The production of petroleum derivatives stands out worldwide among the non-renewable energy production processes, as the most well-known worldwide. In this study, an atmospheric distillation column that processed 100,000 barrels/day (662.5 m3/h) of crude oil was simulated using CHEMCAD® software. From this procedure, the Process Flow Diagram (PFD) and the Piping and Instrumentation Diagram (PI&D) for the unit, corresponding to its automation, were obtained. Subsequently, a HAZOP (Hazard and Operability Study) analysis was conducted in order to identify risks in the unit that, although not dangerous, could compromise its ability to achieve its productivity. The main risks of the process were related to fires, explosions and environmental contamination from leaks and ruptures in pipes, pumps, heat exchangers, the column itself, among other equipment. The HAZOP analysis was able, through the use of guide words, to identify possible operational risks arising from deviations in operating intentions, such as the possibility of fires, explosions, environmental contamination and their consequences. It was possible to identify the risks associated with the selection of materials, the mechanical design of the equipment and the specifications of the accessories. Therefore, the study carried out is an important survey for reducing possible failures in the oil industry. And, since this study is an in-depth study on the distillation processes for petroleum-derived products. It is understood that their in-depth study, as a result of the development of new renewable products, especially sustainable aviation fuels (SAFs), because they are similar purification processes, employ the same methodology to identify possible failures in production.
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