Heat release rate in combustion systems must be understood in order to control thermoacoustic instabilities, flame extinction, and heat losses. Traditionally OH chemiluminescence (OH*) is used to trace heat release rate (HRR) in H2/air flames, but its accuracy as a tracer has not been assessed. Lean premixed H2/air cellular tubular flames are a good test case to evaluate HRR tracers due to the presence of highly reactive flame cells surrounded by regions of near extinction. Comparing the calculated heat release rate to OH* concentration, one finds that [OH*] profiles correlate with the regions of high reactivity (flame cells) but the correlation fails in the low reactivity regions where the HRR is much higher than the [OH*] value indicates. Alternate HRR tracers including [H] and pixel-by-pixel products of [O2]x[H], [OH]x[H2], and [O]x[H2] are analyzed with detailed numerical simulations. The chosen products derive from the main chain reaction steps that contribute to overall HRR in lean, premixed H2/air flames. Findings suggest that [H] is an accurate yet simple way of tracking HRR. Planar measurements of HRR are possible if LIF measurements of [H] are improved.
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