Groundwater System Research Articles

Highly porous NiFe-mixed metal oxides derived from calcinated layered double hydroxide for efficient antibiotics removal

Tetracycline (TC), a widely employed broad-spectrum antibiotic with global prevalence, possesses the ability to infiltrate soil matrices and potentially reach groundwater systems, thereby posing a consequential human health risk. To address this concern, a novel NiFe-mixed metal oxides (MMO) composite was synthesized and employed within quartz sand as a strategic measure to regulate the downward migration of TC. In-depth investigations of TC transport behavior in quartz sand, complemented by NiFe-MMO, were conducted via a series of rigorous batch and saturation-filled column experiments. The impacts of NiFe-MMO dosage, ionic strength, cationic types, solution pH, and flow rates on TC transport were systematically and comprehensively scrutinized. Our findings reveal that even minute quantities of NiFe-MMO prompt substantial TC adsorption, facilitated by electrostatic interactions and surface complexation, notably in low-concentration background solutions. Additionally, the presence of Ca2+ engenders a bridging effect, further enhancing TC adsorption onto the sand. These significant observations bear far-reaching implications in elucidating the fate of antibiotics within the intricate interplay of soil and groundwater domains. The strategic amalgamation of NiFe-MMO and quartz sand offers innovative prospects for managing TC dissemination, thereby augmenting endeavors toward sustainable environmental protection.

Microplastics in groundwater: An overview of source, distribution, mobility constraints and potential health impacts during the anthropocene

Microplastics (MPs) have already been detected in various environmental matrices like soil, sediment, and surface water, and recently in groundwater also. The occurrence of MPs in groundwater depends up on the transportation through recharge and may controlled by source and local hydrogeology, and partly on the process of surface water-groundwater interaction (SW-GW). Based on the available studies, we intended to establish a hypothetical overview on the source and process-dependent occurrence of MPs in groundwater across terrestrial and coastal aquifers. Groundwater recharge from agricultural stagnant water, losing streams near dumping sites and agricultural fields, effluents from wastewater treatment plants, septic system failure etc. are the potential sources of MPs in groundwater. The factors like sea level rise and tidal pumping are among the major factors which may control the migration of MPs in coastal aquifer along with the physical and chemical properties of the aquifer media. These MPs have another ecological concern as they can adsorb persistent organic pollutants as well as heavy metals and transfer them to animal tissues through food chain. Studies are being conducted mainly focusing the MP contamination in surface water, marine environment and soil, and very limited studies are available to address the source of MPs in groundwater. However, no such study has been done on the existence, profusion, or environmental factors that contribute to MP pollution in the groundwater in relation to the present climate change scenario. Understanding the extent of MP contamination in groundwater systems is necessary for developing effective management strategies and minimizing their impact on the environment and human health. This study focusses on the source along with the controlling factors of the migration of MPs towards groundwater including the effect of climate change.

Hydrochemical characteristics and salt intrusion in groundwater of the lower Chao Phraya river basin: Insights from stable isotopes and hydrochemical analysis

Saltwater intrusion is a significant hydrogeological challenge in coastal regions. This study investigates salt intrusion and hydrogeological processes in the Lower Chao Phraya River basin using stable isotopes and hydrochemical analysis. One Hundred groundwater wells sampled from different aquifers were analyzed for major ions spanning from 2010 to 2021, as well as stable isotopes specifically for the samples in the year 2021. The results reveal four distinct groundwater types: Ca(HCO3)2, NaHCO3, NaCl, and CaSO4, based on their predominant cations and anions. Shallow groundwater, which represents the discharge zone affected by salt intrusion, halite dissolution, and cation exchange reactions, exhibits a significant concentration of NaCl. Water-rock interactions play a crucial role in shaping groundwater chemistry, with carbonate dissolution and precipitation dominating the Ca(HCO3)2 type and silicate weathering influencing the CaSO4 type. The NaHCO3 type is associated with ion exchange and seawater intrusion. Silicate and carbonate rock weathering are the dominant processes in the region. Stable isotope analysis indicates that groundwater recharge primarily comes from rainfall and surface water, with limited contributions from deep sources. Overall, this study provides valuable insights into the hydrochemical characteristics and complex water-rock interactions within the groundwater system of the Chao Phraya River basin. As a result, it holds significant potential for informing effective groundwater management practices and facilitating resource planning in the region. Furthermore, the findings and methodologies presented here offer valuable lessons for addressing saltwater intrusion and hydrogeological challenges in other coastal regions worldwide.

Comprehensive approach to sustainable groundwater management in semi-arid Ninh Thuan plain, Vietnam

Vietnam is a country with a long coastline and a high population density residing in the coastal plains. The largest dry area in Vietnam, the coastal plain of Ninh Thuan province, always lacks water in the first dry months of the year (Jan., Feb., Mar., and Apr.). Groundwater is an extremely valuable resource for supplies at this time. Therefore, the objective of this study is to establish a comprehensive approach to sustainable groundwater management in this semi-arid region. This approach is not only mitigating the negative impacts of factors such as climate change, sea level rise, and socio-economic development but also suggesting measures for management of aquifer recharge. A groundwater model for a 3-layer system with variable density flow SEAWAT is built to predict the impacts of climate change and sea level rise without a change in groundwater abstraction. This model helps to understand the trend of salt intrusion and lowering groundwater level in the study area. Afterwards, scenarios with different ground water abstraction and groundwater development such as ground dam, infiltration basin have been set up to meet the demands of socio-economic development in the future. Predicted results will show the impacts of the groundwater systems in the area such as groundwater level change, and saltwater intrusion. Controlled groundwater abstraction and some measures of groundwater development such as infiltration basin, underground dam would allow for an increase of up to 50000m3/day in the year 2050 without negative impacts on the aquifer system.

Rapid detection of subterranean fauna from passive sampling of groundwater eDNA

AbstractGroundwater is an essential source of freshwater that supports surface ecosystems as well as organisms adapted to living underground. The impacts of anthropogenic climate change, extraction, and pollution pose major threats to groundwater ecosystem health, prompting a need for efficient and reliable means to detect and monitor subterranean faunal communities. Conventional survey of subterranean fauna relies on the collection of organisms for morphological identification, which can be biased, labor intensive, and often indeterminate at lower taxonomic levels. Environmental DNA (eDNA)‐based methods can dramatically improve on stygofaunal surveys, but currently rely on time consuming active water filtration that limits the number of samples that can be processed. Passive eDNA sampling, which involves submersion of absorbent material (e.g. filter membrane, sponge etc.) into the sampled environment for a fixed period, has shown promise as a viable alternative to active filtration in aquatic ecosystems and may be applicable to groundwater systems. Here, we compared groundwater eDNA collected from active pump filtered water samples, membranes submerged in water for 10 min and 24 h, and haul‐net samples morphologically identified from bores at two geographically distinct locations in Western Australia. Our results show that while the relative abundance of eDNA in groundwater (measured through qPCR) is 100–800 times lower in passive samples, the species richness detected is comparable between passive and active eDNA collection. Additionally, standard metabarcoding assays (18S and COI) of passive eDNA samples detected most subterranean orders identified morphologically (12/17), and this proportion may be improved with increased sampling and application of DNA extraction methods that increase DNA yield. Our findings demonstrate that passive eDNA sample collection is a non‐invasive survey method with the potential to improve the efficiency and replication level of stygofaunal surveys but will benefit from further development.

Coral Reveals a Transition in Sources of Seawater Vanadium From Submarine Groundwater Discharge to Upwelling in the Northern South China Sea

AbstractIn recent decades, vanadium (V) levels in the environment have dramatically increased and will continue to rise alarmingly in the future. Conventional methods for assessing oceanic V typically only involved the collection of seawater and sediments, which significantly limited our understanding of the dynamics of oceanic V and its relationship to environment and climate. Here, the interannual temporal variations in surface seawater V levels in the northern South China Sea, were reconstructed utilizing a 137‐year record of V/Ca ratios from Porites lutea coral from Xiaodonghai Bay off Sanya. We observed that anthropogenic activities had a limited impact on the V levels of surface seawater in the study area, whereas V variability exhibited significant disparities across different time periods. Precipitation‐related submarine groundwater discharge (SGD) recharge was the primary driver of V variation prior to 1990, with tropical cyclones (TCs) playing a detectable role in total precipitation during this period. Conversely, changes in surface seawater V levels after 1990 were predominantly linked to increasingly intense upwelling driven by summer winds. The recharge processes in unconfined groundwater systems within the study area might generate favorable oxic and alkaline conditions, which facilitated mineral dissolution and/or desorption reactions that elevated V concentrations along the groundwater flow path, which were recorded in coral skeletal V/Ca ratios. This study confirmed the seawater V was dominated by SGD and upwelling near Sanya, providing essential evidence for comprehending the geochemical behavior of V and the impact of ocean‐atmospheric climate interactions on long‐term variations in seawater V levels.

Transport of bisphenol A, bisphenol S, and three bisphenol F isomers in saturated soils.

With the limitation of the use of bisphenol A (BPA), the production of its substitutes, bisphenol S (BPS), and bisphenol F (4,4'-BPF) is increasing. Understanding the fate and transport of BPA and its substitutes in porous media can help reduce their risk of contaminating soil and groundwater systems. In this study, column and batch adsorption experiments were performed with 14C-labeled bisphenol analogs and combined with mathematical models to investigate the interaction of BPA, BPS, 4,4'-BPF, 2,2'-BPF, and 2,4'-BPF with four standard soils with different soil organic matter (SOM) contents. The results show that the transport capacity of BPS and 4,4'-BPF in the saturated soils is significantly stronger than that of BPA. Meanwhile, the mobility of the three isomers of bisphenol F exhibits variability in saturated soils with high SOM content. The two-site nonequilibrium sorption model was applied to simulate and interpret column experimental data, and model simulations described the interactions between the bisphenol analogs and soil very well. The fitting results underscore SOM's role in providing dynamic adsorption sites for bisphenol analogs. Hydrophobicity primarily accounts for the disparity in adsorption affinity between BPA, BPS, 4,4'-BPF, and soil, whereas hydrogen bonding forces may predominantly influence the differential adsorption affinity between 4,4'-BPF and its isomers and soil. The results of this study indicate that BPS and three isomers of BPF, as alternatives to BPA, have higher mobility in saturated soils and may pose a substantial risk to groundwater quality. This study enhances our understanding of bisphenol analogs' behavior in natural soils, facilitating an assessment of their environmental implications, particularly regarding groundwater contamination.

Electrical Resistivity Investigation of Dumpsites in Gusau Metropolis, Zamfara State, Nigeria

Electric resistivity survey was carried out in three selected dumpsites in Gusau metropolis for groundwater contamination. The dumpsites were investigated by conducting Vertical Electrical Soundings (VES) using Schlumberger array with maximum current electrode separations of 180 m. Five VES were conducted on each dumpsite making a total of fifteen VES along three profiles. The field data obtained from VES were analyzed using WinGlink softwar. The VES results revealed three subsurface layers. The topsoil had resistivity ranging from 1.45 Ωm to 48.2 Ωm while the thicknesses varied from 0.47 m to 3.37m across the profiles. The second layer's resistivities varied from 5.4 Ωm to 144.35 Ωm and their thicknesses' ranges from 1.36 m to 16.93 m. The third geoelectric layer had resistivity from 70.0 Ωm to 6003.0 Ωm. The results indicated that the top soils in all the dumpsites were characterized by very low resistivity depicting possible pollution and contamination. Findings from this study indicated that there may be possible contamination of shallow groundwater system in the nearest future if proper mitigation measures are not taken into consideration at the dumpsites.

Climatic controls on the water balance of a pilot-scale oil sands mining pit lake in the Athabasca oil sands region, Canada

ABSTRACT Energy companies in the Athabasca Oil Sands Region in Alberta, Canada are evaluating the viability of incorporating pit lakes into reclamation closure designs to both sequester tailings and re-integrate the mining lease into the broader natural landscape. Lake Miwasin is a pilot-scale oil sands pit lake encompassed by a constructed catchment where the volume of the water cap is not actively managed. This study compared the water balance during the open water season over two consecutive years with contrasting levels of summertime precipitation. The first year had above average rainfall triggering surface water inflow events that diluted the over-winter water volume by ~ 25%. Flushing of the deepest layers of the water column was restricted from May – September as thermal stratification inhibited complete lake mixing. The second year had below average rainfall resulting in minimal surface water inflow and a drop in lake stage of ~ 30 cm. As the constructed catchment lacks both natural water bodies and connectivity to a legacy groundwater system, freshwater additions to the lake during the summer season were governed by rainfall. This research highlights challenges with constructing sustainable reclamation landscapes within a region characterised by variations in interannual and decadal water cycles.

Correlating Groundwater Storage Change and Precipitation in Alabama, United States from 2000–2021 by Combining the Water Table Fluctuation Method and Statistical Analyses

The complexity of aquifers poses a challenge for fully comprehending the impact of climate change on groundwater. In this study, we employed a suite of hydrological and statistical methods, including the water table fluctuation (WTF) method, wavelet analysis, the Hurst exponent, and temporal trend analysis, to assess groundwater storage (GWS) changes and their correlation with precipitation in Alabama, located in the southeastern United States. These approaches were used to evaluate the temporal variability of GWS as derived from well data and large-scale model estimates that incorporated satellite observations. The results unveiled a nuanced and regionally variable relationship between GWS changes and precipitation over the past two decades. While the Mann–Kendall test did not reveal any statistically significant overarching trends in GWS changes, Sen’s slope analysis indicated subtle regional variations, including a minor decline of −0.2 mm/year for GWS in southern Alabama and modest increases of 0.5 mm/year and 0.38 mm/year in the western and northern regions, respectively, from 2000–2021. Wavelet coherence analysis showed significant co-variation between GWS and precipitation in cycles ranging from 8 to 32 months, suggesting potential cyclic or intermittent influences. Furthermore, we detected strong persistence within the groundwater system using the Hurst exponent, indicating the substantial temporal memory impact. These findings are useful for developing effective groundwater management strategies in a changing climate.

Identifying potential hotspots of groundwater-climate interaction in the Great Artesian Basin, Australia

Groundwater aquifers around the world are experiencing stress due to the composite influence of climate change and excessive groundwater withdrawal. Despite this influence, there is still insufficient knowledge on climate-groundwater interaction dynamics in complex aquifers like Australia's Great Artesian Basin. This understanding can inform improved management, which can in turn, increase resilience of groundwater system to on-going groundwater withdrawal and climate change. The main aim of this research was to assess the impacts of climatic change on groundwater storage (GWS) changes over the Great Artesian Basin (GAB) using a range of multi-scale indicators, including Gravity Recovery and Climate Experiment (GRACE)-derived groundwater observations and standardized precipitation evapotranspiration indices (SPEI). Rotated principal component analysis (rPCA) was used to identify climatic hotspots (where GWS variation is particularly sensitive or vulnerable to the impacts of climate change), and correlation analyses were used to assess the relationship between these hotspots and changes in groundwater over space and time. The localized spatial pattern via rPCA was uncovered in the GAB's southeastern region, where annual variations in GWS exhibited conspicuous peaks in 2002, 2014, and 2015. Another finding was that the southeast region of the GAB experienced higher GWS variations as compared to other sub-basins during 2007–2008, which resulted in low groundwater recharge. These findings underscore the variations in GWS within the GAB, emphasizing its responsiveness to climatic variations (e.g., rainfall contributes to recharge of groundwater system and drought intensifies water extraction and restricts discharge). Moreover, this study found a substantial negative correlation (r = −0.7), between SPEI at 12-month scale and GWS variation in the southern GAB region. This relationship highlights the vulnerability of groundwater storage in the southern GAB region to prolonged drought conditions. Furthermore, this study identified positive correlations (r = 0.4 to 0.8), between key climate indices such as the El Niño-Southern Oscillation (ENSO), Pacific Decadal Oscillation (PDO) with GWS anomalies in the southeast and northern GAB regions. These correlations underscore the pivotal roles played by ENSO and PDO in shaping GWS variations in these areas, highlighting the need to incorporate an understanding of these climatic processes into water resource management strategies. This consideration is crucial for ensuring sustainable water management practices that can adapt to the influence of these climate phenomena. These findings provide essential insights into the dynamics of groundwater in the face of changing environmental conditions, with implications for sustainable water management.

Establishing a water baseline for the unconventional gas industry: A multiple environmental isotopes assessment (18O, 2H, 3H, 13C, and 14C) of surface and groundwater in the São Francisco Basin, Brazil

Unconventional hydrocarbon production has become the target of an intensive environmental debate due to the risks it poses to water resources. Fracking, while enabling the extraction of oil and gas from ultra-low permeability reservoirs, also possesses the risk of polluting water systems through failures from hydraulic fracturing and its associated procedures. The need to foster national industrial development with a transitional energy matrix has led Brazil to discuss the environmental suitability before producing its large unconventional reserves. Many studies have highlighted the need for a robust environmental characterization before the development of the unconventional industry. In this sense, multiple environmental isotopes may work as a proxy for identifying water contamination right from the early stages. Environmental isotopes may also be applied to enhance the understanding of the natural geochemical processes intrinsic to a given area. This study presents an environmental isotopes baseline for the groundwater and riverine water systems within the São Francisco Basin, a proven tight gas reservoir in Brazil, in a pre-operational context. δ18O, δ2H, 3H, δ13C, and Δ14C were evaluated in three different seasons in groundwater and surface water samples, along with other auxiliary parameters such as physical-chemical parameters (in situ), major ions, and d-excess. The δ2H and δ18O in surface water shows an upstream → downstream enrichment trend, with some variations suggesting baseflow interactions in the surface water systems. An evaporation line for the study area was defined as δ2H = 4.6903 δ18O + 10.362. δ13C indicates a mutual dissolution of silicates and carbonates in the groundwater system and suggests a group of samples highly related to the recharge areas. Groundwater dating denotes the Serra da Saudade Formation as a modern fractured aquifer with a strong recharge capacity. These findings support stakeholders in environmental monitoring and management of the unconventional gas industry.

Molecule-based quantification of dissolved organic matter sources in high-arsenic groundwater

Compositions of dissolved organic matter (DOM) in high-arsenic groundwater are usually sourced from the recharged groundwater DOM and the in-situ mobilized organic matter (OM) from aquifer sediments. However, relative importance of the two sources in DOM remains unclear. To quantify sources of DOM, Fourier transform ion cyclotron resonance mass spectrometry was used to analyze molecular characteristics of groundwater DOM and water-soluble organic matter (WSOM) in sediments along an inferred groundwater flow path in the Hetao Basin, China. Results showed that dissolved arsenic concentrations gradually increased from 1.92 to 402 μg/L along the flow path, being mainly due to the DOM degradation-triggered Fe(III) oxide reduction. The DOM molecules being unique to the background groundwater represented the in-situ mobilized OM, which showed the similar abundance to the DOM molecules being common to its depth-matched WSOM. An increasing trend of the relative abundance of the in-situ mobilized OM to the total DOM molecules along the flow path was recognized (from 0 % to 44.5 %). This suggests that the relative contribution of the in-situ mobilized OM to the groundwater DOM increased along with dissolved arsenic concentration. Furthermore, the biodegradable pool among the in-situ mobilized OM was significantly positively correlated with dissolved arsenic, indicating that this in-situ mobilized OM exhibited a dominant role in groundwater arsenic enrichment. The study provides novel insights into contribution of the in-situ mobilized OM to DOM and arsenic mobility in groundwater systems.

Impacts of Tidal Oscillations on Coastal Groundwater System in Reclaimed Land

The impact of tidal oscillations on groundwater in coastal reclamation land demonstrates the complex hydrodynamic interaction between seawater and coastal hydrological aquifer systems. The tidal action not only affects the temporal variability of groundwater levels but also exerts a significant influence on the groundwater gradients of salinity within the subsurface aquifers. This study takes the Songmu Area as an example to investigate this ocean–groundwater interaction. Songmu Area is located on a peninsula with coastal land reclamation in Dalian, China. Field campaigns were conducted in this area to measure the tidal action and groundwater parameters in a coastal reclaimed area at artificial backfill layers with pressure and salinity sensors, where the tidal signal can influence groundwater levels and salinity up to a one-kilometer range of inland. Tidal changes in the surface of the sea can be broken down into a number of simple, regular harmonic vibrations, each of which is called a tidal split. The tide and groundwater data were extracted using an enhanced harmonic analysis method. The fluctuations of groundwater levels and salinity were decomposed in response to the periodic tidal oscillation. Various constituents of tide attenuation in the coastal groundwater system were investigated. Our research shows that there is an exponential reduction in the fluctuating amplitude of groundwater levels and the groundwater salinity as distance further inland from the coast. The constituents of tide M2 (the period is 12.42 h of semi-diurnal tides, S2 (the period is 12.00 h of semi-diurnal tides), K1 (the period is 23.93 h of full-diurnal tides), and O1 (the period is 25.82 h of full-diurnal tides) behave differently for the tidal wave propagation and salinity variability in the coastal aquifer of reclaimed land. Among those constituents, M2 and S2 exhibit a higher degree of attenuation compared with K1 and O1. Understanding the relationship between groundwater levels and tidal fluctuations in coastal backfill areas is crucial for effective groundwater management strategies and mitigating the adverse impacts of seawater intrusion. This study can serve as a good understanding for assessing the impacts of various mitigation strategies.

Validation of the efficiency of arsenic mitigation strategies in southwestern region of Bangladesh and development of a cost-effective adsorbent to mitigate arsenic levels

World's highest arsenic (As) contamination is well-documented for the groundwater system of southwestern region (mainly Jashore district) of Bangladesh, where the majority of inhabitants are underprivileged. To mitigate As poisoning in southwestern Bangladesh, numerous steps have been taken so far by the government and non-governmental organizations (NGOs). Among them, digging deep tube wells and As removal by naturally deposited Fe(OH)3 species are being widely practiced in the contaminated areas. However, these actions have been left unmonitored for decades, making people unaware of this naturally occurring deadly poison in their drinking water. Hence, water samples (n = 63, both treated and untreated) and soil samples (n = 4) were collected from different spots in Jashore district to assess the safety level of drinking water and to understand the probable reasons for high As(III) contamination. About 93.7% of samples were found to contain As(III) above 10 μg/L; among them, 38% contained above 50 μg/L. The study shows that current As(III) removal strategies in the study area are ineffective. In this connection, a simple low-cost As(III) removal adsorbent is proposed that can be prepared with very cheap and locally available materials like iron sludge and charcoal. The adsorbent was characterized in terms of SEM, EDX, and XPS. The optimal dosage of the adsorbent was investigated for real-life application concerning several vital water quality parameters. The Fe–C adsorbent exhibited a maximum As(III) removal efficiency of 92% in real groundwater samples. The study will allow policymakers for informed decision-making regarding water body management as well as enable the local people to avail As-safe water in a way that aligns with their economic factors.

Hydrochemical analysis and groundwater suitability for drinking and irrigation in an arid agricultural area of the Northwest China

Groundwater is the foremost water source in the arid and semiarid regions of Northwest China. Assessing groundwater's drinking and irrigation quality is essential for protecting these valuable groundwater resources. In this study, a total of 24 confined groundwater samples and 54 phreatic groundwater samples were collected in the southern and central Ningxia area for hydrochemical analysis and quality assessment. The hydrochemical results revealed that hydrochemical types of phreatic and confined groundwater consistently belonged to Na-SO4-Cl and Na-Mg-SO4-Cl types. The driving forces of groundwater chemistry were determined by gypsum dissolution, silicate dissolution, and positive cation exchange for phreatic and confined aquifers. The entropy-weighted water quality index (EWQI) and irrigation water quality index (IWQI) showed that the drinking water quality and irrigation quality were better in phreatic groundwater than in confined groundwater due to the Neogene-Paleogene groundwater system recharge and strong evaporation. Measures such as controlling groundwater extraction and optimizing well placement need to be implemented. The achievements would be helpful for groundwater management and protection in agricultural areas under semi-arid and arid climates.

Identifying hydraulic connectivity among the vadose zone, unconfined and confined aquifers in the thick loess deposits using multiple tracers

Low water flux and a thick vadose zone increase the likelihood that water bearing units are hydraulically disconnected in shallow groundwater systems. Particularly for the thick loess deposit of China, hydraulic connectivity among the vadose zone, unconfined and confined aquifers is still unclear since it is controversial whether the unconfined groundwater is recharged by precipitation or confined groundwater. Taking several loess tablelands as example, we collected precipitation, soil water, unconfined and confined groundwater to measure the contents of multiple tracers (e.g., hydrochemistry, δD, δ18Owater, δ17Owater, δ34S, δ18Osulfate, δ13C and 14C) to evaluate hydraulic connectivity among the vadose zone, unconfined and confined aquifers. Deep soil water can be recharged by precipitation with intensities ≥ 30–40 mm/day, and then vertically discharge to unconfined water primarily through matrix flow with an infiltration velocity of 0.15 m/year. Matrix flow dominates the water flux from the vadose zone to the unconfined aquifer with the rates of 85.4 ± 39.6 mm/year, reflecting the regional hydraulic equilibrium. The unconfined and confined aquifers exhibit negligible vertical hydraulic connectivity because of different recharge periods, flow patterns, water − rock interaction, water residence time and sulfate evolution behaviors. The identified connectivity supports local precipitation as the recharge source, which conflicts with the external source hypothesis. The utilization of multiple tracers in this study can complement each other to provide more comprehensive results, and the results greatly improve the conceptualization of vertical water exchange processes in the loess deposits.

Groundwater Level Dynamic Impacted by Land-Cover Change in the Desert Regions of Tarim Basin, Central Asia

Groundwater is essential to residents, ecology, agriculture, and industry. The depletion of groundwater impacted by climatic variability and intense human activities could threaten water, food, and socioeconomic security in arid regions. A thorough understanding of groundwater level dynamics and its response to land-cover change is necessary for groundwater management and ecosystem improvement, which are poorly understood in arid desert regions due to a scarcity of field monitoring data. In our study, spatiotemporal characteristics of groundwater level impacted by land-cover change and its relationship with vegetation were examined using 3-years in-situ monitoring data of 30 wells in the desert regions of Tarim Basin during 2019–2021. The results showed that the depth to groundwater level (DGL) exhibited obvious spatial and seasonal variations, and the fluctuation of DGL differed significantly among the wells. The cultivated land area increased by 1174.6, 638.0, and 732.2 km2 during 2000–2020 in the plains of Yarkand, Weigan-Kuqa, and Dina Rivers, respectively, mainly transferring from bare land and grassland. Annual average Normalized Difference Vegetation Index (NDVI) values increased with time during the period in the plains. DGL generally exhibited a weakly increasing trend from 2019 to 2021, mainly due to human activities. Land-cover change significantly affected the groundwater level dynamic. Generally, the groundwater system was in negative equilibrium near the oasis due to agricultural irrigation, was basically in dynamic equilibrium in the desert region, and was in positive equilibrium near the Tarim River Mainstream due to irrigation return water and streamflow. NDVI of natural desert vegetation was negatively correlated with DGL in the desert regions (R2 = 0.78, p < 0.05). Large-scale land reclamation and groundwater overexploitation associated with water-saving irrigation agriculture development have caused groundwater level decline in arid oasis-desert regions. Hence, controlling groundwater extraction intensity, strengthening groundwater monitoring, and promoting water-saving technology would be viable methods to sustainably manage groundwater and maintain the ecological environment in arid areas.

Predicting the impact and duration of persistent and mobile organic compounds in groundwater systems using a contaminant mass discharge approach

This study investigated methods for predicting the duration and impact on groundwater quality from persistent and mobile organic compounds (PMOCs) at a drinking water well field affected by multiple contaminant sources. The fungicide metabolite N,N-dimethylsulfamide (DMS), which frequently occurs above the Danish groundwater quality criterion (0.1 μg/L), was used as an example. By combining contaminant mass discharge (CMD) estimations, modeling, and groundwater dating, a number of important discoveries were made. The current center of contaminant mass was located near the source area. The CMD at the well field was predicted to peak in 2040, and an effect from the investigated sources on groundwater quality could be expected until the end of the 21st century. A discrepancy in the current CMD at the well field and the estimated arrival time from the studied source area suggested an additional pesticide source, which has not yet been thoroughly investigated. The presence of the unknown source was supported by model simulations, producing an improved mass balance after inclusion of a contaminant source closer to the well field.The approach applied here was capable of predicting the duration and impact of DMS contamination at a well field at catchment scale. It furthermore shows potential for identification and quantification of the contribution from individual sources, and is also applicable for other PMOCs. Predicting the duration of the release and impact of contaminant sources on abstraction wells is highly valuable for water resources management and authorities responsible for contaminant risk assessment, remediation, and long-term planning at water utilities.

Co-transport of Microplastics and a surrogate for Human Enteric Viruses in a saturated column packed with Quartz Sand

Groundwater can be contaminated with infective human enteric viruses from various sources, such as wastewater treatment plant discharge, landfills, septic tanks, agricultural practices, and artificial groundwater recharge. Anthropogenic pollutants, such as microplastics, may exhibit an affinity to transport biocolloids (bacteria, viruses) further and reduce their degradation rates in the natural environment. Human enteric viruses (poliovirus, hepatitis A, rotavirus, and adenovirus) can adsorb to the abiotic surface of microplastics and are simultaneously present in wastewater discharge. These newly formed clumps of pathogens and microplastics could penetrate deeper into soils as vectors for preferential flow and threaten groundwater systems, triggering a higher risk for drinking water and possibly followed by a disease outbreak. The mechanisms behind the adsorption of human enteric viruses on microplastic surfaces and their potential role in prolonging virus survival and promoting environmental transport remain unclear. This study aims to explore the possibility of co-transport of microplastics and human enteric viruses in saturated porous media, using PRD1 bacteriophage as a surrogate. PRD1 bacteriophages have been widely used as surrogates of rotavirus because they share many fundamental properties and features. Column experiments were performed using quartz sand (soil grain size: 0.60 - 1.30 mm) as a porous media in a 30 cm long and 7 cm diameter column. The column experiments were conducted by maintaining Darcy velocity of 2.65 m/day. Three different influent solution scenarios were considered in the experiments: PRD1 mixed with microplastics, PRD1 alone, and microplastics alone. The enumeration of PRD1 in the effluent solution was performed using quantitative polymerase chain reaction (qPCR) as well as the culture method, in order to differentiate between infective and inactive virus transport. Microplastics were quantified using Solid-Phase Cytometry (SPC). Results were analyzed by calculating the collision and sticking efficiencies of the microplastics and PRD1 using the classical colloid filtration theory and Hydrus 1D modeling tool. There was no evidence of interference or inhibition of microplastics on the performance of qPCR and DNA extraction in the methodological setup. Additionally, the efficacy of qPCR and DNA extraction methods did not yield significantly different results across any of the influent solution conditions. Preliminary results suggest that the presence of microplastics enhanced the transport of PRD1, which led to reduced attachment of PRD1 in the porous media. The concentration of infective phages showed a delayed sharp increase, indicating that there may be a sorption mechanism that delays their breakthrough. It is possible that a portion of the active phages possess a higher sticking efficiency and that population heterogeneity contributes to this phenomenon. A comprehensive understanding of the processes that govern virus transport with globally distributed microplastics is crucial for protecting public health.