Hazard Index Research Articles

Occurrence, non-carcinogenic and carcinogenic risk assessment of trace elements in rainwater in the vicinity of a cement factory in northeastern Nigeria

Rapid industrialization and urbanization result in atmospheric pollution with trace elements precipitated and deposited by rain, affecting human health. This study determined the concentrations and non-carcinogenic and carcinogenic risks associated with trace elements in rainwater in the vicinity of the Ashaka cement factory. Samples were collected using a bulk sampler fitted with a high-density polythene funnel. A total of 140 samples were collected in 2020 and analyzed for 15 trace elements using ICP-OES. Multivariate analysis was used to identify the sources of the rainwater trace elements. The results show that the abundance of trace elements in the collected samples was in the following order: Fe > Sb > Cu > Ba > V > Sc > Sr > Mn > Zn > Ti > Hg > Al > Mo > Co. Crustal enrichment factors (EFc) indicated that the samples were extremely enriched with Hg, Sb, Cu, and Mo, moderately enriched with Zn, Ba, V, Co, Sr, Cr, and Sc, and unenriched with Fe, Mn, Ti, and Al. Chronic daily intake (CDI) for both the ingestion and dermal pathways was in the order Fe > Cu > Ba > Cr > V > Mn > Zn > Hg > Mo. The hazard index (HI) was > 1 through the ingestion pathway, indicating a likely non-carcinogenic advertising effect. Similarly, the carcinogenic risk (CR) exceeded the (1.0 × 10–4—1.0 × 10–4) acceptable limit for children and adults, indicating the likely development of cancer among consumers. This revealed that the elements present in rainwater are anthropogenic and are brought about by cement production.

Assessment of heavy metals concentration and health hazard indices in soil and plants from Kokona Local Government Area of Nasarawa State, Nigeria

Human dependence, on the plants grown on soil and the threat posed by contaminated soil to the ecosystem and general public has become a source of concern. The health risks caused by heavy metals concentration to the study area were evaluated. Fifteen (15) plant samples and soil samples each from the study area were collected and analyzed using an Energy Dispersive X-ray Fluorescence Spectroscopy (EDXRF) for Lead (Pb), Cadmium (Cd), Chromium (Cr), Nickel (Ni), Copper (Cu), and Zinc (Zn). The Measured concentrations of these heavy metals were in the order of Cd>Ni>Cu>Zn>Pb>Cr for the plant samples and Cr>Cd>Ni>Cu>Pb for soil samples with Cd and Cr as the highest contributors to cancer risk in term of the carcinogenic risk estimate. The Health Hazard Index value for all pathways were found to be 7.34 x 10-1 making non-carcinogenic risk component less significant to the adult population and in case of children, the Hazard Index value was 1.21, a value greater than unity (1), which present a severe non-carcinogenic risk component to children living in the study area. The carcinogenic risk was found to be 8.68 x 10-6 implying that 1 person in every 5882 adults may be affected and 1 in 2725 children may be affected (9.6 x 10-5) These carcinogenic risk values were both higher than acceptable values.

Assessment of transboundary macro-litter on the remote island of Andaman and Nicobar: Unveiling the governing factors and risk assessment

The increasing occurrence of mismanaged plastic litter along India's coastline and the ominous challenges it poses to biodiversity and ecosystem health is a growing environmental concern. To address this issue, we comprehensively investigated the abundance, composition, and probable sources of marine litter on North Cinque Island, a remote uninhabited island in the Andaman and Nicobar archipelago, Bay of Bengal. This island is a designated wildlife sanctuary and serves as an important nesting site for Green, Hawksbill and Leatherback turtles. A total of 6227 litter items were enumerated, with an average concentration of 0.12 items/m2, representing 20 diverse litter types, with plastic dominating the litter composition (86 %). The cleanliness and environmental hazards of the coast due to the litter were assessed using different indices such as the Clean Coast Index (CCI), Plastic Accumulation Index (PAI), Hazardous Item Index (HII), and Clean Environment Index (CEI). CCI indicates the moderately clean-to-clean status of the surveyed sites. PAI points to low to moderate accumulation of plastic litter. HII of all five coasts fell in category II, suggesting a moderate abundance of hazardous items that can inflict injuries to the foraging turtle and their hatchlings. The CEI articulates the moderately clean to very clean status of the sites. Litter brand audit suggests a considerable amount of stranded litter on the coasts was transboundary and originated from six Indian Ocean Rim Countries (IORC), namely Thailand, Myanmar, Malaysia, Indonesia, Sri Lanka, and UAE. Joint solid waste management by the IORC is the need of the hour to avert litter accumulation on the pristine, remote islands.

Assessment of the Drought Risk in Constanta County, Romania

Drought poses a significant risk in many parts of the world, especially in regions reliant on agriculture. Evaluating this risk is an essential step in preventing and reducing its impact. In this context, we assess the drought intensity at six sites in Constanța County (Romania) using the de Martonne aridity index. The risk of aridity and vulnerability to drought were evaluated by the Drought Hazard Index (DHI) and Drought Risk Index (DRI), computed based on the Standardized Precipitation Index (SPI). The de Martonne index indicates a variation between the slightly arid and semi-arid climates for Adamclisi station, with periodic changes from semi-arid to arid. At Cernavodă station, we notice a passage from an arid period towards a moderately humid one (in 2005), followed by a movement in the opposite direction to the limit of the arid zone (in 2011), and a return inside the “limits” of the semi-arid to moderately arid climate. A similar variation for 2000–2018 is noticed at Medgidia, Hârșova, and Mangalia. DRI classifies two stations in the low risk to drought category and one in the moderate risk to drought class. The other two locations experience a high or very high risk of drought. The drought intensities varied in the intervals 0.503–1.109 at Constanța, 0.473–1.363 at Mangalia, 0.511–1.493 at Adamclisi, 0.438–1.602 at Hârșova, 0.307–1.687 at Medgidia, and 0.463–1.307 at Cernavodă, and the prolonged drought periods were over 99 months at all stations.

Nitrate Content in Root, Tuber, and Leafy Vegetables in Wet Markets in Hanoi: A Health Risk Assessment

Nitrate (NO3–) is a natural compound occurring in foods, especially plant produces, and are also used as additives in industrially processed foods. This study aims to assessing the nitrate contents and health risk in root, tuber, and leafy vegetables in several wet markets in Hanoi. The results showed that the mean nitrate concentration in root and tuber vegetables, herbs and leafy vegetables ranged from 59 to 1118 mg/kg, from 580 to 1204 mg/kg, and from 122 to 3600 mg/kg, respectively. NO3– content in some vegetables at the local market and supermarket were from 1.2 (green beans) to 2.4 times (cucumber) and from 1.4 (long wax gourd) to 3.7 times (radish) higher than World Health Organization (WHO) standards, respectively. The risk assessment of the Estimated Daily Intake (EDI) results shows that the vegetable samples was 23% and 61% in the acceptable value according to WHO for children and adults, respectively. The Hazard Index (HI) shows that, the HI values of nitrate for all samples except for celery were < 1, indicating that health risks for adults associated with nitrate exposure were not significant. On the contrary, 70% of vegetable samples had HI > 1, suggesting adverse effects on children health that consume these vegetables.

Human health risk assessment of metal contamination in cereals and pulses in the mica mining areas of Jharkhand, India

This study was carried to investigate the contamination levels of heavy in food crops (rice, wheat, maize, and pulses) grown in the vicinity of the mica mine in Jharkhand, India. Except for Pb and Zn in select places, the metal concentrations in the food crops were below the maximum allowed levels for food in India. The principal component analysis identified three components that accounted for 71.3 % of the variability in the data. The components that were retrieved indicated that soil, irrigation water, and air dust deposition could be the sources of metals in the food crops. The estimated daily intake (EDI) and target hazard quotient (THQ) of food crop consumption were used to highlight the potential health concerns associated with metal exposure. In several samples, local individuals' daily intakes of Pb was greater than the WHO's recommended daily intakes of these heavy metals. Taking into account the geometric mean of metal concentrations in food crops samples from the, the hazard index (HI) for the consumers was 10.28 which is far above unity. Pb, Co, and As were the primary contributors to the potential non-carcinogenic risk. The HI ranged from 7.22 to 18.29 across different locations, indicating a significant health risk to the consumers of locally grown food crops in the vicinity of the mica mining areas.

Assessment of natural radioactivity levels in rice samples and their implications for radiological protection

ABSTRACT This study investigates the levels of natural and artificial radioactivity in rice samples collected from various local markets in Islamabad, Pakistan. The 226Ra, 232Th, and 40K activity concentrations were measured through gamma-ray spectrometry with a NaI(Tl) detector. The average activity concentrations were 1.67 ± 1.19 Bq kg−1 for 226Ra, 3.31 ± 1.83 Bq kg−1 for 232Th, and 88.51 ± 11.65 Bq kg−1 for 40K. Calculated radium equivalent (Raeq) values ranged from 7.35 to 18.08 Bq kg−1, with a mean value of 11.11 Bq kg−1, all below the permissible maximum of 370 Bq kg−1. The absorbed dose rates ranged from 6.85 to 16.39 nGy h−1, with an average of 10.64 nGy h−1, falling below the acceptable limit of 51 nGy h−1. The outdoor and indoor radiation hazard indices (Hex and Hin) had mean values of 0.03, both below the threshold value of one. The external and internal hazard indices (Iγ and Iα ) were both 0.088, also below the critical value of one. The excess lifetime cancer risk (ELCR) ranged from 0.28 to 0.11, with a mean value of 0.18, which is less than the critical value of one. Overall, the radioactivity levels in the analyzed rice samples are within the acceptable limits set by the International Commission on Radiological Protection and are below global averages. These results offer important insights into the radiological safety of rice consumption in the study area.

Quantification and characterization of municipal solid waste at aler dumpsite, Lira City, Uganda: Assessing pollution levels and health risks

Managing municipal solid waste (MSW) in urban areas of developing countries is a significant challenge due to rapid urbanization and inadequate infrastructure. This study aims to quantify the MSW at Aler dumpsite in Lira City, Uganda, and assess the associated environmental and health risks. Our findings revealed a daily dumping rate of 7.38 tons, predominantly organic waste. Leachate from the site exceeded WHO limits for nutrients and heavy metals, with exceptionally high amounts of cadmium (Cd) found in soil (4.8 mg/kg) and vegetables. The water quality in nearby streams was poor, rendering it unfit for consumption due to elevated ion and nutrient levels. Health risk assessments indicated significant non-carcinogenic risks from heavy metal ingestion, with a hazard index (HI) of 4.6 for adults and 9.6 for children. While dermal exposure risks were generally low, children were at risk from stream 1 (HQderm = 1.165). Vegetable analysis revealed levels of lead (Pb), cadmium (Cd), zinc (Zn), and nickel (Ni) above safe doses, posing significant non-carcinogenic risks. To address these issues, we recommend increasing public awareness to avoid consuming water and vegetables from areas around the dump site. Additionally, we suggest that the responsible authorities improve MSW management by constructing sanitary landfills to minimize water, soil, and plant pollution from landfill leachate.

Evaluation of radioactivity levels and hazard indices of Th-232, Ra-226 and K-40 in sediment and water samples of Lake Victoria, Jinja, Uganda

This study evaluates the levels of natural radioactivity in sediment and water samples from Lake Victoria in Jinja, Uganda, with a focus on the radionuclides potassium-40 (40 K), radium-226 (226Ra), and thorium-232 (232Th). We investigated four distinct zones around the lake: fishing (Zone A), farming (Zone B), domestic/livestock (Zone C), and a control zone (Zone D). A total of 15 sediment samples and 15 water samples were collected and analyzed. Sediment samples were obtained using a gravity corer, with a maximum penetration depth of 50 cm. 40 K ranged from 170.479 to 524.883 Bqkg−1 across all zones, 226Ra ranges from 1.51 to 56.78 Bqkg−1 across all zones, and 232Th ranges from 18.18 to 73.10 Bqkg−1 across all zones. 40 K concentrations were highest in the farming zone, likely due to the use of nitrogen, phosphorus, and potassium (NPK) fertilizers. 226Ra and 232Th levels were also elevated in the farming zone, suggesting potential contributions from phosphate fertilizers. Absorbed dose rates varied across the zones, ranging from 28.33 to 58.17 nGyh-1. The measured absorbed dose rates across all zones were within the global average of 59 nGyh−1. The effective annual dose rate ranged from 0.35 to 0.91 mSvy−1 across all zones. Effective annual dose rates did not exceed the United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) recommended limit of 1 mSv y−1, indicating low risks to public health from sediment radioactivity. The external index was below the safety threshold, suggesting minimal health risks. In water samples, gross alpha and beta activity concentrations were analyzed. Zone B had the highest average alpha activity concentration (0.64 BqL−1) and beta activity concentration (0.72 BqL−1), while Zone A had the lowest for both alpha (0.16 BqL−1) and beta (0.25 BqL−1) activity concentrations. Gross beta activity was generally higher than gross alpha activity, reflecting potential anthropogenic influences. Most water samples were within the UNSCEAR recommended limits for drinking water quality, except in areas affected by agricultural runoff. This study demonstrates that while the sediments of Lake Victoria in Jinja, Uganda, exhibit varying levels of naturally occurring radionuclides influenced by farming practices, the overall radiation exposure remains within safe limits. Continuous monitoring and regulatory measures are essential to maintain these safety levels and mitigate potential risks from increasing agricultural activities.

Ecological and Human Health Risk Assessment Based on Stream Sediments from Coastal Oecusse (Timor)

Timor Island is located in a geologically complex region strongly affected by the collision of the Australian margin with the Banda volcanic arc. In Oecusse, an enclave of East Timor in the western part of Timor, crop out several lithological units of the Banda Terrane that are associated with the obduction of oceanic crust and upper mantle on the Australian continental crust. This study reports the geochemistry of stream sediments from the coastal region of the Oecusse enclave, where the Banda Terrane is best represented, employing statistical analyses to discern the sources of metal(oid)s and assessing ecological and health risks. Arsenic, Cr, and Ni are the elements with higher potential ecological risk factors. The potential ecological risk index (PERI), which combines single indexes of ecological risk factors for multiple elements, is very high in a stream sourced by the Lolotoi-Mutis Complex. Significant risks for human health were found for As (sourced by the Lolotoi-Multis Metamorphic Complex and basalts of the Barique Formation), Mn (sourced by the Maubisse and Barique formations), and V (sourced by the Manamas Formation). The highest values of hazard index (HI), however, were determined with Cr, in particular for children (HI higher than 10 in 12 sediments sourced by ultramafic units and their covering sedimentary units). This investigation shows that high geogenic concentrations of several elements, particularly those derived from the oceanic crust and the upper mantle, raise significant cancer and non-carcinogenic risks.

Natural radioactivity and technological properties of kaolinized granite from the Motajica mine, Bosnia and Herzegovina

For the production of ceramic tiles, it is necessary to use high-quality and economical raw materials, which will optimize the properties of the final product and meet the prescribed standards. For this reason, it is necessary to examine the properties of each potential raw material. This paper examines radioactivity and technological properties of kaolinized granite from the Motajica mine, in Bosnia and Herzegovina. Chemical analysis, X-ray diffraction (XRD), and thermal analysis (DTA) were carried out. In order to examine the technological (ceramic) properties of this raw material, ignition tests of the composite obtained by introducing kaolinized granite (with a content of 25 %) into the standard factory series of ceramic tiles were conducted at four selected temperatures (1050, 1100, 1120, and 1150 ℃). Total linear shrinkage, flexural strength, and water absorption were determined for the produced biscuit. Using gamma spectrometry, the activity concentrations of radionuclides 226Ra, 232Th and, 40K were measured, and then the radiation risk for external exposure of workers in the industry was assessed using hazard indices and doses. The radiation risk from the use of manufactured unglazed ceramic tiles in houses was also assessed. Statistical analysis of radionuclides for 100 samples of kaolinized granite was performed using descriptive statistics and hierarchical cluster analysis (HCA). It was observed that the average values of 226Ra, 232Th, and 40K are above the average for building materials in the world and amount respectively to 122 Bq kg−1, 96 Bq kg−1, and 1068 Bq kg−1. All other obtained values indicate that it is a quality raw material that, despite having an increased content of radioactive elements compared to the world average, does not represent a radiological hazard for workers and people who stay indoors on an annual basis. The tested raw material satisfies all technological criteria for further use and can be considered a desirable ingredient of ceramic composites because it can partially or completely replace feldspar.

Spatial Distribution, Leaching Characteristics, and Ecological and Health Risk Assessment of Potential Toxic Elements in a Typical Open-Pit Iron Mine Along the Yangzi River

Potential toxic elements (PTEs) pollution in the soil of abandoned open-pit mines can lead to great ecological risk to the areas around the mining districts. This study selected a typical abandoned open-pit iron mine along the Yangzi River in southeast China to investigate the spatial distribution, leaching characteristics, and ecological and health risk of the soil PTEs (As, Pb, Cd, Ni, Cr, Cu, and Zn). Leaching tests and sequential extraction were applied to study the migration of PTEs under the condition of rainfall. Different risk assessment methods were used to analyze the pollution and ecological risk of PTEs. The contents of As and Cu exceeded the background value of the Chinese soil guideline, with average contents of 50.71 ± 1.59 and 197.47 ± 16.09, respectively. The leaching test and sequential extraction indicated that sites 8 and 9 posed the greatest risk of PTE migration. According to the map of the Nemerow integrated pollution index (NIPI), the pollution level of the middle bare area of the study area was the highest, and Cu possessed the highest pollution index (PI) of 3.92. The average geo-accumulation index (Igeo) of As and Cu was between 1 and 2, reaching the pollution level of moderately contaminated. The average potential ecological risk coefficient (Ei) of As was the highest, and the contributions of As, Cu, and Cd to the potential ecological risk of the whole study area were 46.7%, 29.7%, and 14.3%, respectively. The range of the hazard index (HI) and the range of the As carcinogenic risk (CRAs) of all the sampling sites for children were 1.30–3.94 and 2.19 × 10−4–7.20 × 10−4, and As accounted for more than 85% of the total noncarcinogenic risk, indicating that the comprehensive pollution of PTEs in the study area posed great carcinogenic and noncarcinogenic risks to children. This study can be a proper reference for the subsequent recovery methods and environmental management of the whole mining area.

Evaluation of selected minerals and health risk and proximate analysis of wasawasa (a street food)

This study was carried out to determine the proximate composition and the potential heavy metal health risk that may be associated with the consumption of wasawasa, a dish made from locally milled yam peels, by examining the presence of six metals (iron, nickel, chromium, sodium, and magnesium and potassium) in samples procured. Sixteen (16) samples of ready-to-eat wasawasa were collected from Aboabo, Manhyia, Sawaba, Asawase, Adenyase, and Ayigya in Kumasi, since these are the communities where wasawasa is mainly produced, sold, and consumed. The samples were digested with a nitric, perchloric, and sulfuric acid mixture and analyzed using a microwave plasma atomic emission spectrometer (Agilent 4210 MP-AES). The average concentrations of metals were Na (8506.88 mg/kg), Mg (222.63 mg/kg), Fe (84.45 mg/kg), Cr (2.31 mg/kg), K (1702.08 mg/kg, and Ni (1.12 mg/kg). Proximate analysis was used to determine Protein, fat, ash, moisture, and fiber content of the local wasawasa, which were found to be 15.667 %, 0.45 %, 1.00 %, 27.54 %, and 0.41 %, respectively. The hazard index of the heavy metals (Fe, Ni and Cr) for both adults and children were each greater than one, indicating the population is likely to experience non-carcinogenic effects from the consumption of wasawasa.

Pollution and health risk assessments related to heavy metals on three prominent beaches in Makkah Province, Kingdom of Saudi Arabia: Concerning levels of cadmium pollution.

Beach pollution can impact the health of people living in or visiting coastal areas. The primary goal of this research was to investigate the presence of heavy metal pollutants and associated health risks in three distinct coastal cities, Jeddah, Al-Lith, and Al-Qunfudhah, located along Saudi Arabia's Red Sea coast. Forty-three soil samples were collected from different locations, heavy metals including Fe, Zn, Mn, Cu, Cd, and Pb were isolated, and analyzed using inductively coupled plasma optical emission spectroscopy. Various metrics such as pollution indices (PI), integrated pollution indices (IPI), enrichment factors (EF), daily dose averages (ADD), hazard quotients (HQ), and hazard indices (HI), as well as principal component analysis (PCA) and cluster analysis were employed to evaluate the environmental impacts and health risks posed by these heavy metals. The results revealed that Fe, Pb, Cu, Mn, and Zn concentrations in beach zones were below their respective background levels, while concentrations of Cd exceeded corresponding background levels. PCA revealed the highest levels of Pb, Fe, and Mn on Al-Qundudah beach, while Cd and Cu were highest on Al-Lith beach, and Zn was highest on Jeddah beach. PI values highlighted extremely high levels of Cd pollution on all designated beaches. The findings provide a foundational basis for further investigations into health problems potentially related to Cd contamination, such as chronic kidney disease (CKD), osteomalacia, and osteoporosis.

Spatial distribution, ecological and human health risks of potentially toxic elements (PTEs) in river Ravi, Pakistan: A comprehensive study

Significant quantities of potentially toxic elements have been and are still being discharged into Pakistan's rivers through natural sources and anthropogenic activities. The present study provides a comprehensive study of potentially toxic element contamination in the water and sediment of the Ravi River, Pakistan. The research aims to examine the extent of pollution, its ecological risks, and the potential human health impacts through detailed geospatial analysis and statistical correlation. Water and sediment representative samples were taken and analyzed for potentially toxic elements, including Cobalt (Co), Cadmium (Cd), Zinc (Zn), Nickel (Ni), Arsenic (As), Chromium (Cr), Lead (Pb), Copper (Cu), and Manganese (Mn). Various pollution indices, such as the “Geo-accumulation Index (Igeo), Modified degree of Contamination (mCd), Nemerow comprehensive pollution index (Pt), Contamination factor (CF), Enrichment factor (EF), Pollution Load Index (PLI), and Potential Ecological Risk Index (PERI),” were calculated to determine the contamination levels and ecological risks. The results indicated significant spatial variability in metal concentrations, with higher levels observed in industrial and urban areas (near Lahore). Cd and As were identified as the most critical pollutants, exhibiting high Igeo, CF, EF, and PERI values. The PLI revealed that several regions along the river are heavily polluted. Pt shows high comprehensive pollution near Lahore and moderate to high pollution in surrounding areas. According to mCd, most of the study area, especially sampling points near Lahore, ranges between 8 and 16, indicating a high degree of pollution. The Human Health Risk (HHR) assessment, considering ingestion, inhalation, and dermal contact pathways, highlighted that children are particularly vulnerable, showing higher Hazard Quotient (HQ) and Hazard Index (HI) values for several metals. Correlation analysis revealed significant relationships between certain metals, suggesting common sources of contamination, likely from industrial discharges and urban runoff. The comprehensive mapping and statistical analysis underscore the urgent need for implementing effective pollution control measures to mitigate the risks posed by potentially toxic element contamination in the Ravi River. This study provides critical insights for policymakers and environmental managers to prioritize areas for remediation and to develop strategies to protect both ecological and human health in the region.

Bioaccumulation and Health Risk Assessment of Heavy Metals in Labeo rohita and Mystus seenghala from Jhelum River, Punjab, Pakistan

The bioaccumulation of trace elements and heavy metals in aquatic organisms is a critical environmental concern due to its potential impact on ecosystem health and human safety. This study investigated the level of trace elements and heavy metals bioaccumulation in Labeo rohita and Mystus seenghala from the River Jhelum in the district Khushab, Punjab, Pakistan. The concentration of calcium, magnesium, iron, nickel, copper, arsenic, cadmium, zinc, chromium, manganese, cobalt, and lead in the gills, liver, and muscle tissues of these fish was measured using inductively coupled plasma-mass spectrometry. Then, the extent of contamination and its possible health risks were assayed. Our findings indicate significant variations in the elemental and metal concentrations among different organs and between species, reflecting their diverse feeding habits and habitats. The health risk assessment based on the estimated daily intake, estimated weekly intake, maximum permissible intake, target hazard quotient, hazard index or total target hazard quotient, health risk index, and target cancer risk revealed potential risks to human consumers of these fish. This study emphasizes the need for continuous monitoring, as new data and insights are crucial for understanding and mitigating these risks. Strict regulatory measures are also necessary to safeguard public health and preserve the ecosystem of Jhelum River.

Risk assessments of microplastic exposure in bivalves living in the coral reefs of Vietnam

This study aimed to assess the presence of microplastics in bottom sediment and bivalve species, including Pinna bicolor, Atrina vexillum, Saccostrea sp., and Pinctada margaritifera, living in coral reefs on Vietnam's Southern coastal. The average microplastic abundance were 0.45 ± 0.13 items/g of wet soft tissue weight or 5.60 ± 1.49 items/individual in bivalve samples and 294 ± 43 items/kg dry weight of sediment samples. The fragment shape, size smaller than 100 μm, and polyethylene, polyamide, cellophane and polyethylene terephthalate were identified as the predominant constituents of the microplastics. The pollution load and potential ecological risk index of microplastics were at a minor level, whereas the polymer hazard index was at a high level. Overall, this study provides a basis for assessing the risks posed by microplastics in the marine ecosystems of Vietnam.

Metals in honey, cow’s milk and eggs in North-East Algeria and health risk

ABSTRACT Metal contamination of foodstuffs is a major public health challenge of increasing concern. The present study aimed to determine lead, cadmium and mercury in honey, cow’s milk and poultry eggs collected from the North-Eastern region of Algeria and to evaluate the health risks associated with their regular consumption. To this aim 30 samples of each foodstuff were analysed using ICP-MS. Among the quantified heavy metals, Pb was found at the highest level in both honey (0.752 ± 0.16 µg g−1) and poultry egg (0.988 ± 0.19 µg g−1) in the region of Skikda. The highest values of Cd (0.798 ± 0.12 µg g−1) and Hg (0.097 ± 0.02 µg g−1) were found in poultry eggs collected from the same region. For infants the Hazard Index was well above 1 in honey samples from all three locations, in cow’s milk collected from Mila and Skikda and in poultry eggs collected from Skikda.

ASSESSMENT OF THE LEVELS OF NATURAL RADIOACTIVITY AND THE POSSIBILITY OF RADIATION RISKS IN SOIL SAMPLES TAKEN FROM DIFFERENT LOCATIONS IN SOUTHERN ALMAZAR-ALKARAK, JORDAN

A wide study of environmental radioactivity levels in soil samples from Southern Almazar-Alkarak in Jordan was performed to develop a radiological map of the area. 15 soil samples were collected from different locations across the region and subjected to analysis using a high-purity germanium detector (HPGe). The study showed that the average levels of natural radionuclides 226Ra, 232Th, 238U and 40K were 34.5±0.98, 25.6±1.3, 32.2±3.7 and 278.5±15.7 Bq.kg−1, respectively. Also, to evaluate the radiological danger, the radium equivalent activity (Raeq) is calculated, absorbed gamma dose rate (D), annual effective dose equivalent (AEDE) and external hazard index (Hex), internal hazard index (Hin). The average values for these parameters were determined to be 92.5 Bq.kg−1, 43.0 nGy h−1, 52.7 µSv y−1 and 0.25Bq.kg−1, 0.34Bq.kg−1 respectively. The values of the gathered samples stay below the allowable limits. Consequently, the examined region does not present any radiation risk to the general population. Moreover, it has been discovered that there is no concentration of 137Cs radionuclide activity in the studied area.

Determination of concentration and risk assessment of toxic metals in the settled dust from school yards of Mashhad metropolis.

The present study aims to measure the values of metal pollutants in the dust of schools in Mashhad metropolis, determine the source of metal pollution, evaluate the degree of pollution, assess the health risk (carcinogenicity/non-carcinogenicity) and evaluate the potential ecological risk. For this purpose, after measuring the concentration of metals using an inductively coupled plasma-mass spectrometer, from various indices including Geoaccumulation Index (Igeo), Pollution Load Index (PLI), Contamination Factors (CF), Potential Ecological Risk Index (PERI), Enrichment Factor (EF), and Health Risk Indices such as Hazard Quotient (HQ), Hazard Index (HI), Carcinogenic Risk (CR) were used. The average concentrations of iron, arsenic, cadmium, chromium, copper, nickel, lead, vanadium and zinc (Fe, As, Cd, Cr, Cu, Ni, Pb, V and Zn) were 6361.50, 5.96, 0.59, 61.89, 37.13, 61.31, 28.93, 25.64 and 142.00µgg-1, respectively. Based on CF, PLI and Igeo indices, most of the findings for the studied elements were at the low pollution level. The results also showed that the most likely origin of the studied metals was anthropogenic sources. The results of PERI indices showed that potential ecological risk at only one of the collection sites. In contrast, a high ecological risk was obtained for Cd. Hazard Index values were below safe levels for all studied elements. CR levels for elements were also classified as negligible and acceptable or tolerable risk, although the highest CR value for Cr indicated possible harm to humans. The findings showed the need for more attention and continuous monitoring of the concentration of metals, especially chromium, to announce a possible warning and prevent their harmful effects. It should be noted that the present study is the first research with mentioned objectives in Mashhad city and also in Khorasan Razavi province.