A field study was conducted on a Hubbard loamy sand low in exchangeable Ca to determine the influence of gypsum on cauliflower (Brassica oleracea Botrytis cv. ‘Snow Crown') nutrition, yield, and quality. Four rates of gypsum (0, 560, 1120, and 2240 kg/ha) were incorporated before planting. Extractable soil Ca and S increased linearly with increasing gypsum rate. Despite increases in tissue Ca with gypsum application, tipburn of immature leaves was apparent in all treatments. Gypsum had no effect on final yield, curd size, or tipburn severity. Relative levels of Ca, K, P, and Mg were determined in frozen‐hydrated and freeze‐dried leaf tissue from tipburned and non‐tipburned leaves using a scanning electron microscope with x‐ray microanalysis. Distribution of these elements was also determined in digested leaf tissue using an ICP spectrometer. Results of x‐ray microanalysis indicated that Ca was relatively low and K and P relatively high near necrotic tip areas. No consistent differences in Ca, K, ...