In this work, electrostatic minimum quantity lubrication (EMQL) has been applied in grinding. When the droplets were charged, it could promote penetrability in the processing area. The electric field formed between the charged droplets and the surface of Cr12 die steel could affect the hardness of the workpiece surface. The grinding mechanism of EMQL has been revealed under different charging voltage by analyzing the wetting angle of droplets and the hardness of Cr12 surface. The reduction of grinding force (11.5% to 49%), surface roughness (10% to 22.1%), and the increase in grinding ratio (1.9% to 27.3%) and surface quality of EMQL under various charging voltages were studied. The results showed that the wetting angle decreased when the droplets were charged. Compared to MQL, the charged lubricant droplets with better penetrability are easier to penetrate and spread on the contact surface between the grinding wheel and the workpiece, thereby improving the lubrication of the friction interface and obtaining better grinding performance. Moreover, we also found that the positively charged EMQL not only effectively improves the penetrability of droplets but reduces the hardness of the Cr12 surface. Thus, the grinding performances under positively charged EMQL are always better than these under negatively charged when grinding Cr12.
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