Green Principles Research Articles

Eco-friendly formulation preparation of fungal biopesticide Metarhizium anisopliae and its impact on the viability, insecticidal activity and pesticidal compatibility

Aim: The present investigation evaluated the effect of various formulations on the viability, pesticide compatibility and biocontrol potential of fungal biopesticidal agent Metarhizium anisopliae under laboratory conditions. Methodology: Soil isolate of M. anisopliae biomass was formulated with different oils like sunflower, groundnut, neem oil, water and diesel using green principles. Results: Sunflower oil recorded maximum viability among the formulations, revealing 91.4% formulation efficacy, followed by groundnut oil, which showed 87.2% efficacy. The viability of the fungal isolate was found to be low in diesel formulation, which showed 69.2% formulation efficacy. A compatibility study revealed that sunflower oil formulation showed high tolerance to all the tested pesticides. Sunflower oil formulation also showed a high rate of mortality against S. litura. Interpretation: The present study suggests using oil formulation as an effective carrier for the fungal biopesticide Metarhizium anisopliae with high compatibility and viability. Key words: Biopesticide, Fungal strains, Metarhizium anisopliae, Sunflower oil

Unlocking the potential of biogenic Ag@g-C3N4 in sustainable water purification: A kinetic and photocatalytic study

This research introduces a pioneering biogenic deposition-precipitation method for synthesis of Ag@g-C3N4 nanocomposites (NCs) employing fennel seed extract (FSE). This technique involves the reduction and capping of silver nanoparticles (AgNPs) onto g-C3N4, employing polyphenolic content of FSE, consequently establishing a strong Schottky junction. The, NCs were characterized through various spectroscopic and microscopic techniques, confirming successful biogenic deposition of AgNPs and purity of prepared nanomaterials. Further, the synthesized NCs were utilized for photocatalytic degradation of various hazardous pollutants viz. Rhodamine-B (Rh-B) dye, Tetracycline (TCy) antibiotic, Imidacloprid (IMD) insecticide and deactivation of E. coli microbes. Amongst the synthesized NCs, 3 wt% Ag@g-C3N4 NCs exhibited superior photocatalytic mitigation of Rh-B (99.26%, k = 90.4 × 10−3 min−1), TCy (96.86%, k = 40.2 × 10−3 min−1), IMD (95.7%, k = 34.96 × 10−3 min−1) and E. coli deactivation (99.5%, k = 49.19 × 10−3 min−1). Moreover, the rate constants revealed many-fold increase in photocatalytic degradation of pollutants, contrary to pristine g-C3N4 (k = 11.8 × 10−3 min−1). This investigation also unveils an intricate photocatalytic mitigation pathway for the aforementioned-contaminants, elucidating key role of superoxide radical anions in photocatalytic mitigation. One of the significant highlights of this research is the sustainable and cost-effective synthesis methodology involving fennel seeds, which not only ensures the wide availability of resources but also guarantees environmental safety, in alignment with green principles.

Review on Green Bioanalytical Chemistry with Sustainable Approaches in Method Development: Unveiling the Crucial Role of Sustainable Bioanalysis in the Future of Chemistry

Green bioanalytical chemistry, with its focus on incorporating sustainable practices into developing bioanalytical methods, has the potential to significantly reduce the environmental impact of laboratory activities. This approach, while maintaining the high standards required for analytical precision and accuracy, includes key strategies such as reducing hazardous chemicals, optimizing energy use, and implementing waste-reduction practices. This review highlights recent advancements in green bioanalytical chemistry, including green solvent systems, miniaturized techniques, and eco-friendly analytical platforms. We discuss the benefits, such as reduced environmental pollution and improved resource efficiency, challenges, and future perspectives of integrating green principles into bioanalytical method development, emphasizing the balance between sustainability and analytical performance.

Pathways for Green Governance and Legalization in Mega-Cities

The realization of China's style of modernization relies on the high-quality development of cities, which represents the modernization of megacity governance, with the fundamental goal of enhancing the well-being of the population. The ecological governance of megacities encompasses the entire process from urban planning to design to renewal in the temporal dimension, and in the spatial dimension, it covers the entire economic, social, and ecological landscape. Summarizing the environmental governance experiences in domestic megacities, deepening the fundamental paradigm of ecological governance focusing on energy conservation, emissions reduction, mutual assistance, sharing, and the empowerment of the digital economy, and using the green principles established by the Civil Code as guidance to prevent risks and address challenges, ultimately explores a universally applicable new path for green governance in megacities.

A Review on Climate Change, Credit Risk and Agriculture

Abstract Climate change poses a significant threat to agricultural productivity, necessitating a comprehensive understanding of its implications for both agricultural firms and capital lenders. This systematic literature review aims to elucidate emerging trends in addressing climate-related risks in agriculture and credit sectors. Drawing from a rigorous analysis of 39 articles sourced from Scopus and Web of Science databases, three key thematic dimensions have emerged: (i) agricultural lending and credit risk, (ii) green principles and sustainability, and (iii) the context of developing countries. From the impact of climate change on the recoverability of loans to the imperative of transitioning towards a greener and more sustainable economy, alongside the nuanced challenges faced by agriculture in developing countries, we analyzed prominent and recent literary approaches. The findings underscore the need to integrate climate change considerations into agricultural and credit policies. Policymakers and financial institutions should prioritize climate education for farmers and promote sustainable financial approaches. Anticipated climate risks will impact lenders’ capital reserves, necessitating portfolio adjustments. A deep understanding of climate change’s interplay with agriculture lending and credit risk is vital, urging proactive policy and practice. Addressing climate challenges in agriculture demands a multifaceted strategy encompassing tailored credit policies, improved access to credit, financial empowerment, and the mitigation of social inequalities. This review highlights the urgent need for proactive strategies to mitigate climate risks and ensure a resilient agricultural sector, emphasizing the crucial role of research and policy interventions in navigating the complex landscape of climate change impacts on agriculture.

Systematic review turning existing Egyptian residential buildings in green ones

Due to the continuous technological advancements, expensive utility bills became a major concern for the world residents as well as governments. As a result, energy consumption mitigation became a prominent target for modern researchers. Consequently, solutions were introduced, suggesting that green principles be applied to the construction field. However, even if newly built structures became completely green and emitted no harmful emissions, the net emissions of a given city's overall construction would still be in operation, harming and polluting the environment with all their might. Therefore, it is needed to work on the net green score and rather focus on the conversion of existing buildings into green. Using a questionnaire to create a hypothetical typical Egyptian home, this study aims to apply green solutions to existing buildings in Egypt. The questionnaire also tackles other areas of Egyptian society in order to better understand their awareness and understanding of green concepts. The study’s methodology is based on the collective data gathered from other researchers in the field with applied case studies in climates similar to Egypt’s due to its lack of these solutions applications and concepts. The solutions suggested included solar panels as a retrofitting solution, and windows orientation and window-to-wall ratio (WRR) as a renovating one. As a result, the "windows" solutions suggested in this paper happened to be the most effective.

Instant green synthesis: obtaining stable nanoparticles and understanding the extract's behavior in the particle formation mechanism

Numerous plant extracts are abundant in biomolecules that can be employed in the biogenic synthesis of metallic nanoparticles owing to their potent reducing capabilities. The mechanism by which biomolecules act as reducers and expedite the reduction of silver ions remains poorly understood. This study presents an instantaneous and environmentally friendly synthesis of silver nanoparticles (AgNPs) using varying concentrations of commercially available green tea and concentrations of a dextrose-reducing solution. The AgNPs formed instantaneously, likely due to the competitive reaction between the polyphenols present in green tea and the dextrose. The best AgNPs produced using a diluted green tea solution at a concentration of 0.05 g of tea/ml and 100 μl of dextrose solution exhibited high stability over a period of 90 days, as confirmed by UV–vis spectroscopy and dynamic light scattering. The results of antioxidant properties from diluited tea showed 2,2-diphenyl-1-picrylhydrazyl (DPPH) 0.013 ± (0.1) μmol Trolox Equivalent Anyioxidant Capacity (TEAC) TEAC/g, Ferric Reducing Antioxidant Power (FRAP) 10.3 ± (0.1) μmol TEAC/g and Total Polyphenol Content (TPC) 0.12 ± (.001) μgGAE(Galic Acid Equivalent)/g). The resulting nanoparticles are extremely small, measuring approximately 30 to 50 nm in size, and exhibit a spherical morphology as evidenced by SEM imaging. The plasmon bandwidth is better in more diluted tea and higher proportions of dextrose added than the others condition of synthesis. Probably, the results of 2nd extraction of green tea diluted can be evidence that phenolic compounds, mainly, caffeine and gallic acid, are contributing to forming and stabilizing the silver nanoparticles. This fundamental knowledge showed the method employed is ecologically sound and adheres to green principles.

Biodegradable polylactic acid emulsion ink based on carbon nanotubes and silver for printed pressure sensors

Investigating biodegradable and biocompatible materials for electronic applications can lead to tangible outcomes such as developing green-electronic devices and reducing the amount of e-waste. The proposed emulsion-based conducting ink formulation takes into consideration circular economy and green principles throughout the entire process, from the selection of materials to the production process. The ink is formulated using the biopolymer polylactic acid dissolved in a sustainable solvent mixed with water, along with conductive carbon nanotubes (CNTs) and silver flakes as fillers. Hybrid conductive fillers can lower the percolation threshold of the ink and the production costs, while maintaining excellent electrical properties. The coating formed after the deposition of the ink, undergoes isothermal treatment at different temperatures and durations to improve its adhesion and electrical properties. The coating’s performance was evaluated by creating an eight-finger interdigitated sensor using a Voltera PCB printer. The sensor demonstrates exceptional performance when exposed to various loading and unloading pressures within the 0.2–500.0 kPa range. The results show a consistent correlation between the change in electrical resistance and the stress caused by the applied load. The ink is biodegradable in marine environments, which helps avoiding its accumulation in the ecosystem over time.

Beyond green borders: an innovative model for sustainable transportation in supply chains

Modern requirements necessitate the establishment of sustainable transportation systems, considering the substantial growth in transportation activities over recent years, which is expected to continue. Companies are facing the challenge of modeling their system transport to align with green principles. Sustainable transport relied on involving diverse stakeholders, particularly scientific research, in the development of this field. In light of this, maintaining sustainable transport quality involves conducting thorough investigations into an innovative study focusing on an uncertain interval programming model for a multi-stage, multi-objective, multi-product transportation challenge within budget constraints and safety measures in a green supply chain. Human languages often contain imperfect or unknown information, inherently lacking certainty; achieving precision in describing existing states or future outcomes is frequently unattainable. In probability theory, sufficient historical information is crucial for estimating probability distributions; while in fuzzy theory, determining a reliable membership function proves challenging; hence, there is often a hesitant estimation of the degree of belief in the occurrence of each condition. Addressing such uncertainties, the theory of uncertain intervals proves highly valuable. Given these considerations, the elements of the specified problem are recognized as uncertain intervals. To manage this lack of assurance, a fusion of interval theory and methods from uncertain programming is used to formulate two distinct models: an expected value model and a chance-constrained model. The equivalent deterministic models are then formulated and solved utilizing Weighted Sum Method, fuzzy programming, and goal programming. Following this, a numerical example is utilized to assess the model’s performance, and the results obtained are compared. Finally, the document concludes with a sensitivity analysis and outlines future directions.

Study of Reducing Transmission Losses in Java-Bali System with the Addition of Capacitors along with Optimal Capacitor Placement Methods Using Quasi-Dynamic Simulation

The Java-Bali electricity system is the largest electricity system in Indonesia which consists of 5 areas including Jakarta-Banten area, West Java area, Central Java area, East Java area and Bali area. This system is operated to meet the economic, reliability, quality, and green principles. In the case of reliability, one of the essential aims is minimization of transmission losses due to importance in system improvement to increase system operational efficiency to the possible extent. Transmission losses are an inevitable part of the electric power transfer process from generation stations to consumers. The power losses in a transmission line are inversely proportional to the square of the line voltage. This implies that lower line voltages result in higher power losses. Therefore, it is crucial to maintain optimal voltage levels to minimize transmission losses and ensure efficient energy delivery across the power system. One effective way to achieve this is by integrating capacitors into the system. In this study, we have explored two methods that aim to pinpoint the most advantageous locations for the integration of new capacitors. The goal is to optimize capacitor planning, with an emphasis not only on improving voltage levels but also on minimizing transmission losses within the Java-Bali system. The research results indicate that implementing two proposed methods can significantly reduce transmission losses in The Java-Bali system. Method-1 involves identifying the lowest voltage over the course of a year, while Method-2 focuses on the lowest voltage value within the first quartile (Q1/25%) during the same period

Indoor Environmental Quality Effect Analysis in Green and Non-green Office Building to Staff’s Performance and Satisfaction in Surabaya

The energy efficiency in an office building can decrease the company’s operational cost. Even so, the operational cost for staff is still larger than the cost for energy. It is important to reassure that the impact given by the building’s indoor environmental quality (IEQ) is positive to staff. This research focusses on two office building in Surabaya, one of them is designed using the green principles and calculations, and the other is not. The building’s IEQ aspects being inspected includes indoor air quality, thermal, lighting, acoustics and layout. A questionnaire survey was held to obtain the reaction from the full time staff regarding the building’s IEQ performance, their satisfaction to it and their self-assessed performance. There are IEQ aspects that affects staff’s performance and satisfaction significantly. The IEQ mean score differs significantly in green and non-green building, but the mean difference in satisfaction and performance were found not significant.

A Review on the Effect of Metal Oxide Nanoparticles on Tribological Properties of Biolubricants.

This review provides a comprehensive and accessible literature review on the integration of nanoparticles into biolubricants to enhance wear and friction regulation, thus improving the overall lubricated system performance. Nanotechnology has significantly impacted various industries, particularly in lubrication. Nanobiolubricants offer promising avenues for enhancing tribological properties. This review focuses on oxide nanoparticles, such as zinc oxide (ZnO), aluminum oxide (Al2O3), copper oxide (CuO), titanium dioxide (TiO2), zirconium dioxide (ZrO2), and graphene oxide (GO) nanoparticles, for their ability to enhance lubricant performance. The impact of nanoparticle concentration on biolubricant properties, including viscosity, viscosity index, flash point temperature, and pour point temperature, is analyzed. The review also addresses potential obstacles and limitations in nanoparticle incorporation, aiming to propose effective strategies for maximizing their benefits. The findings underscore the potential of nanobiolubricants to improve operational efficiency and component lifespan. This review aims to provide valuable insights for researchers, engineers, and professionals in exploring and leveraging nanotechnology's potential in the lubrication industry. This review paper explores the basics of tribology along with its significance, green principles, mechanisms, and energy savings because of friction, wear, and lubrication. Condition monitoring techniques are also explored to achieve brief knowledge about maintaining reliability and safety of the industrial components. Recent advances in tribology including superconductivity, biotribology, high-temperature tribology, tribological simulation, hybrid polymer composite's tribology, and cryogenic tribology are investigated, which gives a thorough idea about the subject.

Green leadership in manufacturing industry: Unveiling the green Revolution's impact on organizational performance

This study aims to analyze the role of green transformational leadership and human resource management in organizational performance with the mediating effect of green innovation. The study also proposes the moderating role of commitment to management change. The study used a quantitative research method with a random sampling technique and surveyed 235 managers from the Cement industry across Pakistan. The statistical techniques used to assess the study's hypotheses were partial least squares structural equation modeling (PLS-SEM) and SPSS. The findings show that green transformational leadership and HRM positively impact organizational performance, with green innovation partially mediating effect. Furthermore, affective commitment to management change strongly moderates the relationship between green innovation and organizational performance. In addition, the proposed relationship is based on the resource-based view (RBV) theory. Therefore, Managers and executives should adopt green principles and practices and build an environmentally friendly culture that encourages employees to engage in green behaviors and activities to improve organizational performance. To successfully implement green practices in a developing country like Pakistan, the Cement sector must understand how the cement industry improves its performance and whether employees demonstrate green innovation.

Energy recovery and clean water remediation using antibiofouling polysaccharide coated PAN hollow fiber membrane obtained via green route synthesis

Biofouling is an important biological constrain in the water treatment process, and the control or management strategies using green principles have gained recent attention. Antibiofouling agents based on the biological source are now extensively studied due to their high efficacy and are environmentally friendly. In this present study, Poly Acrylo Nitrile (PAN)/Ulvan hollow fibre membranes of four different modules were fabricated for water treatment studies by testing against B. subtilis and E. coli along with separation efficiency studies on proteins such as albumin, pepsin, and clay. Ulvan (Ulv), green seaweed sulfated polysaccharide extracted from Ulva fasciata, was coated on PAN hollow fibres, fabricated using a wet-spinning process. Ulvan was dip-coated on membrane surface followed by cross-linking and resultant changes in terms of performance and morphology. PAN/Ulv hollow fibre membranes were examined for the pure water flux and protein separation analysis to analyse the membrane efficiency. SEM was used to analyse the membrane structure and ATR- FTIR for the determination of functional groups. Ulvan coated (310 C) hollow fibre membrane showed better performance than the other three membranes with a flux of 398.1 L m−2 h−1. Higher sample concentration of suspended solids paved simpler route for enhanced COD sequestration efficacy. Pepsin, albumin, and clay particles were rejected by the 310C Ulvan adorned membranes at rates greater than 80%. By incrementing suspended particles beyond 3200 mg/L, the greatest power recovery was reduced that portrays an adverse influence of bio-fouling process on membrane operation. Experimental results demonstrated that synthesised 310 C membrane possessed better separation performance and antifouling characteristics for aquatic water systems.

Research on Judicial Application Dilemmas of the Green Principles in the Civil Code: Translated from 32 Legal Documents as Analytical Samples

Research on Judicial Application Dilemmas of the Green Principles in the Civil Code: Translated from 32 Legal Documents as Analytical Samples

Co(II)-Cu(II) mixed-oxide catalysts for single-step synthesis of 2,4,5-triaryl-1H-imidazole derivatives under microwave irradiation.

In this study, a catalyst composite of Co-Cu was prepared from chloride-containing precursor of Co(II) and Cu(II) metals using the milky latex of the Euphorbia neriifolia plant following green principles of synthesis. The catalyst composite was characterized using XRD, EDAX, SEM, HR-TEM, FTIR, XPS and TOF-MS. The crystallinity of the mixed-oxide composite with a distorted octahedral nature was confirmed from analysis. Chemical charge analysis of the Co-Cu mixed phase based on XPS revealed Co2+ and Cu2+ oxidation states. This material was used for synthesizing 2,4,5-triaryl-1H-imidazole (TIMDZOL) derivatives. Analysis of reaction conditions revealed that EtOH : PEG at 8 : 2 ratio under microwave conditions showed better yields with less time and better reusability of the Co-Cu catalyst.

Integration Green Chemistry into Learning Process

This research aims to synthesize the related research with green chemistry as the topic which focuses on chemistry learning research in the recent ten years from various Scopus journals and proceedings focusing on the recent ten years. After doing the searching on the national and international reputable databases by using the relevance key pattern (Pattern 1: “green chemistry” “green chemistry learning”; Pattern 2: “green chemistry” “curricula”; Pattern 3: “green chemistry” “chemistry education), from 20 relevant articles to be systematically reviewed. The systematic goal is to result in the general review and knowledge for teachers about the integration of green chemistry in the learning process. At the middle school level, the integration of green chemistry through project-based practicum activities, textbooks, modules, and games. The result shows that the chemistry topic which can be integrated with green chemistry is by making soap, fossil fuels, recycling processes, environmental problems arising from the use of fuel, chemical reactions, and plastic waste. While 12 green principles in some articles are discussed thoroughly while others don’t. There are only 5 or 6 green chemistry principles integrated either in modules, games, and practicum activities. By doing the research, it is expected to give knowledge to the teachers related to green chemistry integration in the process of learning to support the Merdeka curriculum in chemistry learning.

Determination of polycyclic aromatic hydrocarbons in bud-derived supplements by magnetic molecular imprinted microparticles and GC-MS: D-optimal design for a fast method optimization

Within the world of natural food supplements, organic extracts deriving from young plant meristematic tissue (bud-derivatives) are becoming attractive, thanks to their richness in bioactive molecules. This natural source is scarce, but every year, tons of plant material, including buds, come from city pruning. If this sustainable source is rather promising from a circular economy point of view, the safety of the obtained supplements must be assessed. In fact, anthropic microcontaminants, such as polycyclic aromatic hydrocarbons (PAHs), could adsorb onto the urban buds, leading to a possible contamination of the bud-derivatives. In this study, we developed a magnetic dispersive solid phase extraction (m-dSPE) based on molecularly imprinted microparticles, combined with GC-MS, to quantify the 16 priority PAHs in such extracts. The D-optimal experimental design was implemented to maximize analytes’ recovery with the smallest set of experiments. The optimized method was characterized by great selectivity thanks to the molecular imprinted polymer and ease of use provided by m-dSPE. Moreover, it complies with green principles, thanks to the minimum consumption of organic solvent (1.5 mL of acetone per sample). The recoveries ranged from 76 to 100% and procedural precision was below 10% for most PAHs. Despite the matrix complexity, low quantification limits (0.7–12.6 μg kg−1) were reached. This guaranteed the PAHs’ quantitation at levels below those indicated as safe by a European Community regulation on food supplements. None of the analyzed samples, coming from different anthropically impacted areas, showed concerning PAHs levels.

Euphorbia royleana Boiss Derived Silver Nanoparticles and Their Applications as a Nanotherapeutic Agent to Control Microbial and Oxidative Stress-Originated Diseases.

Nanotechnology is one of the most advance and multidisciplinary fields. Recent advances in nanoscience and nanotechnology radically changed the way we diagnose, treat, and prevent various diseases in all aspects of human life. The use of plants and their extracts is one of the most valuable methods towards rapid and single-step protocol preparation for various nanoparticles, keeping intact "the green principles" over the conventional ones and proving their dominance for medicinal importance. A facile and eco-friendly technique for synthesizing silver nanoparticles has been developed by using the latex of Euphorbia royleana as a bio-reductant for reducing Ag+ ions in an aqueous solution. Various characterization techniques were employed to validate the morphology, structure, and size of nanoparticles via UV-Vis spectroscopy, XRD, SEM, and EDS. FTIR spectroscopy validates different functional groups associated with biomolecules stabilizing/capping the silver nanoparticles, while SEM and XRD revealed spherical nanocrystals with FCC geometry. The results revealed that latex extract-mediated silver nanoparticles (LER-AgNPs) exhibited promising antibacterial activity against both gram-positive and -negative bacterial strains (Bacillus pumilus, Staphylococcus aureus, E. coli, Pseudomonas aeruginosa, and Streptococcus viridians). Both latex of E. royleana and LER-AgNPs were found to be potent in scavenging DPPH free radicals with respective EC50s and EC70s as 0.267% and 0.518% and 0.287% and 0.686%. ROSs produced in the body damage tissue and cause inflammation in oxidative stress-originated diseases. H2O2 and OH* scavenging activity increased with increasing concentrations (20-100 μg/mL) of LER-AgNPs. Significant reestablishment of ALT, AST, ALP, and bilirubin serum levels was observed in mice intoxicated with acetaminophen (PCM), revealing promising hepatoprotective efficacy of LER-AgNPs in a dose-dependent manner.

Mechanochemical Nickel-Catalyzed Carbon-Sulfur Bond Formation between Aryl Iodides and Aromatic Sulfur Surrogates.

The formation of aromatic thioethers from C-S coupling is of great importance in synthetic chemistry. Traditional solution strategies through transition-metal catalysis generally require bulk solution, heat, and longer reaction time. Herein, a mechano-promoted sulfenylation of aryl iodides with nickel catalysis is described. The active aromatic sulfide agents are in-situ generated from aromatic thiol or disulfide and subsequently adapted in the nickel catalytic cycle, with a tolerance of broad substituted groups under optimized conditions. In addition to the gram-scale synthesis that reveals the application potential of the method, the radical trapping and competitive experiments are also conducted for the mechanistic study, thus providing a plausible mechanism rationally. Furthermore, the proposed methodology is certificated as being versatile and following the green principles with ideal calculated values of green chemistry metrics, and the comparison with other approaches for C-S bond formation is also demonstrated.