This paper proposes a technique for decomposing the buckling solution of thin-walled members into pure deformation modes (global, distortional, local, or other), aiming at providing an insight into the buckling behavior of these members. The calculation of critical loads associated with a specific or combined deformation mode is performed constraining general finite element models. A general constraining procedure is presented, in which the critical load of any mode, combining different section deformation modes and different harmonic shape functions in the longitudinal direction, can be determined. Cases where all possible harmonic terms may be automatically considered are also described. Cross-section deformation modes are defined in the context of the constrained finite strip method (base vectors), and the proposed constraining procedure is implemented by means of relationships between degrees of freedom of the finite element mesh in commercial software. Calculation of combined buckling modes inherently makes it possible to quantify the participation of the considered modes, including along specific longitudinal segments of the member. Results from the analysis of a lipped channel member are presented to demonstrate the concepts and, later, the analysis of a member with a more complex cross-section and intermediate boundary conditions along length is detailed. A discussion on the base vectors chosen for the constraining method is presented. Finally, the potential of the proposed method is discussed.