The balance between the burial of biospheric organic carbon (OCbio) in the ocean and the oxidation of rock-derived organic carbon across landscapes (OCpetro) helps to regulate atmospheric CO2 and O2 over geological time. However, we lack reconstructions of these processes over the timescales necessary to properly understand the drivers and feedbacks operating. Here we use a sediment core from the Zhuoshui River delta in Taiwan, which receives sediments from a rapidly uplifting and eroding catchment, to reconstruct the variations in OC content and radiocarbon composition since the Last Glacial Maximum (LGM). We find that the export of OCbio and the oxidation of OCpetro are both modulated by climate-driven changes in physical erosion and temperature. During cold and dry periods, such as the LGM and the Younger Dryas (YD), shallow erosion and low temperature enhanced the preservation of OCbio in the biosphere in catchment, while deep erosion and high temperature during warm and wet periods, such as the Holocene, favored the dilution and degradation of OCbio. The weathering intensity of OCpetro (ω) was inversely related to physical erosion, suggesting a lower intensity of oxidation during the Holocene period while the overall oxidation flux was enhanced. This suggests that the degree of weathering was primarily controlled by physical erosion. We propose a proxy to estimate the ratio of fluxes of OCbio export and OCpetro oxidation, and show that the net balance between these two processes shifted from a carbon sink during the late deglacial period to a carbon source during the mid-late Holocene. Our study reveals that with CO2 rise, a warmer and wetter climate would promote the exposure and oxidation of OCpetro by erosion in this mountain range, leading the organic carbon balance towards a CO2 source to the atmosphere.
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