Hard Materials Research Articles

Identifying the plateau sodium storage behavior of hard carbon through the spin state

Hard carbon has emerged as a promising anode material for rechargeable sodium-ion batteries, owing to its abundant precursor sources and remarkable reversible charge storage capacity. The key to achieving an extended sodium storage capacity lies in the plateau capacity largely associated with the closed-pore structure, yet a comprehensive understanding in this area remains incomplete. In our study, we utilized electron paramagnetic resonance (EPR) spectra to discern the spin state of unpaired electrons within hard carbon materials, enabling the identification of sodium storage plateau regions. Hard carbon anodes with plateau capacity predominantly exhibit delocalized spins, evident in the EPR spectrum by limited spin density and a linewidth exceeding 100 G. These spins originate from the extended aromatic structure within small-sized but curved nano-graphite and the closed-pore walls, which are crucial for plateau capacity. Conversely, hard carbon anodes exclusively possessing slope capacity are characterized by localized spins, presenting a typical narrow and intense Lorentzian EPR signal. These localized spins arise from the edge defects of the nano-graphite structure, serving as favourable sites for sodium adsorption. Our development of a methodology to discern hard carbon plateau capacity behavior based on EPR spectra presents a facile and rapid approach for advancing high-performance hard carbon materials.

Enhancing the Weld Quality of Polylactic Acid Biomedical Materials Using Rotary Friction Welding.

Polylactic acid (PLA) stands out as a biomaterial with immense potential, primarily owing to its innate biodegradability. Conventional methods for manufacturing PLA encompass injection molding or additive manufacturing (AM). Yet, the fabrication of sizable medical devices often necessitates fragmenting them into multiple components for printing, subsequently requiring reassembly to accommodate the constraints posed by the dimensions of the AM platform. Typically, laboratories resort to employing nuts and bolts for the assembly of printed components into expansive medical devices. Nonetheless, this conventional approach of jointing is susceptible to the inherent risk of bolts and nuts loosening or dislodging amid the reciprocating movements inherent to sizable medical apparatus. Hence, investigation into the joining techniques for integrating printed components into expansive medical devices has emerged as a critical focal point within the realm of research. The main objective is to enhance the joint strength of PLA polymer rods using rotary friction welding (RFW). The mean bending strength of welded components, fabricated under seven distinct rotational speeds, surpasses that of the underlying PLA substrate material. The average bending strength improvement rate of welding parts fabricated by RFW with three-stage transformation to 4000 rpm is about 41.94% compared with the average bending strength of PLA base material. The average surface hardness of the weld interface is about 1.25 to 3.80% higher than the average surface hardness of the PLA base material. The average surface hardness of the weld interface performed by RFW with variable rotational speed is higher than the average surface hardness of the weld interface performed at a fixed rotating friction speed. The temperature rise rate and maximum temperature recorded during RFW in the X-axis of the CNC turning machine at the outer edge of the welding part surpassed those observed in the internal temperature of the welding part. Remarkably, the proposed method in this study complies with the Sustainable Development Goals due to its high energy efficiency and low environmental pollution.

The role of embedded coordinates for disclinations and disconnection components

The standard model is applied for partial disclination pairs in hard materials. These defects comprise two partial disclinations and an intervening fault that can be a twin boundary, grain boundary or interphase boundary. In three dimensions there are six types. Two of them can be considered Somigliana disclinations. The standard model includes geometrically nonlinear embedded coordinates. It entails partitioning of displacements that result in configurations and strain fields not considered classically for partial disclinations. These concepts are applied to boundary junctions, disconnections, and multiple twins. Recovered stress-free structures are considered.

Identifying the stone toolkit of Copper Age and Bronze Age metallurgists: A new contribution from use-wear and XRF analysis carried out on experimental tests

Use-wear analysis of stone tools involved in metallurgical processes is a recent field of research within functional analysis. In order to consolidate the methodological framework of such research, experiments were carried out on the production of copper and bronze objects. Several production steps were tested, on the basis of archaeological questions relating to sites dated from the 3rd and the 2nd millennium BC in north-west Europe. The crushing of copper ore was tested in order to compare use-wear traces created by three different actions: breaking block, fragmenting into small pieces and grinding into powder. In addition, various parts of a test group of copper and tin bronze axeheads and daggers were shaped by hammering: this hammering involved deburring and regularization of the sides of the axeheads and daggers, as well as thinning out the cutting edges immediately after casting or at a later stage. Finally, the sides and edges of the copper and bronze axeheads were abraded and polished. The combination of use-wear and XRF analysis of the tools involved in this series of experiments consolidates the methodological background of the functional analysis of stone tools. They allow better differentiation of wear traces resulting from the processing of ores within the broader spectrum of hard mineral materials. They also raise questions about the preservation of metal residues on the surface of stone tools depending on the different activities carried out. Finally, the distinction between copper and bronze objects is also discussed. Examples of the analysis of various metallurgists’ stone tools from the Early Bronze in north-west Europe support the demonstration.

Considerations Regarding the Effects of Temperature Increase on the Hardness of Materials in Friction Couplings with Sliding Motion

Abstract The temperature on the surfaces in sliding motion changes as a result of the operating conditions. The temperature distribution generated during the friction process depends on the forces generated in operation, the speed of sliding, the topography of the surface,the properties of the materials that form the friction coupling. The purpose of this paper is to analyze the effects of temperature increase on surfaces in sliding motion with implications on the hardness of friction coupling materials.

Effects of various beverages on characteristics of provisional restoration materials.

To investigate the effect of common beverages on four currently used provisional restoration materials: Protemp®4, Integrity®, polymethyl methacrylate(PMMA) block, and acrylic resin. Flowable resin composite is included as a control group. Each material was formed into disks of 10-mm diameter and 4-mm thickness (N = 40) by loading the material into acrylic molds. The exposed surface in the mold was covered using a glass slide to prevent an oxygen inhibition layer, and polymerization then proceeded. The solidified disks were placed in distilled water for 24 h. These samples (n = 8) were then immersed for 14 days in one of four different beverages: water, orange juice, cola, and coffee. Changes in color dimension, hardness, and roughness were observed and then analyzed using two-way repeated analysis of variance. The provisional materials had more obvious changes in all three color dimensions than the flowable resin composite. Integrity showed the biggest changes, followed by acrylic resin and PMMA block, whereas Protemp had the smallest changes. The hardness of all the materials significantly decreased after immersion in any of the beverages for 14 days. There were no changes in surface roughness when the materials were immersed in distilled water. The surface roughness of the PMMA block significantly decreased in orange juice whereas that of Integrity and acrylic resin significantly increased in cola. Different kinds of provisional materials had different degrees of staining due to their composition. Moisture had a significant influence on the hardness of materials, and the acidity of cola significantly roughened the surface of the provisional materials.

Unsaturated polyester resin based composites: A case study of lignin valorisation

Materials from green resources boast a low carbon footprint, forming the foundation of the circular economy approach in materials science. Thus, in this study, waste poly(ethylene terephthalate) (PET) was subjected to depolymerization using propylene glycol (PG), and subsequent polycondensation with bio-based maleic anhydride (MA) produced unsaturated polyester resin (b-UPR). Bio-derived acryloyl-modified Kraft lignin (KfL-A) served as a vinyl reactive filler in the b-UPR matrix to create b-UPR/KfL-A composites. The structural characterization of KfL-A and b-UPR involved the use of FTIR and NMR techniques. The mechanical properties of the newly fabricated composites were assessed through tensile strength, Vickers microhardness, and dynamic mechanical tests. The addition of KfL-A to the rigid b-UPR matrix enhanced material flexibility, resulting in less stiff and hard materials while preserving composite toughness. For instance, incorporating 10 wt% of KfL-A in b-UPR led to a 17% reduction in hardness, a 48% decrease in tensile strength, and a 20% reduction in toughness. Positive environmental impact was achieved by incorporation of 64 wt% of renewable and recycled raw material. Analogously prepared b-UPR/KfL composites showed structural inhomogeneity and somewhat better mechanical properties. Transmission (TEM) and scanning (SEM) electron microscopies revealed a suitable relationship between mechanical and structural properties of composites in relation to the extent of KfL-A addition. The UL94V flammability rating confirmed that flame resistance increased proportionally with the KfL-A addition. Once deposited in a landfill, these composites are expected to disintegrate more easily than PET, causing less harm to the environment and contributing to sustainability in the plastics cycle.

Effect of Welding Time Variation in Resistance Spot Welding on Mechanical Properties of Dissimilar Joints on Mild Steel and AISI 304 Stainless Steel

Resistance spot welding plays an important role in the automotive industry for working on car bodies or frames. Welding with two different steel materials is used in automotive structures. However, the low strength of the joints of different steel materials is a major problem, limiting the scope of its application. The quality of the welding connection Resistance spot welding is influenced by several factors, namely, time, welding current, and electrode pressure applied during welding and post-welding treatment. In this research, mild steel plate with AISI 304 stainless steel is welded by Resistance spot welding with different variations of welding time, material hardness and tensile testing that will be investigated. The results showed that the highest Rockwell Hardness time was obtained at a welding time variation of 8 seconds with a current of 6000 Ampere was 112.2 so the higher the welding time, the higher the hardness obtained. welding 8 seconds with a welding current of 6000 Ampere obtained a maximum tensile strength of 20.4 kgf/mm2 so the greater the welding current, the tensile strength will increase.

Hardness and elastic modulus properties of PEEK material as an alternative to Poly Methyl Metha Acrylate (in- vitro study)

Hardness and elastic modulus properties of PEEK material as an alternative to Poly Methyl Metha Acrylate (in- vitro study)

Experimental investigation of the impact of GMAW welding parameters on the mechanical properties of AISI 316L/ER 316L using quaternary shielding gas

In this study, the parameters of Metal Inert Gas (MIG) and Metal Active Gas (MAG) were investigated of AISI 316L/ER 316L. A quaternary shielding gas mixture consisting of Argon (Ar), Helium (He), Carbon Dioxide (CO2), and Nitrogen (N2) was chosen. The Taguchi orthogonal array (OA-L9) methodology was employed to explore optimal welding settings, including arc current (120A, 160A, 200A), wire feed rate (3, 3.5, 4 m min−1), and shielding gas combination (G1, G2, G3). The findings highlighted the importance of shielding gas in influencing the ultimate tensile strength (UTS), elongation percentage (EL%), and material toughness of welding joints. Notably, the highest UTS (515.77 MPa), EL% (20.85%), and material toughness (133J) were achieved by the specific group gas combination shown as G1. It is recommended to configure welding parameters to an arc current of 160A, a wire feed rate of 4 m min−1, and the G1 gas combination. Welded specimens using a G1 gas mixture showcased the best UTS and EL%. Additionally, it was found that the fusion zone (FZ) and heat-affected zone (HAZ) hardness are most profoundly influenced by the choice of gas combination (G2), resulting in the best hardness values of 253.79 HV and 239.68 HV, respectively. The optimal parameters for achieving the desired material hardness were precisely identified as (120A, 3 m min−1, G2). These insights offer a pathway to enhance welding performance and, in turn, elevate the quality and efficiency of industrial applications.

EFFECT ON COMPRESSIVE STRENGTH OF CONCRETE WITH ADDITION OF SOLID WASTE ASH

The availability of raw material is very limited due to the increased use of concrete. The standard practice of concreting is dosing, mixing (all raw materials), transportation, on-site compaction, finishing and hardening of all raw materials are done industrially. In developed countries like India, the amount of concrete is more and the availability of raw materials is very limited. A complete replacement of concrete is not possible, because no material can fulfil the role of concrete in terms of strength, durability and workability. To achieve the desired workability, strength and durability of concrete, the entire material must be partially replaced. This article provides an explanation of solid waste ash materials used in concrete. The test procedure involved preparing concrete samples with a percentage of cement replaced by fly ash (0%, 5%, 10% and 15%) and evaluating their compressive strength (7 and 28 days) and split tensile strength after 28 days of curing.

Experiment Comparative Analysis of Feed Rate with Velocity Control in Cutting Mono Crystalline Silicon Using a Diamond Wire Saw.

Fixed-diamond abrasive wire saw cutting is one of the most common methods for cutting hard and brittle materials. This process has unique advantages including a narrow kerf and the ability to use a relatively small cutting force. In the cutting process, controlling the main process parameters can improve the processing efficiency, obtaining a better processing surface roughness. This work designs the PI controller (Proportional-Integral controller) based on the reciprocating wire saw cutting process. The control objects are the workpiece feed rate and wire saw velocity, and the control objective is the normal cutting force. For the control trials, several reference values of various normal cutting forces were chosen. The effects of feed rate and saw velocity on the cutting surface finish and cutting time were investigated in this work using wire saw cutting analysis on a square monocrystalline silicon specimen. The results of this study showed that under a constant applied force of 2.5 N, the optimal feed rate of the diamond wire through the specimen could reduce cutting time by 42% while achieving a 60% improvement in the measured surface finish. Likewise, optimal control of the wire saw velocity could reduce cycle time by 18% with a 45% improvement in the surface finish. Consequently, the feed speed control is more effective than the wire saw velocity.

Investigation and Optimization on Parameters of Gas Additive Powder Mixed Near Dry –EDM (GAPMNDEDM) by using Taguchi based- Grey Relational Optimization

The Gas Additive Powder Mix near Dry Electric Discharge Machining (GAPMND-EDM) serves a manufacturing purpose, specifically for cutting hard materials. This involves the removal of material from a workpiece via fusion, ablation, and evaporation caused by the heat energy generated through electric sparks during energy supply. The process offers several advantages in terms of performance and characteristics. This research project aims to optimize key process parameters, including material removal rate, surface roughness, residual stresses, and microhardness. The study employs a methodology that combines the standard deviation-based objective weighting method with GRA (Gray Relational Analysis) optimization to enhance the hybrid GAPMND-EDM process when applied to EN-31 material. Experimental runs were conducted to evaluate the impact of various input factors, such as pulse-on time, discharge current, dielectric fluid pressure, and metallic powder concentration. The taguchi-based GRA method was utilized for this purpose, and the experimental design followed an L-27 orthogonal array with the assistance of Minitab-19 software. A total of 27 experiments were performed, encompassing diverse combinations of process parameters. Subsequently, an ANOVA (Analysis of Variance) was executed to analyze the influence of pulse-on time, discharge current, dielectric fluid pressure, and metallic powder concentration on Material Removal Rate (MRR), Surface Roughness (SR), Residual Stress (RS), and Microhardness (MH). The result shows the optimal combination of parameters, denoted as A2B2C2D1, was identified as the preferred configuration.

Microstructure and Wear Resistance of Grx-Ti-BN Composite Coating on TC4 by Argon Arc Cladding

The TC4 (Ti-6Al-4V) alloy has problems such as low material hardness, poor wear resistance, and abnormal sensitivity to adhesive wear and fretting wear. In this study, we used graphene-reinforced Ti/BN composite coatings prepared on the surface of the TC4 alloy by argon arc cladding technology. We explored the optimal content of graphene to improve its hardness and wear resistance. The physical phases and microstructures of the coatings were analyzed using an X-ray diffractometer, metallurgical microscope, and scanning electron microscope. Microhardness and wear properties of the cladding coating were measured by a Vickers hardness tester and a universal friction and wear tester. The incorporation of graphene resulted in a transformation of the reinforcing phase in the coating from TiN to Ti(N, C). The C element in the molten pool was substituted with the N element in an unending solid solution, resulting in the formation of Ti(N, C) through intermittent nucleation. As the amount of graphene in the molten pool increases, the concentration of carbon (C) also increases. This leads to the continuous growth of Ti(N, C) particles, resulting in a coarser coating structure and a decrease in coating performance. When the graphene content is 5 wt.%, the microstructure refinement of the coating is the most obvious, the microhardness is 900 HV0.2, which is 3 times higher than that of the matrix, and the wear rate is 4.9 × 10−5 mm3/(N·m), which is 4.9 times higher than that of the matrix. The wear mechanism of the coating is primarily abrasive wear with some slight adhesive wear.

Structure and mechanical properties of PR-03N18K9M5TYu steel grade fabricated by selective laser melting and post-processing

We fabricate samples of PR-03N18K9M5TYu steel (equivalent to ChS4) using selective laser melting (SLM) in a nitrogen atmosphere. Our research focused on the influence of hot isostatic pressing (HIP) combined with heat treatment (HT), specifically hardening and aging, on the steel's structure and its physical and mechanical properties (σucs, σys, δ, ψ). Through tensile testing, we evaluated the impact of post-processing treatments (HIP followed by HT) on the material's strength. We also assessed how different post-processing protocols affected residual porosity. Our findings indicate that samples exhibiting the highest strength and plastic properties correspond to those with the least structural defects and minimal residual porosity. In-depth microstructural analysis revealed that the optimal structure–a fine-grained, homogeneous configuration–is achieved via the combined application of SLM, HIP, and subsequent HT. The improvement in mechanical properties can be primarily attributed to the dispersed hardening effect, which is a consequence of the precipitation of the superfluous Ni3Ti phase. Fractographic examination revealed that the post-processing leads to a ductile and dimple fracture, occurring through mechanisms of shearing and detachment, giving rise to mixed-type fractures. The samples that displayed superior mechanical properties were characterized by a homogenous ductile intergranular fracture surface with clear evidence of plastic deformation. We measured the hardness (Н), modulus of elasticity (Е), and elastic recovery via indentation methods. The post-processing treatments notably enhanced material hardness and elastic modulus, with an increase from H = 4.6 GPa and E = 194 GPa in the sample post-HIP to H = 8.5 GPa and E = 256 GPa following HIP coupled with hardening and aging.

Revealing the temperature-dependent hardening mechanisms of non-uniformly distributed defects for ion-irradiated metals: Experiments and modeling

In this work, an integrated approach including experimental examinations and theoretical modeling was employed to examine the temperature-dependent hardening of structural materials under ion irradiation. Experimental procedures involved the characterization of grain morphology and size distribution by electron backscatter diffraction (EBSD). Irradiation experiments were conducted utilizing high-energy Au-ions at elevated temperatures, with transmission electron microscopy (TEM) employed for observing irradiation-induced defects. Moreover, mechanical properties were assessed through high-temperature nano-indentation tests (HTNIT), revealing the concurrent occurrence of irradiation hardening and high-temperature softening in the considered materials. For theoretical modeling, a mechanistic model was developed to address the depth-dependent hardness. This model innovatively characterized the hardening mechanisms resulting from non-uniformly distributed defects in the irradiated layer while simultaneously incorporating the temperature effect. Calibration of the model demonstrated its capability to elucidate the hardness-depth relationships at different irradiation doses and testing temperatures. Further theoretical analyses indicated distinct evolution laws in irradiation hardening behavior with varying indentation depths, while the increment in temperature accelerated the expansion of the plastic zone, resulting in a moderate indentation size effect (ISE). With increasing indentation depth, the hardening contributions of geometrically necessary dislocations (GNDs) and irradiation-induced defects gradually diminished. At substantial indentation depths, the dominant hardening mechanism was then controlled by statistically stored dislocations (SSDs).

Rechargeable Manganese Dioxide||Hard Carbon Lithium Batteries in an Ether Electrolyte

Earth-abundant, cost-effective electrode materials are essential for sustainable rechargeable batteries and global decarbonization. Manganese dioxide (MnO2) and hard carbon both exhibit high structural and chemical tunability, making them excellent electrode candidates for batteries. Herein, we elucidate the impact of electrolytes on the cycling performance of commercial electrolytic manganese dioxide in Li chemistry. We leverage synchrotron X-ray analysis to discern the chemical state and local structural characteristics of Mn during cycling, as well as to quantify the Mn deposition on the counter electrode. By using an ether-based electrolyte instead of conventional carbonate electrolytes, we circumvent the formation of a surface Mn(II)-layer and Mn dissolution from LixMnO2. Consequently, we achieved an impressive ∼100% capacity retention for MnO2 after 300 cycles at C/3. To create a lithium metal-lean full cell, we introduce hard carbon as the anode which is compatible with ether-based electrolytes. Commercial hard carbon delivers a specific capacity of ∼230 mAh g−1 at 0.1 A g−1 without plateau, indicating a surface-adsorption mechanism. The resulting manganese dioxide||hard carbon full cell exhibits stable cycling and high Coulombic efficiency. Our research provides a promising solution to develop cost-effective, scalable, and safe energy storage solutions using widely available manganese oxide and hard carbon materials.

Impacts of working bone and antler on a bronze knife: Experimental and use-wear studies

To answer the question if metal knives found in late Bronze Age deposits in Karmin in W Poland (ca. 900–800 BCE) could have been used as multi-tools in processing hard materials like red deer antler and animal bone, we applied an experimental method followed by the use-wear analysis of a replica of late Bronze Age bronze knife. This is the first experiment that focuses on the tool instead of the processed material. It included five movements engaging various sections of a knife blade and tip and producing diversified traces depending on the type of technique and raw material worked. We showed that an adequately cast knife, hardened then by cold working, could have been applied in all stages of manufacturing antler and bone objects, from initial material division (cross-cutting) over shaping (surface cutting, whittling) to finishing (scraping, drilling). Although the tool required frequent resharpening, it efficiently performed various movements. The traces on the replica, such as U-shaped notches, chips, blunting, bows, scratches, and serrated and wavy edges, correspond well with those observed on the knives from Karmin.

Multi-layer solid-state ultrasonic additive manufacturing of aluminum/copper: local properties and texture

Ultrasonic additive manufacturing (UAM) is an advanced joining technique that utilizes ultrasonic vibrations to bond layers of metal foil together. UAM offers several benefits over traditional manufacturing methods, including enhanced design flexibility and reduced material waste, and its potential applications in various industries such as aerospace, automotive, and biomedical engineering are being actively explored. The study employs a nanoindentation apparatus to investigate the effect of the UAM process on the local mechanical properties of the bonded interface, along with changes in microstructure, which were investigated using scanning electron microscopy and electron back-scattered diffraction. The results revealed a significant correlation between material hardness and local plasticity. EBSD has revealed that the grain size distribution of Al far from the interface contains 57% of the grains less than 3 µm in size, while at the interface this number rises to approximately 78%, indicating that the average grain size decreases as it approaches the interface. This result is consistent with nanoindentation results that demonstrated a gradual change in the hardness of Al foil far from the interface to close to the interface (the maximum penetration depth near the interface was 500 nm less than far from the interface). Both EBSD and nanoindentation disclose the effect of work hardening close to the interface, which is related to dislocation accumulation with a density of 8.6×10-10cm-2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$8.6\ imes {10}^{-10} {{\ ext{cm}}}^{-2}$$\\end{document} beneath the interface. The consistency of hardness and Young’s modulus with the pole figures and microscopic images demonstrated that plasticity flow and fine grain distribution would only occur in the vicinity of the interface in the softer metal region. Although the harder metal did not exhibit plasticity or recrystallization, the hardness, and Young’s modulus map indicated the formation of a layer of small grains close to the interface on the aluminum side owing to strain hardening and dynamic recrystallization.

Physiological Changes in the Cornea When Wearing Rigid Gas Permeable Contact Lenses

Rigid gas permeable (RGP) contact lenses are made of materials with excellent oxygen permeability and wettability, so they not only improve oxygen permeability compared to existing lenses, but also provide correction of refractive errors and improved vision in irregular corneas such as keratoconus. However, the hard material of the lens along with hypoxia and hypercapnia of the cornea caused by wearing RGP contact lenses cause various physiological changes in the cornea. Physiological changes in the cornea that may occur when wearing RGP contact lenses include mucin balls, decreased corneal epithelial thickness and increased size, decreased epithelial barrier function, corneal erosion and staining, decreased keratocyte density, decreased corneal sensitivity, and stromal opacities, contact lens‐induced peripheral ulcers, endothelial blebs, increased endothelial polymegethism, and changes in corneal shape. It is necessary to know the performance of the RGP contact lenses being prescribed, be aware of the physiological changes in the cornea caused by wearing RGP contact lenses, and provide the correct lens prescription along with appropriate education to the patient.