Inefficient performance of CO2 refrigerant in hot climates has become a major obstacle to its wide application in electric vehicles. In this paper, the vacant heating core in cooling mode was exploited to increase the heat transfer area of evaporator and improve system performance. With the aid of a validated evaporator model and an experimental test rig, performance improvements brought by this added area were evaluated. Results indicated that this area is not suggested to be directly added to cooling core. This necessitates a dual-evaporator (D-E) configuration. For case I (small CO2 pressure drop), the growth rate in heat transfer rate brought by D-E configuration is 19∼20% and less sensitive to parallel or series operation. Nevertheless, this growth rate for case II (large CO2 pressure drop) is greatly affected, 30.6∼32.6% for parallel operation and 7.5∼17.6% for series operation. Specifically, it is around 17.5% and 7.5∼13.6% for series cross-parallel and cross-counter arrangements, respectively. By comprehensive consideration, the cross-parallel arrangement is recommended to be adopted. Experimental results indicated that the cross-parallel D-E configuration greatly increases the evaporation temperature and exhibits a slight impact on optimum high pressure within the transcritical cycle. The enhancement in COP brought by this configuration is around 6∼12% without additional cost, and it rises with the decreased air flowrate through evaporator and air velocity through gas cooler and the increased ambient temperature. This indicates that this configuration is an effective and economical technology to alleviate the efficiency degradation issue of transcritical CO2 automotive air-conditioners.