Groundwater Monitoring Wells Research Articles

Does Pumping Volume Affect the Concentration of Micropollutants in Groundwater Samples?

AbstractInformation on concentrations of micropollutants (such as pharmaceuticals, pesticides, and industrial chemicals) in most highly dynamic riverbank filtration (RBF) systems is lacking, in contrast to data on standard chemical parameters. Sampling protocols have thus far been based on the stabilization of standard chemical parameters in relatively pristine environments. To determine whether groundwater samples for micropollutant analysis can be taken at a similar pumping volume as samples for testing standard chemical parameters in both environments, three groundwater monitoring wells in an RBF system were sampled at two points in time (after pumping of 3 well volumes and after pumping of 15 well volumes). Micropollutant concentrations were not significantly different between the two sampling points; therefore, appropriate samples can be drawn after pumping 3 well volumes. For a specific microbiological parameter (leucin incorporation), a statistically significant difference was found.

Monitoring of the temporal and spatial variation of groundwater storage in the Three Gorges area based on the CORS network

The variation of groundwater storage is not well understood due to the complex hydrodynamic environment in the Three Gorges area. The variation of monthly groundwater storage from January 2011 to June 2015 was directly inverted in the Three Gorges area of China based on 26 Continuously Operating Reference Station (CORS) and eight gravity stations with a resolution of 2′×2′ using the Earth's gravity field and the load deformation theory. The results were then compared with the water level from groundwater monitoring wells. The comparison indicates that it is possible to calculate the temporal and spatial variation of groundwater with high precision based on the continuous observation data of CORS and a small amount of gravity stations. Our analysis shows that the groundwater storage was consistent in the Three Gorges area from 2011 to 2014. The Three Gorges Reservoir has a large impact on the variation of groundwater storage. The variation of the groundwater storage derived from CORS agrees well with that of the groundwater monitoring wells. The new data are important references for the research of hydrodynamic environmental change in the Three Gorges area and for the analysis of the impact of water impoundment and drainage in the Three Gorges Reservoir.

Small Purge Method to Sample Vapor from Groundwater Monitoring Wells Screened Across the Water Table

AbstractGroundwater monitoring wells are present at most hydrocarbon release sites that are being assessed for cleanup. If screened across the vadose zone, these wells provide an opportunity to collect vapor samples that can be used in the evaluation of vapor movement and biodegradation processes occurring at such sites. This paper presents a low purge volume method (modified after that developed by the U.S. EPA) for sampling vapor from monitoring wells that is easy to implement and can provide an assessment of the soil gas total petroleum hydrocarbon (TPH) and O2 concentrations at the base of the vadose zone. As a result, the small purge method allows for sampling of vapor from monitoring wells to support petroleum vapor intrusion (PVI) risk assessment. The small purge volume method was field tested at the Hal's service station site in Green River, Utah. This site is well‐known for numerous soil gas measurements containing high O2 and high TPH vapor concentrations in the same samples which is inconsistent with well‐accepted biodegradation models for the vapor pathway. Using the low purge volume method, monitoring wells were sampled over, upgradient, and downgradient of the light nonaqueous phase liquid (LNAPL) footprint. Results from our testing at Hal's show that vapor from monitoring wells over LNAPL contained very low O2 and high TPH concentrations. In contrast, vapor from monitoring wells not over LNAPL contained high O2 and low TPH concentrations. The results of this study show that a low purge volume method is consistent with biodegradation models especially for sampling at sites where low permeability soils exist in and around a LNAPL source zone.

Regional analysis of groundwater phosphate concentrations under acidic sandy soils: Edaphic factors and water table strongly mediate the soil P-groundwater P relation

Historic long-term P application to sandy soils in NW-Europe has resulted in abundant sorption, saturation and eventually leaching of P from soil to the groundwater. Although many studies recognize the control of site-specific factors like soil texture and phosphate saturation degree (PSD), the regional-scaled relevance of effects exerted by single factors controlling P leaching is unclear. Very large observational datasets of soil and groundwater P content are furthermore required to reveal indirect controls of soil traits through mediating soil variables. We explored co-variation of phreatic groundwater orthophosphate (o-P) concentration and soil factors in sandy soils in Flanders, Belgium. Correlation analyses were complemented with an exploratory model derived using ‘path analysis’. Data of oxalate-extractable Al, Fe, P and pHKCl, phosphate sorption capacity (PSC) and PSD in three depth layers (0–30, 30–60, 60–90 cm), topsoil SOC, % clay and groundwater depth (fluctuation) were interpolated to predict soil properties on exact locations of a very extensive net of groundwater monitoring wells. The mean PSD was only poorly correlated to groundwater o-P concentration, indicating the overriding control of other factors in the transport of P to the groundwater. A significant (P < 0.01) positive non-linear relationship was found between groundwater o-P concentrations and pHKCl for all depth layers. Likewise, lower SOC% (P < 0.01) and shallower groundwater level (MHL or MLL) corresponded (P < 0.01) with higher o-P concentrations. Groundwater o-P unexpectedly correlated positively to clay% and path analysis indicated this to be an indirect effect of the groundwater level. Path analysis furthermore indicated an important indirect control of pH on groundwater o-P concentrations and a considerable direct effect of Pox, 0-90, Alox, 0-90 and MHL. The fact that groundwater o-P concentration was stronger controlled by soil pH and groundwater table depth than by PSD indicates the likely oversimplification of the latter index to measure the long-term potential risk of P leaching. Accounting for controls on leaching not included in PSD via an alternative index, however, seems problematic as in Flanders for example groundwater o-P turned out to be higher in finer textured soils or soils with higher pedogenic Fe content, probably because of their lower pedogenic Al content and higher soil pH. Path analysis of extensive soil and groundwater datasets seems a viable way to identify prime local determinants of soil P leaching and could be further on used for ‘ground-truthing’ more complex P-migration simulation models.

Parameter correlation in wastewater dispersal area groundwater monitoring wells serving Corolla Light #1 Wastewater Treatment Facility in Currituck County, North Carolina

More than half of North Carolina’s population utilizes groundwater as a drinking water source. Efforts to protect water sources include groundwater monitoring around some of the larger wastewater s...

Impacts of deep groundwater monitoring wells on the management of deep geothermal Pre-Neogene aquifers in the Mura-Zala Basin, Northeastern Slovenia

Management of deep geothermal resources in Slovenia is very complex because of the depth of the geothermal aquifers. In this study we have developed a conceptual model for the management of deep geothermal aquifers in Northeastern Slovenia, which has turned out to be much more complex. Evolution of the problems that occurred when developing a conceptual model are based on previous and newly collected data of geothermal waters of Pre-Neogene aquifers in Mura-Zala Basin. Isotope and chemical compositions of groundwater revealed that mixing of deep groundwater in the Pre-Neogene aquifers occurs in exploitation wells at Veržej and Petišovci.According to the history of explotation well construction it is difficult to identify the real cause of mixing of groundwater and of pressure lowering with increasing depth inside wells. Monitoring of groundwater wells in the Mura-Zala Basin based only on exploitation and not monitoring the wells may lead to misleading results. Groundwater mixing is thought to be due either to inadequate construction of exploitation wells in the past, which were and still are used for monitoring or to changed hydrodynamic conditions resulting from uncontrolled exploitation of groundwater without reinjection rate. In this respect, new construction of multilayer monitoring wells in the future is needed, which could lead to more reliable monitoring results, better control of better control of groundwater resources and the hydrogeological system of the Pre-Neogene aquifers.

Spatiotemporal variation of groundwater quality in an arid area experiencing long-term paper wastewater irrigation, northwest China

Groundwater is crucial for multiple uses over the world, especially in arid and semiarid regions. However, human activities significantly decreased groundwater quality. In this study, the spatiotemporal variation of groundwater quality was evaluated in an arid area where long-term paper wastewater irrigation has been implemented. For this study, seven wells were regularly monitored for physicochemical parameters over a period of 1 year. Statistical and graphical approaches were applied to interpret the spatiotemporal variation of groundwater quality parameters in the wastewater irrigation zone. Correlation analysis was also carried out to reveal the sources of some major ions. The results indicate that the groundwater type in the study area is dominated by the Cl–Na, followed by the HCO3–Na, the HCO3–Ca·Mg, and the SO4·Cl–Ca·Mg types. Groundwater in the area is significantly contaminated locally with fluoride, nitrite and ammonia, and the chemical oxygen demand levels were increased in some groundwater monitoring wells. Most contaminants showed an increasing trend from the Yellow River water irrigation zone toward the wastewater irrigation zone. Rock weathering, mineral dissolution, and cation exchange are important processes controlling groundwater quality, but human activities, such as wastewater irrigation, play an undeniable role in affecting groundwater quality in this area. The results of this study contribute to the understanding of the formation and circulation of groundwater under human activities and provide a scientific basis for regional water quality evaluation, water quality improvement, and protection.

Characterising Bedrock Aquifer Systems in Korea Using Paired Water-Level Monitoring Data

This study focused on characterising aquifer systems based on water-level changes observed systematically at 159 paired groundwater monitoring wells throughout Korea. Using spectral analysis, principal component analysis (PCA), and cross-correlation analysis with linear regression, aquifer conditions were identified from the comparison of water-level changes in shallow alluvial and deep bedrock monitoring wells. The spectral analysis could identify the aquifer conditions (i.e., unconfined, semi-confined and confined) of 58.5% of bedrock wells and 42.8% of alluvial wells: 93 and 68 wells out of 159 wells, respectively. Even among the bedrock wells, 50 wells (53.7%) exhibited characteristics of the unconfined condition, implying significant vulnerability of the aquifer to contaminants from the land surface and shallow depths. It appears to be better approach for deep bedrock aquifers than shallow alluvial aquifers. However, significant portions of the water-level changes remained unclear for categorising aquifer conditions due to disturbances in data continuity. For different aquifer conditions, PCA could show typical pattern and factor scores of principal components. Principal component 1 due to wet-and-dry seasonal changes and water-level response time was dominant covering about 55% of total variances of each aquifer conditions, implying the usefulness of supplementary method of aquifer characterisation. Cross-correlation and time-lag analysis in the water-level responses to precipitations clearly show how the water levels in shallow and deep wells correspond in time scale. No significant differences in time-lags was found between shallow and deep wells. However, clear time-lags were found to be increasing from unconfined to confined conditions: from 1.47 to 2.75 days and from 1.78 to 2.75 days for both shallow alluvial and deep bedrock wells, respectively. In combination of various statistical methods, three types of water-level fluctuation patterns were identified from the water-level pairs: Type I of identical aquifer systems (77.8%), Type II of the different aquifer systems with different recharge flow paths (9.5%), and Type III of unmatched aquifer system pairs and correlations (12.7%). Type I and II could be used as verification of aquifer condition in the paired monitoring system. However, Type III shows the complexity of water-level fluctuation in different aquifer conditions. This study showed that confined or not-confined conditions are not directly related to the depth of wells in the aquifer. Therefore, the utilisation of groundwater as a water-supply source should be carefully designed, tested for its hydrogeologic conditions, and managed to ensure sustainable quantity and quality.

New Distributional Records of the Stygobitic CrayfishCambarus cryptodytes(Decapoda: Cambaridae) in the Floridan Aquifer System of Southwestern Georgia

Cambarus cryptodytes (Dougherty Plain Cave Crayfish) is an obligate inhabitant of groundwater habitats (i.e., a stygobiont) with troglomorphic adaptations in the Floridan aquifer system of southwestern Georgia and adjacent Florida panhandle, particularly in the Dougherty Plain and Marianna Lowlands. Documented occurrences of Dougherty Plain Cave Crayfish are spatially distributed as 2 primary clusters separated by a region where few caves and springs have been documented; however, the paucity of humanly accessible karst features in this intermediate region has inhibited investigation of the species' distribution. To work around this constraint, we employed bottle traps to sample for Dougherty Plain Cave Crayfish and other groundwater fauna in 18 groundwater-monitoring wells that access the Floridan aquifer system in 10 counties in southwestern Georgia. We captured 32 Dougherty Plain Cave Crayfish in 9 wells in 8 counties between September 2014 and August 2015. We detected crayfish at depths ranging from 17.9 m to 40.6 m, and established new county records for Early, Miller, Mitchell, and Seminole counties in Georgia, increasing the number of occurrences in Georgia from 8 to 17 sites. In addition, a new US Geological Survey (USGS) Hydrologic Unit Code 8 (HUC8) watershed record was established for the Spring Creek watershed. These new records fill in the distribution gap between the 2 previously known clusters in Georgia and Jackson County, FL. Furthermore, this study demonstrates that deployment of bottle traps in groundwater-monitoring wells can be an effective approach to presence—absence surveys of stygobionts, especially in areas where surface access to groundwater is limited.

Integrated evaluation of urban groundwater hydrogeochemistry in context of fractal behaviour of groundwater level fluctuations

ABSTRACTThe present study was carried out as part of a complex survey of urban groundwater quality and quantity in Szeged, southeast Hungary. The concentrations of 12 inorganic contaminants in 28 shallow groundwater monitoring wells were determined over a 2-year period (2010–2012). The evaluation of concentrations indicates remarkable contamination all over the city. Discriminant analysis (DA) was used to evaluate the spatial changes of groundwater quality. The groundwater levels were measured over a 14-year period (2000–2013). The fractal properties of water level fluctuations time series characterizing the groundwater system and Tisza River were investigated using rescaled range (R/S) analysis. The resulting Hurst exponents clearly showed the persistency and thus long memory effects of both the groundwater and the river flow. Comparison of the results of DA with the results of R/S analysis thus implies that the geological conditions and the changing groundwater quantities are not related to groundwater quality.EDITOR A. CastellarinASSOCIATE EDITOR A. Fiori

A computational assessment of representative sampling of soil gas using existing groundwater monitoring wells screened across the water table

Representative sampling is of great importance to decision making regarding contaminant site risks and remedial effectiveness. A focus here is whether existing groundwater monitoring wells screened across the water table can be sampled to yield representative indicators of soil gas composition. For the first time, we provide multi-phase, multi-component computational simulations to address this. We simulated high and low gas extractions rate strategies to sample the gas phase over short and extended screening intervals across the water table. We investigated the options against a field data set representative of typical hydrocarbon vapour profiles, inclusive of major gases, oxygen and carbon dioxide. We also evaluated the sampling options for uniform and non-uniform multi-component gasoline LNAPL distributions, including hazardous chemicals. Less sensitivity to the sampling option was observed for depth-wise increasing concentration profiles with a near-constant concentration across the screen. Significant discrepancy between the ratio of different compounds in the sample and in-situ (real) values was observed for high-rate gas extraction (particularly for an extended-screen). Low-rate gas extraction provided satisfactory results for all the scenarios. Shorter screening slightly improved the accuracy of this option. Graphical representations are provided to allow assessment of the applicability of each sampling option for various site conditions.

Stream-aquifer and in-stream processes affecting nitrogen along a major river and contributing tributary

This study assesses the spatio-temporal patterns of water and nutrient mass exchange in a stream-riparian system of a major river and a contributing tributary in an irrigated semi-arid region. Field monitoring is performed along reaches of the Arkansas River (4.7km) and Timpas Creek (2.0km) in southeastern Colorado during the 2014 growing season, with water quantity and water quality data collected using a network of in-stream sampling sites and groundwater monitoring wells. Mass balance approaches were used to identify temporal and spatial trends in flow, nitrogen (N), and salinity in stream-aquifer exchange. In the Arkansas River, percent decrease of N concentration along the study reach averaged 36% over the period, with results from a stochastic mass balance simulation indicating a 90% probability that 44% to 50% of NO3-N mass in the study reach (109–124kg/day/km) was removed by in-stream processes between 1 September and 8 November. Results suggest that contact with organic-rich river bed sediments has a strong impact on N removal. A greater decrease in concentrations of NO3-N along the reach during the low flow period suggests the effect of both in-stream processes and dilution by inflowing groundwater that undergoes denitrification as it flows through the riparian and hyporheic zones into the river. In contrast, N concentration decreases in the smaller Timpas Creek were negligible. Results for the Arkansas River also are in contrast with other large agriculturally-influenced rivers, which have not exhibited capacity to remove N at significant rates. Results provide important insights across spatial and temporal scales and point to the need for investigating nutrient dynamics in large streams draining agriculturally-dominated watersheds.

New insights into nitrate dynamics in a karst groundwater system gained from in situ high-frequency optical sensor measurements

Understanding nitrate dynamics in groundwater systems as a function of climatic conditions, especially during contrasting patterns of drought and wet cycles, is limited by a lack of temporal and spatial data. Nitrate sensors have the capability for making accurate, high-frequency measurements of nitrate in situ, but have not yet been evaluated for long-term use in groundwater wells. We measured in situ nitrate continuously in two groundwater monitoring wells —one rural and one urban—located in the recharge zone of a productive karst aquifer in central Texas in order to resolve changes that occur over both short-term (hourly to daily) and long-term (monthly to yearly) periods. Nitrate concentrations, measured as nitrate-nitrogen in milligrams per liter (mg/L), during drought conditions showed little or no temporal change as groundwater levels declined. During aquifer recharge, extremely rapid changes in concentration occurred at both wells as documented by hourly data. At both sites, nitrate concentrations were affected by recharging surface water as evidenced by nitrate concentrations in groundwater recharge (0.8–1.3mg/L) that were similar to previously reported values for regional recharging streams. Groundwater nitrate concentrations responded differently at urban and rural sites during groundwater recharge. Concentrations at the rural well (approximately 1.0mg/L) increased as a result of higher nitrate concentrations in groundwater recharge relative to ambient nitrate concentrations in groundwater, whereas concentrations at the urban well (approximately 2.7mg/L) decreased as a result of the dilution of higher ambient nitrate concentrations relative to those in groundwater recharge. Notably, nitrate concentrations decreased to as low as 0.8mg/L at the urban site during recharge but postrecharge concentrations exceeded 3.0mg/L. A return to higher nitrate concentrations postrecharge indicates mobilization of a localized source of elevated nitrate within the urbanized area of the aquifer. Changes in specific conductance were observed at both sites during groundwater recharge, and a significant correlation between specific conductance and nitrate (correlation coefficient [R]=0.455) was evident at the urban site where large (3-fold) changes in nitrate occurred. Nitrate concentrations and specific conductance measured during a depth profile indicated that the water column was generally homogeneous as expected for this karst environment, but changes were observed in the most productive zone of the aquifer that might indicate some heterogeneity within the complex network of flow paths. Resolving the timing and magnitude of changes and characterizing fine-scale vertical differences would not be possible using conventional sampling techniques. The patterns observed in situ provided new insight into the dynamic nature of nitrate in a karst groundwater system.

Sources of dissolved oxygen in monitoring and pumping wells

Groundwater monitoring and pumping wells set in anoxic aquifers require attention to keep the groundwater free of dissolved oxygen (DO). In properly constructed monitoring or pumping wells, two processes can however still introduce oxygen to anoxic groundwater: (1) permeation of oxygen through polymer materials such as silicone, PVC, HDPE or Teflon, and (2) thermally driven convection, which can occur in all types of piezometers or wells, regardless of construction material, when the water table or pressure head is close (<10 m) to the land surface. Here, field measurements (temperature and DO well loggings) from a monitoring well in Bilthoven, the Netherlands, are combined with analytical and numerical modelling to investigate the role of both processes on oxygenation of anoxic groundwater in wells. The results of numerical and analytical modeling show that both permeation and convection can introduce oxygen into anoxic wells to near saturation concentrations. In the field data gathered, convection is primarily responsible for oxygen intrusion up to a depth of around 12 m. Oxygen intrusion through convection and permeation in monitoring and pumping wells may influence groundwater sampling and analyses, and may contribute to well clogging, depending on site conditions. The combination of field and modelling provides new insights into these processes, which can be used for both groundwater sampling and pumping well design.

Groundwater Impacts on Surface Water and Sediment-Gowanus Canal, Brooklyn, New York

The Gowanus Canal Superfund Site in Brooklyn, New York, is an approximately 1.5-mile (1.61-km) long estuary that was historically converted into a canal for industrial and commercial purposes. Three manufactured gas plants (MGPs) were formerly located on the Gowanus Canal and discharged waste into it. Surface sediments remain highly contaminated with polycyclic aromatic hydrocarbons (PAHs) long after the MGPs were razed. A hydrogeologic assessment indicates that groundwater passes through the deeper coal tar–contaminated sediment prior to discharging to the canal. This study was undertaken to investigate if groundwater passing through coal tar–contaminated sediment could be responsible for the ongoing contamination of both surface sediments and surface water in the canal. PAH compound distributions in surface water samples collected from the tidal canal at low tide were compared with PAH compounds found in adjacent groundwater-monitoring wells, point sources (combined sewer overflows [CSOs]), and surface sediments. The results indicate a strong correlation between PAH contaminant distributions in groundwater, sediment, and surface water, indicating that contaminated groundwater passing through the deeper coal tar–contaminated sediments is the primary mechanism contributing to the contamination of both surface sediment and surface water in the canal. Therefore, any sediment remediation efforts in the Gowanus Canal that fail to evaluate and control the upward transport processes have a high chance of failure due to recontamination from below. ©2016 Wiley Periodicals, Inc.

Environmental data analysis based on the gamma distribution: compliance assessment using tolerance limits and exceedance fractions

The gamma distribution has found extensive applications in the modeling and analysis of environmental data. Furthermore, for groundwater monitoring and environmental monitoring, an upper tolerance limit (i.e., an upper confidence limit for a percentile) can be used for checking compliance and is recommended in some of the standards published by the U.S. EPA. In addition, estimation of the proportion of samples where the measurements exceed a threshold (proportion of non‐compliance, for example), referred to as an exceedance fraction, is of obvious interest. Thus the computation of an accurate upper tolerance limit, and an accurate upper confidence limit for the exceedance fraction, are important. The problems are somewhat challenging since environmental samples are typically not large, and large sample methods cannot be used. In the present investigation, we have succeeded in obtaining accurate solutions to the above problems using a small sample modification of the likelihood based method. The results are also applied for analyzing a data set on vinyl chloride concentrations in ground water monitoring wells.

Responses of submarine groundwater to silty-sand coast reclamation: A case study in south of Laizhou Bay, China

Coastal reclamation can result in considerable changes in the quality and quantity of submarine groundwater at the land/sea interface. In this study, submarine groundwater monitoring wells and water samples were designed and implemented to get data of groundwater level, electrical conductivity, temperature, and hydrochemistry data to examine the responses of silty-sand submarine groundwater in different sedimentary strata to reclamation in south of Laizhou Bay. The submarine groundwater is mainly saline water and its salinity in the deep aquifer is higher than that of seawater and close to brine. It was formed in the Late Pleistocene and Holocene. Drilling core data indicates that there is a stratigraphic boundary at a depth of 18.58 m, with Holocene strata above, and Late Pleistocene strata below, this level. Continuous electrical conductivity data indicates that the submarine groundwater properties are stratigraphically distributed in this study area. And there is an interface at a depth of 38 m. Above the 38 m depth, the water quantity of submarine ground-saline water is freshening. The major ions showed a tendency to change continually above 25 m, but the tended to stabilize below 25 m depth. Freshwater is the major recharge source in the upper section of the Holocene strata, between the surface and 8.00 m depth, and the hydrochemical type has changed from ClNa to Cl·HCO3Na. In the lower section of Holocene strata (8.00–23.00 m) and upper section of late Late Pleistocene strata (23.00–38.00 m), groundwater is influenced by seawater and groundwater of upper aquifer. The freshwater, seawater, and groundwater recharge in the upper aquifer has no influence on the groundwater in the section below the late Late Pleistocene (between 38.00 and 49.15 m) and the early Late Pleistocene strata (between 49.15 and 75.00 m). The filling layer, added in the coastal reclamation project, is comprised of clayey silt and fine sand, and its high porosity means that it is suitable for water storage. After the reclamation, meteoric water was stored in the filling layer that became the stable recharge resource. The recharge resource and the filling layer can improve the properties of the confined aquifer to increase the groundwater level. They may also influence the groundwater quantity and the flow direction. The groundwater in the Holocene strata is clearly influenced by recharge and the previously saline water aquifers receive freshwater on an on-going basis, such that the water is now becoming fresh.

Groundwater recharge assessment in an upland sandstone aquifer of southern California

The Chloride Mass Balance (CMB) method was used to obtain long-term recharge values for the Santa Susana Field Laboratory (SSFL) site, which features a groundwater flow system beneath an upland ridge formed of sandstone and shale beds in the Simi Hills, Ventura County, southern California. This application relied on the availability of on-site measurements of bulk atmospheric chloride deposition comprised of dry fallout and wet concentration, a large number of groundwater samples (∼1490) collected over three decades from 206 wells spanning a depth range from 10 to 360m, and measurements of chloride in surface runoff during rain events. The use of the CMB method is suited to the assessment of recharge for the study area because the mean chloride values in groundwater show minimal spatial trends, indicating no sources other than atmospheric. In addition, the Cl/Br ratio was used to exclude wells with possible anthropogenic chloride. The site-wide average recharge ranges between 1.8 and 9.5% of the mean annual precipitation (455mm) with a mean value of 4.2%. The measured surface runoff varies from 2.3 to 10.2% with mean value of 6.1% (28 mm) and, therefore, the volume of water lost to evapotranspiration is between 95.9 and 80.3% with a mean value of 89.6% (408mm). The long-term recharge calculated using the CMB method is consistent with tritium distribution based on a subset of groundwater monitoring wells and with an analysis of steady flow in the groundwater mound beneath the SSFL. Furthermore, the recharge value matches those in the literature for sandstone aquifers in arid and semi-arid climates. This recharge estimate has important relevance for site characterization in terms of constraining the volumetric groundwater flow rates and water balance and understanding the mechanisms of transport towards the water table. Moreover, this is the first application of the CMB in an upland area of California. Hence, the method is demonstrated to be robust and applicable to many upland bedrock areas in southern California and similar regions around the world, and can be used to quantify groundwater flow rates and supplies relevant to water resource management.

Geochemical modeling and low-frequency geoelectrical methods to evaluate the impact of an open dump in arid and deltaic environments

In Mexico, open dumps that are maintained by the municipality but provide no covering of waste are not uncommon. Further, disposal at these sites is often performed by burning. The aim of this study was to determine the leachate plume from an open dump located in a depositional deltaic environment, with arid climate, low rainfall and where the water table is about 2 m below the surface. The methodology comprised analysis of groundwater monitoring wells and geophysical and geochemical prospecting techniques. The 3D geoelectric interpretation shows a typical area of these depositional environments with low resistive values (10–20 Ω-m) associated with the presence of sands and clays interbedded. However, there is a very low resistivity zone associated with the dump’s impact which reaches values below 5 Ω-m, and it is located where the disposal and burning of wastes occurred. Another zone with values above 16 Ω-m appears as a limit for the advance of the saline. This is interpreted as a sandy lenses area. These sandy lenses with higher porosity transport aquifer’s water. Thus the dump is in direct contact by this conduct with clean groundwater. Piper diagrams constructed with the chemical data analysis reveal that the groundwater in the area corresponds to the chlorinated and/or sulfated sodium type, showing the impact caused by the dump. The monitoring well (NP8, on-site) with the highest dissolved solids content behaves anomalously and belongs to the more conductive zone according to the geoelectric profiles. The subsoil geochemical behavior is influenced by the seasonal water table variations provoking the dissolution of burned and unburned wastes, but the effects of slow flows in the direction of the regional flow are not discarded. Although the most impacted area within the dump is characterized to a depth of 10 m, there is a slow flow in the direction of the regional flow that has been moving pollutants out of the dumpsite during its almost 20 years of operation. The results of this study provide valuable information for the authorities to carry out an appropriate restoration project.

An Environmental Impact Assessment of the underground operations at the designed Petrikov potash mine, Belarus

Abstract The Petrikov deposits of potash salt is situated in Gomel oblast of Belarus in the south-east of Pripyat Trough, and have Northern and Southern prospects. Underground mining of potash salt will start at the Northern prospect with an area of 166 km2. It is expected that mining will last for between 50-80 years. An Environmental Impact Assessment (EIA) was carried out at the design stage of the Petrikov mining and processing plant. The standard EIA procedure included a set of investigations, including assessments of surface subsidence, changes in groundwater level, changes in productivity of forest phytocoenoses and crops, and assessment of groundwater pollution due to production of potash fertilizers. Maximum values of possible surface subsidence (up to 2.3 m) will occur within the area, where the surface will be affected by the mining of potash layers 1, 2, and 3 of the productive horizon IV-Π, using a long-pillar mining system. Surface subsidence will influence surface topography, surface and groundwater, landscape structure and land resources. The result of surface subsidence will lead to inundation and swamping of land, as well as to an increase in the areas affected by annual floods in the valleys of the Pripyat and Bobrik rivers. Surface subsidence will affect the whole area of the prospect within the limits of planned mining fields, except the areas above safety pillars. In the result of raised groundwater levels the area with groundwater depth of more than 2 m will decrease from 69.1% to 17.8%, and the areas with groundwater depth from 3 to 5 m will disappear. The area with a groundwater depth less than 1 m will increase from 0.1% to 34.0%. In 19.5% of the area the groundwater level will raise above the surface level (the area of inundation). Surface subsidence and change in groundwater level will cause certain decreases in yields of timber and crops, and 2564 ha of forest, 68 ha of arable land and 324 ha of meadows will be inundated. In order to prevent inundation within certain areas protective engineering facilities have been designed, and an arrangement of groundwater monitoring wells has been proposed.