Unveiling the temperature-dependent deformation mechanisms of single crystal gallium nitride in nanoscratching

Abstract

The surface grinding process of single crystal gallium nitride (GaN) is intricate, and localized high temperature generated during interactions between the workpiece and the abrasives on grinding wheel is inevitable. Elevated temperatures significantly affect the deformation mechanisms of GaN, which remains inadequately elucidated. In this study, nanoscratching experiments were systematically conducted on the (0001) plane of GaN single crystal across a temperature range up to 500 ℃, and the resultant deformation patterns were thoroughly characterized. The results indicate that temperature elevation delays the brittle-to-ductile transitions in GaN and enhance its anisotropy. Additionally, GaN exhibits increased plasticity as temperature rises, leading to distinct scratch-induced subsurface deformation patterns at varying temperatures: at room temperature, the thickness of the subsurface damaged layer is primarily influenced by the penetration depth of cross slips, whereas at 500 ℃, basal slipping predominantly defines the thickness of the subsurface damaged layer. The plastic deformation patterns at both room temperature and 500 ℃ mainly involve phase transition, polycrystal formation, slips, stacking faults, dislocations and lattice distortions. The discrepancies in deformations at varying temperatures were thoroughly investigated by transmission electron microscopy and molecular dynamics simulations, and the underlying mechanisms were elucidated.