results from simulated and welded specimens were also found to be quite similar. Therefore, the proposed methodology showed itself adequate not only for the study of duplex stainless steels, but also of materials with similar thermal and mechanical properties, including the extrapolation of welding parameters.

In Situ Design of a Nanostructured Interface between NiMo and CuO Derived from Metal-Organic Framework for Enhanced Hydrogen Evolution in Alkaline Solutions.

Hydrogen shows great promise as a carbon-neutral energy carrier that can significantly mitigate global energy challenges, offering a sustainable solution. Exploring catalysts that are highly efficient, cost-effective, and stable for the hydrogen evolution reaction (HER) holds crucial importance. For this, metal-organic framework (MOF) materials have demonstrated extensive applicability as either a heterogeneous catalyst or catalyst precursor. Herein, a nanostructured interface between NiMo/CuO@C derived from Cu-MOF was designed and developed on nickel foam (NF) as a competent HER electrocatalyst in alkaline media. The catalyst exhibited a low overpotential of 85 mV at 10 mA cm-2 that rivals that of Pt/C (83 mV @ 10 mA cm-2). Moreover, the catalyst's durability was measured through chronopotentiometry at a constant current density of -30, -100, and -200 mA cm-2 for 50 h each in 1.0 M KOH. Such enhanced electrocatalytic performance could be ascribed to the presence of highly conductive C and Cu species, the facilitated electron transfer between the components because of the nanostructured interface, and abundant active sites as a result of multiple oxidation states. The existence of an ionized oxygen vacancy (Ov) signal was confirmed in all heat-treated samples through electron paramagnetic resonance (EPR) analysis. This revelation sheds light on the entrapment of electrons in various environments, primarily associated with the underlying defect structures, particularly vacancies. These trapped electrons play a crucial role in augmenting electron conductivity, thereby contributing to an elevated HER performance.

On the cutting-edge of non-recyclable plastic waste valorization: From pyrolysis char to nitrogen-enriched activated carbon for landfill biogas upgrading

The rejected fraction of post-consumer plastics collected by mechanical sorting is a source of chemical recycling by processes such as pyrolysis, promoting the circular economy. The char residue produced in this process has been valorized, reinforcing the introduction in the consumption chain, as an adsorbent aimed at the upgrading of a biogas stream. The char was activated with KOH (496 m2 g−1) and the surface of the material was enriched with nitrogen groups (6% wt. by XPS) to raise the CO2 uptake. KOH and urea were used following different strategies, demonstrating that sequential activation and modification is the most efficient approach. Although the surface area was decreased after N insertion, i.e. from 497 to 389 m2 g−1, the CO2 uptake was raised. Specifically, comparing the CO2 uptake per micropore surface was considerably improved after urea functionalization (0.351 vs 0.235 mg m−2). The selectivity was not considerably modified, but the isosteric adsorption heat of the urea-modified sample was higher than the bare one. The behavior in the dynamic tests was studied in fixed-bed column, assessing the effect of temperature, and inlet CO2/CH4 concentration, individually and in mixtures. There was no appreciated loss of performance in the adsorption-desorption cycles. The urea-modification in a two-pot synthesis process proved a better performance in dynamic tests if compared to the non-modified activated char. This work sheds insights into the feasibility of the recycling of plastic residues giving to new added-value materials such as functionalized carbonaceous adsorbents, promoting a circular economy basis.

Compressive mechanical response and microstructures in low strain rate plastic deformation of stainless steel 316L fabricated by selective laser melting

Characterization of the mechanical properties plays an essential role in the post-processing and evaluation of the functionality of the additively manufactured metallic parts. A number of studies have been focused on the tensile properties of additively manufactured metals. However, the quasi-static compression test of the additively manufactured 316L blocks with different heat-treatment conditions and scanning strategies seems to be overlooked in the literature. This paper aims to provide a comprehensive study of compressive mechanical response in plastic deformation of SS316L fabricated by selective laser melting (SLM). The mechanical response and microstructures in compressive deformation is analyzed for three printing strategies with 0°-, 90°- and 67.5°- scanning and three heat treatment conditions (450 °C for 3 h, 1100 °C for 1 h with furnace cool and 1100 °C for 1 h with water quenching) for selective laser melted (SLMed) stainless steel 316L in comparison with wrought stainless steel 316L in this work. Alteration of mechanical properties, microstructure evolution and compressive deformation mechanism is studied. Melt pool features are not significantly affected by low-temperature heat treatment (450 °C for 3 h) but fully dissolved through high-temperature heat treatment (1100 °C for 1 h). High-temperature heat treatment provides a higher resistance to compressive plastic deformation for SLMed 316L compared with the low-temperature heat-treated and as-built samples where more twinnings are observed. The compressive plastic deformation mechanism of 90°- and 67.5°-scanning samples is similar, which mainly results from twinning-induced plasticity. For 0°-scanning samples, the strong crystallographic texture is the main cause of anisotropic deformation. Modelling and simulation have been conducted to explain the anisotropic deformation mechanism of the 0°-scanning strategy. Simulation results suggest that the morphology difference of laser-scanning tracks and melt pools, which leads to material flow along the laser scanning direction, explains the anisotropic deformation mechanism.

STUDY ON THE IMPACT OF POST WELD HEAT TREATMENT ON TIG AND A-TIG INCONEL 617 WELDMENTS

This study analyzes the effects of Post Weld Heat Treatment (PWHT) on the mechanical properties and microstructure of Inconel 617 weldments produced by the Activated Tungsten Inert Gas (A-TIG) welding and Tungsten Inert Gas (TIG) welding. The TIG weld joints considered for this study were in an as-welded condition and underwent two different conditions of heat treatment including 1050∘C for 3 and 5[Formula: see text]h, respectively. The A-TIG weld joints studied were the as-welded type and the weldment was heat-treated at 1050∘C for 3[Formula: see text]h. The microstructure and the characterization of mechanical properties were performed for all weldments and a comparative assessment was made. Tensile strength and the hardness of the heat-treated samples were considerably higher than that of the as-welded samples. Impact toughness was slightly reduced after PWHT. Improvement in tensile strength could be attributed to the precipitation of the carbides and segregation of Chromium (Cr) and molybdenum (Mo).

Evolution of prototyping in automotive engineering: a Comprehensive Study on the reliability of Additive Manufacturing for advanced powertrain components

Additive manufacturing (AM) could be used to reduce the production times of prototypes; however, further research is required to address metals structural parts. To obtain the correct properties, some relevant factors to be considered are the build volume, shape factor, and the need for specific heat treatments. This study aims to evaluate the reliability of AM prototypes applied at a new powertrain system developed to reduce vehicle emissions. Firstly, it was investigated the mechanical behavior, microstructure, and the effect of sample size and heat treatments on both specimens and prototypes made of AM 17-4PH steel. Finite Element Analysis (FEA) was performed to evaluate the structural resistance. Finally, the prototypes were produced, analyzed, and tested on a functional engine test bench to evaluate their reliability. The mechanical properties decreased with an increase in the sample volume. After heat treatment, the yield strength increased, due to the transformation of δ-ferrite in martensite and the reduction of retained austenite. The engine test bench was successfully completed. The conclusions set the basis for similar future applications of time-effective prototypes that can be dimensioned owing to appositely developed postprocesses that guarantee the required resistance.

Synergistic effects of graphene additives and piston ring surface treatment on friction properties of engine oil

The use of nano-additives improves the performance of lubricants by minimizing energy loss due to friction and wear. In this study, tribological properties of cylinder liner-piston ring were improved by modifying monolayer graphene with surfactants. Additionally, surface chemical chromium coating and chemical heat treatment were conducted on the friction surfaces of specially made piston ring samples to further enhance the friction of piston ring. From the comparison of experimental results, the best lubrication performance was exhibited by the use of 0.05 wt% modified graphene nano-lubricant, which reduced the friction coefficient by approximately 31.1% and improved the anti-wear performance by approximately 59.6% compared to the base oil. In addition, the effect of the graphene nano-lubricant on the friction performance of chromium-coated samples was more substantial than that of the chemically heat-treated samples. Under high-temperature and heavy-load conditions, the corresponding friction coefficient was reduced by 15.5% and 34%, respectively, when compared to the base oils. This can be attributed to the porous surface of the chromium-coated sample, which promotes the storage of the graphene nano-lubricant. The results highlight the synergistic effect of graphene additives and piston ring surface treatment on the tribological performance.

Fabrication and Electrical Characterization of p/n PbSe Diodes

Lead selenide (PbSe) diodes were fabricated using a magnetron sputtering process system with a pulsed DC power supply and a 2-inch PbSe target with a purity of 5N. For p-type PbSe thin films, the process variable was the oxygen ratio in the mixed gas of argon and oxygen. The electrical characteristics of the thin films were observed after heat treatment. For the n-type PbSe, nickel (Ni) was used as a doping material. The deposition and doping were performed simultaneously using a co-sputtering method. During co-sputtering, the input power of the Ni sputter gun was adjusted as a process variable. Hall measurement experiments were performed to measure the doping concentration and resistivity of both the p-type and n-type PbSe semiconducting films. The maximum doping concentration was 2.33×10&lt;sup&gt;19&lt;/sup&gt; cm&lt;sup&gt;-3&lt;/sup&gt; for p-type PbSe and 7.55×10&lt;sup&gt;20&lt;/sup&gt; cm&lt;sup&gt;-3&lt;/sup&gt; for n-type PbSe thin films, respectively. The p-n junction IV curve showed that the lowest forward voltage generation point, V&lt;sub&gt;f&lt;/sub&gt;, was 1.5 V and the reverse breakdown voltage was -4.3 V. In the photocurrent measurement, the photo sensitivities of the heat-treated samples were higher than that of the non-treated sample, and the maximum value was 5.148. Photo responsivity was also higher in the heat-treated samples. Its maximum was 0.7306 mA / W.