Bubble Growth Research Articles

Formation of bubbles and microexplosions in burning boron agglomerates

Combining laser ignition tests with quenched particle cross-sectional analyses, this study explores the formation of bubbles and microexplosions in burning boron agglomerates, and discusses the plausible mechanisms behind the microexplosion (expansion–rupture) phenomenon. High-resolution images reveal that these phenomena are caused by bubble nucleation and growth within the molten droplet. Based on the timescale, it is categorized into weak expansion and strong expansion phenomena. The expansion rate of droplets during the weak expansion process mostly ranges between 0.006 m/s and 0.4 m/s, while during the strong expansion process, it predominantly falls between 0.4 m/s and 1 m/s. An increase in ambient pressure results in the delayed occurrence and reduced frequency of the expansion–rupture phenomenon. When the ambient pressure exceeds 3 atm, the expansion phenomenon no longer occurs. In addition, a decrease in the initial diameter of the agglomerates lowers the overall occurrences of expansion–rupture. Analysis of the quenched particle cross-sections reveals that the size and density distributions of the pores within the boron agglomerates reduce gradually during the combustion process. In addition, the surface oxide layers of certain pores are removed during combustion. Estimates of the vaporization rates of (BO)n and B2O3 support the speculation that the expansion of molten boron droplets is attributed to the evaporation of boron oxide layer. In this process, the molten boron acts as a heating surface to evaporate the boron oxide trapped inside the droplet, thus producing B2O3, B2O2, and BO, and leading to droplet growth and tearing of the liquid film. Analysis of bubble growth indicates that the merging of adjacent bubbles to reach the critical nucleation size is probable the starting point of the expansion process. These results can be helpful in promoting the combustion efficiency of boron within the combustion chamber.

Performance Enhancement of Electrocatalytic Hydrogen Evolution through Coalescence-Induced Bubble Dynamics.

The evolution of electrogenerated gas bubbles during water electrolysis can significantly hamper the overall process efficiency. Promoting the departure of electrochemically generated bubbles during (water) electrolysis is therefore beneficial. For a single bubble, a departure from the electrode surface occurs when buoyancy wins over the downward-acting forces (e.g., contact, Marangoni, and electric forces). In this work, the dynamics of a pair of H2 bubbles produced during the hydrogen evolution reaction in 0.5 M H2SO4 using a dual platinum microelectrode system is systematically studied by varying the electrode distance and the cathodic potential. By combining high-speed imaging and electrochemical analysis, we demonstrate the importance of bubble-bubble interactions in the departure process. We show that bubble coalescence may lead to substantially earlier bubble departure as compared to buoyancy effects alone, resulting in considerably higher reaction rates at a constant potential. However, due to continued mass input and conservation of momentum, repeated coalescence events with bubbles close to the electrode may drive departed bubbles back to the surface beyond a critical current, which increases with the electrode spacing. The latter leads to the resumption of bubble growth near the electrode surface, followed by buoyancy-driven departure. While less favorable at small electrode spacing, this configuration proves to be very beneficial at larger separations, increasing the mean current up to 2.4 times compared to a single electrode under the conditions explored in this study.

The growth of a single rising bubble in viscous solution and the resulting volatile removal

In the foam devolatilization, volatiles are removed accompanying with the growth of rising bubbles, and determining the amount of removed volatile is important in the design of devolatilization device. In this work, acetone and polydimethylsiloxane were used as the volatile and polymer respectively to study the single bubble growth process in the foam devolatilization. The variation of single bubble spherical equivalent radius and rising velocity in viscous solution were experimentally determined, and the effects of operational parameters (i.e., polymer viscosity, vacuum degree, solution temperature and volatile concentration) on bubble growth were evaluated. By analyzing the mechanics of bubble devolatilization, and based on the mass transfer boundary layer theory, the mass of removed volatile during bubble rising is determined, together establishing a correlation to predict the volatile removal amount.

Modeling of a liquid nitrogen droplet evaporating inside an immiscible liquid pool

Evaporation of liquid nitrogen in another immiscible liquid occurs in many industrial applications. Existing oversimplified one-dimensional (1D) quasi-steady models, although can quantitatively predict the evaporation rate by introducing an empirical fitting parameter, rely on configurations inconsistent with experimental observation so more rigorous models are required to get in-depth physical insights and improve modeling capability. This study proposes a 2D quasi-steady-state theoretical model, free of fitting parameters, that predicts the bubble growth rate and estimates the heat transfer rate for a liquid nitrogen droplet evaporating inside a liquid pool within the spherical bubble regime. The droplet's shape and position within a spherical bubble are determined by the equilibrium between the gravitational force and the upward pressure force resulting from the vapor flow between the droplet and the pool. The vapor layer thickness is calculated to be on the order of 10 microns. Notably, the primary contribution to heat transfer arises from the lower portion of the droplet, leading to local heat flux values up to approximately six times higher at the bottom compared to the top. The predicted bubble growth is quantitatively consistent with experimental data within the capillary spherical bubble regime. Furthermore, the overall heat transfer rate Q exhibits a distinct scaling relationship with the volume ratio between the bubble and droplet, yielding Q∼(Vb/Vd)−0.1.

Mass transport at gas-evolving electrodes

Direct numerical simulations are utilised to investigate mass-transfer processes at gas-evolving electrodes that experience successive formation and detachment of bubbles. The gas–liquid interface is modelled employing an immersed boundary method. We simulate the growth phase of the bubbles followed by their departure from the electrode surface in order to study the mixing induced by these processes. We find that the growth of the bubbles switches from a diffusion-limited mode at low to moderate fractional bubble coverages of the electrode to a reaction-limited growth dynamics at high coverages. Furthermore, our results indicate that the net transport within the system is governed by the effective buoyancy driving induced by the rising bubbles and that mechanisms commonly subsumed under the term ‘microconvection’ do not significantly affect the mass transport. Consequently, the resulting gas transport for different bubble sizes, current densities and electrode coverages can be collapsed onto one single curve and only depends on an effective Grashof number. The same holds for the mixing of the electrolyte when additionally taking the effect of surface blockage by attached bubbles into account. For the gas transport to the bubble, we find that the relevant Sherwood numbers also collapse onto a single curve when accounting for the driving force of bubble growth, incorporated in an effective Jakob number. Finally, linking the hydrogen transfer rates at the electrode and the bubble interface, an approximate correlation for the gas-evolution efficiency has been established. Taken together, these findings enable us to deduce parametrisations for all response parameters of the systems.

Optical Limiting Response of Porous Carbon Dispersions.

With the wide application of intense lasers, the protection of human eyes and detectors from laser damage is becoming more and more strict. In this paper, we study the nonlinear optical limiting (OL) properties of porous carbon with a super large specific surface area (2.9 × 103 m2/g) using the nanosecond Z-scan technique. Compared to the traditional OL material C60, the porous carbon material shows an excellent broadband limiting effect, and the limiting thresholds correspond to 0.11 J/cm2 for 532 nm and 0.25 J/cm2 for 1064 nm pulses, respectively. The nonlinear scattering experiments showed that the OL behavior was mainly attributed to the nonlinear scattering effect, which is caused by the rapid growth and expansion of bubbles in the dispersion induced by laser irradiation, and the scattered light distribution is consistent with the results of Mie's scattering. These results suggest that porous carbon materials are expected to be applied to the field of laser protection in the future to further protect the human eye and precision optical instruments.

Prior implantation of hydrogen as a mechanism to delay helium bubbles, blistering, and exfoliation in titanium

This study explores the delaying of the formation of helium bubbles and blisters in pure titanium by hydrogen pre-implantation. Titanium, implanted with helium (40 KeV, 5 × 1017 ions/cm²), exhibited large bubbles that cause exfoliation after heat treatment, whereas hydrogen pre-implantation inhibited bubble growth at room temperature and reduced the exfoliation after heat treatment.In the samples pre-implanted with hydrogen, we found evidence of helium diffusion delay by: (a) a fourfold reduction in bubble pressure (b) faceted cavities in the samples (c) a smaller increase in titanium lattice parameters (d) a 16-fold reduction in average bubble size and a sixfold reduction in bubble area fraction (e) a more than twofold decrease in exfoliation (f) a tendency toward the formation of larger bubbles as a result of heat treatment. We believe that it is reasonable to assume that the inhibition of helium diffusion between tetrahedral interstitial lattice sites takes place because of the occupation of the intermediate octahedral sites by hydrogen atoms.Evidence for the opposite effect, that is inhibition of the diffusion of hydrogen in the presence of helium, is found in the retention of hydrogen in the specimens at elevated temperatures. This retention allowed the existence of titanium hydride after heat treatment at 680 °C. The present study sheds light on the intricate interplay between hydrogen and helium in titanium, providing insights into mechanisms that can potentially mitigate helium-induced damage in materials.

Effect of nanocavity geometry on nanoscale nucleate boiling heat transfer

In recent years, surfaces with nanocavities have been identified to considerably improve boiling heat transfer, that is highly promising for advanced thermal energy systems. To boost developments in nanostructured boiling surfaces, effects of nanocavity geometry on nucleate boiling at the nanoscale are systematically studied for the first time by utilizing molecular dynamics simulation. Three typical nanocavities with rectangular, semicircular, and triangular cross-sectional shapes are constructed, which have the identical width and depth (8 nm and 4 nm). Moreover, three representative wetting conditions corresponding to different solid-liquid interaction strengths are further considered to provide a comprehensive understanding of geometry effects. The results manifest that nanocavity geometry effect on nucleate boiling can be attributed to the differences in their solid-liquid contact area and solid-liquid interactions play a vital role in reinforcement effectiveness. When the solid-liquid interaction is sufficiently strong (energy coefficient equals 1.5, termed ultra-superhydrophilicity), variations in nanocavity geometries will induce remarkable effects on boiling performance. Among three geometric configurations, the rectangular nanocavity exhibits the highest heat transfer efficiency and achieves maximum boiling enhancement, including significant improvements in bubble nucleation and growth, as well as critical heat flux. This study provides an essential insight into nanoscale boiling reinforcement mechanism.

Multi-tiered configurations improved flow boiling performance: Comparation investigation of leaf vein inspired two-tiered and three-tiered open microchannels

Microchannel heat sinks with expanding flow area along with the flow direction are able to suppress flow instability and reduce pressure drop during two-phase flow boiling by offering broadening volume for bubble elongation and growth that suppress the slug blockage and flow reversal. In this regard, microchannels with expanding area perpendicular to flow direction are supposed to obtain the comparable results, as the bubbles migrate to the downstream and top of microchannels simultaneously. However, the relevant study about multi-tiered microchannel heat sinks was limited and the corresponding flow boiling characteristics remained elusive. In this work, leaf vein inspired two-tiered open microchannel (LTWOMC) and three-tiered one (LTHOMC) were proposed and comparative flow boiling experiments were carried out. The outcomes indicated that LTWOMC obtained earlier ONB, which was 6.4 °C lower than LTHOMC at G = 220 kg/m2·s, the average local convective heat transfer coefficient (hcon) and average two-phase one (htp) of LTWOMC were maximumly enhanced up to 36.3% and 148.7% at G = 150 kg/m2·s, respectively. The pressure drop (ΔP) of LTWOMC was generally larger than LTHOMC at all mass fluxes, which led to the cooling coefficient of performances (COPs) of LTHOMC superior compared to LTWOMC under all working conditions. Moreover, LTHOMC exhibited better flow stability than LTWOMC with lower amplitudes and standard deviations of both wall temperature and pressure drop. In general, the three-tiered hierarchical configuration is more suitable than two-tiered one for flow boiling heat transfer.

He bubble-induced phase transformation of W grain boundaries revealed by accelerated molecular dynamics

The growth of He bubbles and the resulting impact on the microstructural evolution of W are of paramount importance to the plasma-facing materials community due to the application of W in Tokamak fusion reactors. Using accelerated molecular dynamics (AMD) techniques, we outline the structural evolution of grain boundaries (GBs) caused by growing He bubbles. It is discovered that when an alternative, low energy, high density GB structure or phase is available, He bubbles can induce a progressive phase transformation of the GB to the higher density phase by the continual nucleation of W Frenkel pairs. We find that the resulting W self-interstitials migrate to sites at the GB which are structurally related to the higher density phase, leading to the transformation. We discuss the implications of this progressive microstructural evolution on the growing He bubble and consider in general how He bubbles will impact the structural evolution of an arbitrary W GB. These findings of GB phase transformation are predicted to impact other damage events in W such as recrystallization, GB migration and defect segregation which must take these findings into account in order to accurately simulate a realistic W microstructure and hence extract experimentally meaningful data.

Effect of Al addition on the mechanical property and irradiation resistance of NbMoZr-based medium-entropy alloys

In this work, the Nb50Mo30Zr20 and Al5Nb50Mo30Zr15 alloys are successfully fabricated and the samples are irradiated by 5 MeV Xe+ ions at 350 °C and 750 °C. Room temperature compression results show that the addition of Al can effectively increase the compressive yield strength from ∼ 1288 MPa in NbMoZr alloy to ∼ 1703 MPa in AlNbMoZr alloy. The increase in strength is attributed to the solid solution strengthening, second phase strengthening and dendrite refinement strengthening due to the minor Al additions. After irradiation at 350 °C and 750 °C, the HCP-structured Zr phases precipitate in ternary NbMoZr alloy. In contrast, with the addition of Al atoms, the dendritic matrix of AlNbMoZr alloy can still maintain the BCC structure after irradiation, which exhibit a higher phase stability than NbMoZr alloy. Moreover, the Al suppress the growth of Xe bubbles and decrease the dislocation loops in AlNbMoZr alloy, as compared with those in the Al-free NbMoZr alloy. The relevant results can provide theoretical guidance for developing high-performance metals used in the field of advanced nuclear fuels.

Insights of rising bubble dynamics of air‐blown biomass gasification in bubbling fluidized bed gasifier

AbstractUnderstanding the complex dynamics and spatial distribution of rising bubbles in fluidized bed gasifiers is crucial for designing, optimizing, and scaling up of the reactor. However, existing studies on bubble dynamics mainly focused on cold flow investigations, failing to capture the behavior of bubbles under the influence of chemical reactions and intricate coupling of heat transfer. Therefore, a reactive Lagrangian model is established to explore intricate bubble behaviors during biomass air gasification. The model is well validated with experiment, and the impact of operating parameters including bed temperature and equivalence ratio (ER) on the bubble behaviors is studied. The growth, coalescence, break, and eruption of rising bubbles are studied. A lower ER is recommended for better gasification performance. With an increase in the ER from 0.12 to 0.3, both the lower heating value and combustible gas concentration experienced a decrease of approximately 38.5% and 38.3%, respectively. The lateral feeding of biomass leads to asymmetrical distribution of bed temperature and bubble properties. Near the biomass inlet, a larger bubble aspect ratio is observed, possibly attributed to the hindrance in the lateral bubble growth due to the lateral biomass feeding. The bubble coordinate number is introduced to characterize the degree of bubble distribution density in a specific region. It is found that increasing the operating temperature results in a reduction in the density and an increase in the volume of bubbles at the bottom, resulting in a denser distribution of bubbles in this region. Although this concentrated bubble distribution may impact local heat and mass transfer, the differences in bubble distribution under temperature dominance gradually decrease along the reactor height. The impact of the operating conditions on the thermal properties and spatial distribution of bubbles obtained in this work can provide valuable guidance for practical gasification operations.

Size-dependent irradiation tolerance and mechanical properties in WTaTiVCr/W multilayered films

Increasing the interface density in nuclear-material systems has been proposed to be a promising strategy for annihilating defects introduced by ion irradiation. The role of interface characteristics between the WTaTiVCr refractory high entropy alloy (RHEA) and metal tungsten (W) on the irradiation resistance is rather unclear because of the distinct defect energy that exists in these two kinds of materials. Here, the nano-crystalline and amorphous mixed structures were obtained in WTaTiVCr/W multilayers to investigate the irradiation tolerance and mechanical properties. After being exposed to a 60 keV helium (He) ion irradiation platform at a fluence of 1 × 1017 cm−2, the grain sizes in irradiated multilayers were slightly decreased from 12.4 nm to 7.2 nm with increasing individual thickness, which was explained from the perspective of He+ energy deposition. The dependence of bubble growth in multilayers on the individual thickness was disclosed based on the analysis of bubble size and its pressure in the RHEA and W layers. The phase structures and element distributions in WTaTiVCr/W multilayers were also revealed by the defect formation and crystallization. Also, a maximum irradiation hardening of 1.91 GPa in the RHEA(10)/W(7) multilayer was disclosed, and the irradiation hardening in the multilayers exhibited a decreasing trend with increasing monolayer thickness, and the corresponding mechanisms about the hardening behaviors in these multilayers were also discussed based on the interface density and irradiation-induced defects.

Extraction of geometric features and analysis of flow mechanism of high loaded compressor airfoils at low Reynolds number

When the aircraft cruising at high altitude, the aerodynamic performance of the compressor sharply decreases due to the enhanced boundary layer separation loss. Therefore, it is of great significance to design the high-performance airfoils suitable for low Reynolds numbers (Re) to improve the aerodynamic performance of compressor. In this paper, numerical simulations were carried out on a high-loaded subsonic compressor cascade V103 at low Re. Meanwhile, a multi-objective optimization of blade profile was performed to get optimal solutions, and data mining techniques were applied to extract valuable design knowledge from the optimal database. The results show that the Pareto-optimal airfoils achieve a maximum reduction of 27.32% in total pressure loss coefficient under design condition and 36.71% under near stall condition. Compared with the original airfoil, the curvature distribution law of the camber line with larger values at both ends and smaller values in the middle is advantageous for the performance of the compressor cascade under design condition. This distribution pattern causes a forward shift for the loading distribution of airfoils, accompanied by an earlier transition onset. Additionally, it reduces adverse pressure gradient at the rear part of suction surface, which suppresses the development and growth of laminar separation bubble and delays the separation of turbulent boundary layer. Under near stall condition, maintaining larger leading edge angle and uniform flow diffusion is beneficial for improving the performance of compressor cascade. This is because the larger leading edge angle reduces incidence angle, while the uniform flow diffusion inhibits a great flow separation.

Reconciling petrologic magma ascent speedometers for the June 12th, 1991 eruption of Mt. Pinatubo, Philippines

We investigate whether decompression rates derived from three often-disparate petrologic techniques (microlites, bubbles, and melt embayments) can be reconciled or integrated for a more complete understanding of magma ascent in the conduit. We focus on the well-studied and -documented earliest Plinian eruptions (June 12, 1991) of Mount Pinatubo. Using a newly developed two-stage decompression-diffusion model, volatile profiles in quartz-hosted embayments reveal an initial stage of decompression nearly two orders of magnitude slower than final rates. In applying time-integrated models of microlite and bubble nucleation and growth, initial decompression rates from embayments are supported by microlite modeling results, whereas final rates are in close agreement with bubble number densities. This consistency and continuity between speedometers supports the sensitivity of different petrologic recorders to specific regions of the conduit system and highlights the fidelity of embayments as recorders of decompression throughout the entire conduit. Ascent timescales derived from Pinatubo embayments range from hours to days, coinciding with the visual onset of lava effusion leading to explosive activity.

Non-equilibrium activation dynamics of superheated phase-change contrast agents

Phase-change contrast agents, such as superheated perfluorocarbon droplets, potentially offer exciting new opportunities in diagnostic and therapeutic applications of ultrasound. An important advantage of droplets over, e.g., microbubble agents is that they can be “activated” (vaporised) by a reduction in ambient pressure, initiated by an externally applied ultrasound pulse. Controlling the timing and location of droplet activation, however, is vitally important to avoid safety concerns. Current theoretical models for droplet vaporisation assume that a critical stable bubble embryo forms that is in thermal and mechanical equilibrium. Model predictions are, however, inconsistent with some experimental observations. The aim of this study is to develop a non-equilibrium model for droplet activation wherein initial bubble growth rate and vapour pressure are dependent upon the bubble nucleus size. We demonstrate how incorporating nonequilibrium effects into theoretical models of droplet vaporisation dynamics enables better agreement of the droplet expansion with experimental data and thus provide greater insight into control of the activation process.

The synergetic effect of He and Kr irradiation on helium bubble evolution in SiC/SiC composite: Combining in-situ TEM observation with MD simulation

SiC fiber reinforced SiC matrix composites (SiC/SiC composites) are considered as one of the promising structural materials for liquid type breeding blanket in the fusion energy system. The transmutation gas production rate in fusion reactor is significantly higher compared with fission reactors. An innovative method combining in-situ irradiation and TEM observation and MD simulation was utilized to evaluate the synergetic effects of helium and irradiation on SiC/SiC composites. A comprehensive experiment matrix including Kr irradiation, He pre-implantation with sequential Kr irradiation as well as simultaneous dual beam at 1073 K to 16 dpa and 2400 appm He (150 appm/dpa) was performed using 800 keV Kr and 50 keV He ions. With the support of MD results, the impact of relative concentration ratio of vacancies and helium atoms on the bubble evolution was systematically investigated and the corresponding mechanism was further unraveled, which provides the basis of limiting the bubble density in SiC/SiC composites. Additionally, the direct evidence for the competition of irradiation-assisted bubble growth and re-dissolution was in-situ observed in SiC matrix for the first time.

Experimental and simulation study on flow heat transfer characteristics of flat pulsating heat pipe with wide and narrow interphase channels

The miniaturization and high density of electronic devices have made temperature control an increasingly important technical challenge. This paper presents a design for a wide and narrow interphase channel plate pulsating heat pipe to address the issue of efficient and stable operation under horizontal and negative inclination angles. A test platform was constructed to evaluate the performance of the heat pipe. The study investigated the operating characteristics of plate pulsating heat pipes in wide and narrow interphase channels by controlling different dip angles, filling rates, and cooling water temperatures. Numerical simulations were conducted using Fluent for 30 % and 50 % filling rates at 90° inclination angle. The results indicated that the wide and narrow channel plate pulsating heat pipe can operate stably at a 50 % liquid filling rate and a −5° incline angle. At an incline angle of 60° and a filling rate of 50 %, the study observed a minimum thermal resistance of 0.44 K/W at 60 W heating power. The influence of different cooling water temperatures on the average temperature difference in the evaporation section decreases as the heating power increases. The working medium undergoes three stages during the start-up stage: bubble formation, bubble growth, and gas plug movement.

Simulation on mass removal by recoil pressure, thermal stress, and bubble growth of concrete irradiated by a millisecond Nd: YAG pulsed laser

The present paper reports on the study of millisecond pulsed Nd: YAG laser ablation of concrete material using the finite element method simulation to elucidate the complex mass removal processes such as melt ejection by recoil pressure, spallation as a result of thermal stress and gas bubble growth which are not well documented. The simulated results showed that the mass removal of concrete by melt ejection dominates over evaporation. Effects of laser intensity and linear laser pulse overlap on mass removal of concrete were also discussed. When the laser intensity was varied over a range from 2.4×1010 W/m2 to 4.4×1010 W/m2, both the temperature and mass ablation increased, however, the ablation efficiency remained constant i.e. 0.18 mg/J indicating the mass removal process remained unchanged. The simulated results are validated with both the experimental data and analytical results.

A new microlayer depletion model for numerical simulation of bubble growth during nucleate boiling

In this study, a new microlayer depletion model was developed to simulate bubble growth during the nucleate boiling of water and ethanol. By improving the coupled volume-of-fluid and level set model, the macro-two-phase flow was accurately tracked, eliminating velocity jumps at the interface. The proposed model was validated against pool boiling measurements in water and ethanol at atmospheric pressure. The results demonstrated that the microlayer contributed approximately 15 and 33.17 % to the growth of water and ethanol bubbles, respectively. Under the influence of the interfacial temperature, the mass accommodation coefficient of water could vary from 0.004 to 0.027. Considering the impact of the interfacial temperature on the mass accommodation coefficient could reduce the prediction error of the evaporative thermal resistance from 17.2 to 4.67 %. Furthermore, the study revealed that the evaporative thermal resistance of the water is comparable to the microlayer conductive thermal resistance, whereas the maximum evaporative thermal resistance of ethanol is less than 5 % of the microlayer conductive thermal resistance and can be neglected.