H2O Lines Research Articles

HERSCHEL * FAR-INFRARED SPECTROSCOPY OF THE GALACTIC CENTER. HOT MOLECULAR GAS: SHOCKS VERSUS RADIATION NEAR Sgr A

We present a 52-671um spectral scan toward SgrA* taken with the PACS and SPIRE spectrometers onboard Herschel. The achieved angular resolution allows us to separate, for the first time at far-IR wavelengths, the emission toward the central cavity (gas in the inner central parsec of the galaxy) from that of the surrounding circum-nuclear disk. The spectrum toward SgrA* is dominated by strong [OIII], [OI], [CII], [NIII], [NII], and [CI] fine structure lines (in decreasing order of luminosity) arising in gas irradiated by UV-photons from the central stellar cluster. In addition, rotationally excited lines of 12CO (from J=4-3 to 24-23), 13CO, H2O, OH, H3O+, HCO+ and HCN, as well as ground-state absorption lines of OH+, H2O+, H3O+, CH+, H2O, OH, HF, CH and NH are detected. The excitation of the 12CO ladder is consistent with a hot isothermal component at Tk ~ 10^{3.1} K and n(H2)< 10^4 cm^{-3}. It is also consistent with a distribution of temperature components at higher density with most CO at Tk<300 K. The detected molecular features suggest that, at present, neither very enhanced X-ray, nor cosmic-ray fluxes play a dominant role in the heating of the hot molecular gas. The hot CO component (either the bulk of the CO column or just a small fraction depending on the above scenario) results from a combination of UV- and shock-driven heating. If irradiated dense clumps/clouds do not exist, shocks likely dominate the heating of the hot molecular gas. This is consistent with the high-velocity gas detected toward SgrA*.

GASPS—A Herschel Survey of Gas and Dust in Protoplanetary Disks: Summary and Initial Statistics

ABSTRACTWe describe a large-scale far-infrared line and continuum survey of protoplanetary disk through to young debris disk systems carried out using the ACS instrument on the Herschel Space Observatory. This Open Time Key program, known as GASPS (Gas Survey of Protoplanetary Systems), targeted ∼250 young stars in narrow wavelength regions covering the [OI] fine structure line at 63 μm the brightest far-infrared line in such objects. A subset of the brightest targets were also surveyed in [OI]145 μm, [CII] at 157 μm, as well as several transitions of H2O and high-excitation CO lines at selected wavelengths between 78 and 180 μm. Additionally, GASPS included continuum photometry at 70, 100 and 160 μm, around the peak of the dust emission. The targets were SED Class II–III T Tauri stars and debris disks from seven nearby young associations, along with a comparable sample of isolated Herbig AeBe stars. The aim was to study the global gas and dust content in a wide sample of circumstellar disks, combining the results with models in a systematic way. In this overview paper we review the scientific aims, target selection and observing strategy of the program. We summarise some of the initial results, showing line identifications, listing the detections, and giving a first statistical study of line detectability. The [OI] line at 63 μm was the brightest line seen in almost all objects, by a factor of ∼10. Overall [OI]63 μm detection rates were 49%, with 100% of HAeBe stars and 43% of T Tauri stars detected. A comparison with published disk dust masses (derived mainly from sub-mm continuum, assuming standard values of the mm mass opacity) shows a dust mass threshold for [OI]63 μm detection of ∼10-5 M⊙. Normalising to a distance of 140 pc, 84% of objects with dust masses ≥10-5 M⊙ can be detected in this line in the present survey; 32% of those of mass 10-6–10-5 M⊙, and only a very small number of unusual objects with lower masses can be detected. This is consistent with models with a moderate UV excess and disk flaring. For a given disk mass, [OI] detectability is lower for M stars compared with earlier spectral types. Both the continuum and line emission was, in most systems, spatially and spectrally unresolved and centred on the star, suggesting that emission in most cases was from the disk. Approximately 10 objects showed resolved emission, most likely from outflows. In the GASPS sample, [OI] detection rates in T Tauri associations in the 0.3–4 Myr age range were ∼50%. For each association in the 5–20 Myr age range, ∼2 stars remain detectable in [OI]63 μm, and no systems were detected in associations with age >20 Myr. Comparing with the total number of young stars in each association, and assuming a ISM-like gas/dust ratio, this indicates that ∼18% of stars retain a gas-rich disk of total mass ∼1 MJupiter for 1–4 Myr, 1–7% keep such disks for 5–10 Myr, but none are detected beyond 10–20 Myr. The brightest [OI] objects from GASPS were also observed in [OI]145 μm, [CII]157 μm and CO J = 18 - 17, with detection rates of 20–40%. Detection of the [CII] line was not correlated with disk mass, suggesting it arises more commonly from a compact remnant envelope.

Accurate measurements of carbon monoxide in humid air using the cavity ring-down spectroscopy (CRDS) technique

Abstract. Accurate measurements of carbon monoxide (CO) in humid air have been made using the cavity ring-down spectroscopy (CRDS) technique. The measurements of CO mole fractions are determined from the strength of its spectral absorption in the near-infrared region (~1.57 μm) after removing interferences from adjacent carbon dioxide (CO2) and water vapor (H2O) absorption lines. Water correction functions that account for the dilution and pressure-broadening effects as well as absorption line interferences from adjacent CO2 and H2O lines have been derived for CO2 mole fractions between 360–390 ppm and for reported H2O mole fractions between 0–4%. The line interference corrections are independent of CO mole fractions. The dependence of the line interference correction on CO2 abundance is estimated to be approximately −0.3 ppb/100 ppm CO2 for dry mole fractions of CO. Comparisons of water correction functions from different analyzers of the same type show significant differences, making it necessary to perform instrument-specific water tests for each individual analyzer. The CRDS analyzer was flown on an aircraft in Alaska from April to November in 2011, and the accuracy of the CO measurements by the CRDS analyzer has been validated against discrete NOAA/ESRL flask sample measurements made on board the same aircraft, with a mean difference between integrated in situ and flask measurements of −0.6 ppb and a standard deviation of 2.8 ppb. Preliminary testing of CRDS instrumentation that employs improved spectroscopic model functions for CO2, H2O, and CO to fit the raw spectral data (available since the beginning of 2012) indicates a smaller water vapor dependence than the models discussed here, but more work is necessary to fully validate the performance. The CRDS technique provides an accurate and low-maintenance method of monitoring the atmospheric dry mole fractions of CO in humid air streams.

EVIDENCE FOR A SNOW LINE BEYOND THE TRANSITIONAL RADIUS IN THE TW Hya PROTOPLANETARY DISK

We present an observational reconstruction of the radial water vapor content near the surface of the TW Hya transitional protoplanetary disk, and report the first localization of the snow line during this phase of disk evolution. The observations are comprised of Spitzer-IRS, Herschel-PACS, and Herschel-HIFI archival spectra. The abundance structure is retrieved by fitting a two-dimensional disk model to the available star+disk photometry and all observed H2O lines, using a simple step-function parameterization of the water vapor content near the disk surface. We find that water vapor is abundant (~10^{-4} per H2) in a narrow ring, located at the disk transition radius some 4AU from the central star, but drops rapidly by several orders of magnitude beyond 4.2 AU over a scale length of no more than 0.5AU. The inner disk (0.5-4AU) is also dry, with an upper limit on the vertically averaged water abundance of 10^{-6} per H2. The water vapor peak occurs at a radius significantly more distant than that expected for a passive continuous disk around a 0.6 Msun star, representing a volatile distribution in the TW Hya disk that bears strong similarities to that of the solar system. This is observational evidence for a snow line that moves outward with time in passive disks, with a dry inner disk that results either from gas giant formation or gas dissipation and a significant ice reservoir at large radii. The amount of water present near the snow line is sufficient to potentially catalyze the (further) formation of planetesimals and planets at distances beyond a few AU.

WATER VAPOR IN THE PROTOPLANETARY DISK OF DG Tau

Water is key in the evolution of protoplanetary disks and the formation of comets and icy/water planets. While high excitation water lines originating in the hot inner disk have been detected in several T Tauri stars (TTSs), water vapor from the outer disk, where most of water ice reservoir is stored, was only reported in the closeby TTS TW Hya. We present spectrally resolved Herschel/HIFI observations of the young TTS DG Tau in the ortho- and para- water ground-state transitions at 557, 1113 GHz. The lines show a narrow double-peaked profile, consistent with an origin in the outer disk, and are ~19-26 times brighter than in TW Hya. In contrast, CO and [C II] lines are dominated by emission from the envelope/outflow, which makes H2O lines a unique tracer of the disk of DG Tau. Disk modeling with the thermo-chemical code ProDiMo indicates that the strong UV field, due to the young age and strong accretion of DG Tau, irradiates a disk upper layer at 10-90 AU from the star, heating it up to temperatures of 600 K and producing the observed bright water lines. The models suggest a disk mass of 0.015-0.1 Msun, consistent with the estimated minimum mass of the solar nebula before planet formation, and a water reservoir of ~1e2-1e3 Earth oceans in vapour, and ~100 times larger in the form of ice. Hence, this detection supports the scenario of ocean delivery on terrestrial planets by impact of icy bodies forming in the outer disk.

H2O emission in high-zultra-luminous infrared galaxies

Using IRAM PdBI we report the detection of H2O in six new lensed ultra-luminous starburst galaxies at high redshift, discovered in the Herschel H-ATLAS survey. The sources are detected either in the 2_{02}-1_{11} or 2_{11}-2_{02} H_2O emission lines with integrated line fluxes ranging from 1.8 to 14 Jy.km/s. The corresponding apparent luminosities are mu x L_H2O ~ 3-12 x 10^8 Lo, where mu is the lensing magnification factor (3 < mu < 12). These results confirm that H2O lines are among the strongest molecular lines in such galaxies, with intensities almost comparable to those of the high-J CO lines, and same profiles and line widths (200-900 km/s) as the latter. With the current sensitivity of PdBI, H2O can therefore easily be detected in high-z lensed galaxies (with F(500um) > 100 mJy) discovered in the Herschel surveys. Correcting the luminosities for lensing amplification, L_H2O is found to have a strong dependence on the IR luminosity, varying as ~L_IR^{1.2}. This relation which needs to be confirmed with better statistics, may indicate a role of radiative (IR) excitation of the H2O lines, and implies that high-z galaxies with L_IR >~ 10^13 Lo tend to be very strong emitters in H2O, that have no equivalent in the local universe.

Observations of D/H ratios in H2O, HCl, and HF on Venus and new DCl and DF line strengths

Intensities of the spectral lines in the fundamental bands of D35Cl and DF were calculated using the semi-empirical dipole moment functions derived from the most accurate and precise measurements of intensities of the ro-vibrational lines of H35Cl and HF. Values obtained in this way for the deuterated species are superior to any available measured or calculated data to date.Our study of the D/H ratios in H2O, HCl, and HF on Venus is based on spatially-resolved high-resolution spectroscopy using the CSHELL spectrograph at NASA IRTF. Search for DF on Venus using its R5 (1-0) line at 3024.054cm−1 results in a DF mixing ratio of 0.23±0.11ppb that corresponds to (D/H)HF=420±200 times that in the Standard Mean Ocean Water (SMOW). H2O abundances on Venus were retrieved using lines at 3022.366 and 3025.761cm−1 that were observed at an exceptionally low overhead telluric water abundance of 0.3pr.mm. The measured H2O mixing ratios at 74km vary insignificantly between 55°S and 55°N with a mean value of 3.2ppm. When compared with simultaneous observations of HDO near 2722cm−1, this results in (D/H)H2O=95±15 times SMOW. Reanalysis of the observation of the D35Cl R4 (1-0) line at 2141.540cm−1 (Krasnopolsky, V.A. [2012b]. Icarus 219, 244–249) using the improved line strength and more thorough averaging of the spectra gives (D/H)HCl=190±50 times SMOW.The similarity of the measured (D/H)H2O=95±15 at 74km with 120±40 observed by De Bergh et al. (De Bergh, C., Bezard, B., Owen, T., Crisp, D., Maillard, J.P., Lutz, B.L. [1991]. Science 251, 547–549) below the clouds favors the constant (D/H)H2O from the surface to the mesosphere, in accord with the prediction by theory. D/H≈100 removes a difference of a factor of 2 between H2O abundances in the observations by Krasnopolsky (Krasnopolsky, V.A. [2010b]. Icarus 209, 314–322) and the Venus Express nadir observations (Cottini, V., Ignatiev, N.I., Piccioni, G., Drossart, P., Grassi, D., Markiewicz, W.J. [2012]. Icarus 217, 561–569). Equivalent widths of the HDO and H2O lines are similar in our observations; therefore some errors cancel out in their ratios. Photochemistry of HCl in the mesosphere tends to enrich D in HCl and deplete it in H2O. This may be an explanation of the twofold difference between the observed D/H in HCl and H2O.An alternative explanation is based on (D/H)H2O≈200 observed in the mesosphere by Bjoraker et al. (Bjoraker, G.L., Larson, H.P., Mumma, M.J., Timmermann, R., Montani, J.L. [1992]. Bull. Am. Astron. Soc. 24, 995) and Fedorova et al. (Fedorova, A. et al. J. Geophys. Res. 113, E00B22). This means an effective exchange of D between H2O and HCl and almost equal D/H in both species. However, this requires a twofold increase in D/H from the lower atmosphere to the mesosphere. This increase is not supported by theory; furthermore, condensation processes usually deplete D/H above the clouds.Photochemistry of HF has not been studied; it proceeds mostly in the lower thermosphere, and D/H in HF may be very different from that in H2O. Overall, the observational data on D/H in all hydrogen-bearing species on Venus are helpful to solve the problem of deuterium fractionation on Venus.

Warm water deuterium fractionation in IRAS 16293-2422

Measuring the water deuterium fractionation in the inner warm regions of low-mass protostars has so far been hampered by poor angular resolution obtainable with single-dish ground- and space-based telescopes. Observations of water isotopologues using (sub)millimeter wavelength interferometers have the potential to shed light on this matter. Observations toward IRAS 16293-2422 of the 5(3,2)-4(4,1) transition of H2-18O at 692.07914 GHz from Atacama Large Millimeter/submillimeter Array (ALMA) as well as the 3(1,3)-2(2,0) of H2-18O at 203.40752 GHz and the 3(1,2)-2(2,1) transition of HDO at 225.89672 GHz from the Submillimeter Array (SMA) are presented. The 692 GHz H2-18O line is seen toward both components of the binary protostar. Toward one of the components, "source B", the line is seen in absorption toward the continuum, slightly red-shifted from the systemic velocity, whereas emission is seen off-source at the systemic velocity. Toward the other component, "source A", the two HDO and H2-18O lines are detected as well with the SMA. From the H2-18O transitions the excitation temperature is estimated at 124 +/- 12 K. The calculated HDO/H2O ratio is (9.2 +/- 2.6)*10^(-4) - significantly lower than previous estimates in the warm gas close to the source. It is also lower by a factor of ~5 than the ratio deduced in the outer envelope. Our observations reveal the physical and chemical structure of water vapor close to the protostars on solar-system scales. The red-shifted absorption detected toward source B is indicative of infall. The excitation temperature is consistent with the picture of water ice evaporation close to the protostar. The low HDO/H2O ratio deduced here suggests that the differences between the inner regions of the protostars and the Earth's oceans and comets are smaller than previously thought.

Mapping water in protostellar outflows withHerschel

We investigate on the spatial and velocity distribution of H2O along the L1448 outflow, its relationship with other tracers, and its abundance variations, using maps of the o-H2O 1_{10}-1_{01} and 2_{12}-1_{01} transitions taken with the Herschel-HIFI and PACS instruments, respectively. Water emission appears clumpy, with individual peaks corresponding to shock spots along the outflow. The bulk of the 557 GHz line is confined to radial velocities in the range \pm 10-50 km/s but extended emission associated with the L1448-C extreme high velocity (EHV) jet is also detected. The H2O 1_{10}-1_{01}/CO(3-2) ratio shows strong variations as a function of velocity that likely reflect different and changing physical conditions in the gas responsible for the emissions from the two species. In the EHV jet, a low H2O/SiO abundance ratio is inferred, that could indicate molecular formation from dust free gas directly ejected from the proto-stellar wind. We derive averaged Tkin and n(H2) values of about 300-500 K and 5 10^6 cm-3 respectively, while a water abundance with respect to H2 of the order of 0.5-1 10^{-6} along the outflow is estimated. The fairly constant conditions found all along the outflow implies that evolutionary effects on the timescales of outflow propagation do not play a major role in the H2O chemistry. The results of our analysis show that the bulk of the observed H2O lines comes from post-shocked regions where the gas, after being heated to high temperatures, has been already cooled down to a few hundred K. The relatively low derived abundances, however, call for some mechanism to diminish the H2O gas in the post-shock region. Among the possible scenarios, we favor H2O photodissociation, which requires the superposition of a low velocity non-dissociative shock with a fast dissociative shock able to produce a FUV field of sufficient strength.

H2O line positions in the 784–795 nm region with 10−9 accuracy

H216O lines in the spectral range of 12,573–12,753cm−1 have been recorded by cavity ring-down spectroscopy. Low-pressure water vapor (0.25Torr) was used to limit the pressure-induced line shift. The absolute line positions were calibrated with Rb atomic transitions and a thermo-stabilized Fabry–Pérot interferometer. Positions of 73 lines with intensities larger than 1×10−25cm−1/(moleculecms−2) have been determined. For well-isolated lines, the absolute frequency accuracy is estimated to be 3×10−5cm−1, which is also confirmed by the ground-state combination differences. Comparison between the line positions obtained in this work and those from HITRAN shows a systematic deviation of 0.001cm−1.

The complete far-infrared and submillimeter spectrum of the Class 0 protostar Serpens SMM1 obtained withHerschel

We present the first complete 55-671 um spectral scan of a low-mass Class 0 protostar (Serpens SMM1) taken with the PACS and SPIRE spectrometers on board Herschel. More than 145 lines have been detected, most of them rotationally excited lines of 12CO (full ladder from J=4-3 to 42-41), H2O, OH, 13CO, HCN and HCO+ . Bright [OI]63,145um and weaker [CII]158 and [CI]370,609um lines are also detected. Mid-IR spectra retrieved from the Spitzer archive are also first discussed here, they show clear detections of [NeII], [FeII], [SiII] and [SI] fine structure lines as well as weaker H2 S(1) and S(2) pure rotational lines. The observed line luminosity is dominated by CO (~54%), H2O (~22%), [OI] (~12%) and OH (~9%) emission. A non-LTE radiative transfer model allowed us to quantify the contribution of the 3 different temperature components suggested by the 12CO rotational ladder (Tk(hot)~800 K, Tk(warm)~375 K and Tk(cool)~150 K). Gas densities n(H2)~5x10^6 cm^-3 are needed to reproduce the observed far-IR lines arising from shocks in the inner protostellar envelope for which we derive upper limit abundances of x(CO)~10^-4, x(H2O)~0.2x10^-5 and x(OH)~10^-6. The lower energy submm 12CO and H2O lines show more extended emission that we associate with the cool entrained outflow gas. Fast dissociative J-shocks (v_s > 60 km s^-1) as well as lower velocity non-dissociative shocks (v_s < 20 km s^-1) are needed to explain both the atomic lines and the hot CO and H2O lines respectively. Observations also show the signature of UV radiation and thus, most observed species likely arise in UV-irradiated shocks. Dissociative J-shocks produced by an atomic jet are the most probable origin of [OI] and OH emission and of a significant fraction of the warm CO emission. In addition, H2O photodissociation in UV-irradiated non-dissociative shocks can also contribute to the [OI] and OH emission.

MASER OBSERVATIONS OF WESTERLUND 1 AND COMPREHENSIVE CONSIDERATIONS ON MASER PROPERTIES OF RED SUPERGIANTS ASSOCIATED WITH MASSIVE CLUSTERS

We report the results of Australia Telescope Compact Array (ATCA) observations of the Westerlund~1 (Wd1) region in the SiO v=1, J=1-0 and H2O 6(16)-5(23) maser lines, and we also report the analysis of maser properties of red supergiants (RSGs) associated with 6 massive clusters including Wd1. The primary purpose of this research is to explore possibilities of using maser emission for investigating the nature of massive clusters and associated RSGs. The SiO v=1, J=1-0 and H2O 6(16)-5(23) maser lines are detected toward 2 of 4 known RSGs in Wd1. The large velocity ranges of maser emission are consistent with the RSG status. RSGs with maser emission tend to exhibit redder log (F21/F12) and [K-12.13] colors compared to RSGs with no maser emission. The mass-loss rates derived from dust radiative transfer modeling suggest that RSGs with maser emission tend to exhibit larger mass-loss rates compared to RSGs with no maser emission. In an extended sample of 57 RSGs in 6 massive clusters, detections in the SiO line tend to homogeneously distribute in absolute luminosity L, whereas those in the H2O line tend to distribute in a region with large L values.

Simultaneous Measurements of Multiple Parameters at Elevated Temperature Using a Frequency-Division Multiplexing Scheme with Tunable Diode Lasers

A multiplexed diode-laser sensor system based on second harmonic detection of wavelength modulation spectroscopy (WMS) is developed for application at elevated temperatures with two near-infrared diode lasers multiplexed using a frequency-division multiplexing scheme. One laser is tuned over a H(2)O line pair near 7079.176 and 7079.855 cm(-1), and another laser is tuned over a pair of CO(2) and CO lines near 6361.250 and 6361.344 cm(-1). Temperature and concentrations of H(2)O, CO(2), and CO could be measured simultaneously by this system. In order to remove the need for calibration and correct for transmission variation due to beam steering, mechanical misalignments, soot, and windows fouling, the WMS-1f normalized 2f method is used. Demonstration experiments are conducted in a heated static cell. The precision of temperature and the concentrations for H(2)O, CO(2), and CO are found to be 1.57%, 3.87%, 3.01%, and 3.58%, respectively. These results illustrate the potential of this sensor for applications at high temperatures.

An upper limit for the water outgassing rate of the main-belt comet 176P/LINEAR observed withHerschel/HIFI

176P/LINEAR is a member of the new cometary class known as main-belt comets (MBCs). It displayed cometary activity shortly during its 2005 perihelion passage that may be driven by the sublimation of sub-surface ices. We have therefore searched for emission of the H2O 110-101 ground state rotational line at 557 GHz toward 176P/LINEAR with the Heterodyne Instrument for the Far Infrared (HIFI) on board the Herschel Space Observatory on UT 8.78 August 2011, about 40 days after its most recent perihelion passage, when the object was at a heliocentric distance of 2.58 AU. No H2O line emission was detected in our observations, from which we derive sensitive 3-sigma upper limits for the water production rate and column density of < 4e25 molec/s and of < 3e10 cm^{-2}, respectively. From the peak brightness measured during the object's active period in 2005, this upper limit is lower than predicted by the relation between production rates and visual magnitudes observed for a sample of comets by Jorda et al. (2008) at this heliocentric distance. Thus, 176P/LINEAR was likely less active at the time of our observation than during its previous perihelion passage. The retrieved upper limit is lower than most values derived for the H2O production rate from the spectroscopic search for CN emission in MBCs.

The abundance, vertical distribution and origin of H2O in Titan’s atmosphere: Herschel observations and photochemical modelling

Disk-averaged observations of water vapor in Titan’s atmosphere acquired with the Herschel satellite are reported. We use a combination of unresolved measurements of three H2O rotational lines at 66.4, 75.4 and 108.0μm with the PACS instrument, and spectrally-resolved observations of two other transitions at 557GHz (538μm) and 1097GHz (273μm) with the HIFI instrument, to infer the vertical profile of H2O over the 100–450km altitude range. Monitoring of the 66.4μm line indicates no variation between Titan leading and trailing sides, nor variation over a ∼1year interval. Both the narrow (2–4MHz) widths of the HIFI-observed lines, and the relative contrasts of the five H2O lines indicate that the H2O mole fraction strongly increases with altitude, with a best fit mole fraction of q0=(2.3±0.6)×10−11 at a pressure p=12.1mbar, a slope −d(lnq)/d(lnp)=0.49±0.07, and a H2O column density of (1.2+/−0.2)×1014cm−2. This H2O profile also matches the original ISO observations of Titan H2O. Water vertical profiles previously proposed on the basis of 1-D photochemical models are too water-rich, and none of them have the adequate slope; in particular, the water profiles of Lara et al. (Lara, L.M., Lellouch, E., López-Moreno, J.J., Rodrigo, R. [1996]. J. Geophys. Res. E 101, 23261–23283) and Hörst et al. (Hörst, S.M., Vuitton, V., Yelle, R.V. [2008]. J. Geophys. Res. E 113, E10006) are too steep and too shallow, respectively, in the lower stratosphere. Photochemical models of oxygen species in Titan’s atmosphere are reconsidered, updating the Lara et al. model for oxygen chemistry, and adjusting the eddy diffusion coefficient in order to match both our H2O observations and the C2H6 and C2H2 vertical profiles determined from Cassini/CIRS. We find that the H2O profile can be reproduced by invoking a OH/H2O influx of (2.7–3.4)×105molcm−2s−1, referred to the surface. This is essentially one order of magnitude lower than invoked by previous modellers, and also a factor of ∼10 less than required to match the observed CO2 mole fraction. As H2O has a more shorter atmospheric lifetime than CO2 (∼9years vs ∼450years), we suggest that this reflects a temporal change in the oxygen influx into Titan, that could be currently much smaller than averaged over the past centuries. Both interplanetary dust particles and Enceladus’ activity appear to provide sufficient supply for the current Titan H2O. We tentatively favor the latter source as potentially more prone to time variability.

THE CHESS SURVEY OF THE L1157-B1 SHOCK REGION: CO SPECTRAL SIGNATURES OF JET-DRIVEN BOW SHOCKS

The unprecedented sensitivity of Herschel coupled with the high resolution of the HIFI spectrometer permits studies of the intensity-velocity relationship I(v) in molecular outflows, over a higher excitation range than possible up to now. In the course of the CHESS Key Program, we have observed toward the bright bowshock region L1157-B1 the CO rotational transitions between J=5-4 and J=16-15 with HIFI, and the J=1-0, 2-1 and 3-2 with the IRAM-30m and the CSO telescopes. We find that all the line profiles I_{CO}(v) are well fit by a linear combination of three exponential laws exp(-|v/v_0|) with v_0= 12.5, 4.4 and 2.5km/s. The first component dominates the CO emission at J_up > 13, as well as the high-excitation lines of SiO and H2O. The second component dominates for 3 < J_up < 10 and the third one for J_up < 2. We show that these exponentials are the signature of quasi-isothermal shocked gas components: the impact of the jet against the L1157-B1 bowshock (T= 210K), the walls of the outflow cavity associated with B1 (T= 64K) and the older cavity L1157-B2 (T= 23K), respectively. Analysis of the CO line flux in the Large-Velocity Gradient approximation further shows that the emission arises from dense gas (n(H2) > 1e5-1e6 cm-3) close to LTE up to J=20. We find that the CO J=2-1 intensity-velocity relation observed in various other molecular outflows is satisfactorily fit by similar exponential laws, which may hold an important clue to their entrainment process.

Herschel/PACS observations of young sources in Taurus: the far-infrared counterpart of optical jets

Observations of the atomic and molecular line emission associated with jets and outflows emitted by young stellar objects can be used to trace the various evolutionary stages they pass through as they evolve to become main sequence stars. To understand the relevance of atomic and molecular cooling in shocks, and how accretion and ejection efficiency evolves with the source evolutionary state, we will study the far-infrared counterparts of bright optical jets associated with Class I and II sources in Taurus (T Tau, DG Tau A, DG Tau B, FS Tau A+B, and RW Aur). We have analysed Herschel/PACS observations of a number of atomic ([OI]63um, 145um, [CII]158um) and molecular (high-J CO, H2O, OH) lines, collected within the OTKP GASPS. To constrain the origin of the detected lines we have compared the FIR emission maps with the emission from optical-jets and millimetre-outflows, and the line fluxes and ratios with predictions from shock and disk models. All of the targets are associated with extended emission in the atomic lines correlated with the direction of the optical jet/mm-outflow. The atomic lines can be excited in fast dissociative J-shocks. The molecular emission, on the contrary, originates from a compact region, that is spatially and spectrally unresolved. Slow C- or J- shocks with high pre-shock densities reproduce the observed H2O and high-J CO lines; however, the disk and/or UV-heated outflow cavities may contribute to the emission. While the cooling is dominated by CO and H2O lines in Class 0 sources, [OI] becomes an important coolant as the source evolves and the environment is cleared. The cooling and mass loss rates estimated for Class II and I sources are one to four orders of magnitude lower than for Class 0 sources. This provides strong evidence to indicate that the outflow activity decreases as the source evolves.

Dosage de la 25OH D : enquête descriptive et rétrospective de 627 dosages pendant l’hiver 2010–2011 dans un centre hospitalier du Nord de la France

Intensities of the spectral lines in the fundamental bands of D35Cl and DF were calculated using the semi-empirical dipole moment functions derived from the most accurate and precise measurements of intensities of the ro-vibrational lines of H35Cl and HF. Values obtained in this way for the deuterated species are superior to any available measured or calculated data to date.Our study of the D/H ratios in H2O, HCl, and HF on Venus is based on spatially-resolved high-resolution spectroscopy using the CSHELL spectrograph at NASA IRTF. Search for DF on Venus using its R5 (1-0) line at 3024.054 cm−1 results in a DF mixing ratio of 0.23 ± 0.11 ppb that corresponds to (D/H)HF = 420 ± 200 times that in the Standard Mean Ocean Water (SMOW). H2O abundances on Venus were retrieved using lines at 3022.366 and 3025.761 cm−1 that were observed at an exceptionally low overhead telluric water abundance of 0.3 pr. mm. The measured H2O mixing ratios at 74 km vary insignificantly between 55°S and 55°N with a mean value of 3.2 ppm. When compared with simultaneous observations of HDO near 2722 cm−1, this results in (D/H)H2O = 95 ± 15 times SMOW. Reanalysis of the observation of the D35Cl R4 (1-0) line at 2141.540 cm−1 (Krasnopolsky, V.A. [2012b]. Icarus 219, 244–249) using the improved line strength and more thorough averaging of the spectra gives (D/H)HCl = 190 ± 50 times SMOW.The similarity of the measured (D/H)H2O = 95 ± 15 at 74 km with 120 ± 40 observed by De Bergh et al. (De Bergh, C., Bezard, B., Owen, T., Crisp, D., Maillard, J.P., Lutz, B.L. [1991]. Science 251, 547–549) below the clouds favors the constant (D/H)H2O from the surface to the mesosphere, in accord with the prediction by theory. D/H ≈ 100 removes a difference of a factor of 2 between H2O abundances in the observations by Krasnopolsky (Krasnopolsky, V.A. [2010b]. Icarus 209, 314–322) and the Venus Express nadir observations (Cottini, V., Ignatiev, N.I., Piccioni, G., Drossart, P., Grassi, D., Markiewicz, W.J. [2012]. Icarus 217, 561–569). Equivalent widths of the HDO and H2O lines are similar in our observations; therefore some errors cancel out in their ratios. Photochemistry of HCl in the mesosphere tends to enrich D in HCl and deplete it in H2O. This may be an explanation of the twofold difference between the observed D/H in HCl and H2O.An alternative explanation is based on (D/H)H2O ≈ 200 observed in the mesosphere by Bjoraker et al. (Bjoraker, G.L., Larson, H.P., Mumma, M.J., Timmermann, R., Montani, J.L. [1992]. Bull. Am. Astron. Soc. 24, 995) and Fedorova et al. (Fedorova, A. et al. J. Geophys. Res. 113, E00B22). This means an effective exchange of D between H2O and HCl and almost equal D/H in both species. However, this requires a twofold increase in D/H from the lower atmosphere to the mesosphere. This increase is not supported by theory; furthermore, condensation processes usually deplete D/H above the clouds.Photochemistry of HF has not been studied; it proceeds mostly in the lower thermosphere, and D/H in HF may be very different from that in H2O. Overall, the observational data on D/H in all hydrogen-bearing species on Venus are helpful to solve the problem of deuterium fractionation on Venus.

Resonator spectroscopy of the atmosphere in the 350–500 GHz range

Results of studies of the absorption spectra of laboratory air and major atmospheric gases mixed with water vapor in the 350–500GHz frequency range at atmospheric pressure and room temperature are presented. The spectra were registered for the first time by highly sensitive microwave method employing the resonator spectrometer. Analysis of the spectra allowed determining integrated intensities and values of nitrogen, oxygen and air pressure shift and broadening of the most intense lines of H2O and O2 molecules within this range. Some parameters were measured for the first time. The values of parameters were compared with results of earlier measurements and calculations. In addition, a complementary investigation of collisional parameters of the most intense water lines within the considered range by means of the spectrometer with radioacoustic absorption detection at low pressure was performed. Data of these measurements agree with results of analysis of atmospheric spectra within statistical accuracy of both experiments. The research made is important, in particular, for enhancing accuracy of models of radiation propagation in the atmosphere.

Influence of velocity effects on the shape of N2 (and air) broadened H2O lines revisited with classical molecular dynamics simulations

The modeling of the shape of H(2)O lines perturbed by N(2) (and air) using the Keilson-Storer (KS) kernel for collision-induced velocity changes is revisited with classical molecular dynamics simulations (CMDS). The latter have been performed for a large number of molecules starting from intermolecular-potential surfaces. Contrary to the assumption made in a previous study [H. Tran, D. Bermejo, J.-L. Domenech, P. Joubert, R. R. Gamache, and J.-M. Hartmann, J. Quant. Spectrosc. Radiat. Transf. 108, 126 (2007)], the results of these CMDS show that the velocity-orientation and -modulus changes statistically occur at the same time scale. This validates the use of a single memory parameter in the Keilson-Storer kernel to describe both the velocity-orientation and -modulus changes. The CMDS results also show that velocity- and rotational state-changing collisions are statistically partially correlated. A partially correlated speed-dependent Keilson-Storer model has thus been used to describe the line-shape. For this, the velocity changes KS kernel parameters have been directly determined from CMDS, while the speed-dependent broadening and shifting coefficients have been calculated with a semi-classical approach. Comparisons between calculated spectra and measurements of several lines of H(2)O broadened by N(2) (and air) in the ν(3) and 2ν(1) + ν(2) + ν(3) bands for a wide range of pressure show very satisfactory agreement. The evolution of non-Voigt effects from Doppler to collisional regimes is also presented and discussed.