HCN Abundance Research Articles

Investigation of the Origins of Comets as Revealed through Infrared High-resolution Spectroscopy I. Molecular Abundances

Abstract We report and analyze updated molecular abundances in 20 comets obtained by employing modern data reduction procedures and molecular models. Using box and scatter plots, we examine how the different molecular species are distributed among the comet population, while by means of pie charts, we investigate the relative proportions of these molecular species in each comet. We compare these results with the orbital parameters of the selected comets to identify trends related to their dynamical history. With these analyses, we tentatively identify at least three chemical classes based mainly on relative abundances of CO, CH3OH, CH4, C2H6, HCN, and NH3. The combination of relative abundances and orbital parameters is then compared with recent chemical models of planetary system formation. This approach may help in investigating the origins and evolution of the material in cometary nuclei. Among other aspects, we underline the need to increase our sample size, especially for hypervolatiles (i.e., CH4 and CO) in Jupiter family comets.

HCN/HNC chemistry in shocks: a study of L1157-B1 with ASAI

ABSTRACT Hydrogen cyanide (HCN) and its isomer hydrogen isocyanide (HNC) play an important role in molecular cloud chemistry and the formation of more complex molecules. We investigate here the impact of protostellar shocks on the HCN and HNC abundances from high-sensitivity IRAM 30 m observations of the prototypical shock region L1157-B1 and the envelope of the associated Class 0 protostar, as a proxy for the pre-shock gas. The isotopologues H12CN, HN12C, H13CN, HN13C, HC15N, H15NC, DCN, and DNC were all detected towards both regions. Abundances and excitation conditions were obtained from radiative transfer analysis of molecular line emission under the assumption of local thermodynamical equilibrium. In the pre-shock gas, the abundances of the HCN and HNC isotopologues are similar to those encountered in dark clouds, with an HCN/HNC abundance ratio ≈1 for all isotopologues. A strong D-enrichment (D/H ≈ 0.06) is measured in the pre-shock gas. There is no evidence of 15N fractionation neither in the quiescent nor in the shocked gas. At the passage of the shock, the HCN and HNC abundances increase in the gas phase in different manners so that the HCN/HNC relative abundance ratio increases by a factor 20. The gas-grain chemical and shock model uclchem allows us to reproduce the observed trends for a C-type shock with pre-shock density n(H) = $10^5\hbox{cm$^{-3}$}$ and shock velocity $V_\mathrm{ s}= 40\hbox{kms$^{-1}$}$. We conclude that the HCN/HNC variations across the shock are mainly caused by the sputtering of the grain mantle material in relation with the history of the grain ices.

Multifrequency high spectral resolution observations of HCN toward the circumstellar envelope of Y Canum Venaticorum

High spectral resolution observations toward the low mass-loss rate C-rich, J-type asymptotic giant branch (AGB) star Y CVn were carried out at 7.5, 13.1, and 14.0 μm with the Echelon-cross-echelle Spectrograph mounted on the Stratospheric Observatory for Infrared Astronomy and the Texas Echelon-cross-echelle Spectrograph on the Infrared Telescope Facility. Around 130 HCN and H13CN lines of bandsν2, 2ν2, 2ν2−ν2, 3ν2− 2ν2, 3ν2−ν2, and 4ν2− 2ν2were identified involving lower levels with energies up to ≃3900 K. These lines were complemented with the pure rotational linesJ= 1−0 and 3–2 of the vibrational states up to 2ν2acquired with the Institut de Radioastronomie Millimétrique 30 m telescope, and with the continuum taken with Infrared Space Observatory. We analyzed the data in detail by means of a ro-vibrational diagram and with a code written to model the absorption and emission of the circumstellar envelope of an AGB star. The continuum is mostly produced by the star with a small contribution from dust grains comprising warm to hot SiC and cold amorphous carbon. The HCN abundance distribution seems to be anisotropic close to Y CVn and in the outer layers of its envelope. The ejected gas is accelerated up to the terminal velocity (≃8 km s−1) from the photosphere to ≃3R⋆, but there is evidence of higher velocities (≳9–10 km s−1) beyond this region. In the vicinity of the star, the line widths are as high as ≃10 km s−1, which implies a maximum turbulent velocity of 6 km s−1or the existence of other physical mechanisms probably related to matter ejection that involve higher gas expansion velocities than expected. HCN is rotationally and vibrationally out of local thermodynamic equilibrium throughout the whole envelope. It is surprising that a difference of about 1500 K in the rotational temperature at the photosphere is needed to explain the observations at 7.5 and 13–14 μm. Our analysis finds a total HCN column density that ranges from ≃2.1 × 1018to 3.5 × 1018cm−2, an abundance with respect to H2of 3.5 × 10−5to 1.3 × 10−4, and a12C/13C isotopic ratio of ≃2.5 throughout the whole envelope.

Sulfur chemistry in the atmospheres of warm and hot Jupiters

ABSTRACT We present and validate a new network of atmospheric thermochemical and photochemical sulfur reactions. We use a 1D chemical kinetics model to investigate these reactions as part of a broader HCNO chemical network in a series of hot and warm Jupiters. We find that temperatures approaching $1400\, \mathrm{K}$ are favourable for the production of H2S and HS around $\mathrm{10^{-3}\, bar}$ at mixing ratios of around 10−5, an atmospheric level where detection by transit spectroscopy may be possible. At $\mathrm{10^{-3}\, bar}$ and at lower temperatures, down to $1000\, \mathrm{K}$, mixing ratios of S2 can be up to 10−5, at the expense of H2S and HS, which are depleted down to a mixing ratio of 10−7. We also investigate how the inclusion of sulfur can manifest in an atmosphere indirectly, by its effect on the abundance of non-sulfur-bearing species. We find that in a model of the atmosphere of HD 209458 b, the inclusion of sulfur can lower the abundance of NH3, CH4, and HCN by up to two orders of magnitude around $\mathrm{10^{-3}\, bar}$. In the atmosphere of the warm Jupiter 51 Eri b, we additionally find the inclusion of sulfur depletes the peak abundance of CO2 by a factor of 5, qualitatively consistent with prior models. We note that many of the reactions used in the network have poorly determined rate constants, especially at higher temperatures. To obtain an accurate idea of the impact of sulfur chemistry in hot and warm Jupiter atmospheres, experimental measurements of these reaction rates must take place.

Planck Cold Clumps in the λ Orionis Complex. III. A Chemical Probe of Stellar Feedback on Cores in the λ Orionis Cloud

Abstract Massive stars have a strong impact on their local environments. However, how stellar feedback regulates star formation is still under debate. In this context, we studied the chemical properties of 80 dense cores in the Orion molecular cloud complex composed of the Orion A (39 cores), B (26 cores), and λ Orionis (15 cores) clouds using multiple molecular line data taken with the Korean Very Long Baseline Interferometry Network 21 m telescopes. The λ Orionis cloud has an H ii bubble surrounding the O-type star λ Ori, and hence it is exposed to the ultraviolet (UV) radiation field of the massive star. The abundances of C2H and HCN, which are sensitive to UV radiation, appear to be higher in the cores in the λ Orionis cloud than in those in the Orion A and B clouds, while the HDCO to H2CO abundance ratios show the opposite trend, indicating warmer conditions in the λ Orionis cloud. The detection rates of dense gas tracers such as the N2H+, HCO+, and H13CO+ lines are also lower in the λ Orionis cloud. These chemical properties imply that the cores in the λ Orionis cloud are heated by UV photons from λ Ori. Furthermore, the cores in the λ Orionis cloud do not show any statistically significant excess in the infall signature of HCO+ (1–0), unlike those in the Orion A and B clouds. Our results support the idea that feedback from massive stars impacts star formation in a negative way by heating and evaporating dense materials, as in the λ Orionis cloud.

First Comet Observations with NIRSPEC-2 at Keck: Outgassing Sources of Parent Volatiles and Abundances Based on Alternative Taxonomic Compositional Baselines in 46P/Wirtanen

Abstract A major upgrade to the NIRSPEC instrument at the Keck II telescope was successfully completed in time for near-infrared spectroscopic observations of comet 46P/Wirtanen during its exceptionally close flyby of Earth in 2018 December. These studies determined the abundances of several volatiles, including C2H2, C2H6, CH3OH, NH3, HCN, H2CO, and H2O. Long-slit spatial distributions of gas rotational temperature and column density are diagnostic for the presence of icy grains in the coma and understanding if different volatiles are associated with common or distinct outgassing sources. These spatial distributions suggest that C2H2, C2H6, and HCN have a common outgassing source, whereas H2O and CH3OH have additional, more extended sources. The synergy of these findings with observations by space missions (Rosetta and EPOXI) motivates continuing studies to address whether or not C2H6, C2H2, and HCN have a common source of release (plausibly associated with CO2) in a larger sample of comets and whether systematic differences exist in the release of these species compared to H2O and CH3OH. Abundances of volatiles are reported relative to H2O, as traditionally done, as well as C2H6. While not unique, the choice of C2H6 demonstrates the value of extending the chemical taxonomy of parent volatiles in comets toward additional compositional “baselines” and, importantly, closer integration between coma abundances and the underlying volatile associations as revealed by spatial distributions. Our findings on composition and sources of outgassing include information relevant to future evaluations of 46P/Wirtanen as a prospective spacecraft target.

Resolved molecular line observations reveal an inherited molecular layer in the young disk around TMC1A

Context.Physical processes that govern the star and planet formation sequence influence the chemical composition and evolution of protoplanetary disks. Recent studies allude to an early start to planet formation already during the formation of a disk. To understand the chemical composition of protoplanets, we need to constrain the composition and structure of the disks from whence they are formed.Aims.We aim to determine the molecular abundance structure of the young disk around the TMC1A protostar on au scales in order to understand its chemical structure and any possible implications for disk formation.Methods.We present spatially resolved Atacama Large Millimeter/submillimeter Array observations of CO, HCO+, HCN, DCN, and SO line emission, as well as dust continuum emission, in the vicinity of TMC1A. Molecular column densities are estimated both under the assumption of optically thin emission from molecules in local thermodynamical equilibrium (LTE) as well as through more detailed non-LTE radiative transfer calculations.Results.Resolved dust continuum emission from the disk is detected between 220 and 260 GHz. Rotational transitions from HCO+, HCN, and SO are also detected from the inner 100 au region. We further report on upper limits to vibrational HCNυ2= 1, DCN, and N2D+lines. The HCO+emission appears to trace both the Keplerian disk and the surrounding infalling rotating envelope. HCN emission peaks toward the outflow cavity region connected with the CO disk wind and toward the red-shifted part of the Keplerian disk. From the derived HCO+abundance, we estimate the ionization fraction of the disk surface, and find values that imply that the accretion process is not driven by the magneto-rotational instability. The molecular abundances averaged over the TMC1A disk are similar to its protostellar envelope and other, older Class II disks. We meanwhile find a discrepancy between the young disk’s molecular abundances relative to Solar System objects.Conclusions.Abundance comparisons between the disk and its surrounding envelope for several molecular species reveal that the bulk of planet-forming material enters the disk unaltered. Differences in HCN and H2O molecular abundances between the disk around TMC1A, Class II disks, and Solar System objects trace the chemical evolution during disk and planet formation.

ALMA 0.″02 Resolution Observations Reveal HCN-abundance-enhanced Counter-rotating and Outflowing Dense Molecular Gas at the NGC 1068 Nucleus

Abstract We present ALMA ∼0.″02 resolution observations of the nucleus of the nearby (∼14 Mpc) type 2 active galactic nucleus NGC 1068 at HCN/HCO+/HNC J = 3–2 lines, as well as at their 13C isotopologue and vibrationally excited lines, to scrutinize the morphological, dynamical, chemical, and physical properties of dense molecular gas in the putative dusty molecular torus around a mass-accreting supermassive black hole. We confirm almost east–west-oriented dense molecular gas emission both morphologically and dynamically, which we regard as coming from the torus. Bright emission is compact (≲3 pc), and low-surface-brightness emission extends out to 5–7 pc. These dense molecular gas properties are not symmetric between the eastern and western torus. The HCN J = 3–2 emission is stronger than the HCO+ J = 3–2 emission within the ∼7 pc torus region, with an estimated dense molecular mass of (0.4–1.0) × 106 M ⊙. We interpret that HCN abundance is enhanced in the torus. We detect signatures of outflowing dense molecular gas and a vibrationally excited HCN J = 3–2 line. Finally, we find that in the innermost (≲1 pc) part of the torus, the dense molecular line rotation velocity, relative to the systemic velocity, is the opposite of that in the outer (≳2 pc) part, in both the eastern and western torus. We prefer a scenario of counter-rotating dense molecular gas with innermost almost Keplerian rotation and outer slowly rotating (far below Keplerian) components. Our high-spatial-resolution dense molecular line data reveal that torus properties of NGC 1068 are much more complicated than the simple axisymmetrically rotating torus picture in the classical active galactic nucleus unification paradigm.

HCN Production in Titan’s Atmosphere: Coupling Quantum Chemistry and Disequilibrium Atmospheric Modeling

Abstract Hydrogen cyanide (HCN) is a critical reactive source of nitrogen for building key biomolecules relevant for the origin of life. Still, many HCN reactions remain uncharacterized by experiments and theory, and the complete picture of HCN production in planetary atmospheres is not fully understood. To improve this situation, we develop a novel technique making use of computational quantum chemistry, experimental data, and atmospheric numerical simulations. First, we use quantum chemistry simulations to explore the entire field of possible reactions for a list of primary species in N2-, CH4-, and H2-dominated atmospheres. In this process, we discover 33 new reactions with no previously known rate coefficients. From here, we develop a consistent reduced atmospheric hybrid chemical network (CRAHCN) containing experimental values when available and our calculated rate coefficients otherwise. Next, we couple CRAHCN to a 1D chemical kinetic model (ChemKM) to compute the HCN abundance as a function of atmospheric depth on Titan. Our simulated atmospheric HCN profile agrees very well with the Cassini observations. CRAHCN contains 104 reactions; however, nearly all of the simulated atmospheric HCN profile can be obtained using a scaled-down network of only 19 dominant reactions. From here, we form a complete picture of HCN chemistry in Titan’s atmosphere, from the dissociation of the main atmospheric species, down to the direct production of HCN along four major channels. One of these channels was first discovered and characterized in Pearce et al. and this work.

An Evolutionary Study of Volatile Chemistry in Protoplanetary Disks

Abstract The volatile composition of a planet is determined by the inventory of gas and ice in the parent disk. The volatile chemistry in the disk is expected to evolve over time, though this evolution is poorly constrained observationally. We present Atacama Large Millimeter/submillimeter Array observations of C18O, C2H, and the isotopologues H13CN, HC15N, and DCN toward five Class 0/I disk candidates. Combined with a sample of 14 Class II disks presented in Bergner et al., this data set offers a view of volatile chemical evolution over the disk lifetime. Our estimates of C18O abundances are consistent with a rapid depletion of CO in the first ∼0.5–1 Myr of the disk lifetime. We do not see evidence that C2H and HCN formation are enhanced by CO depletion, possibly because the gas is already quite under-abundant in CO. Further CO depletion may actually hinder their production by limiting the gas-phase carbon supply. The embedded sources show several chemical differences compared to the Class II stage, which seem to arise from shielding of radiation by the envelope (impacting C2H formation and HC15N fractionation) and sublimation of ices from infalling material (impacting HCN and C18O abundances). Such chemical differences between Class 0/I and Class II sources may affect the volatile composition of planet-forming material at different stages in the disk lifetime.

Observations of the Hydrogen Cyanide in Comet 46P/Wirtanen at a 3.4 mm Wavelength

Abstract We searched for rotational lines of H12C14N in comet 46P/Wirtanen, using the Purple Mountain Observatory 13.7 m radio telescope. The J = 1–0 lines of HCN (3.4 mm wavelength) were unambiguously detected in 46P during the 2018 December 14–15 period, with a beam resolution of 62.″2 and a velocity resolution of ∼0.21 km s−1 per channel. The molecular production rates were computed. The mean HCN(1–0) production rate of 46P was (6.45 ± 1.31) × 1024 molec s−1 in the above two days. We found possible indications of time variation in the outgassing activity. The average HCN abundance relative to water Q [HCN]/ of 46P was (0.09 ± 0.01)%. The HCN line shapes gave primary information on the kinematics of the cometary atmosphere. The HCN linewidths provided a direct determination of the coma expansion velocity, which was about 0.5 ± 0.05 km s−1 at post-perihelion (1.056 au).

Chemical and kinematic structure of extremely high-velocity molecular jets in the Serpens Main star-forming region

Context. Outflows are one of the first signposts of ongoing star formation. The fastest molecular component of protostellar outflows, extremely high-velocity (EHV) molecular jets, are still puzzling since they are seen only rarely. As they originate deep inside the embedded protostar-disk system, they provide vital information about the outflow-launching process in the earliest stages. Aims. The first aim is to analyze the interaction between the EHV jet and the slow outflow by comparing their outflow force content. The second aim is to analyze the chemical composition of the different outflow velocity components and to reveal the spatial location of molecules. Methods. The Atacama Large Millimeter/submillimeter Array 3 mm (Band 3) and 1.3 mm (Band 6) observations of five outflow sources at 0.′′3 – 0.′′6 (130–260 au) resolution in the Serpens Main cloud are presented. Observations of CO, SiO, H2CO, and HCN reveal the kinematic and chemical structure of those flows. The following three velocity components are distinguished: the slow and the fast wing, and the EHV jet. Results. Out of five sources, three have the EHV component. The comparison of outflow forces reveals that only the EHV jet in the youngest source, Ser-emb 8 (N), has enough momentum to power the slow outflow. The SiO abundance is generally enhanced with velocity, while HCN is present in the slow and the fast wing, but disappears in the EHV jet. For Ser-emb 8 (N), HCN and SiO show a bow-shock shaped structure surrounding one of the EHV peaks, thus suggesting sideways ejection creating secondary shocks upon interaction with the surroundings. Also, the SiO abundance in the EHV gas decreases with distance from this protostar, whereas it increases in the fast wing. H2CO is mostly associated with low-velocity gas, but, surprisingly, it also appears in one of the bullets in the Ser-emb 8 (N) EHV jet. No complex organic molecules are found to be associated with the outflows. Conclusions. The high detection rate suggests that the presence of the EHV jet may be more common than previously expected. The EHV jet alone does not contain enough outflow force to explain the entirety of the outflowing gas. The origin and temporal evolution of the abundances of SiO, HCN, and H2CO through high-temperature chemistry are discussed. The data are consistent with a low C/O ratio in the EHV gas versus a high C/O ratio in the fast and slow wings.

The Greenhouse Effect in Buried Galactic Nuclei and the Resonant HCN Vibrational Emission

Abstract Recent interferometric observations have shown bright HCN emission from the ν 2 = 1 vibrational state arising in buried nuclear regions of galaxies, indicating an efficient pumping of the ν 2 = 1 state through the absorption of 14 μm continuum photons. We modeled the continuum and HCN vibrational line emission in these regions, characterized by high column densities of dust and high luminosities, using a spherically symmetric approach, simulating both a central heating source (active galactic nucleus, AGN) and a compact nuclear starburst (SB). We find that when the H2 columns become very high, N H2 ≳ 1025 cm−2, trapping of continuum photons within the nuclear region dramatically enhances the dust temperature (T dust) in the inner regions, even though the predicted spectral energy distribution as seen from the outside becomes relatively cold. The models thus predict a bright continuum at millimeter wavelengths for a luminosity surface brightness (averaged over the model source) of ∼108 L ⊙ pc−2. This greenhouse effect significantly enhances the mean mid-infrared intensity within the dusty volume, populating the ν 2 = 1 state to the extent that the HCN vibrational lines become optically thick. AGN models yield higher T dust in the inner regions and higher peak (sub)millimeter continuum brightness than SB models, but similar HCN vibrational J = 3–2 and 4–3 emission owing to both optical depth effects and a moderate impact of high T dust on these low-J lines. The observed HCN vibrational emission in several galaxies can be accounted for with an HCN abundance of ∼10−6 (relative to H2) and luminosity surface brightness in the range (0.5–2) × 108 L ⊙ pc−2, predicting a far-infrared photosphere with T dust ∼ 80–150 K, in agreement with the values inferred from far-infrared molecular absorption.

Chemical evolution of HC3N in dense molecular clouds

ABSTRACT We investigated the chemical evolution of HC3N in six dense molecular clouds, using archival available data from the Herschel infrared Galactic Plane Survey (Hi-GAL) and the Millimeter Astronomy Legacy Team Survey at 90 GHz (MALT90). Radio sky surveys of the Multi-Array Galactic Plane Imaging Survey (MAGPIS) and the Sydney University Molonglo Sky Survey (SUMSS) indicate these dense molecular clouds are associated with ultracompact H ii (UCH ii) regions and/or classical H ii regions. We find that in dense molecular clouds associated with normal classical H ii regions, the abundance of HC3N begins to decrease or reaches a plateau when the dust temperature gets hot. This implies UV photons could destroy the molecule of HC3N. On the other hand, in the other dense molecular clouds associated with UCH ii regions, we find the abundance of HC3N increases with dust temperature monotonously, implying HC3N prefers to be formed in warm gas. We also find that the spectra of HC3N (10-9) in G12.804−0.199 and RCW 97 show wing emissions, and the abundance of HC3N in these two regions increases with its non-thermal velocity width, indicating HC3N might be a shock origin species. We further investigated the evolutionary trend of N(N2H+)/N(HC3N) column density ratio, and found this ratio could be used as a chemical evolutionary indicator of cloud evolution after the massive star formation is started.

Post-perihelion volatile production and release from Jupiter-family comet 45P/Honda-Mrkos-Pajdušáková

High-resolution infrared spectra of Jupiter-family comet 45P/Honda-Mrkos-Pajdušáková were obtained with NIRSPEC at the W. M. Keck Observatory on two post-perihelion dates (UT 2017 February 13 and 19), when the comet was at heliocentric distances of 1.01 and 1.10 AU, respectively. On UT February 13, H2O was measured simultaneously with six trace parent molecules: CH3OH, C2H6, HCN, NH3, C2H2, and H2CO. On UT February 19, CH4 and CO were also targeted in addition to the species measured on UT February 13. Abundances of CO, CH4, and C2H2 relative to H2O are consistent with values obtained from IRTF/iSHELL observations of 45P in early January 2017 just after perihelion when the heliocentric distance was 0.55–0.56 AU. Differences are seen in H2CO/H2O, C2H6/H2O, CH3OH/H2O, and HCN/H2O in February compared to January. Additionally, NH3 abundances appear highly variable during the February measurements, suggesting possible fluctuations of a factor of ten; however, there is significant uncertainty in quantifying NH3 owing to the marginal detections of only one or two lines on each of the two dates. Combining all infrared spectroscopic observations of 45P in January and February 2017, a post-perihelion relationship of Q(H2O) = (2.81 ± 0.25) × 1027 [Rh(−3.83±0.18)] molecules s−1 is derived. However, all measurements suggest significant variability in H2O production on timescales of hours and days. Compared to other comets, volatile abundances relative to H2O in 45P are as follows: CO (depleted relative to all measured comets), CH3OH (enriched/all comets), CH4 and C2H6 (typical/all comets, enriched/Jupiter-family comets), C2H2 (depleted/all comets, typical/Jupiter-family comets), H2CO (January: typical, February depleted/all comets), HCN (January: severely depleted, February: typical/Jupiter-family comets). The small geocentric distances of the comet in February 2017 provide high spatial resolution in the coma of 45P (~12 and 19 km/pixel on February 13 and 19, respectively). Overall, the spatial distributions of volatiles and dust suggest a relatively symmetric and uniform coma during the UT February 13 and 19 observations, with small spatial differences noted between some volatile species. Measured C2H2 and HCN abundances are consistent with HCN as the primary parent of CN and C2H2 as a significant but not primary parent for C2, based on C2 and CN production rate measurements from the 2017 and previous apparitions. Extracted spectra show an increase in the dust-to-gas ratio in 45P from February 13 to 19 in agreement with contemporaneous narrowband optical measurements.

Gas phase Elemental abundances in Molecular cloudS (GEMS): I. The prototypical dark cloud TMC 1.

GEMS is an IRAM 30m Large Program whose aim is determining the elemental depletions and the ionization fraction in a set of prototypical star-forming regions. This paper presents the first results from the prototypical dark cloud TMC 1. Extensive millimeter observations have been carried out with the IRAM 30m telescope (3 mm and 2 mm) and the 40m Yebes telescope (1.3 cm and 7 mm) to determine the fractional abundances of CO, HCO+, HCN, CS, SO, HCS+, and N2H+ in three cuts which intersect the dense filament at the well-known positions TMC 1-CP, TMC 1-NH3, and TMC 1-C, covering a visual extinction range from A V ~ 3 to ~20 mag. Two phases with differentiated chemistry can be distinguished: i) the translucent envelope with molecular hydrogen densities of 1-5×103 cm-3; and ii) the dense phase, located at A V > 10 mag, with molecular hydrogen densities >104 cm-3. Observations and modeling show that the gas phase abundances of C and O progressively decrease along the C+/C/CO transition zone (A V ~ 3 mag) where C/H ~ 8×10-5 and C/O~0.8-1, until the beginning of the dense phase at A V ~ 10 mag. This is consistent with the grain temperatures being below the CO evaporation temperature in this region. In the case of sulfur, a strong depletion should occur before the translucent phase where we estimate a S/H ~ (0.4 - 2.2) ×10-6, an abundance ~7-40 times lower than the solar value. A second strong depletion must be present during the formation of the thick icy mantles to achieve the values of S/H measured in the dense cold cores (S/H ~8×10-8). Based on our chemical modeling, we constrain the value of ζ H2 to ~ (0.5 - 1.8) ×10-16 s-1 in the translucent cloud.

Exploring the Origins of Earth’s Nitrogen: Astronomical Observations of Nitrogen-bearing Organics in Protostellar Environments

Abstract It is not known whether the original carriers of Earth’s nitrogen were molecular ices or refractory dust. To investigate this question, we have used data and results of Herschel observations toward two protostellar sources: the high-mass hot core of Orion KL, and the low-mass protostar IRAS 16293−2422. Toward Orion KL, our analysis of the molecular inventory of Crockett et al. indicates that HCN is the organic molecule that contains by far the most nitrogen, carrying of nitrogen-in-organics. Following this evidence, we explore HCN toward IRAS 16293−2422, which is considered a solar analog. Toward IRAS 16293−2422, we have reduced and analyzed Herschel spectra of HCN, and fit these observations against “jump” abundance models of IRAS 16293−2422's protostellar envelope. We find an inner-envelope HCN abundance X in = 5.9 ± 0.7 × 10−8 and an outer-envelope HCN abundance X out = 1.3 ± 0.1 × 10−9. We also find the sublimation temperature of HCN to be T jump = 71 ± 3 K; this measured T jump enables us to predict an HCN binding energy E B/k = 3840 ± 140 K. Based on a comparison of the HCN/H2O ratio in these protostars to N/H2O ratios in comets, we find that HCN (and, by extension, other organics) in these protostars is incapable of providing the total bulk N/H2O in comets. We suggest that refractory dust, not molecular ices, was the bulk provider of nitrogen to comets. However, interstellar dust is not known to have 15N enrichment, while high 15N enrichment is seen in both nitrogen-bearing ices and in cometary nitrogen. This may indicate that these 15N-enriched ices were an important contributor to the nitrogen in planetesimals and likely to the Earth.

TBX18 overexpression enhances pacemaker function in a rat subsidiary atrial pacemaker model of sick sinus syndrome.

Key points The sinoatrial node (SAN) is the primary pacemaker of the heart. SAN dysfunction, or ‘sick sinus syndrome’, can cause excessively slow heart rates and pauses, leading to exercise limitation and syncope, currently treated by implantation of an electronic pacemaker.‘Biopacemaking’ utilises gene therapy to restore pacemaker activity by manipulating gene expression. Overexpressing the HCN pacemaker ion channel has been widely used with limited success.We utilised bradycardic rat subsidiary atrial pacemaker tissue to evaluate alternative gene targets: the Na+/Ca2+ exchanger NCX1, and the transcription factors TBX3 and TBX18 known to be involved in SAN embryonic development.TBX18 overexpression restored normal SAN function, as assessed by increased rate, improved heart rate stability and restoration of isoprenaline response. TBX3 and NCX1 were not effective in accelerating the rate of subsidiary atrial pacemaker tissue.Gene therapy targeting TBX18 could therefore have the potential to restore pacemaker function in human sick sinus syndrome obviating electronic pacemakers. The sinoatrial node (SAN) is the primary pacemaker of the heart. Disease of the SAN, sick sinus syndrome, causes heart rate instability in the form of bradycardia and pauses, leading to exercise limitation and syncope. Biopacemaking aims to restore pacemaker activity by manipulating gene expression, and approaches utilising HCN channel overexpression have been widely used. We evaluated alternative gene targets for biopacemaking to restore normal SAN pacemaker physiology within bradycardic subsidiary atrial pacemaker (SAP) tissue, using the Na+/Ca2+ exchanger NCX1, and the transcription factors TBX3 and TBX18. TBX18 expression in SAP tissue restored normal SAN function, as assessed by increased rate (SAN 267.5 ± 13.6 bpm, SAP 144.1 ± 8.6 bpm, SAP‐TBX18 214.4 ± 14.4 bpm; P < 0.001), improved heart rate stability (standard deviation of RR intervals fell from 39.3 ± 7.2 ms to 6.9 ± 0.8 ms, P < 0.01; root mean square of successive differences of RR intervals fell from 41.7 ± 8.2 ms to 6.1 ± 1.2 ms, P < 0.01; standard deviation of points perpendicular to the line of identity of Poincaré plots (SD1) fell from 29.5 ± 5.8 ms to 7.9 ± 2.0 ms, P < 0.05) and restoration of isoprenaline response (increases in rates of SAN 65.5 ± 1.3%, SAP 28.4 ± 3.4% and SAP‐TBX18 103.3 ± 10.2%; P < 0.001). These changes were driven by a TBX18‐induced switch in the dominant HCN isoform in SAP tissue, with a significant upregulation of HCN2 (from 1.01 × 10−5 ± 2.2 × 10−6 to 2.8 × 10−5 ± 4.3 × 10−6 arbitrary units, P < 0.001). Biophysically detailed computer modelling incorporating isoform‐specific HCN channel electrophysiology confirmed that the measured changes in HCN abundance could account for the observed changes in beating rates. TBX3 and NCX1 were not effective in accelerating the rate of SAP tissue.

Spatially Resolved Dense Molecular Gas Excitation in the Nearby LIRG VV 114

Abstract We present high-resolution observations (0.″2–1.″5) of multiple dense gas tracers, HCN and HCO+ (J = 1–0, 3–2, and 4–3), HNC (J = 1–0), and CS (J = 7–6) lines, toward the nearby luminous infrared galaxy VV 114 with the Atacama Large Millimeter/submillimeter Array. All lines are robustly detected at the central gaseous filamentary structure, including the eastern nucleus and the overlap region, the collision interface of the progenitors. We found that there is no correlation between star formation efficiency and dense gas fraction, indicating that the amount of dense gas does not simply control star formation in VV 114. We predict the presence of more turbulent and diffuse molecular gas clouds around the overlap region compared to those at the nuclear region, assuming a turbulence-regulated star formation model. The intracloud turbulence at the overlap region might be excited by galaxy-merger-induced shocks, which also explains the enhancement of gas-phase CH3OH abundance previously found there. We also present spatially resolved spectral line energy distributions of HCN and HCO+ for the first time, and derive excitation parameters by assuming optically thin and local thermodynamic equilibrium (LTE) conditions. The LTE model revealed that warmer, HCO+-poorer molecular gas medium is dominated around the eastern nucleus, harboring an active galactic nucleus (AGN). The HCN abundance is remarkably flat (∼3.5 × 10−9) independently of the various environments within the filament of VV 114 (i.e., AGN, star formation, and shock).

Community Targets of JWST’s Early Release Science Program: Evaluation of WASP-63b

Abstract We present observations of WASP-63b by the Hubble Space Telescope (HST) as part of “A Preparatory Program to Identify the Single Best Transiting Exoplanet for James Webb Space Telescope (JWST) Early Release Science (ERS).” WASP-63b is one of the community targets under consideration for the JWST ERS program. We present a spectrum derived from a single observation by HST Wide Field Camera 3 in the near-infrared. We engaged groups across the transiting exoplanet community to participate in the analysis of the data and present results from each. Extraction of the transmission spectrum by several independent analyses find an H2O absorption feature with varying degrees of significance ranging from 1σ to 3σ. The feature, in all cases, is muted in comparison to a clear atmosphere at solar composition. The reasons for the muting of this feature are ambiguous due to a degeneracy between clouds and composition. The data does not yield robust detections of any molecular species other than H2O. The group was motivated to perform an additional set of retrieval exercises to investigate an apparent bump in the spectrum at ∼1.55 μm. We explore possible disequilibrium chemistry and find this feature is consistent with super-solar HCN abundance but it is questionable if the required mixing ratio of HCN is chemically and physically plausible. The ultimate goal of this study is to vet WASP-63b as a potential community target to best demonstrate the capabilities and systematics of JWST instruments for transiting exoplanet science. In the case of WASP-63b, the presence of a detectable water feature indicates that WASP-63b remains a plausible target for JWST observations.