Groundwater Accumulation Research Articles

Groundwater potential assessment in the Eastern Cape, South Africa, using analytical hierarchical process (AHP) technique

Groundwater is crucial for the growth of any country. It is a vital resource for drinking water, agriculture, industry, and economic development. However, delineating the groundwater potential zones requires a systematic approach. This study assessed the groundwater potential zones (GWPZ) in the Ntabankulu municipality using remote sensing, geographic information systems, and analytical hierarchical process (AHP) techniques. Six groundwater controlling parameters were integrated to assess groundwater potential zones, including lithology, slope, lineaments density, land use/land cover, drainage density, and rainfall. The AHP pairwise comparison matrix was utilized to determine the normalized weight of the parameters. The parameters and their classes were assigned ranks, taking into account their influence on groundwater accumulation. The resultant GWPZ map was generated by integrating the parameters and their assigned weights in ArcGIS 10.8 software. The final map from the AHP technique showed five GWPZ, including very poor (13.06%), poor (25.36%), moderate (26.93%), good (22.72%), and very good (11.93%). Validation was done by using the existing 242 boreholes in the study area. Furthermore, the receiver operating characteristics (ROC) curve was plotted, and the area under the curve (AUC) analysis indicated a satisfactory accuracy prediction (AUC = 61%). The results of this study will assist in developing a proper plan for sustainable utilization of groundwater resources within the Ntabankulu municipality.

Combining stable isotopes and spatial stream network modelling to disentangle the roles of hydrological and biogeochemical processes on riverine nitrogen dynamics

Intensive agricultural activities have significantly altered watershed hydrological and biogeochemical processes, resulting in water quality issues and loss of ecosystem functions and biodiversity. A major challenge in effectively mitigating nitrogen (N) loss from agricultural watersheds stems from the heterogeneity of N transformation and transport processes that complicates accurate quantification and modeling of N sources and sinks at the watershed scale. This study utilized stable isotopes of water and nitrate (NO3−) in conjunction with spatial stream network modeling (SSNMs) to explore watershed hydrology, N transformation, and sources within a mesoscale river network in the U.S. Corn Belt (Cannon River Watershed, Minnesota) under contrasting hydrological conditions. The results show that the wet season had elevated riverine NO3− concentration (medium: 8.4 mg N L−1), driven by high watershed wetness conditions that mobilizes NO3− from the near-surface source zone. Furthermore, the strong hydrologic connectivity also reduced the denitrification potential by shortening water travel times. In comparison, the dry season showed lower NO3− concentrations (0.9 mg N L−1) and stronger denitrification NO3− isotope signals. During this period, the decrease in hydrologic connectivity shifted the predominant water source to deep groundwater, with longer water travel time promoting denitrification. After accounting for isotopic fractionations during nitrification and denitrification, we identified fertilizer N as the main NO3− source during the wet season (98.2±1.3%), whereas the dry season showed contributions from diverse sources (64.4±11.9% fertilizer, 26.0±15.8% soil N, and 9.5±6.0% manure and sewage). During the dry season, karst regions with high hydrologic connectivity display increased shallow groundwater inputs, carrying elevated NO3− levels from leaching of applied chemical fertilizers. These findings highlight the importance of integrating drainage water management and N accumulation in groundwater into nutrient management strategies to develop adaptive measures for controlling N pollution in agricultural watersheds.

Relationships between microbial characteristics and the arsenic cycle in high-arsenic groundwater

Abstract Microbial activities play a pivotal role in the migration and transformation of arsenic (As) within groundwater systems, particularly at high concentrations. Focusing on the Kuitun River Basin, this study used high-throughput sequencing to unravel the intricate diversity of microbial communities and their influence on As enrichment. Groundwater with elevated As hosted richer and more diverse microbial populations compared to that with lower As levels. The Sobs and Shannon diversity indices for the high-As group initially declined before rising with increasing As concentrations. Key microbial taxa dominating these ecosystems included Pseudomonas, Acinetobacter, Aquabacterium, Novosphingobium, and Sphingobium, with Pseudomonas showing substantial variation in abundance across different As concentrations. Distance-based redundancy analysis emphasized the importance of dissolved oxygen in shaping the microbial landscape, followed closely by the interplay between iron and As concentrations. Flavobacteriaceae and Burkholderiaceae displayed inverse correlations with As levels, highlighting the multifaceted relationship between microbial communities and groundwater chemistry. This investigation underscores the profound impact of As concentration gradients on microbial biodiversity and elucidates a complex regulatory framework where environmental parameters and microorganisms collaborate in governing As accumulation in groundwater. The results enrich our understanding of the biogeochemical dynamics underlying arsenic behavior in subterranean aquatic habitats.

A review of groundwater iodine mobilization, and application of isotopes in high iodine groundwater.

Excessive intake of iodine will do harm to human health. In recent years, high iodine groundwater has become a global concern after high arsenic and high fluorine groundwater. A deep understanding of the environmental factors affecting iodine accumulation in groundwater and the mechanism of migration and transformation is the scientific prerequisite for effective prevention and control of iodine pollution in groundwater. The paper comprehensively investigated the relevant literature on iodine pollution of groundwater and summarized the present spatial distribution and hydrochemical characteristics of iodine-enriched groundwater. Environmental factors and hydrogeological conditions affecting iodine enrichment in aquifers are systematically summarized. An in-depth analysis of the hydrologic geochemistry, physical chemistry, biogeochemistry and human impacts of iodine transport and transformation in the surface environment was conducted, the results and conclusions in the field of high iodine groundwater research are summarized comprehensively and systematically. Stable isotope can be used as a powerful tool to track the sources of hydrochemical components, biogeochemistry processes, recharge sources and flow paths of groundwater in hydrogeological systems, to provide effective research methods and means for the study of high iodine groundwater system, anddeepen the understanding of the formation mechanism of high iodine groundwater, the application of isotopic technique in high iodine groundwater is also systematically summarized, which enriches the method and theory of high iodine groundwater research. This paper provides more scientific basis for the prevention and control of groundwater iodine pollution and the management of groundwater resources in water-scarce areas.

Occurrences of nitrate-contaminated groundwater in the piedmont aquifers: hydrogeochemical characteristics and health risks.

Groundwater nitrate (NO3-) contamination is a global concern. The distribution patterns, enrichment mechanisms, and human health risks of NO3- contaminated groundwater were investigated using 144 groundwater samples collected from domestic and irrigation wells in the piedmonts of the North China Plain (Beijing and Shijiazhuang areas). The results showed that the groundwater was neutral to weakly alkaline, and 47% of the groundwater samples had NO3- concentrations exceeding 50mg/L, a threshold proposed by world health organization to threaten infants up to 3months. Groundwater NO3- concentrations were generally higher in the Beijing piedmont than in the Shijiazhuang piedmont and decreased with depth in both piedmonts. High-NO3- (> 50mg/L) groundwater was distributed sporadically spatially and mainly was of Ca-Mg-HCO3 hydrochemical facies. Stable isotopes (D and 18O) compositions and NO3-/Cl- ratios indicated that NO3- accumulation in groundwater was primarily due to use of N-fertilizers under agricultural practices, and was associated with groundwater recharge sources such as septic tank leakage and re-infiltration of reclaimed irrigation water. Water quality evaluation showed that groundwater quality was highly dependent on NO3- concentration, with entropy-weighted water quality index values increasing linearly with increasing NO3- concentrations. The potential health risk of high-NO3- groundwater was the most serious for infants in both the piedmonts. Therefore, reducing NO3- input from sources and drinking water intake is recommended to minimize the human health risk.

Industrial effluents and N-nitrosamines in karst aquatic systems: a study on distribution and ecological implications.

The discharge of electroplating wastewater, containing high concentrations of N-nitrosamines, poses significant risks to human health and aquatic ecosystems. Karst aquatic environment is easily impacted by N-nitrosamines due to the fragile surface ecosystem. However, it's still unclear in understanding N-nitrosamine transformation in karst water systems. To explore the response and transport of nine N-nitrosamines in electroplating effluent within both karst surface water and groundwater, different river and groundwater samples were collected from both the upper and lower reaches of the effluent discharge areas in a typical karst industrial catchment in Southwest China. Results showed that the total average concentrations of N-nitrosamines (∑NAs) in electroplating effluent (1800ng/L) was significantly higher than that in the receiving river water (130ng/L) and groundwater (70ng/L). The dynamic nature of karst aquifers resulted in comparable average concentrations of ∑NAs in groundwater (70ng/L) and river water (79ng/L) at this catchment. Based on the principal component analysis and multiple linear regression analysis, the electroplating effluent contributed 89% and 53% of N-nitrosamines to the river water and groundwater, respectively. The results based on the species sensitivity distribution model revealed N-nitrosodibutylamine as a particularly toxic compound to aquatic organisms. Furthermore, the average N-nitrosamine carcinogenic risk was significantly higher in lower groundwater reaches compared to upper reaches. This study represents a pioneering effort in considering specific N-nitrosamine properties in evaluating their toxicity and constructing species sensitivity curves. It underscores the significance of electroplating effluent as a primary N-nitrosamine source in aquatic environments, emphasizing their swift dissemination and significant accumulation in karst groundwater.

Impact of groundwater nitrogen legacy on water quality

The loss of agricultural nitrogen (N) is a leading cause of global eutrophication and freshwater and coastal hypoxia. Despite regulatory efforts, such as the European Union’s Nitrogen Directive, high concentrations of N persist in freshwaters. Excessive N leaching and accumulation in groundwater has created a substantial N reservoir as groundwater travel times are orders-of-magnitude slower than those of surface waters. In this study we reconstructed past and projected future N dynamics in groundwater for four major river basins, the Rhine, Mississippi, Yangtze and Pearl, showcasing different N trajectories. The Rhine and Mississippi river basins have accumulated N since the 1950s and although strategies to reduce excess agricultural N have worked well in the Rhine, groundwater legacy N persists in the Mississippi. The Yangtze and Pearl river basins entered the N accumulation phase in the 1970s and the accumulation is expected to continue until 2050. Policies to reduce N pollution from fertilizers have not halted N accumulation, highlighting the importance of accounting for the N legacy in groundwater. Restoring groundwater N storage to 1970 levels by diminishing N leaching will therefore take longer in the Yangtze and Pearl (>35 years) than in the Rhine (9 years) and Mississippi (15 years). Sustainable watershed management requires long-term strategies that address the impacts of legacy N and promote sustainable agricultural practices aligned with the Sustainable Development Goals to balance agricultural productivity with water conservation.

Effect of Fallow on Nitrogen Accumulation in Soil Profile and Shallow Groundwater in Cropland Around Fuxian Lake

Soil nitrogen accumulation in cropland and groundwater nitrogen pollution can be effectively alleviated by reducing exogenous nitrogen input, and fallow is an important measure for reducing exogenous nitrogen input. To explore the effects of fallow on nitrogen accumulation in the soil profile and shallow groundwater, the soil profile and shallow groundwater in cropland around Fuxian Lake were selected as research objects. The changes in nitrogen accumulation in the 0-100 cm soil profile and nitrogen concentration in shallow groundwater before (December 2017) and after (August 2020 and April 2021) fallow and their relationships were analyzed. The results showed that the content and storage of nitrogen in soil profiles were significantly reduced by fallow, and the contents of TN, ON, DTN, NO3--N, and NH4+-N in 0-30, 30-60, and 60-100 cm soil profiles after fallow decreased by 18.4 %-36.5 %, 16.1 %-26.8 %, 54.0 %-130.2 %, 59.5 %-90.8 %, and 60.1 %-110.6 %, respectively. The storages of TN, ON, DTN, NO3--N, and NH4+-N in 0-100 cm soil profiles before fallow were (17.20 ±0.97) t·hm-2, (15.50 ±1.23) t·hm-2, (0.68 ±0.06) t·hm-2, (266.8 ±31.17) kg·hm-2, and (18.7 ±3.04) kg·hm-2, respectively. However, their storages after fallow decreased by 25.5 %, 23.3 %, 44.7 %, 80.1 %, and 59.9 %, respectively. Fallow also changed the concentration and composition of different forms of nitrogen in shallow groundwater. The concentrations of TN, ON, NO3--N, and NH4+-N in groundwater after fallow decreased by 88.4 %, 82.7 %, 92.1 %, and 65.8 %, respectively, and ON/TN and NH4+-N/TN increased from 26 % and 6 % before fallow to 39 % and 17 % after fallow, respectively, whereas NO3--N/TN decreased from 61 % before fallow to 41 % after fallow. Changes in nitrogen concentrations and their forms in groundwater were closely related to DTN, NO3--N, and NH4+-N in the soil profile and pH, ORP, and DO in groundwater before and after fallow. Our study highlights that fallow effectively reduced nitrogen accumulation in cropland soil profiles, further alleviating nitrogen pollution in shallow groundwater, and was conducive to preventing the deterioration of water quality in plateau lakes.

Microplastic accumulation in groundwater: Data-scaled insights and future research

Given that microplastics (MPs) in groundwater have been concerned for risks to humans and ecosystems with increased publications, a Contrasting Analysis of Scales (CAS) approach is developed by this study to synthesize all existing data into a hierarchical understanding of MP accumulation in groundwater. Within the full data of 386 compiled samples, the median abundance of MPs in Open Groundwater (OG) and Closed Groundwater (CG) were 4.4 and 2.5 items/L respectively, with OG exhibiting a greater diversity of MP colors and larger particle sizes. The different pathways of MP entry (i.e., surface runoff and rock interstices) into OG and CG led to this difference. At the regional scale, median MP abundance in nature reserves and landfills were 17.5 and 13.4 items/L, respectively, all the sampling points showed high pollution load risk. MPs in agricultural areas exhibited a high coefficient of variation (716.7%), and a median abundance of 1.0 items/L. Anthropogenic activities at the regional scale are the drivers behind the differentiation in the morphological characteristics of MPs, where groundwater in residential areas with highly toxic polymers (e.g., polyvinylchloride) deserves prolonged attention. At the local scale, the transport of MPs is controlled by groundwater flow paths, with a higher abundance of MP particles downstream than upstream, and MPs with regular surfaces and lower resistance (e.g., pellets) are more likely to be transported over long distances. From the data-scaled insight this study provides on the accumulation of MPs, future research should be directed towards network-based observation for groundwater-rich regions covered with landfills, residences, and agricultural land.

Groundwater Exploration Within Shallow Depths Around Distinct Litho-Petrological Contact Zones

The world’s increasing demand for freshwater has put a strain on existing reserves in recent years, necessitating further exploration of new groundwater reserves. However, geologic provinces located within the contact boundary of Sedimentary Basin-Basement Complex region are somewhat faced with the problem of shallow sediment thickness. As a result, exploring for groundwater poses a challenge as the sediment thickness might be insufficient to host productive aquifers. Hence, exploring for faults and fractures zones that are embedded on the hard rock underneath the sediment is very essential and complimentary. In this study, high resolution aeromagnetic data over a litho-petrological contact zone of the Middle Benue Trough (MBT) and the Adamawa Massif were analyzed to delineate groundwater exploration areas using a simplified qualitative and quantitative approach. Visual inspection of isolated and aggregate anomalies is performed by analyzing their shapes, dimensions, lateral extents, and discontinuities. Lineaments were then extracted from the residual magnetic map to determine faults, fractures, and joints. A two-source-depth model is indicated by the Spectral Analysis technique used to determine the thickness of the sediments in the area. The deeper source (Z1) has a thickness of 0.9 - 3.6 km, while the shallow source (Z2) has a thickness of 0.1 - 0.8 km. While in some areas the overburden thickness may be sufficient for groundwater exploration, in others it was not, as indicated by the shallow magnetic depth, Z2. Nonetheless, areas of shallow thickness but with aggregates of faults, fractures, and joints were identified as possible locations for groundwater accumulation through magnetic lineament exploration.

Groundwater Exploration using Geoelectric Technique in Oru-Ijebu, South-West Nigeria

Forty Vertical Electrical Soundings (VES) were carried out using Allied Ohmega resistivity meter with schlumberger configuration in parts of Oru-Ijebu to determine the necessary geoelectrical parameters for delineating the aquiferous zones. Four to five distinct geoelectric layers were delineated from the survey area except for VESORU21 which exhibited six geoelectric layers namely the top soil, clayey sand/laterite, clay and granite gneiss. The first layer serves as the topsoil with high variable resistivity ranging from 11.2Ωm (VESORU7) to 153.8Ωm (VESORU25) with their corresponding thickness of 0.9m to 3.8m respectively. The thickness of the entire top soil of the investigated area ranges from 0.4m to 3.8m. The second layer is composed of sand, clay sand, laterite and partly sandy clay. The resistivity of clay/clayey sand overburden varying from 16.2Ωm with a thickness of 8.7m in VESORU17 and 484.3Ωm with a thickness of 3m VESORU6. The highest resistivity exhibited by the second layer is 974 Ωm in VESORU30 while its lowest resistivity is 21.9Ωm in VESORU34. The resistivity of the third layer which stands as a weathered lithology ranges from 17.2Ωm with a thickness of 10.3m at VESORU7 to 233.2Ωm at VESORU23 whose thickness is indeterminate due to current termination in the field to 196 Ωm; typically diagnostic of clay/clayey sand horizon except beneath VESORU1, VESORU2, VESORU11, VESORU30, VESORU32, VESORU34, and VESORU36 where the inferred lithology is sandstone, fresh basement and partly sandy-clay. The fourth and fifth layers are composed of fresh basement formation notably granite-gneiss rocks with resistivity values ranging from 88.5Ωm VESORU20 to 384Ωm in VESORU15. The maximum aquifer thickness is encountered beneath VESORU25. The weathered layer for the study area is thick enough for groundwater accumulation making it a very prolific one. VESORU1, VESORU2 and VESORU23 are marked by a low groundwater yield due to the dip and the thickness.

Identification of potential groundwater sources using Electrical Resistivity Imaging (ERI) method in Jambu Lawar, Machang, Kelantan

The study area is primarily composed of volcanic rock and plain quaternary sediment. Extrusive and intrusive rocks are the two varieties of igneous rock that have been found. In the examined location, igneous intrusive rock, specifically biotite granite, makes up most of the rock formation. Grey to white colour, biotite granite has a phaneritic, coarse- grained texture. On the other hand, andesite, an igneous extrusive rock, makes up the minor rock formation. The study aims to identify the potential groundwater resources of the study area. Groundwater viability is examined using the Electrical Resistivity Imaging (ERI) method. Each of the survey lines extends over a length of 200 meters, incorporating 41 takeouts positioned at 5m spacing, and adopts the Schlumberger array electrode configuration. Both surface water and groundwater are essential resources in Kelantan for daily life; nevertheless, ongoing groundwater exploitation causes depletion. This potential is defined by low resistivity materials that can store large amounts of groundwater. As biotite granite is inherently unsuitable for groundwater collection between grains, possible fracture zones are highlighted as likely sites for groundwater presence. The 2D pseudosection results for all three survey lines emphasize a substantial accumulation of groundwater in a spatially expansive zone. This is because the resistivity value for all the survey lines is below 100 Ωm.

Evaluation of geohydraulic response properties of hydrogeological units in Littoral hydro-lithofacies in Uyo, Southern Nigeria

Aquifer geohydraulic response properties are important parameters in groundwater resource management and exploitation. However, geohydraulic properties in the study area is sketchy and due to wildcat drilling. This practice, which leads to inadequate inventory of groundwater parameters, deprived the area of efficient exploitation, monitoring and management of groundwater resources. This study is aimed at evaluating the geo-hydraulic response properties of hydrogeological units in littoral hydro-lithofacies in Uyo, Southern Nigeria. Vertical electrical sounding (VES) technique was carried out, and a total of fifteen geoelectric soundings were obtained using IGIS Resistivity metre model SSR-MP-ATS and its accessories employing Schlumberger electrode configuration. The interpreted data give sets of geoelectric curves from which the aquifer resistivity and thickness were determined. The results reveal the aquifer bulk resistivity ranging from 23.4 to 1306.2 Ωm with an average of 347.99 Ωm, while aquifer thickness spanned from 7.4 to 56.3 m. The formation factor, fractional porosity and transmissivity ranged from 2.41 to 12.52, 0.20 to 0.46, and 0.001 to 0.037m2/s, respectively. The formation tortuosity also ranged from 1.05 to 1.58; longitudinal conductance ranged from 0.020 to 1.004 Ω−1; and transverse resistance ranged from 549.90 to 69,097.98 Ωm2. These parameters were contoured, and their variations are displayed on the contour maps generated. The graphs plotted showed strong correlation coefficient and earth response function that can be used in modelling the aquifer repositories in areas with similar geomaterials. The results of this study indicate that the survey area has a good prospect for groundwater accumulation, and the results can be useful in installing matching hydraulic pumps in boreholes in the survey area.

Direct Detection of Groundwater Accumulation Zones in Saprock Aquifers in Tectono-Thermal Environments

Some vertical electrical sounding (VES) data from tectono-thermal environments usually plot anomalously on a VES curve, thereby distorting the curve trend at the points of their occurrence. These datasets usually plot noisily in the form of a sudden rise and drop in electrical resistivity values. They constitute abnormal datasets that are usually deleted to recover trends and consequently develop confidence in both the datasets and the modelling and interpretational processes. This study was conducted to assess their origin and consequently gain an understanding of their contributions to groundwater accumulation and transmission in saprock aquifers. The results, supported by co-located drilling and pumping test data, show that these datasets are indicators of subsurface conditions where high-resistivity unconformal structures directly overlie saturated (low-resistivity) porous media, provided that the resistivity of the first breakout point is less than those from subsequent points. Remote sensing data reveal that these types of curves are common in hard rock and metasedimentary environments. Borehole groundwater yields can also be assessed qualitatively from the number and trend of breakoff points. The integrity of the breakoff points must be affirmed by using more sensitive equipment for data acquisition and repeating the measuring process using different potential electrode separations and—where possible—VES profile orientation.

Understanding the Deep Structure of the Essaouira Basin Using Gravity Data: Hydrogeological Inferences for a Semiarid Region in Central-Western Morocco

The Essaouira Basin, located in central western Morocco, faces a significant threat of water shortage due to both the substantially reduced rainfall caused by climate change and the continuously increasing demand for this essential resource. Groundwater resources are being increasingly exploited to meet the needs of the population, whether for agricultural or domestic purposes. Therefore, it has become necessary to intensify investigations across the entire basin, particularly through indirect methods such as geophysical techniques, to accurately delineate the productive zones. In this context, the present study was undertaken to investigate the deep structure of this basin with the aim of comprehending the functioning of its aquifer system. This study is based on the interpretation of gravity data covering the Essaouira Basin. In addition to their qualitative analysis, these data underwent a methodological approach involving transformations to extract meaningful insights. The observed anomalies were interpreted in terms of (i) thickness variations within the slightly folded sedimentary series of the basin; (ii) Paleozoic basement topography; and (iii) the presence of salt deposits. In fact, among the negative anomalies, some coincide with evaporitic deposits that are known either from the geological outcrops or the seismic surveys carried out in the Essaouira Basin within the framework of petroleum exploration programs, while others coincide with areas of increased thickness of sedimentary sequences. The latter include synclines and basement depressions, where the accumulation of groundwater tends to occur; as a result, they constitute suitable zones for the drilling of water extraction wells. Groundwater flows observed in some existing wells are consistent with this hypothesis. The results of the contact analysis approach implemented within the framework of the study reveals the Essaouira Basin is affected by a fault network whose main direction is parallel to the Atlantic margin (i.e., NNE–SSW). This implies that the extensional tectonic phase responsible for initiating the rifting of the Central Atlantic in the Triassic era has primarily impacted the structural configuration of this basin. This study demonstrates the strong potential of the gravity method as a tool to delineate the deep structure of sedimentary basins and to identify potentially productive groundwater zones. The final results will provide important support to decision makers in sustainable groundwater management, especially in vulnerable areas.

Contamination Levels of Pb Heavy Metals and Availability of Phytoremediation Plants in the Gampong Jawa Landfill Area, Banda Aceh City

Heavy metal contamination is a major problem that occurs in landfill areas and contamination will continue to increase over time. This condition has a real impact on the increase in the accumulation of various kinds of materials which will have an impact on the occurrence of hazardous material accumulation such as the heavy metal lead (Pb). The purpose of this study was to determine the levels of heavy metal contamination of Pb found in the Gampong Jawa landfill area and the availability of phytoremediation plants as a mechanism to contain pollutant levels in the soil. The method of data collection was carried out by measuring the levels of lead accumulation (Pb) in groundwater in the TPA Gampong Jawa Kota Banda Aceh using the Atomic Absorption Spectrophotometry (AAS) method and for the availability of phytoremediation plants using an observational approach with a descriptive method. under the peacock (0.5648 ppm), under the neem (0.3031 ppm), under the orange garden (0.4438 ppm). The phytoremediation plants found included Samanea saman L, Leucaena leucocephala L, Cymbopogon citratus, Imperata cylindrica L, Desmodium ovalifolium, Azadirachta indica

Hydrological Evaluation of the Groundwater Potential in the Fractured Karoo Aquifer Using Magnetic and Electrical Resistivity Methods: Case Study of the Balfour Formation, Alice, South Africa

The study is aimed at evaluating the groundwater accumulations present in Alice using magnetic and electrical resistivity measurements to examine the trends of structural elements and characterize the groundwater resource for borehole drilling. The magnetic maps show a low magnetic linear structure moving northwest to southeast direction, which may be caused by fractures. The linear high intensities were probably caused by dolerite dykes, while dolerite sills caused broader high-intensity areas. The depth slices show that the near-surface magnetic structures are visible to a depth of about 19 m, and the deep-seated structures are found at a depth of about 31 m, possibly deeper. Twenty-five vertical electrical soundings (VES) of the Schlumberger array were measured with AB/2 varying between 1.5 m and 250 m across the study area. The VES interpretation showed four geoelectric layers composed of HK and HA curve types. The geoelectric layer’s thicknesses are (1) topsoil from 0.4 to 1.8 m, (2) weathered layer from 0.8 to 17.5 m, and (3) weathered/fractured layer from 9.9 to 143.9 m; the third layer could be the productive water-bearing zones, and (4) bedrock layer has an infinite thickness. The layers have resistivity values of 20-5752 Ωm, 3-51 Ωm, 136-352 Ωm, and 44-60428 Ωm, respectively. A correlation of the VES with the borehole log indicated a well-matched result. The magnetic and electrical resistivity surveys provided a detailed subsurface structure and helped identify possible fractures that could act as a passage for groundwater.

Data-driven approaches demonstrate legacy N accumulation in Upper Mississippi River Basin groundwater

Increases in nitrogen (N) fertilizer application, livestock densities, and human population over the last century have led to substantial increases in nitrate contamination. While increases in riverine N loads are well-documented, the total magnitude of N accumulation in groundwater remains unknown. Here we provide a first data-driven estimate of N mass accumulation in groundwater within the Upper Mississippi River Basin (UMRB), an area of intensive row-crop agriculture and the primary contributor to Gulf of Mexico hypoxia. Using approximately 49 000 groundwater nitrate well concentration values and a suite of geospatial predictors, we developed a Random Forest model to produce gridded predictions of depth-varying nitrate concentrations. Our results suggest that approximately 15 Tg of N (328 ± 167 kg-N ha−1) is currently stored in UMRB groundwater recharged over the last 50 years. For context, we compare these predictions to those from a lumped statistical model, which predicts accumulation of 387 ± 133 kg-N ha−1, as well as to a simple N mass balance model of the UMRB, which puts an upper bound on accumulation of approximately 1000 kg-N ha−1 (1967–2017). These findings highlight the importance of considering legacy N when forecasting future water quality, as N in the subsurface will continue to impair drinking water quality and elevate surface water N concentrations for decades to come.

Hydrochemical investigation of groundwater in a trans-Himalayan region of Ladakh, India, using geochemical modelling and entropy technique.

Evaluating the hydrogeochemistry and groundwater quality status is vital to understand the sources and extent of groundwater contamination. Chemometric analysis, geochemical modelling and entropy technique were explored to delineate the hydrogeochemistry of groundwater in the trans-Himalayan region. Analysis of hydrochemical facies revealed that 57.14, 39.29, and 3.57% of samples were Ca-Mg-HCO3-, Ca-Mg-Cl- and Mg-HCO3- water types, respectively. Gibbs diagrams illustrate the effects of the dissolution of carbonates and silicates during weathering on groundwater hydrogeochemistry. The PHREEQC modelling depicted that most of the secondary minerals are supersaturated except for halite, sylvite, and magnetite which are undersaturated and in equilibrium with nature. Multivariate statistical techniques, including principal component analysis, were applied for source apportionment indicating that the hydrochemistry of the groundwater was mainly controlled by geogenic sources (rock-water interaction) along with secondary pollution through increased anthropogenic sources. Heavy metal accumulation in groundwater depicted the order of Cd > Cr > Mn > Fe > Cu > Ni > Zn. EWQI analysis revealed that none of the samples fell into excellent and good categories. In total, 92.86% of groundwater samples were in an average category while the rest of the samples (7.14%) were unfit for drinking. This study will provide baseline data and a scientific framework which can be used in source apportionment studies, predictive modelling and efficient management of water resources.

Mapping potential groundwater accumulation zones for Karachi city using GIS and AHP techniques.

Karachi is the largest industrial metropolitan of Pakistan facing an acute water shortage which is leading to an overdraft of groundwater resources in the city. Groundwater is an important freshwater resource for the city as millions of people depend for sustenance. However, over-exploitation of groundwater has led to decreased groundwater levels within the city leading to environmental issues of depleting aquifers, deteriorating groundwater quality, land subsidence, and harm to groundwater-dependent ecosystems. The objective of the study was to assess the potential groundwater accumulation zones by integrating hydrogeological aspects of the city through nine thematic layers using the Geographic Information System (GIS) based multi-criteria decision analysis (MCDA) technique. The potential groundwater accumulation map reveals that 20% of the area has a low potential, 70% has moderate potential, and around 10% of the area in the city is composed of a high potential accumulation zone. The upstream regions of the city have the highest recharge potential because of sandy soil and barren land use, which promote high infiltration rates. The urbanized downstream areas have the lowest recharge potential due to impervious fabric. The findings reveal that the MCDA technique can be used with confidence in data-scarce regions for groundwater resource assessment and management. The recharge potential map can help better manage groundwater resources in the city by helping explore groundwater extraction opportunities and could hint at areas suitable for artificial recharge wells/ponds.