Hazardous Waste Sites Research Articles

Classification of spent Li-ion batteries based on ICP-OES/X-ray characterization of the cathode materials

Development of lithium-ion batteries (LIBs) during the latest decades resulted in improved performances of the new integrated cathode materials and in their wide applications. This rapid expansion of new materials led to the intensive replacement of the old-fashioned, traditional materials and increased a simultaneous accumulation of both kinds of materials at extremely hazardous electronic waste sites, which additionally increased an urgent need for their recycling. Most importantly, in this way, spent LIBs may further serve as a significant source of valuable metals such as Li and cobalt. However, one of the key problems in LIBs recycling is the absence of a precise battery classification/sorting based on the chemical composition of the used cathode material. In this paper, characterization of the cathode material was performed regarding chemical composition of 40 samples of spent LIBs using inductively coupled plasma - optical emission spectrometry and X-ray diffraction. Preparation of the samples, (pretreatment) included: discharging, dismantling, separation of the main components (cathode, anode and the separator), and detachment of the cathode material from the aluminium foil. The obtained results showed that, in the investigated commercially available LIBs, lithium cobalt oxide was the most frequently used (cathode) material.

Protecting Children from Toxic Waste: Data-Usability Evaluation Can Deter Flawed Cleanup.

Nearly 25 percent of US children live within 2 km of toxic-waste sites, most of which are in urban areas. They face higher rates of cancer than adults, partly because the dominant contaminants at most US hazardous-waste sites include genotoxic carcinogens, like trichloroethylene, that are much more harmful to children. The purpose of this article is to help protect the public, especially children, from these threats and to improve toxics-remediation by beginning to test our hypothesis: If site-remediation assessments fail data-usability evaluation (DUE), they likely compromise later cleanups and public health, especially children’s health. To begin hypothesis-testing, we perform a focused DUE for an unremediated, Pasadena, California toxic site. Our DUE methods are (a) comparing project-specific, remediation-assessment data with the remediation-assessment conceptual site model (CSM), in order to identify data gaps, and (b) using data-gap directionality to assess possible determinate bias (whether reported toxics risks are lower/higher than true values). Our results reveal (1) major CSM data gaps, particularly regarding Pasadena-toxic-site risks to children; (2) determinate bias, namely, risk underestimation; thus (3) likely inadequate remediation. Our discussion shows that if these results are generalizable, requiring routine, independent, DUEs might deter flawed toxic-site assessment/cleanup and resulting health threats, especially to children.

Allocating cleanup costs among potentially responsible parties

AbstractAllocating costs for hazardous waste site cleanup among potentially responsible parties is unique to the specific circumstances, history, and data for the site. As such, distinct technical approaches are often needed considering the Gore and Torres factors to develop an overall allocation. These factors include both technical and nontechnical considerations that the trier of fact must weigh to arrive at the overall allocation. This article reviews the legal and technical framework in allocating cleanup costs at hazardous waste sites and presents several case histories illustrating the integration of fact, science and law in the final allocation.

The Environmental Protection Agency's Use of Community Involvement to Engage Communities at Superfund Sites.

The Environmental Protection Agency’s (EPA) Superfund program was established to identify, assess and clean up the nation’s worst hazardous waste sites to protect human health and the environment. Community involvement is an important part of the Superfund program for at least three reasons. First, involving communities in decision making at Superfund sites is a statutory requirement. Second, community involvement is important so that clean up decisions will support reuse in the surrounding community. Third, because even after cleanup many sites have residual contamination that warrants administrative and legal controls to protect health and the environment, community members should understand these controls to both help protect community members and any limitations on site reuse. Community feedback informs both proposed actions and local reuse decisions. While the EPA recognizes that the agency performs many activities that are helpful to support community involvement, there are areas in need of improvement and further research would be helpful for communities in the future.

Themes Across New Directions in Community Engagement.

The articles in this special issue on New Directions in Environmental Communication in the International Journal of Environmental Research and Public Health present new research and perspectives on engaging communities impacted by Superfund sites—the hazardous waste sites that have been identified by the U.S. Environmental Protection Agency (EPA) as needing cleanup. In particular, these articles focus on the community engagement cores (CECs) that work with affected communities as part the Superfund Research Program at the National Institute of Environmental Health Sciences (NIEHS). The purpose of this closing article is to highlight important themes evident across the eight articles in the special issue. When considered together, the findings reveal important lessons learned about community engagement and environmental communication, but also reveal that much more remains to be known. Recommendations are made for how these teams can continue to practice, reflect on, and research community engagement in ways that build toward a better understanding and implementation of best practices.

Maternal Health in the Aftermath of Hurricanes Irma and Maria in Puerto Rico

OPS 11: Health effects of climate change in low- and middle-income countries, Room 114, Floor 1, August 27, 2019, 10:30 AM - 12:00 PM Background: Prior to Hurricane Maria, Puerto Rico had 200+ hazardous waste sites, significant contamination of water resources, and marked disparities in reproductive health, including higher rates of preterm birth, low birthweight, and infant mortality compared to the mainland US. Since 2010, the Puerto Rico Testsite for Exploring Contamination Threats (PROTECT) Center has been investigating prenatal environmental exposures and preterm birth on the island. When Maria struck Puerto Rico in September 2017, there were 102 pregnant PROTECT participants. Previous research suggests that pregnant women who experience a natural disaster are at higher risk of adverse birth outcomes. Methods: In Fall 2018, we administered a questionnaire to identify hurricane-related sources of stress and environmental exposures to women who were pregnant during Maria or who became pregnant in the aftermath (n=176). Demographic and health data were obtained from the PROTECT database. Results: Women who continued participation or enrolled in PROTECT after Maria had slightly higher income and education compared to previous participants. Currently, 122 women have completed the questionnaire, 7 declined, 2 are pending, and 45 were unreachable. On average, respondents were without electricity for 108 days, and 88% reported use of a power generator during the emergency. In the aftermath of the hurricane, 10% of women reported having asthma during pregnancy and 16% indicated having problems completing their prenatal visits. 24% indicated living in a place other than their pre-hurricane residence, 65% indicated damages to their property, and 31% reported living with stagnant water near or inside their homes. Conclusions: Analysis of questionnaire data in relation to hurricane-related exposures and stress, as well as birth outcomes, is in progress. This work, along with ongoing community engagement efforts, will identify ways to minimize the impact of future natural disasters on maternal and child health in Puerto Rico.

1,4‐Dioxane: Emerging technologies for an emerging contaminant

AbstractThe synthetic chemical, 1,4‐dioxane, is classified by the U.S. Environmental Protection Agency (EPA) as a probable human carcinogen. Between 2013 and 2015, the EPA detected 1,4‐dioxane in public drinking water supplies in 45 states at concentrations up to 33 µg/L and in groundwater from releases at hazardous waste sites across the United States. Although a Federal maximum contaminant level drinking water standard has not yet been proposed, state‐specific standards and criteria are as low as 0.3 µg/L. 1,4‐Dioxane is a recalcitrant chemical in that applications of conventional treatment technologies have had limited success in reducing concentrations in water to meet current and proposed health‐protective levels. Although mainly used as a stabilizer for the solvent 1,1,1‐trichloroethane, it has been used in other industrial processes and has been detected in a variety of consumer products, such as foods, pharmaceuticals, cosmetics, and detergents. The high aqueous solubility of 1,4‐dioxane coupled with limited solubility of chlorinated solvents typically found in conjunction with 1,4‐dioxane contamination is the primary reason for its treatment challenges. In the last several years, an alternative, cost‐effective technology has been developed that has demonstrated treatment to levels significantly lower than the Federal and state‐specific goals. This article provides a Federal and state‐by‐state summary of 1,4‐dioxane‐specific drinking water and groundwater concentration criteria and qualitative comparison of the effectiveness of conventional treatment technologies compared to the effectiveness of an alternative treatment technology. A case study is also provided to present details regarding the application of an alternative treatment technology at an active groundwater remediation site in California.

Extracellular Electron Transfer Mechanisms in a Moderately Halophilic Bacterium from the Great Salt Lake for High Salinity Heavy Metal Biosensing

High saline contamination events are a growing problem due to the increase in frequency and severity of hurricanes and the accompanying torrential rains.1 Storms affecting coastal areas can flood Superfund sites, which are designated hazardous waste sites managed by the Environmental Protection Agency (EPA), and other dangerous industrial waste sites. These events can result in the release of harmful pollutants into the environment, including heavy metals.2 The dimension of the contaminated area, as well as the cost and labor intensive approaches utilized, make the monitoring through standard laboratory methods complicated.3 Accordingly, a comprehensive screening of a community after a contamination event is not feasible. In this contest, biosensors offer a cost-effective alternative. Microbial biosensors are of particular interest for environmental monitoring due to their stability, wide range of analytes, and the ability to report on physiological toxicity.4 However, high salinities pose stress on the cellular membrane of bacteria cells, and few microbes can survive in salinities higher than the ocean (~3.5% NaCl). Such salinities can frequently occur after a natural disaster, due to stagnant water and subsequent evaporative water loss, demonstrating a need for a halophilic microorganism that can report on toxic contaminants. A bacterium that has these characteristics was previously isolated for electroactivity and further evaluated for use in the microbial analysis of toxic pollutants applicable for a widescale screening process in high saline contamination events.5 The bacterium, Salinivibrio EAGSL, was found to tolerate from 0.1 M to 3 M NaCl and showed anode-respiring capability. The bacterium was isolated as a new strain based on 16s rRNA gene sequencing.6 Therefore bioinformatics was employed for sequencing and assembling the genome to discover traits for NaCl, heavy metal, and general environmental stress factors. Interestingly, bioinformatics analysis contributed to unveiling the mechanism of extracellular electron transfer in this bacterium. The strategies for arsenic analysis included a high throughput 96-well plate cytotoxicity assay and an electrochemical assay for steps towards an online hazardous contaminant detection system. The 96-well plate assay provided a screening method for ~50 samples at once, taking around 6 hours to detect concentrations of 75 μM arsenic. To overcome the need for sampling and analysis, an electrochemical method was also developed for continuous monitoring of toxic contaminants in high saline. The net result is a microbial cytotoxicity assay to evaluate the toxicity of contaminants in a high saline environment. Additionally, this study elucidated the endogenous electron mediation mechanism in this bacterium through bioinformatics and electrochemical characterization, in addition to performance with an exogenous monomeric mediation system for increased current output.

The Importance of Community Engagement and Research Translation within the NIEHS Superfund Research Program.

The National Institute of Environmental Health Sciences Superfund Research Program (SRP) funds university-based, solution-oriented research to understand how hazardous substances contribute to disease and how to prevent exposures to these hazardous substances. A unique aspect of the SRP is that, beyond the biomedical, environmental sciences, and engineering research projects, SRP-funded centers are required to include community engagement to build partnerships with affected communities and research translation to communicate and facilitate the use of research findings. The SRP views both as effective ways to inform and advance science for protection of public health. The purpose of community engagement within the centers is to ensure bidirectional communication between the researchers and the community, identify best practices and activities in community engagement for prevention and intervention activities, enhance knowledge, and support the needs of the communities impacted by hazardous waste sites. The SRP views research translation as communicating and facilitating the use of research findings emanating from the center in a manner most appropriate for their application and for the advancement of a center’s research objectives. The SRP has a strong history of seeking opportunities to work with communities and stakeholders, by translating and sharing research findings in an impactful and informative manner with long-lasting benefits to improve public health.

Insights from TSCA Reform: a Case for Identifying New Emerging Contaminants

Federal and state environmental agencies regulate chemicals under a variety of environmental laws. The Lautenberg Chemical Safety for the 21st Century Act (LCSA) amended the Toxic Substances Control Act (TSCA) in 2016, and this update provides a mechanism by which the U.S. Environmental Protection Agency (USEPA) can regulate chemicals used by industry in order to prevent or limit exposures to chemicals. In particular, TSCA requires USEPA to assess the risk of injury to human health or the environment from exposure to chemicals identified as active. USEPA is currently assessing 10 chemicals and recently identified another 20 high priority and 20 low priority chemicals for evaluation. These risk evaluations, which may reflect new toxicological data, may identify new dose-response factors that change our understanding of the toxicity of many chemicals. This could result in either restrictions to chemical use, new cleanup standards, or more stringent cleanup standards. In this article, the authors review the process for identifying high priority chemicals and make predictions for the next set of emerging chemicals. Regulation of these chemicals could lead to a requirement for process changes as well as identify additional chemicals for evaluation at hazardous waste sites.

Communicating the environmental health risk assessment process: formative evaluation and increasing comprehension through visual design

The environmental health risk assessment process informs clean-up activities at hazardous waste sites. Ensuring this process is accessible and transparent to communities is crucial for environmental health literacy initiatives. The goals of this project were to develop plain language and effective visuals that can be used when communicating the risk assessment process and methods used to predict excess cancer risk(s) due to environmental exposures. In this study, a community factsheet entitled, “Understanding Environmental Health Risk Assessment” was developed and a participatory design and formative evaluation approach was implemented with a set of representative users (n = 11). Community members living in the vicinity of two Arizona hazardous waste sites as well as three public health professionals/researchers were asked to evaluate the functionality and accessibility of the factsheet, particularly the graphics and whether the text was written in plain language. Participant responses revealed the following major findings: 1) form follows function, 2) graphic elements should outweigh text, 3) line of sight and layout is critical to information accessibility, 4) color coding dramatically aids the reader, 5) content should be strategically grouped, 6) concepts per figure should be minimized to ensure comprehension, 7) interactive content is preferred over static content, and 8) communication efforts need to interweave new information with the targeted audience's past and current environmental health understandings to aid in their ability to retain new concepts. Based on participant feedback, new and improved layout decisions, infographics and accompanying text were designed and prepared. This research demonstrates the need and importance of participatory design, information design prototyping, formative evaluation, and a cultural model of risk communication.

Abstract 5043: Pre-diagnostic blood levels of organochlorines and risk of non-Hodgkin lymphoma in three population-based cohorts in China and Singapore

Abstract Background: Organochlorines (OCs) are environmentally persistent compounds that have been extensively used as pesticides and for other industrial applications. Residues of OCs have been detected at hazardous waste sites and in various environmental media worldwide and serum levels of OCs continue to be detectable in the general population. Specific OCs have been associated with non-Hodgkin lymphoma (NHL) risk with varying degrees of evidence. These associations have not been evaluated in Asia, where the exposure patterns of substantially high levels of certain OC pesticides and lower levels of polychlorinated biphenyls (PCBs) are different from Western populations. China accounted for nearly 20% of the worldwide production of dichlorodiphenyltrichloroethane (DDT) through 1983 when it was restricted, and historical usage of hexachlorocyclohexane (HCH) in China has been among the highest in the world. Methods: We evaluated the risk of NHL in relation to pre-diagnostic blood levels of five OC pesticides/metabolites (hexachlorobenzene, β-HCH, oxychlordane, trans-nonachlor, and p,p’-DDE, the primary metabolite of DDT) and four PCB congeners (118, 138-158, 153, 180) in a case-control study of 167 NHL cases and 167 controls matched on age, sex, and blood collection date. The study was nested within three population-based cohorts of Chinese men and women in Shanghai and Singapore. Associations between lipid-adjusted OC concentrations and NHL risk were analyzed using conditional logistic regression. Results: Median levels of p,p’-DDE and β-HCH were up to 12 and 65 times higher, respectively, in Shanghai (blood collected between 1986-2000) compared to reported levels in population-based cohorts in the United States (CLUE; Nurse’s Health Study) and Norway (Janus) with blood collected between 1972-1990. Median levels of p,p’-DDE and β-HCH were more comparable in Singapore (blood collected between 2000-2004) relative to the Western cohorts (1-2 fold concentration differences). Levels of β-HCH were associated with increased risk of overall NHL (3rd vs. 1st tertile OR=1.78, 95%CI=0.98-3.23; ptrend =0.049) in the pooled analysis of three cohorts. No significant associations were observed for other OCs and NHL risk, including for p,p’-DDE. Results for β-HCH and p,p’-DDE were consistent across cohorts. Discussion: Associations between β-HCH and NHL risk have not been consistent in studies of Western populations. Our findings provide the first evidence suggesting associations between blood levels of β-HCH and NHL risk in a population in Asia that experienced far higher exposures. Although there is limited evidence that DDT (IARC Group 2A) is associated with NHL based on studies in Western populations, our findings among Asians, who had higher p,p’-DDE levels than reported in the general population in the West, do not support an association with environmental exposure. Citation Format: Bryan A. Bassig, Xiao-Ou Shu, Andreas Sjodin, Woon-Puay Koh, Yu-Tang Gao, Jennifer Adams-Haduch, Mark Davis, Renwei Wang, Yong-Bing Xiang, Mark Purdue, Bu-Tian Ji, Gong Yang, Richard Jones, H. Dean Hosgood, Wei Jie Seow, Wei Hu, Wei Zheng, Jian-Min Yuan, Qing Lan, Nathaniel Rothman. Pre-diagnostic blood levels of organochlorines and risk of non-Hodgkin lymphoma in three population-based cohorts in China and Singapore [abstract]. In: Proceedings of the American Association for Cancer Research Annual Meeting 2019; 2019 Mar 29-Apr 3; Atlanta, GA. Philadelphia (PA): AACR; Cancer Res 2019;79(13 Suppl):Abstract nr 5043.

Cadmium in Human Diseases: It's More than Just a Mere Metal.

Cadmium (Cd), poisoning has been reported from all around the World, causing many deaths annually. Cd is a toxic heavy metal, and is widely present in environment. It has been reported that chronicCd exposure is associated with kidney disease, osteoporosis, cardiovascular diseases and cancer. Smoking causes exposure to significantly higher Cd levels in humans. Tobacco smoke transports Cd into the lungs. Blood then transport it to the rest of the body where it increases effects by potentiating Cd that is already present from Cd-rich food. Other high exposures of Cd can occur with people, who live near hazardous waste sites, or factories that release Cd into the air and people who work in the metal refinery industry. Breathing of Cd can severely damage the lungs and may even cause death. Multiple studies have shown an association between environmental exposure to hazardous chemicals including toxic metals and obesity, diabetes, and metabolic syndrome. At the same time, the existing data on the impact of Cd exposure on obesity and diabetes are contradictory. On the converse, results of epidemiologic studies linking Cd exposure and Osteoporosis, overweight or obesity are far less consistent and even conflicting, also depending on differences in exposure levels. In turn, laboratory studies demonstrated that Cd adversely affects adipose tissue physiopathology through several mechanisms, thus contributing to increased insulin resistance and enhancing diabetes. However, intimate biological mechanisms linking Cd exposure with human diseases are still to be adequately investigated. Therefore, the aim of the present review was to explore the impact of Cd exposure and status on the risk of Cd in human diseases.

Containment of Sources of Groundwater Contamination: Analysis of Mass Fluxes.

Cutoff walls and liners are used frequently as barriers to isolate contaminants at both controlled and uncontrolled hazardous waste sites. Neville and Andrews (2006) presented a containment criterion for contaminant isolation by a barrier. The analysis of Neville and Andrews (2006) yields the inward Darcy flux that balances the diffusive mass flux from the source so that the net mass flux is zero. A requirement of zero net mass flux may not be achievable in all situations. The analysis developed by Neville and Andrews (2006) is extended to develop straightforward expressions for the long-term mass fluxes across a barrier for any conditions. In cases where it may not be possible to satisfy a criterion of zero net mass flux, the results from an exact solution for transient solute transport are used to show how the mass fluxes evolve to their long-term values.

Preliminary assessment of exposure to persistent organic pollutants among pregnant women in Puerto Rico.

Puerto Rico has over 200 hazardous waste sites, as well as higher rates of several adverse health outcomes compared to the mainland US. In response to concerns of potential links between environmental contaminant exposure and preterm birth, the Puerto Rico Testsite for Exploring Contamination Threats (PROTECT) birth cohort was formed. Biomarkers of exposure for several contaminants have been found to be elevated in this cohort compared to women of child-bearing age in the National Health and Nutrition Examination Survey (NHANES). However, exposure to persistent organic pollutants (POPs) has not been evaluated. In this preliminary analysis, we measured four classes of POPs, including perfluoroalkyl substances (PFASs), polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs), and several persistent pesticides in serum samples collected at 16-20 weeks gestation from the first 48 women enrolled in PROTECT. We performed descriptive analyses for each analyte, assessed correlations between analytes using Spearman correlations, and compared serum levels in PROTECT women to levels in NHANES women aged 18-40. Several PFASs were detected in 96-100% of samples, with moderate to strong correlations between most PFASs (range r = 0.44-0.88). BDE47, BDE153, PCB 138-158, PCB153 and p,p'-dichlorodiphenyldichloroethene (p,p'-DDE) were detected in the majority of samples, with strong correlations between PCBs and p,p'-DDE (range r = 0.59-0.74). The median concentration for each analyte was lower than, sometimes by a factor of 4 (e.g. BDE47, p,p'-DDE), the median concentration reported in NHANES women aged 18-40. Although participants in the ongoing PROTECT birth cohort have higher exposure to many environmental contaminants, this preliminary study suggests that they have lower exposure to several POPS, specifically PCBs, OCPs, PFASs, and PBDEs.

Nutrition and Environmental Pollution Extension Curriculum Improved Diet-Related Behaviors and Environmental Health Literacy.

Kentucky experiences some of the nation’s worst health outcomes related to obesity, diabetes, high blood pressure, and other age-related chronic diseases linked with oxidative stress and inflammation, which in turn are associated with poor diet, lack of physical activity, and exposure to certain environmental pollutants. In the Commonwealth, deteriorating infrastructure, inappropriate waste disposal, and potential occupational injury related to mining, agriculture, and other regionally important industries exacerbate the need for residents to have basic knowledge of potential environmental health threats. Unfortunately, community-level understanding of the complex connections between environmental exposures and health is limited, with many Kentuckians unaware that the Commonwealth is home to 13 hazardous waste sites included in the United States Environmental Protection Agency Superfund National Priorities List (NPL). The NPL highlights priority sites for long-term remedial action to reduce environmental contaminants. To enhance the understanding of environmental health and protective actions, the University of Kentucky Superfund Research Center Community Engagement Core developed a 9-lesson extension curriculum “Body Balance: Protect Your Body from Pollution with a Healthy Lifestyle” (Body Balance) and partnered with Kentucky’s Family and Consumer Sciences (FCS) Cooperative Extension Service to pilot the curriculum in Kentucky communities. FCS agents in 4 Kentucky counties delivered the Body Balance pilot study (18-31 participants per lesson). Pre- and post-lesson questionnaires revealed increased knowledge and awareness of the effects of environmental pollution on health and the protective role of dietary strategies. Focus group participants (n = 18) self-reported positive behavior changes because of increases in knowledge and leadership from their FCS agent. The Body Balance curriculum appeared to be a promising mechanism for raising environmental health and diet knowledge, as well as for promoting positive behavior changes among white, middle/older-aged women in rural Kentucky communities.

Birth defects in Tarnaveni area, Romania - preliminary study results.

Background and aimsIn the development of any human body, defects may occur, resulting in the occurrence of congenital malformations, also referred to as birth defects. The aim of this preliminary study was to assess the prevalence of birth defects registered during a period of 5 years in Tarnaveni area. As Tarnaveni is located in close proximity to a former chemical plant, a recognized hazardous waste site, we conducted this pilot study to assess the prevalence of birth defects, in order to evaluate the need for a more comprehensive investigation of a potential relation between the exposure to toxic metals contaminating the environmental media as a result of the past industrial activities, and the prevalence of the birth defects in this area.MethodsWe abstracted birth information (gestational age at delivery (GA), birth weight (BW), birth length (BL), head circumference (HC), and major structural birth defects), from medical records at “Dr. Gheorghe Marinescu“ Tarnaveni Municipal Hospital, of the 2010–2014 period. We expressed BW as Z-scores relative to expected mean values at each gestational age for a reference population, calculated the ponderal index, and determined the 5 years birth defects prevalence among live births during the study interval.ResultsThe 5 years (2010–2014) prevalence of birth defects, was 3.3% (95% confidence interval (CI): 2.47, 4.09). There were n = 163 (8.7%) preterm deliveries (less than 37 weeks of gestation at delivery), mean birth weight was 3108.3 g (standard deviation (SD) = 517.1), ranging from 450–4600 g, and n = 187 (10%) were low birth weight (LBW) (less than 2500 g). The ponderal index was 2.2 g/cm3 on average (SD = 0.5), with range 1.2–20.7 g/cm3.ConclusionsWhile preliminary, our data show a 5 years (2010–2014) prevalence of major structural birth defects among newborns from Tarnaveni area of 3.3%. These pilot results indicate the need for a more comprehensive investigation of a potential relation between the exposure to toxic metals contaminating the environmental media as a result of the past industrial activities and the prevalence of the birth defects in Tarnaveni area.

Resilient remediation: Addressing extreme weather and climate change, creating community value

AbstractRecent devastating hurricanes demonstrated that extreme weather and climate change can jeopardize contaminated land remediation and harm public health and the environment. Since early 2016, the Sustainable Remediation Forum (SURF) has led research and organized knowledge exchanges to examine (1) the impacts of climate change and extreme weather events on hazardous waste sites, and (2) how we can mitigate these impacts and create value for communities. The SURF team found that climate change and extreme weather events can undermine the effectiveness of the approved site remediation, and can also affect contaminant toxicity, exposure, organism sensitivity, fate and transport, long‐term operations, management, and stewardship of remediation sites. Further, failure to consider social vulnerability to climate change could compromise remediation and adaptation strategies. SURF's recommendations for resilient remediation build on resources and drivers from state, national, and international sources, and marry the practices of sustainable remediation and climate change adaptation. They outline both general principles and site‐specific protocols and provide global examples of mitigation and adaptation strategies. Opportunities for synergy include vulnerability assessments that benefit and build on established hazardous waste management law, policy, and practices. SURF's recommendations can guide owners and project managers in developing a site resiliency strategy. Resilient remediation can help expedite cleanup and redevelopment, decrease public health risks, and create jobs, parks, wetlands, and resilient energy sources. Resilient remediation and redevelopment can also positively contribute to achieving international goals for sustainable land management, climate action, clean energy, and sustainable cities.

Effect of dose and exposure protocol on the toxicokinetics and first-pass elimination of trichloroethylene and 1,1,1-trichloroethane

Trichloroethylene (TCE) and 1,1,1-trichloroethane (TRI) are frequent contaminants of drinking water and of groundwater at hazardous waste sites. There is relatively little information on the target organ deposition of TRI, despite its ingestion and common occurrence in humans. An important aim of the study was to delineate and contrast the toxicokinetics (TK) and bioavailability (F) of TRI and its well metabolized congener, TCE. Blood profiles were obtained from male Sprague-Dawley rats given aqueous emulsions of 6 or 48 mg TRI/kg and 10 or 50 mg TCE/kg as an oral bolus (po) or by gastric infusion (gi) over 2 h. TCE exhibited nonlinear TK, with a disproportionate increase in AUC and decrease in clearance and F with increase in dose. TRI exhibited linear TK. F did not vary significantly with TRI dose or dosage regimen. F values were substantially higher for TRI than for the respective TCE groups. TRI was distributed widely to tissues of rats gavaged with 6 mg TRI/kg, with accumulation in fat. This experiment yielded tissue uptake and elimination profiles and in vivo tissue:blood partition coefficients (PCs). Finally, additional rats were given 10 mg/kg of TCE and TRI po, ia and iv, so that first-pass hepatic (FPh) and pulmonary (FPp) elimination could be measured directly. Total and FPh elimination of TCE exceeded that of TRI. TRI, with its higher air:blood PC, exhibited the higher FPp. TCE and TRI, despite several common physical and chemical properties resulting in similar absorption and systemic distribution, displayed dissimilar dosage and dose rate effects on their TK.

Assessment of the experimental conditions affecting natural oxidant demand of soil by permanganate

Excess oxidant requirements are commonly observed during field applications of in situ chemical oxidation by permanganate for the remediation of groundwater. This excess oxidant, generally referred to as natural or soil oxidant demand, is a direct result of organic matter and other naturally occurring reduced species present in the subsurface. Since site conditions vary widely, laboratory scale experiments are often used to determine the natural oxidant demand of soil at hazardous waste sites. Though many researchers have reported values in the literature, experimental conditions often go unreported and few take these factors into consideration. This study provides a broader perspective of the issues and concerns related to determining the permanganate natural oxidant demand of soil while evaluating the effects that initial oxidant concentration, soil to water ratio, and mixing have on the rate and extent of permanganate consumption. It was found that mixing conditions significantly influenced the kinetic expression of permanganate natural oxidant demand while soil to water ratios were not shown to have a significant effect as long as initial permanganate concentrations were sufficient to overcome the oxidant demand of the soil (i.e., were not limiting).