This paper reports experimental results for film condensation on vertical and downward inclined smooth and grooved surfaces subjected to ascending streams of a vapor–air mixture. An experimental facility was built in order to evaluate the heat fluxes for different surface inclinations, surface sub-cooling temperatures and air to vapor ratios in the mixture. Two experimental procedures were employed to evaluate the heat absorption rate during the condensation process. The employment of grooved surfaces resulted in a 10% enhancement of the condensation rate in the case of the pure vapor condensation and a negligible effect when noncondensable gases (NCGs) were present in the mixture.