Hard Component Research Articles

Raising the performances of copoly(ether-imide) films by structural design modulation towards energy storage applications

The present study aims to shed light onto the influence of structural design on the overall properties of a series of aliphatic–aromatic CN-based copoly(ether-imide)s, with emphasis on energy storage performance, with the support provided by selected benchmarks. To boost the energy storage capability of the free-standing films made therefrom, three molar ratios of a CN-aromatic hard segment and a Jeffamine-based soft component were used. Thus, through different chemical strategies and their synergism, the films morphology and their physico-chemical properties like wetting, optical, mechanical, thermal, dielectric and, particularly breakdown strength and energy storage were modulated. The results showed high thermal stability, single glass transition temperatures, good mechanical properties, and relative low dielectric constants of the copolymers. The absence of crystallization demonstrated the amorphous nature of the films due to the good interpenetration of soft and hard components, although some phase separations were observed in some copolymers with no clearly defined boundaries. Due to the balanced thermal stability, dielectric behavior, mechanical features, and film processing ability, these copoly(ether-imide)s display potential applications in high-temperature energy storage field, reaching breakdown strength and energy storage density values up to 459 kV/mm and 2.70 J/cm3, respectively.

Modeling the Energy-dependent Broadband Variability in the Black Hole Transient GX 339–4 Using AstroSat and NICER

We present a spectro-timing analysis of the black hole X-ray transient GX 339–4 using simultaneous observations from AstroSat and the Neutron Star Interior Composition Explorer (NICER) during the 2021 outburst period. The combined spectrum obtained from NICER, Large Area X-ray Proportional Counter and SXT data is effectively described by a model comprising a thermal disk component, hard Comptonization component, and reflection component with an edge. Our analysis of the AstroSat and NICER spectra indicates the source to be in a low/hard state, with a photon index of ∼1.64. The power density spectra obtained from both AstroSat and NICER observations exhibit two prominent broad features at 0.22 Hz and 2.94 Hz. We generated energy-dependent time lag and fractional root mean square (frms) at both frequencies in a broad energy range of 0.5–30 keV and found the presence of hard lags along with a decrease in variability at higher energy levels. Additionally, we discovered that the correlated variations in accretion rate, inner disk radius, coronal heating rate, and the scattering fraction, along with a delay between them, can explain the observed frms and lag spectra for both features.

X-ray spectropolarimetric characterization of GX 340+0 in the horizontal branch: A highly inclined source?

We report the first detection of X-ray polarization in the horizontal branch for as obtained by the Imaging X-ray Polarimetry Explorer ( A polarization degree of 4.3<!PCT!>pm 0.4<!PCT!> at a confidence level of 68<!PCT!> is obtained. This value agrees with the previous polarization measurements of Z-sources in the horizontal branch. The spectropolarimetric analysis, performed using a broadband spectral model obtained by and quasi-simultaneous observations, allowed us to constrain the polarization for the soft and hard spectral components that are typical of these sources. The polarization angle for the two components differs by sim This result can be explained by a misalignment of the NS rotation axis with respect to the accretion disk axis. We compared the results with the polarization that is expected in different models. Theoretical expectations for the polarization of the disk and the Comptonization components favor a higher orbital inclination for than 60 as expected for Cyg-like sources. This is in contrast with the results we report for the reflection component based on the broadband spectrum.

The Origin of Magnetofossil Coercivity Components: Constraints From Coupled Experimental Observations and Micromagnetic Calculations

AbstractBiogenic magnetite crystals produced by magnetotactic bacteria (MTB) and associated magnetofossils in sediments are characterized by variable morphologies, grain sizes, and chain structures. Magnetofossils are widely used in paleomagnetic and paleoenvironmental studies, but the complex magnetofossil shapes and particle arrangements significantly affect magnetic properties, hampering their magnetic detection and proxy interpretation. Here we perform coupled experimental and micromagnetic modeling analyses of typical magnetofossil‐rich sediments, where the effects of magnetofossil crystal forms and microstructures on magnetic properties can be quantitatively separated. Since the in situ magnetofossil chain structures in sediments remain poorly known, we compare results from magnetic measurements and micromagnetic simulations based on realistic magnetofossil shapes and grain size distributions. Our results suggest that bullet‐shaped magnetofossils certainly contribute to the biogenic hard (BH) coercivity component with a minor contribution from elongated prismatic particles, and collapsed equidimensional grains to the biogenic soft (BS) component. Micromagnetic simulations with different collapse models of bullet‐shaped magnetofossils produce variable FORC (first‐order reversal curve) central‐ridge contributions with similar coercivity distributions. Sensitivity test suggests that samples containing different forms of magnetofossils can produce the BH coercivity component if the proportion of the bullet‐shaped particles is more than ∼2%. Magnetofossil assemblages with a higher proportion of bullet‐shaped particles have higher coercivities, squareness ratios, and larger BH contents. Our data shed new light on understanding the origin of magnetofossil coercivity components and the in situ magnetofossil microstructures in sediments, which is widely useful for interpreting magnetofossil proxy signals in geological records.

New magnetic proxies to reveal source and bioavailability of heavy metals in contaminated soils

Environmental magnetism plays an important role in monitoring heavy metal pollution, but most studies are confined to indicating only the levels of heavy metals using magnetic parameters. This study established new magnetic proxies for accurately depicting the sources and bioavailability of heavy metals in contaminated soils. We observed different relationships between χ and SIRM in the soils contaminated by non-ferrous metal smelting compared to those polluted by coal combustion and steel smelting. Furthermore, we found that the soft magnetic components (IRMsoft) in the soils were mainly controlled by the non-ferrous metal smelting activities, while the hard magnetic components (HIRM) might be affected by the iron erosion. These new magnetic proxies enriched the source composition spectrum and improved the accuracy of the source apportionment analyses (principal component analysis and positive matrix factorization), yielding a result that was comparable to that by Pb isotope fingerprinting. We also found strong relationships between magnetic parameters (especially IRMsoft) and bioavailable fractions of heavy metals, indicating that magnetic measurement may be a powerful tool for monitoring the bioavailability of heavy metals. This study expands the application fields of magnetism in environmental science research.

Damage to a High Bypass Ratio Fan During Uas Ingestions

Abstract Foreign object ingestion into engines has been studied for many years, but the focus has been on soft bodies (i.e., birds, ice). Recently, there has been a dramatic increase of uncrewed aircraft systems (UAS) in the airspace that represent a new threat to aircraft engines due to key components like the motor, battery, and camera being composed of hard components. Due to the differences between hard bodies and soft bodies, studies are required to understand the new threat these UAS pose to aircraft. The objective of this study is to investigate the impact of various factors such as impact orientation, fan rotational speed, relative translational speed, and radial impact location on the damage caused to a representative fan assembly. This study aims to analyze the sensitivity of these factors and their influence on the overall damage to the fan. The ingestion simulations will use a representative fan assembly model and a UAS model that has been experimentally validated at the conditions of an ingestion. This work will identify critical parameters of the ingestion and then utilize them to anticipate the extent of damage that may arise during specific stages of a flight where an ingestion is most probable. Moreover, it also compares these cases with some known baseline cases, such as a fan blade out and bird ingestion of similar mass, to understand the likely severity compared to more studied common cases.

Assessment by finite element analysis modelling of tissue strains associated with the use of two different nasogastric tube securement devices.

Nasogastric tube use can lead to pressure injury. Some nasogastric tube securement devices (NG-SD) include hard plastic components. In the current study, we assessed the differences in strain profiles for two NG-SD, one with hard segments and one without hard segments, using finite element analysis (FEA) to measure strain and deformation occurring at the nasogastric tube-tissue interface. FEA in silico models of devices were based on device mechanical test data and clinically relevant placements. Peak strain values were determined by modelling different scenarios using Abaqus software whereby the tubing is moved during wear. The modelling showed peak strains ranging from 52% to 434% for the two NG-SD depending on the tubing placement and device type. Peak strain was always higher for the hard plastic device. Tissue strain energy was a minimum of 133.8 mJ for the NG-SD with no hard parts and a maximum of 311.6 mJ for the NG-SD with hard parts. This study provided evidence through in silico modelling that NG-SD without hard components may impart less strain and stress to tissues which may provide an option for tube securement that is less likely to cause medical device-related pressure injury.

Employing magnetic resonance histology for precision chronic limb-threatening ischemia treatment planning

ObjectiveRecent randomized controlled trials have demonstrated a notable prevalence of immediate technical failures in percutaneous vascular interventions (PVIs) for complex arterial lesions associated with chronic limb-threatening ischemia. Current imaging modalities present inherent limitations in identifying these lesions, making it challenging to determine the most suitable candidates for PVI. We present a novel preprocedural magnetic resonance imaging (MRI) histology protocol for identifying lesions that might present a higher rate of immediate and midterm PVI failure. MethodsWe enrolled 22 patients (13 females, average age 65.8 ± 9.72 years) scheduled for PVI were prospectively and underwent 3T MRI using ultrashort echo time and steady-state free precession contrasts to characterize target lesions before PVI. Lesions were scored as hard if >50% of the lumen was occluded by hard components (calcium/dense collagen) on MRI in the hardest cross-section. Two readers evaluated MRI datasets. Trans-Atlantic Inter-Society Consensus Document on Management of Peripheral Arterial Disease (TASC)/Global Limb Anatomic Staging System (GLASS)/Wound, Ischemia and Foot infection scoring was performed based on intraprocedural angiograms and chart review. The relationship between MRI scoring, TASC/GLASS scoring, and procedural outcomes was investigated using univariate analysis. Midterm follow-up (revascularization and amputation rates) was recorded at 3 and 6 months after the intervention. ResultsOur cohort of 22 patients yielded 40 target lesions. Five lesions were excluded (two for nondiagnostic image quality; three PVIs were ultimately diagnostic only). Six lesions (17%) were scored as hard. MRI-scored hard lesions had a higher proportion of immediate technical failure (hard vs soft 83% [5/6] vs 3% [1/29]; P < .001). Hard vs soft MRI scoring was the only factor significantly associated with immediate PVI technical success (P < .001), as opposed to TASC/GLASS scoring. Both at 3 months and 6 months after PVI, the reintervention rate was significantly higher among those lesions which were scored hard on MRI (3 months hard, 80% vs soft, 16% [P =.011]; 6 months hard, 80% vs soft, 27%; P = .047). ConclusionsMRI histology could be a valuable tool for optimizing PVI patient selection and treatment strategies.

Enhanced precision lapping techniques for fused quartz optical elements: Synergistic integration of mechanical and mechanochemical processes

Fused silica is a material of great importance in the field of precision optical equipment due to its excellent optical properties, e.g. photolithography, laser fusion devices, etc. However, the material's inherent hardness and brittleness render it a challenging material to process. Therefore, an enhanced precision lapping technique was proposed, i.e., a synergistic integration of mechanical and mechanochemical lapping processes. Firstly, a synergistic lapping tool with an outer layer of porous diamond abrasive and an inner layer of CeO2 abrasive was fabricated by hot press forming method. The reduction of layer thickness due to abrasion and detachment of the porous diamond abrasive layer was analyzed, and the lapping mechanism of porous diamond on fused silica materials was revealed. The surface creation mechanism of the CeO2 abrasive layer on fused silica material was analyzed by molecular dynamics simulation and the results were validated by enhanced precision lapping experiment. The results demonstrated that the surface atoms of fused silica are removed in a ‘remote disordered’ manner by conventional diamond abrasive grains, whereas the surface atoms of fused silica are removed in a ‘proximally ordered’ manner by the fine porous diamond abrasive grains through the micro-multi-flute cutting. Consequently, the grinding of a porous diamond abrasive layer can significantly reduce the processing damage, with the surface roughness of the lapping Ra reaching 199 nm. The lapping of CeO2 induces the formation of an oxygen bridge on the surface of fused silica, which then produces bending vibration. This is followed by the adsorption and diffusion of oxygen atoms, which form the -Ce-O-Si intermediate with the oxygen atoms shared with the fused silica. This process results in the formation of CeSiO3 and CaSiO3 compounds. The final surface quality with a surface roughness of Ra 21 nm was obtained by mechanochemical lapping of the cerium oxide abrasive layer. The single mechanical-mechanochemical composite ultra-precision lapping process provides technical support for the efficient and low-damage processing of hard and brittle components.

Microstructure and mechanical properties of cellular (Ti,M)(C,N)-based cermets fabricated by pre-granulation and subsequent vacuum sintering

Cellular (Ti,M)(C,N)-based cermets were fabricated through pre-granulation followed by vacuum sintering. In this study, (Ti,Mo)(C,N) and (Ti,W,Ta)(C,N) solid solutions were utilized as hard phase components in agglomerates. The effects of the (Ti,M)(C,N) powders on the microstructure and mechanical properties of cellular cermets were studied. Cermet A, incorporating (Ti,Mo)(C,N) in the agglomerates, exhibited a cellular microstructure with double-layered agglomerates distributed in the matrix. By contrast, cermet B, which included (Ti,W,Ta)(C,N) in the agglomerates, exhibited a notable contrast between the agglomerates containing irregular elongated grains and the matrix. The mechanical properties of the cellular cermets were analyzed comprehensively in conjunction with the fractal dimension. Compared with cermet A, cermet B exhibited more transgranular fractures within the matrix, with dimples and tearing ridges visible in the agglomerates. Additionally, increased crack deflection, bridging, and bifurcation were observed near the interface, considerably impeding crack propagation. Overall, cermet A with significantly refined grains demonstrated higher hardness and TRS. The fracture morphology and crack propagation in cermet B were more complex and layered, resulting in the enhanced fracture toughness.

A Timing View of the Additional High-energy Spectral Component Discovered in the Black Hole Candidate Swift J1727.8-1613

We present an energy-dependent analysis for the type-C quasiperiodic oscillations (QPOs) observed in the black hole X-ray binary Swift J1727.8–1613 using Insight-HXMT observations. We find that the QPO fractional rms at energies above 40 keV is significantly higher than that below 20 keV. This is the first report of a high energy (HE) rms excess in the rms spectrum of a black hole X-ray binary. In the high energy band, an extra hard component is observed in addition to the standard thermal Comptonization component at a similar energy band. The value of the QPO HE rms excess is not only correlated with the disk parameters and the photon index of the standard Comptonization component but also exhibits a moderate positive correlation with the flux of the additional hard spectral component. No features in the QPO phase-lag spectra are seen corresponding to the additional hard component. We propose that the additional hard component in the spectrum may originate from jet emission and the associated QPO HE rms excess can be explained by the precession of the jet base.

Fermi GBM Observations of the Galactic Magnetar SGR 1935+2154 during Its 2022 January Activity

The X-ray and radio burst-emitting soft gamma-ray repeater SGR 1935+2154 has been the most active magnetar during the past decade, with at least one active episode each year since 2019. We report on the 2022 January activity as observed by the Fermi Gamma-Ray Burst Monitor and present the temporal and time-integrated spectral properties of the observed 112 X-ray bursts. No radio bursts were reported during the activity. The mean burst duration is comparable to most of the previous activities but is shorter than that of 2020, during which the magnetar emitted radio bursts. The mean burst spectrum is softer than the earlier activities and a long-term softening trend since 2016 is evident and is accompanied by a rise in the mean burst fluence and blackbody emission radii. The power-law indices of the RBB2−kTBB correlation also show an evolution during 2019–2022, where the soft component started becoming steeper, whereas the hard component shows a less steep trend. The burst properties show no significant evolution within the activity, which lasted for ∼ 45 days, and none of the observed bursts showed properties reminiscent of those of the hard, long X-ray counterpart to the 2020 fast radio burst FRB 200428 from the source. We discuss the results comparatively with the 8 yr history of the source since its discovery in 2014.

Hard X-rays and QPO in Swift J1727.8−1613: the rise and plateau of the 2023 outburst

ABSTRACT We report on the detection of type-C quasi-periodic oscillations during the initial stages of the outburst of Swift J1727.8–1613 in 2023. Using data of the INTEGRAL observatory along with the data of the Mikhail PavlinskyART-XC telescope on board Spektr-RG and X-ray Telescope (XRT) of the Neil Gehrels Swift observatory the fast growth of the quasi-periodic oscillations (QPO) frequency was traced. We present a hard X-ray light curve that covers the initial stages of the 2023 outburst – the fast rise and plateau – and demonstrate that the QPO frequency was stable during the plateau. The switching from type-C to type-B QPO was detected with the beginning of the source flaring activity. We have constructed a broad-band spectrum of Swift J1727.8−1613 and found an additional hard cutoff power-law spectral component extending at least up to 250 keV. Finally, we have obtained an upper limit on the hard X-ray flux at the beginning of the optical outburst and estimated the delay of the hard X-ray outburst with respect to the optical one.

Optical coherence tomography imaging for the evaluation and treatment of calcified coronary artery disease

Coronary calcific disease represents one of the main challenges for the interventional cardiologist, for whom optimal lesion preparation and percutaneous coronary intervention optimization are paramount for correct management. In this perspective, intravascular imaging using optical coherence tomography (OCT) is becoming an increasingly indispensable tool. This work aims to provide a detailed overview of the complexity of calcified lesions, first analyzing their various morphologies and their clinical impact: spotty calcium seems to be more present in plaques at higher risk of destabilization, while diffuse calcification is typical of stable coronary stenosis; the eruptive calcific nodule is one of the three culprit lesion phenotypes responsible for acute coronary syndromes.In the second part of this review, the available technologies for the treatment of calcified lesions are described, with the aid of illustrative OCT images. Intravascular lithotripsy causes fractures at various levels of the calcified plaque, both circumferentially and longitudinally, with an improvement in vessel compliance; atherectomy acts by modifying the composition of the plaque with selective action on the hard calcific component. OCT, providing a comprehensive overview of lesion characteristics, can guide in the selection of the most appropriate therapeutic strategy, while also offering important information on the effectiveness of the chosen treatment.

Brillouin scattering from biomedical samples: the challenge of heterogeneity

Abstract Brillouin light scattering (BLS), a non-destructive and non-contact technique, offers a powerful tool for probing the micromechanical properties of biological tissues. However, the inherent heterogeneity of biological tissues can pose significant challenges in interpreting BLS spectra. In this study, we introduce a novel method that harnesses the intensity information within a single BLS spectrum to directly estimate the Voigt average of the longitudinal modulus. Additionally, we use a method to determine the ratio of the squared Pockels coefficients for photoelastically heterogeneous samples, based on global analysis of a 2D BLS map. This method is shown to effectively determine the photoelastic ratio of soft and hard components of human bone tissues, enabling the calculation of the average elastic moduli. Furthermore, it has the remarkable ability to generate maps of the filling factor of the scattering volume, shedding valuable light on the intricate structure and topography of rough surfaces under BLS mapping.

Dynamics of Changes in the Intensity of Hard and Soft Components of Cosmic Rays in the Atmosphere

The dynamics of changes in the homogeneous intensity of the hard and soft components of cosmic radiation and the intensity of each of them separately, depending on the length of the atmospheric air layer are studied in the work.

The Impact of Adding Dioxane Derivatives to Polyurethane Structures on their Performance and Degradation in the Environment

The novel dioxane-polyether polyurethanes underwent a 12-month outdoor soil burial test to look into how they would degrade in a natural setting. The structure, thermal properties, surface features, and mechanical strength of the polyurethane films were compared. The initial chemical structure and subsequent chemical alterations were identified using FTIR spectroscopy. The polyurethane samples were less thermally stable throughout the duration of the soil burial test, according to TG/DTG curves. According to all findings, polyurethanes containing 1,3-dioxane-5,5-dimethanol exhibit excellent physical characteristics and mild degradation levels after being buried in soil for a year. These polyether urethanes can break down if the rigid domain structure is exposed to moisture and if microorganisms can spread into the polymer matrix. The physical properties, surface features, and degradation of polyether polyurethanes can be improved by varying the molar ratios of the hard segment components and the dioxane derivative structures.

Nodes for modes: Nodal honeycomb metamaterial enables a soft robot with multimodal locomotion

Soft-bodied animals, such as worms and snakes, use many muscles in different ways to traverse unstructured environments and inspire tools for accessing confined spaces. They demonstrate versatility of locomotion which is essential for adaptation to changing terrain conditions. However, replicating such versatility in untethered soft-bodied robots with multimodal locomotion capabilities have been challenging due to complex fabrication processes and limitations of soft body structures to accommodate hardware such as actuators, batteries and circuit boards. Here, we present MetaCrawler, a 3D printed metamaterial soft robot designed for multimodal and omnidirectional locomotion. Our design approach facilitated an easy fabrication process through a discrete assembly of a modular nodal honeycomb lattice with soft and hard components. A crucial benefit of the nodal honeycomb architecture is the ability of its hard components, nodes, to accommodate a distributed actuation system, comprising servomotors, control circuits, and batteries. Enabled by this distributed actuation, MetaCrawler achieves five locomotion modes: peristalsis, sidewinding, sideways translation, turn-in-place, and anguilliform. Demonstrations showcase MetaCrawler’s adaptability in confined channel navigation, vertical traversing, and maze exploration. This soft robotic system holds the potential to offer easy-to-fabricate and accessible solutions for multimodal locomotion in applications such as search and rescue, pipeline inspection, and space missions.

Electric field lines of charged particle in a helical undulator

One of the devices for generating circularly polarized radiation is a helical undulator in which a relativistic charged particle moves along a helical trajectory. In this paper, the spatial distribution of the electromagnetic field produced by such a particle is analyzed using electric field lines. The equations of electric field lines, which, due to the presence of curvature and torsion in the trajectory are precisely solved. A special algorithm for erasing invisible parts of the lines has been developed to represent the lines in space. Several remarkable features of the field picture are revealed, in particular, the hard component of the radiation is concentrated in the plane orthogonal to the undulator axis and passing through the position of the particle at the current moment of time.

Electromagnetic based flexible bioelectronics and its applications

With the increasing demand in seamless interface between artificial devices and biological structures, flexible bioelectronics has been developed rapidly in recent years. Compared with traditional rigid bioelectronics, flexible devices are more adaptable to the integration for various parts both inside and outside of the organism. Significant achievements have been made in biomedical devices, neuroelectronics and wearable devices. With the development of flexible bioelectronics, electromagnetics is becoming a crucial part in signal interference reduction and information transmission or feedback, taking advantages of strong penetration and rapid response in a variety of biological materials. In this review, we focus on the latest developments in electromagnetic based flexible bioelectronics, involving materials, sensation, seamless integration, and power supply, as well as the latest achievements in the fields of external wearables, internal implants, soft robotics and drug delivery system. Based on these, the main challenges facing flexible bioelectronics, are analyzed, including stretchability caused by mismatch between mechanical properties of soft and hard components, biocompatibility, environmental stability, to facilitate the further development of flexible bioelectronics.