On the strength of analysis of the amide I absorption band contour of the i.r. spectra of polyether urethane elastomers based on poly(tetramethylene oxide), poly(propylene oxide) and 4,4′-diphenylmethane diisocyanate, a scheme of association of urethane groups has been suggested. The amide I band has been shown to include five individual components at 1740, 1730, 1725, 1713 and 1702 cm −1. The isolated bands are considered to be characteristic for urethane groups forming part of various associations.
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