Halite Crust Research Articles

Evolution of Great Salt Lake’s Exposed Lakebed (1984-2023)

The Great Salt Lake has been rapidly shrinking since the highstand of the mid-1980s, creating cause for concern in recent decades as the lake has reached historic lows. Many investigators have assessed the evolution of lake elevation, geochemistry, anthropogenic impacts, and links to climate and atmospheric processes; however, the use of remote sensing to study the evolution of the lake has been significantly limited. Harnessing recent advancements in cloud-processing, specifically Google Earth Engine cloud computing, this study utilizes over 600 Landsat TM/OLI and Sentinel MSI satellite images from 1984-2023 to present time-series analyses of remotely sensed Great Salt Lake water area, exposed lakebed area, surface cover types, and chlorophyll-a analyses paired with modelled estimates for water and exposed lakebed area. Results show that a analyses paired with modelled estimates for water and exposed lakebed area. Results show that area has increased to ~3,500 km2 from ~500 km2. The area of unconsolidated sediments not protected by vegetation or halite crusts has risen to ~2,400 km2. Significant halite crusts are observed in the North Arm, having a max extent of ~150 km2 between 2002 and 2003, while only small extents of halite crusts are observed for the South Arm. Vegetation is more prevalent in the Bear River Bay and South Arm, with surface area increases over 400% since 1990. Gypsum is widely observed independent of halite crusts. The results highlight multiple instances of land-use/water-management that led to observable changes in water/exposed lakebed area and halite crust extent. This study demonstrates the important benefits of maintaining a lake elevation above ~4,194 ft to maximize lake and halite crust area, which would help mitigate possible dust events and maintain a broad lake extent.

Polygons with halite-crusted floors and gypsum-raised rims in western Qaidam Basin and implications for polygonal landforms on Mars

Polygons ranging in size from a few meters to kilometers have been observed in playa fields on Earth and Mars. The historically hyperarid climate of the Qaidam Basin has allowed the development of extensive polygonal landforms with diverse geometric and genetic types. Here we report a terrain of polygons with a pan-like structure, raised rims, and a size of about 60 to 120 m, and spatial variation in mineral composition and geometry from the Dalangtan area of the western Qaidam Basin on the Tibetan Plateau. Spatially, the polygons in the northeastern part of the study area have complete rims, while the polygons in the southwest have incomplete rims. These polygons consist of a halite crust in the subsurface and raised rims formed mainly of gypsum. In some areas, the polygonal rims are broadened and form boundary belts that are up to ~30 m wide and about 1.2 m high. We suggest that the formation of the halite crust in the subsurface redirects upward migration of evaporitic pore fluids that accumulate gypsum deposits to form the wide polygonal boundary belts. We argue that the similarly sized polygons with raised rims on Mars have similar lateral and vertical structures caused successively by the strong evaporation of lacustrine brines and subsurface pore fluids.

Desiccation of ecosystem-critical microbialites in the shrinking Great Salt Lake, Utah (USA)

Great Salt Lake hosts an ecosystem that is critical to migratory birds and international aquaculture, yet it is currently threatened by falling lake elevation and high lakewater salinity resulting from water diversions in the upstream watershed and the enduring megadrought in the western United States. Microbialite reefs underpin the ecosystem, hosting a surface microbial community that is estimated to contribute 30% of the lake’s primary productivity. We monitored exposure, desiccation, and bleaching over time in an area of microbialite reef. During this period, lake elevation fell by 1.8 m, and salinity increased from 11.0% to 19.5% in open-water portions of the outer reef, reaching halite saturation in hydrologically closed regions. When exposed, microbialite bleaching was rapid. Bleached microbialites are not necessarily dead, however, with communities and chlorophyll persisting beneath microbialite surfaces for several months of exposure and desiccation. However, superficial losses in the mat community resulted in enhanced microbialite weathering. In microbialite recovery experiments with bleached microbialite pieces, partial community recovery was rapid at salinities ≤ 17%. 16S and 18S rRNA gene sequencing indicated that recovery was driven by initial seeding from lakewater. At higher salinity levels, eventual accumulation of chlorophyll may reflect accumulation and preservation of lake material in halite crusts vs. true recovery. Our results indicate that increased water input should be prioritized in order to return the lake to an elevation that submerges microbialite reefs and lowers salinity levels. Without quick action to reverse diversions in the watershed, loss of pelagic microbial community members due to sustained high salinity could prevent the recovery of the ecosystem-critical microbialite surface communities in Great Salt Lake.

Applications and limitations of portable density meter measurements of Na-Ca-Mg-K-Cl-SO4 brines

Knowledge of brine density and mineral saturation states under different temperatures contributes to understanding Earth systems, including dissolution and crystallization of chemical sediments, mixing water bodies with variable density, and mineral resource development and evolution. However, these interpretations often rely on geochemical measurements with low accuracies at high salinities. Here, we test the utility of density measurments to advance understanding of brine geochemistry. We demonstrate the accuracy and limits of determining a brine's density and halite saturation state at multiple temperatures with rapid and relatively inexpensive portable density meter measurements. Density measurements at different temperatures are used to create samples' equations of state, which are used to extrapolate measurements. This methodology presents multiple opportunities. We use brine samples from around the world to show that density and equation of state data provide semi-quantitative information about sample composition and temperature-sensitive mineral precipitation. Importantly, density measurements can be used to evaluate error-prone geochemical measurements. We illustrate applications with brine samples from the Bonneville Salt Flats, a landscape in Utah, USA, that is valued for mineral resources and recreation opportunities. We developed system-scale equations of state for these saline pan samples and their halite-saturated counterparts. We evaluated methodological limitations with duplication tests and by determining if diurnal fluctuations in salinity and halite saturation in a shallow pool's brine and shallow groundwater in contact with a halite crust were detectable. Average daily changes in halite saturation of shallow pool brine of approximately 3 kg m−3 were clearly detected, while diurnal halite saturation fluctuations in the shallow halite crust brine of 0.4 to 0.7 kg m−3 were near method limits. Because of their accuracy, low cost, and applications, portable density meter measurements of brines are invaluable in studying brine systems.

High‐resolution facies analysis of a coastal sabkha in the eastern Gulf of Salwa (Qatar): A spatio‐temporal reconstruction

AbstractSabkhas are key landforms along the southern coast of the Arabian Gulf and represent modern analogues for depositional and diagenetic processes controlling properties and quality of ancient hydrocarbon‐bearing carbonates. While previous investigations of coastal sabkhas in Qatar have mainly focused on dolomitization processes, presented here is one of the first studies reconstructing facies changes and coastal formation in great detail. In the sabkha of Al‐Kharayej (Gulf of Salwa), fifteen different facies types were distinguished based on twelve sediment cores, two trenches, as well as grain‐size distribution, X‐ray powder diffraction, thin section and microfossil analyses. Age estimates were based on seventy‐eight 14C‐AMS and optically stimulated luminescence data. The sabkha parasequence comprises pre‐transgressive dune sands, a thin, transgressive layer of reworked dune material, a mid‐energy open‐coast to open‐lagoon facies, a low‐energy lagoon facies, saline lake facies (salina: swallow‐tail gypsum and gypsum mush) and the supratidal sabkha characterized by diagenetic overprinting (buckled gypsum crusts and halite crust). Transgressive marine flooding created open‐coast to open‐lagoon sedimentation after ca 7000 cal yr bp, followed by initial spit formation at the northern sabkha end at the beginning of the relative sea‐level highstand (6000 cal yr bp). This main outer spit prograded southward and a more narrow, low‐energy spit, diverted landward, closing a small lagoon in the northern sabkha 4500 to 4000 cal yr bp. The falling relative sea‐level and longshore drift intensified the southward extension and widening of the main spit, and the main lagoon became more shallow. At 2000 to 1500 cal yr bp, the outer spit had almost closed the main lagoon, leading to salina and, finally, sabkha conditions. It is shown how specific local conditions (coastline orientation; wind, wave, tidal energy, longshore drift; depositional relief; sediment sources) created a spit‐controlled sabkha that is genetically distinct from the classical model of shore‐perpendicular accumulation of coarser sediment during high tides or storms.

Assessment of 16S rRNA Gene-Based Phylogenetic Diversity of Archaeal Communities in Halite-Crystal Salts Processed from Natural Saharan Saline Systems of Southern Tunisia.

Simple SummaryIn the current investigation, we determine the archaeal diversity from halite-crystal salts sampled from Chott Djerid and Chott Douz, two saline Chotts in the Tunisian Sahara, using both culture-dependent and independent approaches citing DGGE (V3 regions), 16S rRNA-gene (full length gene ~ 1500 bp) based clone libraries and high-throughput sequencing technology of Illumina MiSeq platform (V3–V4 regions). The amalgamation of all results yielded a comprehensive view of the archaeal diversity represented by members of Halobacteria and Nanohaloarchaea classes.A thorough assessment of the phylogenetic diversity and community structure of halophilic archaea from three halite-crystal salts, processed from two separated saline systems of Southern Tunisia has been performed using culture dependent and independent methods targeting different regions of 16S rRNA gene sequences including DGGE, 16S rRNA clone libraries and Illumina Miseq sequencing. Two samples, CDR (red halite-crystal salts) and CDW (white halite-crystal salts), were collected from Chott-Eljerid and one sample CDZ (white halite-crystal salts) from Chott Douz. Fourteen isolates were identified as Halorubrum, Haloferax, Haloarcula, and Halogeometricum genera members. Culture-independent approach revealed a high diversity of archaeal members present in all samples, represented by the Euryarchaeal phylum and the dominance of the Halobacteria class. Nanohaloarchaea were also identified only in white halite samples based on metagenomic analysis. In fact, a total of 61 genera were identified with members of the Halorhabdus, Halonotius, Halorubrum, Haloarcula, and unclassified. Halobacteriaceae were shared among all samples. Unexpected diversity profiles between samples was observed where the red halite crust sample was considered as the most diverse one. The highest diversity was observed with Miseq approach, nevertheless, some genera were detected only with 16S rRNA clone libraries and cultured approaches.

Formation and evolution of efflorescent halite speleothems beneath tepee structures in the Red Sea coastal evaporation settings, Jeddah, Saudi Arabia

This study documents the occurrence of efflorescent halite speleothems of stalactites, columns, flowstones, stalagmites and popcorns beneath tepee structures in the Red Sea coastal sabkhas, desiccated halite pond and dykes of saltworks, Jeddah, Saudi Arabia. The study aims to interpret the formation and evolution of efflorescent halite speleothems due to the high relative humidity of the area. Field work and petrographic study revealed that the speleothems form from nighttime dissolution of the tepee halite crusts due to deliquescence at high relative humidity (DRH > 75%) and condensation of capillary vapor moisture at low relative humidity (RH < 75%). Dripping and flowing of deliquescent and condensed saline waters from the underside of the tepee structures by gravity and/or capillary forces are subjected to rapid evaporation in the daytime to deposit efflorescent halite speleothems. The evolution of the different types of efflorescent halite speleothems is controlled by the amount of saline waters droplets and flowing from deliquescence and condensation, air flow below tepee structures, evaporation rate and dynamic nature of the tepee crusts. The tepee structures are resulted from thermal expansion and contraction, and crystallization pressure exerted from growth of clear, early diagenetic and efflorescent halite crystals between primary chevrons, cornets and cubes of the crusts. In brief, the tepee structures form a barrier for escaping of the nighttime capillary vapor moisture to the atmosphere that condensed on the underside of the tepee structures. The daily capillary vapor diffusion, condensation of capillary moisture, deliquescence and evaporation are the factors that lead to precipitation of efflorescent halite speleothems beneath tepee structures in these particular settings of high humidity. The influence of rainfall or dew water for providing saline waters for the formation of the studied speleothems are of minor importance with regard to capillary vapor condensation and deliquescence, and in comparison to other studies described stalactites below tepee structures.

Analyses of Namibian Seasonal Salt Pan Crust Dynamics and Climatic Drivers Using Landsat 8 Time-Series and Ground Data

Salt pans are highly dynamic environments that are difficult to study by in situ methods because of their harsh climatic conditions and large spatial areas. Remote sensing can help to elucidate their environmental dynamics and provide important constraints regarding their sedimentological, mineralogical, and hydrological evolution. This study utilizes spaceborne multitemporal multispectral optical data combined with spectral endmembers to document spatial distribution of surface crust types over time on the Omongwa pan located in the Namibian Kalahari. For this purpose, 49 surface samples were collected for spectral and mineralogical characterization during three field campaigns (2014–2016) reflecting different seasons and surface conditions of the salt pan. An approach was developed to allow the spatiotemporal analysis of the salt pan crust dynamics in a dense time-series consisting of 77 Landsat 8 cloud-free scenes between 2014 and 2017, covering at least three major wet–dry cycles. The established spectral analysis technique Sequential Maximum Angle Convex Cone (SMACC) extraction method was used to derive image endmembers from the Landsat time-series stack. Evaluation of the extracted endmember set revealed that the multispectral data allowed the differentiation of four endmembers associated with mineralogical mixtures of the crust’s composition in dry conditions and three endmembers associated with flooded or muddy pan conditions. The dry crust endmember spectra have been identified in relation to visible, near infrared, and short-wave infrared (VNIR–SWIR) spectroscopy and X-ray diffraction (XRD) analyses of the collected surface samples. According these results, the spectral endmembers are interpreted as efflorescent halite crust, mixed halite–gypsum crust, mixed calcite quartz sepiolite crust, and gypsum crust. For each Landsat scene the spatial distribution of these crust types was mapped with the Spectral Angle Mapper (SAM) method and significant spatiotemporal dynamics of the major surface crust types were observed. Further, the surface crust dynamics were analyzed in comparison with the pan’s moisture regime and other climatic parameters. The results show that the crust dynamics are mainly driven by flooding events in the wet season, but are also influenced by temperature and aeolian activity in the dry season. The approach utilized in this study combines the advantages of multitemporal satellite data for temporal event characterization with advantages from hyperspectral methods for the image and ground data analyses that allow improved mineralogical differentiation and characterization.

Hyperspectroscopic and microtopographic analyses of salt crust forms on arid, silty clay loam desert soils

This paper describes simultaneous uses of field sampling and hyperspectroscopic approaches to understand the distributions of salt crusts and factors affecting them under field conditions. Samples of salt affected soils and associated salt crusts that represented a range of soil salinities, slope, and moisture contents were gathered from the banks of the Rio Grande. The samples were studied for salt identification by optical microscopy and using a high-resolution spectroradiometer, GER 3700, and for salinity level, and moisture content by the wet chemistry method. The study identified two main groups of salt crusts, contaminated halite and gypsum crusts. Reflectivity was correlated negatively with moisture content and positively with slope value, electrical conductivity and salt quantity. Reflectivity of halite-dominated crusts was higher than those of gypsum. Halite occurred over a greater range and higher slope values of soils than gypsum; however, a positive correlation between the slope and mean reflectivity of both salt crusts was reported. Although reflectivity of salt crusts varied according to changes in moisture content, and the salinity of the soil, moisture content can drastically reduce the reflection more effectively? than the other factors. The data reported indicate the possibility of assessing the type of salt crust by estimation of the ratio of slope and reflectivity to the other variables.

Monitoring of playa evaporites as seen with optical remote sensing sensors: case of Chott El Jerid, Tunisia, from 2003 to present

Chott El Jerid in the Zone of Chotts of Tunisia is one of the largest endorheic basins in the world. During the dry period, from May to August, it is generally covered by continental evaporites which result from the desiccation of the lake formed after a flooding event. This lake comprises runoff water from the surrounding relief and also water resurgence. In order to map and monitor these evaporitic surfaces (mineral composition and evolution in space and time), optical multisource, multispectral, and multidate satellite data have been used. Landsat 4–5 TM, Landsat 8 OLI, SPOT 6, and Landsat Surface Reflectance (LSR) constitute the main data set. The central part of the Chott, north and south of the road crossing the Chott over 70 km from Tozeur to Kebili, has been particularly studied, because it corresponds to the major evaporite accumulation zone. These evaporites precipitated as concentric layers (a relatively rare pattern), mainly north of the road, after several recent flooding events during the last 15 years. Winds can play a significant role in the development of the evaporite layers. Image interpretation associated with field data shows that after the final desiccation of the playa lake, the mineralogy of the salt crust comprised an assemblage dominated by halite south of the road and by gypsum north of the road. Halite and gypsum are the only minerals to be identified using satellite remote sensing data. Sulfates such as gypsum can be identified thanks to a drop in reflectance in the short-wave infrared (SWIR) range caused by vibrations of the SO4 group. Gypsum crusts are more widely distributed than halite crusts. LSR data are particularly suitable for multitemporal comparison because they are calibrated and atmospherically corrected. The classical bull’s eye pattern characterizing evaporitic deposits (from carbonates along the rims to halite, gypsum, and finally potassium-magnesium minerals in the center of the basin) is deeply disturbed by the road crossing Chott El Jerid.

Temporal dynamics of flooding, evaporation, and desiccation cycles and observations of salt crust area change at the Bonneville Salt Flats, Utah

The Bonneville Salt Flats (BSF) in Utah is a dynamic saline playa environment responding to natural and anthropogenic forces. Over the last century, the saline groundwater from below BSF has been harvested to produce potash via evaporative mining, mostly used as agricultural fertilizers, while the surface halite crust has provided a significant recreational site for land speed racing. Perceptions of changes in the salt crust through time have spurred debates about land use and management; however, little is known about the timescales of natural change as the salt crust responds to climatic parameters that drive flooding, evaporation, and desiccation (FED) cycles that control surface salt growth and dissolution. Climate data over the last ~30years are examined to identify annual patterns in surface water balance at BSF to identify annual and seasonal climate constraints on FED cycles. Landsat satellite data from 1986 to the present are used to map the areal extent of the surface halite salt crust at BSF at the end of the desiccation season (between August 15 and October 30) annually. Overall, the observed area of the desiccation-stage BSF halite crust has varied from a maximum of 156km2 in 1993 to a minimum of 72km2 in 2014 with an overall trend of declining area of halite observed over the ~30years of analysis. Climatic variables that influence FED cycles and seasonal salt dissolution and precipitation have also varied through this time period; however, the relationship between surface water fluxes and salt crust area do not clearly correlate, suggesting that other processes are influencing the extent of the salt. Intra-annual analyses of salt area and weather illustrate the importance of ponded surface water, wind events, and microtopography in shaping a laterally extensive but thin and ephemeral halite crust. Examination of annual to decadal changes in salt crust extent and environmental parameters at BSF provides insights into the processes driving change and the sustainability of land use in this dynamic environment.

Gypsum stromatolites from Sawda Nathil: relicts from a southern coastline of Qatar

Sawda Nathil is one of a series of inland depressions (inland sabkhas and salinas) that extend nearly continuously along the Southern Qatar border with Saudi Arabia. Six to eight thousand years ago, these depressions were marine embayments that separated the peninsula of Qatar from the mainland. These embayments in-filled rapidly with marine sediments and dune sands, blown southeastward across Qatar. Over time, they have become progressively more evaporitic. Inland depressions like Sawda Nathil host a set of unique environments within Qatar. Most depressions are close to or below sea level, bringing water near the surface in the driest parts of Qatar. Evaporation to salt saturation creates thick gypsum and halite crusts (sabkhas), as well as shallow hypersaline lakes/ponds (salinas) with spectacular domal microbial gypsum stromatolites. The present ground surface is a mosaic of relict marine facies, deflated dune sands, and inland sabkhas and salinas. Sediment of four short push cores was photographed, described, and sampled for petrographic thin-section and X-ray diffraction (XRD) analyses. Radiocarbon (AMS) as well as optically stimulated luminescence (OSL) age-dating were carried out on three samples. Scanning electron microscopy (SEM), carried out on samples from a gypsum stromatolite, was used to resolve the microbial-influence on gypsum precipitation. Radiocarbon dating of marine shells provides ages of approximately 6600 un-calibrated 14C years before present (year BP), coinciding with a well-documented sea-level highstand, approximately 2–4 m higher than present. During that time, Qatar was mostly an island, only connected in the south to the Arabian Peninsula by narrow land bridges (isthmuses). SEM examinations of gypsum stromatolites show gypsum crystals developing in close spatial association with microbial biofilms (filamentous structures). Whether this is purely a passive microbial-influenced gypsum mineralization process or an example where microorganisms actively control the gypsum crystal morphology to obtain ecological advantages, remains to be evaluated.

Analyses of Recent Sediment Surface Dynamic of a Namibian Kalahari Salt Pan Based on Multitemporal Landsat and Hyperspectral Hyperion Data

This study combines spaceborne multitemporal and hyperspectral data to analyze the spatial distribution of surface evaporite minerals and changes in a semi-arid depositional environment associated with episodic flooding events, the Omongwa salt pan (Kalahari, Namibia). The dynamic of the surface crust is evaluated by a change-detection approach using the Iterative-reweighted Multivariate Alteration Detection (IR-MAD) based on the Landsat archive imagery from 1984 to 2015. The results show that the salt pan is a highly dynamic and heterogeneous landform. A change gradient is observed from very stable pan border to a highly dynamic central pan. On the basis of hyperspectral EO-1 Hyperion images, the current distribution of surface evaporite minerals is characterized using Spectral Mixture Analysis (SMA). Assessment of field and image endmembers revealed that the pan surface can be categorized into three major crust types based on diagnostic absorption features and mineralogical ground truth data. The mineralogical crust types are related to different zones of surface change as well as pan morphology that influences brine flow during the pan inundation and desiccation cycles. These combined information are used to spatially map depositional environments where the more dynamic halite crust concentrates in lower areas although stable gypsum and calcite/sepiolite crusts appear in higher elevated areas.

Remote sensing and in situ mineralogic survey of the Chilean salars: An analog to Mars evaporate deposits?

The identification and characterization of hydrated minerals within ancient aqueous environments on Mars are high priorities for determining the past habitability of the planet. Few studies, however, have focused on characterizing the entire mineral assemblage, even though it could aide our understanding of past environments. In this study we use both spaceborne and field (VNIR spectroscopy) analyses to study the mineralogy of various salt flats (salars) of the northern region of Chile as an analog for Martian evaporites. These data are then compared to laboratory based Raman and XRD analyses for a complete overview on mineral assemblages. Central (core) and marginal zones within the salars are easily distinguished on the Landsat 8 band color composites. These areas host different mineral assemblages that often result in different landscapes. The lower elevation Salar de Atacama, located in the Andean pre-depression, is characterized by a unique thick halite crust at its center, whereas various assemblages of calcium sulfates (gypsum, bassanite, anhydrite) and sodium sulfates (mirabilite, thenardite, blodite, glauberite), borates (ulexite, pinnoite), Al/Fe- clays and carbonates (calcite, aragonite) were found at its margin. Sulfates form the main crust of the Andean salars to the east, although various compositions are observed. These compositions appear controlled by the type of feeder brine (Ca, SO4 or mixed), a result of the local geology among other factors. Sulfate crusts were found to be generally thin (<5cm) with a sharp transition to the underlying clay, silt, or sand-rich alluvial deposits. Coupled with morphologic analyses, VNIR spectroscopy provides a powerful tool to distinguish different salt crusts. XRD analysis allowed us to quantify the mineral assemblages and assess the limitations of VNIR techniques in the presence of hydrated sulfates, which tend to mask the signatures of other minerals such as clays, chlorides, and carbonates. We found that the Atacama's unique arid and volcanic environment, coupled with the transition recorded in some of the salars has a strong Mars analog potential. Characterizing the outcrop mineralogy at a variety of environments from alkaline, lake waters to more acidic salar brines may help in constraining geochemical environments on Mars.

Rates and geochemical processes of soil and salt crust formation in Salars of the Atacama Desert, Chile

The hyperarid Atacama Desert contains numerous local basins with surficial salt crusts, known as salars, where evaporation of shallow groundwater drives the major soil processes. We examine chemical and isotopic profiles in two soils of differing ages from the Salar Llamara to determine the geochemical processes involved in their formation. Evaporation, which provides salts to the soils through mineral precipitation, decreases with increasing salt crust thickness, and average~0.03mmm−2d−1 over geological time frames. Salt distribution varies predictably with depth and soil age, with the most soluble compounds concentrated nearest to the land surface, indicating the direction of fluid flow. δ34S values of mineral sulfate tend to decrease with decreasing soil depth, following a pattern indicative of Rayleigh-like fractionation as solute-rich waters migrate toward the land surface. δ13C and δ18O values of carbonate suggest that the uppermost halite layers, which contain very small amounts of carbonate, have a strong biological signature. In contrast, carbonate-rich layers deeper in the profiles consist of largely unmodified lacustrine carbonate that formed in highly evaporitic lake conditions. The continuous upward evaporation of water and dissolved solutes creates a rugged and physically dynamic halite crust composed of rounded salt nodules. The crust undergoes deliquescence as atmospheric relative humidity rises from marine air intrusions, and we found that the halite nodules on the surface of the Salar Llamara are nearly always at or above deliquescence relative humidity. The interiors of these nodules are therefore able to buffer the large diurnal changes in atmospheric relative humidity allowing for the survival of halophilic microbial communities in an otherwise very dry environment. Radiocarbon measurements of occluded organic C in the surface crusts indicate that C cycling occurs at differing rates depending on local micrometeorological conditions, and that a given salt crust feature may persist for thousands of years once formed.

Stable chlorine isotopes in arid non-marine basins: Instances and possible fractionation mechanisms

Stable chlorine isotopes are useful geochemical tracers in processes involving the formation and evolution of evaporitic halite. Halite and dissolved chloride in groundwater that has interacted with halite in arid non-marine basins has a δ37Cl range of 0 ± 3‰, far greater than the range for marine evaporites. Basins characterized by high positive (+1 to +3‰), near-0‰, and negative (−0.3 to −2.6‰) are documented. Halite in weathered crusts of sedimentary rocks has δ37Cl values as high as +5.6‰. Salt-excluding halophyte plants excrete salt with a δ37Cl range of −2.1 to −0.8‰. Differentiated rock chloride sources exist, e.g. in granitoid micas, but cannot provide sufficient chloride to account for the observed data. Single-pass application of known fractionating mechanisms, equilibrium salt-crystal interaction and disequilibrium diffusive transport, cannot account for the large ranges of δ37Cl. Cumulative fractionation as a result of multiple wetting-drying cycles in vadose playas that produce halite crusts can produce observed positive δ37Cl values in hundreds to thousands of cycles. Diffusive isotope fractionation as a result of multiple wetting-drying cycles operating at a spatial scale of 1–10 cm can produce high δ37Cl values in residual halite. Chloride in rainwater is subject to complex fractionation, but develops negative δ37Cl values in certain situations; such may explain halite deposits with bulk negative δ37Cl values. Future field studies will benefit from a better understanding of hydrology and rainwater chemistry, and systematic collection of data for both Cl and Br.

Structural and textural characteristics of surface halite crusts of a supratidal, ephemeral halite pan, South Jeddah, Red Sea Coast, Saudi Arabia

Two saline (halite and gypsum) pans have recently developed overlying lagoonal and sabkha sediments in the Şarūm area, south Jeddah, Saudi Arabia, as a result of the construction of an asphaltic road 30 years ago. Structural and textural characteristics of the halite layers reflect their formation during flooding, evaporative concentration, and desiccation stages of the ephemeral halite pan. The flooding stage textures record partial dissolution of the halite crusts, resulting in the formation of truncation surfaces, microkarst pits, pipes, and vugs. Microbial mats can flourish within dissolution vugs, despite the ambient high salinity of the brine. The evaporative concentration stage is characterized by the formation of thick, flat, halite crusts, in addition to isolated masses resembling cauliflowers, mushrooms, and platforms. The halite crusts and isolated masses consist of cumulate rafts and pyramidal hoppers, chevrons, and cornets. Agitation of the brine by waves or currents induced by wind favors the formation of rippled and clastic halite. Desiccation stage textures are represented by polygonal fractures and ridges, chaotic mud-halite filling microkarst pits and pipes, overgrowths, and displacive and efflorescent halite crystals. Field and petrographic studies and major element geochemistry of the brine indicate that the main recharge to the halite pan is from numerous seawater seepage points without direct connection to the Red Sea water or surface drainage. The results of this study provide valuable sedimentological information that could be useful in the interpretation of similar ancient halite.

The affect of the space environment on the survival ofHalorubrum chaoviatorandSynechococcus(Nägeli): data from the Space Experiment OSMO on EXPOSE-R

AbstractWe have shown using ESA's Biopan facility flown in Earth orbit that when exposed to the space environment for 2 weeks the survival rate ofSynechococcus(Nägeli), a halophilic cyanobacterium isolated from the evaporitic gypsum–halite crusts that form along the marine intertidal, andHalorubrum chaoviatora member of the Halobacteriaceae isolated from an evaporitic NaCl crystal obtained from a salt evaporation pond, were higher than all other test organisms exceptBacillusspores. These results led to the EXPOSE-R mission to extend and refine these experiments as part of the experimental package for the external platform space exposure facility on the ISS. The experiment was flown in February 2009 and the organisms were exposed to low-Earth orbit for nearly 2 years. Samples were either exposed to solar ultraviolet (UV)-radiation (λ &gt; 110 nm or λ &gt; 200 nm, cosmic radiation (dosage range 225–320 mGy), or kept in darkness shielded from solar UV-radiation. Half of each of the UV-radiation exposed samples and dark samples were exposed to space vacuum and half kept at 105pascals in argon. Duplicate samples were kept in the laboratory to serve as unexposed controls. Ground simulation control experiments were also performed. After retrieval, organism viability was tested using Molecular Probes Live–Dead Bac-Lite stain and by their reproduction capability. Samples kept in the dark, but exposed to space vacuum had a 90 ± 5% survival rate compared to the ground controls. Samples exposed to full UV-radiation for over a year were bleached and although results from Molecular Probes Live–Dead stain suggested ~10% survival, the data indicate that no survival was detected using cell growth and division using the most probable number method. Those samples exposed to attenuated UV-radiation exhibited limited survival. Results from of this study are relevant to understanding adaptation and evolution of life, the future of life beyond earth, the potential for interplanetary transfer of viable microbes via meteorites and dust particles as well as spacecraft, and the physiology of halophiles.

Distribution of scytonemin in endolithic microbial communities from halite crusts in the hyperarid zone of the Atacama Desert, Chile.

Scytonemin, a UV-screening molecule produced by certain Cyanobacteria to protect against harmful UV radiation, was studied in endolithic cyanobacterial colonies in the halite crust from one of the driest places on Earth - the hyperarid zone of the Atacama Desert. The distribution of the pigment within the evaporitic crust was studied in detail by various independent analytical methods: Raman spectroscopy (including Raman imaging); advanced microscopic observations (fluorescence microscopy, confocal laser scanning microscopy, low-temperature scanning electron microscopy); and spectrophotometric analyses. The differences in scytonemin biosynthesis were mapped within the colonized interior layers, which can be divided into scytonemin-rich and scytonemin-poor zones. A 532nm laser for excitation proved to be an ideal excitation source with which to observe the relative content of scytonemin within a particular cell aggregate, as well as between different cell aggregates; based on the scytonemin/carotenoid Raman signal intensity ratio of selected corroborative bands for these two compounds. Significantly, scytonemin was found to accumulate within a decayed biomass in the surface portions of the halite crust. These were found to be highly enriched in both the absolute scytonemin content (as documented by UV/VIS spectrophotometry) and its content relative to other pigments associated with the cyanobacterial cells (e.g. carotenoids and chlorophyll).

Tectonic and climatic controls on fan systems: The Kohrud mountain belt, Central Iran

Late Pleistocene to Holocene fans of the Kohrud mountain belt (Central Iran) illustrate the problems of differentiating tectonic and climatic drivers for the sedimentary signatures of alluvial fan successions. It is widely recognised that tectonic processes create the topography that causes fan development. The existence and position of fans along the Kohrud mountain belt, NE of Esfahan, are controlled by faulting along the Qom-Zefreh fault system and associated fault zones. These faults display moderate amounts of historical and instrumental seismicity, and so may be considered to be tectonically active. However, fluvial systems on the fans are currently incising in response to low Gavkhoni playa lake levels since the mid-Holocene, producing incised gullies on the fans up to 30m deep. These gullies expose an interdigitation of lake deposits (dominated by fine-grained silts and clays with evaporites) and coarse gravels that characterise the alluvial fan sediments. The boundaries of each facies are mostly sharp, with fan sediments superimposed on lake sediments with little to no evidence of reworking. In turn, anhydrite–glauberite, mirabilite and halite crusts drape over the gravels, recording a rapid return to still water, shallow ephemeral saline lake sedimentation. Neither transition can be explained by adjustment of the hinterland drainage system after tectonic uplift. The potential influence in Central Iran of enhanced monsoons, the northward drift of the Intertopical Convergence Zone (ITCZ) and Mediterranean climates for the early Holocene (~6–10ka) point to episodic rainfall (during winter months) associated with discrete high magnitude floods on the fan surfaces. The fan sediments were deposited under the general influence of a highstand playa lake whose level was fluctuating in response to climate. This study demonstrates that although tectonism can induce fan development, it is the sensitive balance between aridity and humidity resulting from changes in the climate regime of Central Iran that influences the nature of fan sequences and how they interrelate to associated facies.