Granitoid Protoliths Research Articles

Zircon as a Recorder of Trace Element Changes during High-Grade Metamorphism of Neoarchean Lower Crust, Shevaroy Block, Eastern Dharwar Craton, India

AbstractSystematic changes in whole-rock chemistry, mineralogy, mineral textures, and mineral chemistry are seen along a ca. 95-km traverse of late Archean granitoid orthogneisses in the Shevaroy Block, Eastern Dharwar Craton, southern India. The traverse passes from amphibolite-grade gneisses in the north to granulite-grade rocks (charnockite) in the south. Changes include whole-rock depletion of Rb, Cs, Th, and U in the granulite grade rocks as relative to the amphibolite grade gneisses, and oxidation trends regionally from highly oxidised granulite-facies rocks near the magnetite–haematite buffer to relatively reduced amphibolite-facies rocks below the fayalite-magnetite-quartz. Rare earth elements show limited mobility and are hosted a variety of minerals whose presence is dependent on the metamorphic grade ranging from titanite and allanite in the amphibolite-facies rocks to monazite in the vicinity of the orthopyroxene-in isograd to apatite in the granulite-grade charnockite. Cathodoluminescence and back-scattered electron sub-grain imaging and sensitive high-resolution ion microprobe analysis of zircon from 29 samples of dioritic, tonalitic, and granitic orthogneiss from the traverse reveals magmatic zircon cores that record the emplacement of the granitoid protoliths mostly about 2580 to 2550 Ma, along with a few older mid to late Archean tonalites. Protolith zircon was modified during metamorphism by overgrowth and/or replacement. Relative to igneous cores, U-enriched metamorphic zircon, dominant in the amphibolite-grade gneisses, formed at ca. 2530 Ma, predating retrograde titanite growth at ca. 2500 Ma. Uranium-depleted mantles grew on zircon between 2530 and 2500 Ma in granulite-grade samples south of the orthopyroxene-in isograd. In some of these samples, the U-depleted metamorphic zircon is preceded by mantles of U-undepleted zircon, indicating a progression of metamorphic zircon growth with increasingly depleted compositions between 2530 and 2500 Ma. With increasing metamorphic grade (from amphibolite to granulite) and oxidation state, allanite and monazite disappear from the assemblage and zircon became depleted in U and Th. Whole-rock U-Th compositions became decoupled from relict magmatic zircon compositions, reflecting the development of U-depleted metamorphic zircon and indicating that whole-rock chemical differences along the traverse were produced during metamorphism, rather than just reflecting differences in dioritic vs granitic protoliths. Although in situ anatexis and melt extraction may have played a role, whole-rock and zircon depletion of trace elements can be explained by the action of externally derived, oxidising, low-H2O activity hypersaline fluids migrating up through the mid to lower crust. Fluids and element migration during metamorphism may be the end result of subduction related processes that cumulated in the collision and concatenation of island arcs and continental blocks. These tectonic processes assembled the Dharwar Craton at the end of the Archean.

Buried Triassic rocks and vertical distribution of ores in the giant Jiaodong gold province (China) revealed by apatite xenocrysts in hydrothermal quartz veins

Obtaining geological information at depth by lower-cost proxies is important. Apatite grains from hydrothermal quartz veins and their host K-feldspar altered granites from the Jiaodong gold province reveal key insights into the buried rocks and vertical distribution of ores at depth. Two types of apatite grains from hydrothermal quartz veins and their host K-feldspar altered granites are identified. Type I apatite grains in granites coexist with amphibole and feldspar, indicating a magmatic origin. They yield U-Pb Tera–Wasserburg concordia lower intercept dates of 162 ± 13 Ma and 158 ± 9 Ma, which are within uncertainty of zircon U-Pb dates of ca. 160 Ma, representing the crystallization ages for these rocks. Support vector machine (SVM) apatite classification biplots show that the Type I apatite grains have lower LREEs than their I-type granitoid protolith, indicating that LREEs were leached during alteration, which is also suggested by monazite inclusions in altered domains of the Type I apatite. Apatite xenocrysts (Type II) are observed in hydrothermal veins and yield Tera–Wasserburg concordia lower intercept dates of 227 ± 3 Ma and 227 ± 4 Ma. Two subsets of Type II apatite are recognized. SVM apatite classification biplots show that they were derived from the Late Triassic S-type granites and high-grade metamorphic rocks related to the Late Triassic collision between North China and South China blocks. These rocks were less than 11 ± 1 km under the paleosurface during gold mineralization (ca. 120 Ma) estimated by the closure temperature of apatite U-Pb system (460 ± 10 °C), surface temperature at Jiaodong (20 °C), and paleogeothermal gradient (40 ± 5 °C/km). Given the ore-forming paleodepth of about 7 km calculated by previous fluid inclusion works, the unaltered Type II apatite xenocrysts mark that gold ores in the footwall at Jiaodong didn’t exceed 4 ± 1 km vertically relative to the sample location. The high preservation potential for apatite in hydrothermal veins illustrates the potential to employ apatite xenocryst as a powerful tool for determining buried rocks at depth.

Age and geochemistry of the Paleoproterozoic Bhatwari Gneiss of Garhwal Lesser Himalaya, NW India: implications for the pre-Himalayan magmatic history of the Lesser Himalayan basement rocks

Abstract The Bhatwari Gneiss of Bhagirathi Valley in the Garhwal Himalaya is a Paleoproterozoic crystalline rock from the Inner Lesser Himalayan Sequence. On the basis of field and petrographic analyses, we have classified the Bhatwari Gneiss into two parts: the Lower Bhatwari Gneiss (LBG) and the Upper Bhatwari Gneiss (UBG). The geochemical signatures of these rocks suggest a monzonitic protolith for the LBG and a granitic protolith for the UBG. The UBG has a calc-alkaline S-type granitoid protolith, whereas the LBG has an alkaline I-type granitoid protolith; the UBG is more fractionated. The trace element concentrations suggest a volcanic arc setting for the LBG and a within-plate setting for the UBG. The U–Pb geochronology of one sample from the LBG gives an upper intercept age of 1988 ± 12 Ma ( n = 10, MSWD = 2.5). One sample from the UBG gives an upper intercept age of 1895 ± 22 Ma ( n = 15, MSWD = 0.82), whereas another sample does not give any upper intercept age, but indicates magmatism from c. 1940 to 1840 Ma. Based on these ages, we infer that the Bhatwari Gneiss has evolved due to arc magmatism and related back-arc rifting over a time period of c. 100 Ma during the Proterozoic. This arc magmatism is related to the formation of the Columbia supercontinent. Supplementary material: LA–ICP-MS calibration and adjusted major element data used for computing the isometric log-ratio transformations are available at https://doi.org/10.6084/m9.figshare.c.4272158

Preservation of a Paleoproterozoic rifted margin in the Himalaya: Insight from the Ulleri-Phaplu-Melung orthogneiss

Orthogneiss within the Paleoproterozoic strata of Lesser Himalayan sequence across the Himalaya has been variably linked to development in a continental arc setting, Indian basement, or a continental rift. New whole rock and trace element geochemical data and U/Pb zircon geochronology indicate that the granitoid protoliths to these rocks were derived from upper crustal sources in the Paleoproterozoic and have within-plate, A-type affinities. This is consistent with their generation in a rifted margin and is compatible with paleogeographic reconstructions that indicate an open boundary for present-day northern India in the Paleoproterozoic.

A synthesis of zircon U–Pb ages and Hf isotopic compositions of granitoids from Southwest Mongolia: Implications for crustal nature and tectonic evolution of the Altai Superterrane

Granitoid magmatism is extensively developed in the Altai Superterrane, but the timing of magmatic events is not so well determined. In this study, twelve granitoid intrusions from Southwest Mongolia were dated by the zircon U–Pb method and analyzed for zircon Hf isotopic compositions. The new age data indicated three phases of magmatic emplacement: Middle Paleozoic (398–350Ma), Late Paleozoic (317–289Ma) and Triassic (ca. 244–211Ma). The first-phase magmatism is mainly composed of hornblende-bearing I-type granitoids, formed during a long-lasting subduction process in the Early to Middle Paleozoic. The second-phase magmatism was manifested by a few small intrusions, primarily distributed along the Erqis fault zone, and probably formed in a transitional tectonic regime from subduction to post-tectonic setting in the Late Paleozoic. The third-phase magmatism was represented by post-tectonic granitoids emplaced in an intraplate extensional setting. Model ages that were calculated using the composition of new continental crust are predominantly Neoproterozoic to Early Paleozoic, indicating that the protoliths of granitoids were likely dominated by Paleozoic juvenile crust with minor Neoproterozoic materials. The Altai Superterrane was a huge Paleozoic tectonic collage produced by amalgamation of subduction–accretion complexes in the margin of the Siberian continent and the Tuva–Mongol microcontinent.

The affinity of Archean crust on the Yilgarn—Albany–Fraser Orogen boundary: Implications for gold mineralisation in the Tropicana Zone

Craton margins can be subject to a wide array of gold genesis and redistribution processes, although high-grade terrains on craton margins are frequently viewed as less prospective than lower-grade counterparts. In contrast to this, the high-grade Tropicana Zone, a newly defined Archean crustal component on the eastern margin of the Yilgarn Craton within the Albany–Fraser Orogen (AFO), contains a significant Proterozoic gold deposit. This deposit and zone comprise mid-amphibolite to granulite-facies gneissic rocks with evidence of partial melting and granite injection. The Tropicana Zone contains significant low-Si, LILE-enriched, granites classed as sanukitoids. Along with the distinctive compositions, the rarity of these rocks within any Archean craton suggests that the granitoid protoliths represent a single suite, emplaced during one event.Due to the intense granulite-facies overprinting of the Tropicana Zone rocks, determination of the magmatic protolith age for these sanukitoids is challenging. Nonetheless, the best age estimate for magmatism is 2692±16 Ma, based on the youngest zircons preserving textural evidence of growth within a viscous silicate melt. This age is older than compositionally similar magmatism found within the Yilgarn Craton, although a sanukitoid in the Northern Foreland of the AFO has a similar age. Furthermore, the granulite-facies metamorphic zircon growth in the Tropicana Zone at 2718–2554 Ma was prolonged compared to that in the Yilgarn Craton. Nonetheless, the Hf isotopic signature of the Tropicana Zone zircon shares strong similarity to that from the Eastern Goldfields Superterrane of the Yilgarn Craton. This implies that the Tropicana Zone reflects a deeper crustal level of the Yilgarn Craton, exhumed and thrust NW an unknown distance over the craton edge. In addition, we observe that the granulite-facies zircons have a less radiogenic Hf-isotope signature than the preserved pre-metamorphic zircon cores. Based on correlations with alpha dose, U and Th content and 176Hf/177Hf we suggest this reflects the preferential destruction and release of unradiogenic Hf from inherited zircon whereas the protolith sanukitoid zircon, with lower U and Th content, was more resistant to mobilisation during high-grade metamorphism. We note this situation may be a more general response of the Hf isotopic system, in which zircon grown in a more mafic melt is less likely to contribute to the metamorphic Hf reservoir than its felsic counterpart.Juvenile granitic veins dated at c. 1780 Ma intruded into the Tropicana Zone indicate that the Tropicana Zone was structurally emplaced at or before c. 1780 Ma, given similar Proterozoic magmatic events are well documented from (para)autochthonous adjacent units. Re–Os dating of pyrite coeval with one generation of gold in these rocks indicates model ages of c. 2100 Ma, supportive of a Palaeoproterozoic age of mineralisation. This mineralisation event is distinct from major Proterozoic tectonothermal events elsewhere in the AFO. Sanukitoid magmas are well-known for gold fertility and were likely the original source of gold in the Tropicana Zone, which was subsequently concentrated into brittle structures during several episodes. Gold mineralisation post-dated peak metamorphic conditions and is significantly younger than gold mineralisation within other parts of the adjoining Yilgarn Craton.

Jurassic subduction zone tectonics of the Rhodope Massif in the Thrace region (NE Greece) as revealed by new U–Pb and 40Ar/39Ar geochronology of the Evros ophiolite and high-grade basement rocks

In the Thrace region of NE Greece, the crystallization and post-solidification cooling below 600°C of the intrusive suite of the Circum-Rhodope Belt arc-related Evros ophiolite span from 176.4±0.93 to 163.5±3.85Ma. In the underlying Rhodope high-grade metamorphic basement, (ultra-) high-pressure metamafic rocks are cross-cut by orthogneisses with granitoid protoliths and crystallization ages between 160±0.69 and 154±1.5Ma. This new U–Pb LA–ICP-MS zircon geochronological data provides evidence that the timing of the evolution of the Evros ophiolite coincides, within analytical error, with granitoid magmatism in the underlying high-grade basement. One of the dated metagranitoid rocks cross-cuts amphibolitized eclogite, indicating that the high-pressure conditions have a maximum age of 160Ma postdating one of the proposed ages of ultra-high pressure conditions in the Rhodope Massif. The currently earliest recognised Rhodope high/ultra-high pressure metamorphic event is therefore related to the subduction setting which formed the Evros ophiolite. Based on these new temporal constraints and the regional tectonic–geochronologic framework, we discuss and update the geodynamic context connected to the Jurassic subduction–collisional setting at the Rhodope continental margin of Eurasia.

Feedback between fluid infiltration and rheology along a regional ductile-to-brittle shear zone: The East Tenda Shear Zone (Alpine Corsica)

The East Tenda Shear Zone (ETSZ) is the major Alpine tectonic boundary marking the overthrusting of the ocean-derived Schistes Lustres nappe onto the Variscan crystalline basement of Corsica. New structural, mineralogical, and geochemical investigations along a transect ranging from the Variscan basement to the contact with the Schistes Lustres are used to construct a rheological model for the ETSZ during its polyphase deformation history. The progressive transformation of the isotropic granitoid protolith into gneisses, shear zones, and, locally, phyllonites is described. The textural/mineralogical change suggests a concurrent increasing metasomatism associated with structurally controlled fluid flow. The effect of such textural/mineralogical evolution on the bulk rheology of the ETSZ is estimated. Rheological flow laws are obtained using an averaging procedure based on the integration of single-phase rheological behavior. The flow laws are used to infer strain rates and construct strength envelopes for each structural domain during progressive deformation, which highlight the relative rheological differences of the main textural components of the ETSZ and the variations in their brittle/ductile transition depths. Two competing processes are inferred. On the one hand, the combined effects of the feldspar-to-mica reaction and the development of a strong planar fabric induce weakening and strain localization along shear zones. On the other hand, fluid channeling along these shear zones enhances alkali feldspar neoblastesis, inducing strain hardening. Among the possible consequences of such feedback processes between strain localization and fluid-rock interaction are episodes of rheological transitions from ductile to brittle behavior during the polyphase tectonic evolution of the ETSZ.

Structural Controls on Orogenic Au Mineralization During Transpression: Lupa Goldfield, Southwestern Tanzania

Au mineralization in the western Lupa goldfield, southwestern Tanzania was associated with transpression and reverse sinistral slip along a network of steeply S dipping shear zones with non-Andersonian geometries. Slip was accommodated by: (1) frictional failure and sliding during emplacement of quartz ± Au-bearing veins; and (2) crystal plasticity and fluid-assisted diffusive mass transfer. The Kenge mineral system is situated along a NW-SE-trending shear zone and is characterized by ≤10-m thick, Au-bearing fault-fill veins hosted by well-developed phyllosilicate-rich mylonites. The broadly contemporaneous Porcupine mineral system is situated along an ENE-WSW– to E–W-trending shear zone, which is characterized by narrow, discontinuous mylonitic shear zone within a silicified and nonfoliated granitoid protolith. Au mineralization at Porcupine occurs within steeply dipping fault-fill and subhorizontal extension/oblique-extension veins. Three-dimensional frictional reactivation theory provides a self-consistent explanation for the different vein styles at Kenge and Porcupine and extends the classic fault valve model to the general case of oblique slip along multiple, arbitrarily oriented shear zones. Analysis of the differential stress required for frictional reactivation suggests the following: (1) the Kenge shear zone was intrinsically weaker than the Porcupine shear zone, consistent with the lack of well-developed mylonites at Porcupine; and (2) frictional reactivation of the Kenge shear zone occurred under suprahydrostatic but sublithostatic pore fluid pressures, whereas frictional reactivation of the Porcupine shear zone occurred under near-lithostatic fluid pressures. We hypothesize that near-lithostatic pore fluid pressures relieved effective normal stresses at grain-grain contacts, helping to preserve intragranular and fracture porosity at the Porcupine orebody. As such, these pore spaces may be important microstructural sites for Au mineralization. Low effective normal stresses can also explain the poorly developed phyllosilicate-rich mylonites and limited degree of shear zone weakening at Porcupine.

The augen gneisses of the Peloritani Mountains (NE Sicily): Granitoid magma production during rapid evolution of the northern Gondwana margin at the end of the Precambrian

The medium- to high-grade polymetamorphic basement rocks of the Peloritani Mountains, northern Sicily, include large volumes of augen gneiss of controversial age and origin. By means of a geochemical and SHRIMP zircon study of representative samples, the emplacement age of the original granitoid protoliths of the augen gneisses and the most likely processes and sources involved in that granitoid magmatism have been determined. U–Pb dating of three samples from widely spaced localities in the Peloritani Mountains yielded igneous protolith ages of 565±5, 545±4 and 545±4Ma, respectively. These late Ediacaran/early Cambrian ages are much older than was previously assumed on geological grounds, and are typical of the peri-Gondwanan terranes involved in the geodynamic evolution of the northern Gondwana margin at the end of the Avalonian–Cadomian orogeny. Major and trace element compositions and Sr–Nd isotopic data, in combination with zircon inheritance age patterns, suggest that the granitoid protoliths of the Sicilian and coeval Calabrian augen gneisses were generated by different degrees of mixing between sediment- and mantle-derived magmas. The magmas forming the ca. 545Ma inheritance-rich granitoids appear to have had a significant contribution from partial melting of paragneiss that is the dominant rock type in the medium- to high-grade Peloritanian basement. The closeness of the inferred deposition age of the greywacke protoliths of the paragneisses with the intrusion age of the granitoids indicates rapid latest Precambrian crustal recycling involving erosion, burial, metamorphism to partial melting conditions, and extensive granitoid magmatism in less than ca. 10Ma.

Local shear zone pattern and bulk deformation in the Gran Paradiso metagranite (NW Italian Alps)

The Gran Paradiso nappe of the northwestern Alps mostly consists of augen gneisses derived from the Alpine deformation of Permian granitoids. The regional foliation of the augen gneisses developed at lower amphibolite facies conditions and is associated with a top-to-west sense of shear. The granitoid protolith is preserved in the kilometre-scale low-strain domain of the Piantonetto Valley and mainly consists of a porphyritic metagranite including joints, leucocratic dykes and biotite-rich schlieren. In this low-strain domain, the Alpine deformation is mainly localized in discrete ductile shear zones within weakly foliated metagranite. The shear zones mostly dip towards S–SE in a shallow (shear zones 1) to steep inclination (shear zones 2). The shear zones show typical features that can be explained by reactivation of pre-existing joints and planar compositional heterogeneities. Palaeostress and strain analysis indicate that shear zones and the metagranite foliation both formed in the presence of a strong component of flattening. The kinematics of individual shear zones depends on the orientation of the original heterogeneities (acting as nucleation planes) and by partitioning of strain components at the kilometre-scale with concentration of the flattening component to the Piantonetto low-strain domain. The strain geometry and the kinematics of individual shear zones within Piantonetto are not directly connected to the top-to-west sense of tectonic transport observed elsewhere in the Gran Paradiso nappe. However, the bulk stress ellipsoid reconstructed for the incipient shear zone network within very weakly deformed granites is oriented consistently with the bulk direction of tectonic transport within the Gran Paradiso massif. We conclude that the shear zone network of the Piantonetto Valley is representative of the incipient stages of ductile deformation of a granite nappe. Even if its architecture is determined by the arrangement of pre-existing structural and compositional heterogeneities, aspects of the large-scale bulk strain can be derived from this local shear zone pattern.

Large calcite and bulk-rock volume loss in metacarbonate xenoliths from the Quérigut massif (French Pyrenees)

Chemical mass transfer was quantified in a metacarbonate xenolith enclosed within the granodiorite of the Querigut massif (Pyrenees, France). Mass balance calculations suggest a strong decrease of CaO, SrO and CO2 contents (up to −90%), correlated with a decrease of modal calcite content as the contact is approached. Most other chemical elements behave immobile during metasomatism. They are therefore passively enriched. Only a small increase of SiO2, Al2O3 and Fe2O3 contents occurs in the immediate vicinity of the contact. Hence, in this study, skarn formation is characterized by the lack of large chemical element influx from the granitoid protolith. A large decrease of the initial carbonate volume (up to −86%) resulted from a combination of decarbonation reactions and loss of CaO and CO2. The resulting volume change has potentially important consequences for the interpretation of stable isotope profiles: the isotope alteration could have occured over greater distances than those observed today.

The role of Precambrian mylonitic belts and present-day stress field in the coseismic reactivation of the Pernambuco lineament, Brazil

The Pernambuco lineament is a steeply dipping continental-scale ductile shear zone rooted within the Precambrian lithosphere of intraplate northeastern Brazil. It was formed during the Brasiliano orogeny ~ 600 Ma and reactivated during the Pangea breakup in the Cretaceous, when it controlled fault propagation and sediment accumulation in several rift basins. The region is now under an ~ E–W-trending horizontal compression and ~N–S-trending extension, and faulting occurs predominantly in a strike-slip regime. We investigated two aftershock sequences and the preexisting tectonic fabrics along the Pernambuco lineament in order to evaluate the role of these fabrics in the coseismic reactivation of continental-scale structures. The lineaments consist of a main ENE–WSW-trending mylonitic belt about 2–3 km wide, and two secondary NE-trending mylonitic belts about 100 m wide. They both present steeply dipping mylonitic foliations and shallowing plunging stretching lineations. The mylonites present granitoid protoliths and mineral parageneses that range from amphibolite to greenschist facies. Brittle deformation overprints the ductile fabric in all mylonitic belts. In 1991, coseismic reactivation nucleated along the ENE–WSW-striking, ~ 3.3-5.6 km deep, normal fault of less than 1 km in length in the main mylonitic belt. In 2002, seismicity migrated to a NE-trending secondary mylonitic branch and moved as a right-lateral strike-slip, ~ 1.2 km long, 3.8–4.9 km deep fault plane. Both fault segments reactivated the mylonitic foliation and form part of a major system. We conclude that the interplay between the present-day stress field and preexisting fabrics controls seismogenic fault location, attitude, and kinematics. The Pernambuco lineament is an example of a long-lived continental-scale structure, where selective reactivation has occurred. Other shear zones in the region also show a long history of brittle reactivation and present similar orientation in relation to the present-day stress axes. They might be dormant structures prone for reactivation under the present-day stress field.

Petrologic, isotopic, and radiometric age constraints on the origin and tectonic history of the Malino Metamorphic Complex, NW Sulawesi, Indonesia

The Malino Metamorphic Complex (MMC) is located at the western end of the north arm of Sulawesi. It consists of mica schists and gneisses (derived from proximal turbidite and granitoid protoliths), with intercalations of greenschist, amphibolite, marble, and quartzite, forming an E-W elongated dome-like structure bounded on all sides by faults. The age of the MMC is constrained between Devonian and Early Carboniferous. This Paleozoic age, the presence of Archean and Proterozoic inherited zircons, and the isotopic signature of the mica schists and gneisses indicate that the terrane was derived from the New Guinea-Australian margin of Gondwana. Similarities with basement rocks in the Bird’s Head suggests a common origin. Greenschists forming a discontinuous selvage (metamorphic carapace) around the complex were derived from adjacent autochthonous Paleogene formations. The rocks of the MMC show a Barrovian-type progression from greenschist through epidote-amphibolite to amphibolite facies. P–T estimations suggest a depth of burial of up to 27–30 km. K/Ar and 40Ar/39Ar cooling ages of 23–11 Ma, and a 7 Ma age for unconformably overlying volcanic rocks, indicate that the complex was exhumed during the Miocene. Two tectonic scenarios are considered: 1. the continental fragment docked with Sulawesi during the Mesozoic and was exhumed as a metamorphic core complex during the Miocene; 2. it was subducted beneath the north arm during the late Oligocene and then rapidly returned back to the surface.

Identification of repeated Alpine (ultra) high-pressure metamorphic events by U–Pb SHRIMP geochronology and REE geochemistry of zircon: the Rhodope zone of Northern Greece

U–Pb sensitive high resolution ion microprobe (SHRIMP) zircon geochronology, combined with REE geochemistry, has been applied in order to gain insight into the complex polymetamorphic history of the (ultra) high pressure [(U)HP] zone of Rhodope. Dating included a paragneiss of Central Rhodope, for which (U)HP conditions have been suggested, an amphibolitized eclogite, as well as a leucosome from a migmatized orthogneiss at the immediate contact to the amphibolitized eclogite, West Rhodope. The youngest detrital zircon cores of the paragneiss yielded ca. 560 Ma. This date indicates a maximum age for sedimentation in this part of Central Rhodope. The concentration of detrital core ages of the paragneiss between 670–560 Ma and around 2 Ga is consistent with a Gondwana provenance of the eroded rocks in this area of Central Rhodope. Metamorphic zircon rims of the same paragneiss yielded a lower intercept 206Pb/238U age of 148.8±2.2 Ma. Variable post-148.8 Ma Pb-loss in the outermost zircon rims of the paragneiss, in combination with previous K–Ar and SHRIMP-data, suggest that this rock of Central Rhodope underwent an additional Upper Eocene (ca. 40 Ma) metamorphic/fluid event. In West Rhodope, the co-magmatic zircon cores of the amphibolitized eclogite yielded a lower intercept 206Pb/238U age of 245.6±3.9 Ma, which is interpreted as the time of crystallization of the gabbroic protolith. The metamorphic zircon rims of the same rock gave a lower intercept 206Pb/238U age of 51.0±1.0 Ma. REE data on the metamorphic rims of the zircons from both the paragneiss of Central Rhodope and the amphibolitized eclogite of West Rhodope show no Eu anomaly in the chondrite-normalized patterns, indicating that they formed at least under HP conditions. Flat or nearly flat HREE profiles of the same zircons are consistent with the growth of garnet at the time of zircon formation. Low Nb and Ta contents of the zircon rims in the amphibolitized eclogite indicate concurrent growth of rutile. Based on the REE characteristics, the 148.8±2.2 Ma age of the garnet–kyanite paragneiss, Central Rhodope and the 51.0±1.0 Ma age of the amphibolitized eclogite, West Rhodope are interpreted to reflect the time close to the (U)HP and HP metamorphic peaks, respectively, with a good approximation. The magmatic zircon cores of the leucosome in the migmatized orthogneiss, West Rhodope, gave a lower intercept 206Pb/238U age of 294.3±2.4 Ma for the crystallization of the granitoid protolith of the orthogneiss. Two oscillatory zircon rims around the Hercynian cores, yielded ages of 39.7±1.2 and 38.1±0.8 Ma (2σ errors), which are interpreted as the time of leucosome formation during migmatization. The zircons in the leucosome do not show the 51 Ma old HP metamorphism identified in the neighboring amphibolitized eclogite, possibly because the two rock types were brought together tectonically after 51 Ma. If one takes into account the two previously determined ages of ca. 73 Ma for (U)HP metamorphism in East Rhodope, as well as the ca. 42 Ma for HP metamorphism in Thermes area, Central Rhodope, four distinct events of (U)HP metamorphism throughout Alpine times can be distinguished: 149, 73, 51 and 42 Ma. Thus, it is envisaged that the Rhodope consists of different terranes, which resulted from multiple Alpine subductions and collisions of micro-continents, rather similar to the presently accepted picture in the Central and Western Alps. It is likely that these microcontinents were rifted off from thinned continental margins of Gondwana, between the African and the European plates before the onset of Alpine convergence.

Metagranitoids from the eastern part of the Central Rhodopean Dome (Bulgaria): U?Pb, Rb?Sr and 40Ar/39Ar timing of emplacement and exhumation and isotope-geochemical features

Geochronological data (U–Pb, Rb–Sr and 40Ar/39Ar) are used to unravel the Late Alpine high-grade metamorphism, migmatisation and exhumation of Variscan granitoids within the core of the Central Rhodopean dome, Bulgaria. The age of the granitoid protolith is 300 ± 11 Ma, as determined by U–Pb analyses on single zircons selected from the core of the dome structure.

Neoarchaean magmatism and metamorphism of the western granulites in the central domain of the Mozambique belt, Tanzania: U–Pb shrimp geochronology and PT estimates

U–Pb sensitive high resolution ion microprobe (SHRIMP) dating of zircons from charnockitic and garnet–biotite gneisses from the central portion of the Mozambique belt, central Tanzania indicate that the protolith granitoids were emplaced in a late Archaean, ca. 2.7 Ga, magmatic event. These ages are similar to other U–Pb and Pb–Pb ages obtained for other gneisses in this part of the belt. Zircon xenocrysts dated between 2.8 and 3.0 Ga indicate the presence of an older basement. Major and trace element geochemistry of these high-grade gneisses suggests that the granitoid protoliths may have formed in an active continental margin environment. Metamorphic zircon rims and multifaceted metamorphic zircons are dated at ca. 2.6 Ga indicating that these rocks were metamorphosed some 50–100 my after their emplacement. Pressure and temperature estimates on the charnockitic and garnet–biotite gneisses were obscured by post-peak metamorphic compositional homogenisation; however, these estimates combined with mineral textures suggest that these rocks underwent isobaric cooling to 800–850 °C at 12–14 kbar. It is considered likely that the granulite facies mineral assemblage developed during the ca. 2.6 Ga event, but it must be considered that it might instead represent a pervasive Neoproterozoic, Pan African, granulite facies overprint, similar to the ubiquitous eastern granulites further to the east.

Tectonic evolution of the Zambezi orogenic belt: geochronological, structural, and petrological constraints from northern Zimbabwe

In southern Africa, the Zambezi belt forms the eastern part of a transcontinental orogenic system that connects with the East African orogen and records interactions between the Congo and Kalahari cratons during collisional assembly of the Gondwana supercontinent at the end of the Neoproterozoic. We report the results of reconnaissance studies in the eastern part of the Zambezi belt in northern Zimbabwe, where thick-skinned thrusting has inverted a crustal column comprising a Neoproterozoic supracrustal sequence tectonically overlain by rocks exhumed from the lower crust. An extensive felsic gneiss with A-type geochemical signatures that is inferred to represent a metarhyolitic unit within the supracrustal sequence has yielded a U–Pb zircon crystallization age of ca. 795 Ma, which helps to constrain the timing of supracrustal deposition in this part of the Zambezi belt. The dominant ductile structures in the area record south-vergent thrusting, during which the supracrustal rocks underwent prograde, amphibolite-facies metamorphism as they were overridden by a crystalline thrust stack partly preserving high-pressure granulite-facies assemblages. Complex U–Pb zircon geochronological results for a layered, metagabbroic to meta-anorthositic intrusive complex in the upper part of the thrust stack are interpreted to indicate a minimum igneous crystallization age of ca. 1830 Ma. Polydeformed orthogneisses in the lower part of the thrust stack were derived from granitoid protoliths with U–Pb zircon crystallization ages of ca. 1050 and 870 Ma. The younger granites are inferred to be parts of an A-type magmatic province that can be recognized throughout the Zambezi belt. U–Pb zircon and titanite geochronological results from the layered complex and the underlying orthogneisses are interpreted to record metamorphism associated with thrust emplacement at ca. 550–530 Ma. This is consistent with isotopic age data from adjacent areas, indicating that a major orogenic event affected the Zambezi belt in this time frame, during assembly of central Gondwana.

Dating the TIPA shear zone: an Early Devonian terrane boundary between the Famatinian and Pampean systems (NW Argentina)

The TIPA shear zone is a prominent tectonic element of the Las Termas belt of NW Argentina. The belt is squeezed between the rocks of the Pampean system in the east and those of the Famatinian system in the west and is characterized by NNW–SSE-trending ductile shear zones. Granitoid protoliths of the mylonites yield intrusion ages of 487.5±4.3 and 467.0±3.6 Ma (U–Pb on zircon). During mylonitization, an intense fluid and melt influx, correlated with the intrusion of syn- to late-tectonic pegmatoids, led to a significant change in rock composition and the growth of syntectonic garnet. Mylonitization is dated at 402.0±2.0 Ma (Sm–Nd on garnet). U–Pb ages for apatite (meta-granodiorite 342.3±1.8 Ma; mylonite 328±3 Ma), consistent with the age of granites intruding the whole series, document a Carboniferous heating process that affected the whole crust. Final uplift is indicated by homogeneous biotite cooling ages at 300±4 Ma (Rb–Sr). The time span of approximately 40 Ma between apatite crystallization and closure of the Rb–Sr isotopic system in biotite implies a cooling rate of 3–4 °C/Ma, which indicates total uplift of the series of approximately 4 km.

Age and origin of the Böllsteiner Odenwald

The granitoid protoliths of the gneisses of the Bollsteiner Odenwald, a part of the Mid German Crystalline Rise, intruded at 405 ± 3 Ma. This age was obtained by single zircon 207Pb/206Pb evaporation measurements. It is supported by an upper discordia intercept age of 410 ± 11 Ma from single zircon U/Pb data. These granitoids were derived from hybrid magmas according to their geochemical characteristics. Inherited zircon grains with apparent ages of 882 and 1138 Ma further constrain the source heterogeneity. The isotope data with Nd model ages for the granitoid gneisses between 1.3 and 1.7 Ga also underline the involvement of Proterozoic material into the magma sources. Since the geochemical data indicate a subduction zone environment we suggest that the Bollsteiner Odenwald was formed as part of a Silurian/Early Devonian magmatic arc in an active continental margin. The age data imply that the Bollsteiner Odenwald is closely related to the Spessart and Ruhla Crystalline Complexes but not to the Bergstrasser Odenwald. Therefore the Otzberg zone is considered to be a Variscan suture zone.