Granitoid Plutons Research Articles

ADVANCING PLANETARY SUSTAINABILITY THROUGH LITHOLOGICAL MAPPING: ASTER REMOTE SENSING IN ANTARCTICA’S DRY VALLEYS

The Dry Valleys of South Victoria Land in Antarctica, one of the most extreme deserts on Earth, offers an unparalleled analog for Martian landscapes and a vital record of Earth's geological history. Characterized by a cold, arid climate and minimal atmospheric moisture, the region's ancient rock formations, including early Paleozoic granitoid plutons, Devonian to Triassic sedimentary rocks of the Beacon Supergroup, and Jurassic basalt flows, provide insights into Earth's evolution. The logistical challenges of traditional field-based geological surveys in this remote and fragile environment emphasize the need for sustainable exploration methods. This study leverages Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) remote sensing technology to achieve high-resolution lithological mapping while minimizing environmental impact. Image processing techniques such as Band Ratio (BR) analysis, Principal Component Analysis (PCA), and the Optimal Index Factor (OIF) were employed to enhance the spectral characterization of lithologies. These approaches facilitated the identification of key lithological units, including sandstone, granite, gneisses, and basaltic flows, and the production of an accurate lithological map. By integrating remote sensing with sustainable scientific practices, this research demonstrates the potential to advance planetary sustainability while uncovering critical geological insights in extreme environments.

Origin of Diorites and Coeval Mafic Microgranular Enclaves in the Liuba Region, South Qinling Orogen, Central China: Insights from Petrography, Zircon U-Pb Geochronology and Geochemistry

The formation of early Mesozoic granitoid plutons in the Qinling Orogen is widely regarded as a result of the collision and accretion between the Yangtze Block and the South Qinling Block during the early Mesozoic, but the specific magmatic process, source composition, tectonic environment and deep dynamic background remain controversial. This study reports the petrology, zircon U–Pb geochronology, and whole-rock geochemistry of diorites from the Liuba and Qingyangyi plutons in the South Qinling, to provide new evidence for understanding the final collision tectonic evolution process of Qinling Orogenic belt. The Liuba and Qingyangyi plutons, located in the central part of the South Qinling region, are primarily composed of quartz diorite and quartz monzodiorite, respectively. The results indicate that the weighted mean crystallization ages of the quartz diorite in the Liuba pluton range from 216.1 ± 0.8 Ma to 217.1 ± 1.3 Ma, with the weighted mean crystallization ages of its MMEs being 215.4 ± 1.0 Ma. The crystallization ages of the quartz monzodiorite in the Qingyangyi pluton range from 214.6 ± 0.9 Ma to 215.4 ± 0.9 Ma, suggesting that both plutons were formed in the late Triassic. The investigated plutons are characterized as right-leaning and have weak negative Eu anomalies on the chondrite-normalized REE patterns diagram. The large ion lithophile elements (LILE) Rb, Ba, Th and K are relatively enriched, while high-field strength elements (HFSE) Nb, Ta, Ti and P are strongly depleted. The formation of numerous MMEs in the Liuba pluton is the product of magmatic mixing. The Liuba and Qingyangyi plutons are the results of crust thickening and partial melting of lower crust caused by the comprehensive late Triassic collision between the Yangtze Block and the North China Block (NCB), and are the manifestation of magmatic intrusion along the South Qinling tectonic belt in the late Triassic period.

STRUCTURAL EVOLUTION OF THE CHEKA PLUTON (SOUTHERN URALS): PETROMAGNETIC STUDIES AND FRACTURE ANALYSIS

The Cheka pluton, located in the Magnitogorsk megazone of the Southern Urals and composed of the alkaline granitoids, is meridionally elongated (1–2)×6.5 km. The fracture and anisotropy of magnetic susceptibility analysis was made on the Cheka pluton for the first time. The study materials comprise fracture measurements and core samples. The fractures were classified as either prototectonic or tectonic using the Stereonet software. The prototectonic fractures were classified into three standard types in accordance with the system proposed by G. Cloos: S, Q, and L. The system of tectonic fractures corresponds to the Riedel model, which confirms the formation of the pluton as a dextral magmatic strike-slip duplex supposed earlier. The analysis of magnetic mineralogy revealed that the most prevalent magnetic mineral is fine- to-medium-grained magnetite. Using the anisotropy of magnetic susceptibility data, the main direction of melt flow during the formation of the pluton was determined to be 36° NE. This direction is in close alignment with the orientation of one of the prototectonic fracture systems, which has a strike azimuth of 39° NE. The constructed complex structure model indicates that the Triassic granitoid plutons of the Magnitogorsk megazone were most likely formed during the right-lateral transpression, associated with a local strike-slip fault-related extension zone. These conditions are generally consistent with the Triassic rifting and dextral strike-slip motion in the Southern Urals.

Role of As in the formation of giant Au deposits: Insights from sulfur isotope and geochemistry of pyrite from the Shuangwang Au deposit, West Qinling, central China

The Shuangwang Au deposit (SWGD), located in the Feng-Tai ore district, is one of the largest Au deposits in the West Qinling orogen, central China. Au orebodies in this deposit are mainly hosted in the Upper Devonian Xinghongpu Formation. The source of the fluids and metals, ore-forming processes and the enrichment mechanism of Au in this ore deposit remain equivocal. Here we present results from geochemical studies of pyrite from the SWGD to address these issues through the application of Scanning electron microscopy (SEM), electron probe microanalysis (EPMA), in-situ laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and LA-MC-ICP-MS analyses. Based on detailed petrographic studies of the mineralization and host rocks, we identify seven generations of pyrite. Among these, the pre-ore syn-sedimentary pyrite (Py0) is characterized by relatively elevated concentrations of As, Co, Ni and Au compared to the Py1 in the albite-ankerite veins and Py2 in the quartz-ankerite-pyrite veins, and has positive δ34S values of + 6.00 to + 10.48 ‰, whereas Py3 forms as veinlets or aggregates in the pyrite-tourmaline veins and is enriched in As, Co, Cu, Se and Au. Py4 occur as coarse-grained subhedral to euhedral crystals or aggregates in the ankerite-pyrite veins and exhibit oscillatory zones. Py5 comprises fined-grained subhedral to anhedral grains in the fluorite-ankerite-pyrite cements, and is relatively depleted in trace elements when compared to the other pyrite types. The δ34S values of the different types of pyrite from the SWGD have significant differences, indicating a multiple and mixed source for sulfur and, by inference, for the ore-forming fluid(s). Two periods of Au mineralization are identified in the SWGD: the early NW-trending mineralization sourced from the metamorphism of the metasedimentary sequences in a compressional environment and the late NE-trending mineralization probably exsolved from an unexposed and coeval granitoid pluton at depths in a post-collisional extensional setting. The coupled geochemical behavior of Au and As can be explained by mixing-induced cooling. Our results also indicate that arsenic might have played an important role in the enrichment of Au and the formation of this hydrothermal Au deposit.

Fluid-mediated transition from dynamic rupturing to aseismic slip at the base of the seismogenic continental crust

Chemo-mechanical fluid-rock interactions are critical in controlling the frictional-viscous transition in the continental crust and the competition between seismic and aseismic deformation in fault zones. In this study, we provide quantitative constraints on the timing and magnitude of weakening, and associated changes in slip rates, due to fluid-rock interactions at the base of the seismogenic continental crust. Integrating field, microstructural analyses, and micromechanical modelling we constrain the microstructural and mechanical evolution of phyllosilicate-rich, carbonate-bearing brittle-ductile faults/shear zones developed in the Rieserferner granitoid pluton (Eastern Alps). Here, transient overpressure of (H2O + CO2)-rich fluids triggered dynamic rupturing in the strong host rock (>100 MPa), and promoted the development of weak phyllonites through long-term fluid-mediated feldspar-to-mica reactions. These phyllosilicate-rich fault rocks accommodated frictional-viscous aseismic creep at very low differential stresses (<10 MPa) and near-lithostatic fluid pressure conditions. Microscale vein networks overprinting the phyllonite indicate cyclical embrittlement related to increased creep rates (up to 10−7 s−1) that occurred over a timeframe of days to months and potentially related to slow earthquakes (slip rates of 10−8 m/s). These findings offer new constraints on the development and seismogenic potential of phyllosilicate-rich fault zones and on the effect of fluid chemistry on fault zone rheology. Fluid-mediated fault weakening can occur in rather short time (months-to-years) comparable to the interseismic period, progressively promoting long-term, viscous aseismic creep on a previously strong fault zone developed by dynamic rupturing. The combined effect of strain localization, the low permeability of the phyllonitic cores, as well as of fluid chemistry evolution and CO2-enrichment, may lead to the development of brittle-frictional instabilities during transient accelerated-creep events. Therefore, the fluid-mediated microstructural evolution of phyllosilicate-rich fault rocks controls their seismogenic behaviour, potentially leading to accelerated creep, slow earthquakes and slow slip on otherwise aseismically creeping faults.

The mid-Cretaceous Hohonu Batholith (South Island, New Zealand): Identifying magmatic sources and processes during onset of crustal extension

The Hohonu Batholith is an aggregation of mostly mid-Cretaceous granitoid plutons on the West Coast of the South Island of New Zealand emplaced during a transitional period between subduction-related compression and continental lithospheric extension. This study reports an integrated dataset, comprising in-situ UPb, O and Hf isotope compositions and REE, Ti and other trace and major elements (ZrHf, ThU) for zircons extracted from four representative plutons within the batholith. Our results provide detailed insight into the protracted thermal, chronological and geochemical histories. LA-ICPMS UPb zircon ages indicate a primary episode of magma genesis and emplacement from 107 to 113 Ma, confirming published SIMS dating. However, a younger previously unrecognized age population of ~91–96 Ma is identified, primarily (although not exclusively) in zircon rims. This younger age event coincides with the timing of protracted lithospheric extension and crustal thinning of the Zealandia continent. The cryptic younger zircon ages suggest that Hohonu granitoids experienced a partial thermal overprint (accompanied by Pb loss) mostly recorded in rims. Differences in bulk rock geochemistry between plutons are inferred to reflect variable conditions of partial melting controlled by source mineralogy and H2O content. Isotope and trace element compositions, along with Ti-thermometry, measured on the same micro-volume of CL-imaged zircons, are used to test if source characteristics were imparted from melt to minerals in zircon-saturated silicic systems. Similarities are revealed in the zircon record of the selected plutonic rocks, confirming their broadly consanguineous relationship and the fundamental role of open-system behaviour, involving hybridization or assimilation between mantle-derived (or juvenile mafic) and a crustal-derived components, as previously inferred from whole rock NdSr isotope systematics. However, intra-sample decoupling of zircon OHf isotope systematics may also be linked to residual source component unmixing. This possibility, in addition to mafic recharge, may have obscured melt source compositional characteristics, and hence zircon REE appear as unsuitable fingerprints of source(s) and conditions of partial melting in this granitoid system. Simple compositional and thermal magma evolution trends appear punctuated by episodes of mafic recharge, presumably during lithospheric thinning.

Influence of Lithology and Biota on Stream Erosivity and Drainage Density in a Semi‐Arid Landscape, Central Chile

AbstractDrainage density is a fundamental landscape feature that determines the length scale for hillslope sediment transport and results from the competition of diffusive hillslope and advective stream incision processes, whose efficiencies are known to vary with rock type but are notoriously difficult to quantify. Here, we present a comprehensive analysis of a catchment in semi‐arid Central Chile, where landscapes with different drainage densities, but equal tectonic and climatic conditions, have formed on three neighboring granitoid plutons (a monzogranite and two diorites). We combined topographic analysis of a 1‐m digital elevation model with 10Be‐derived denudation rates to estimate stream erosivity and soil diffusivity in the different landscapes. We find that the higher drainage density in the monzogranite is primarily due to higher stream erosivity, whereas soil diffusivity is similar between rock types. Remote sensing data from Landsat imagery confirm field observations of higher vegetation cover in the diorites, especially with regard to deeper‐rooted shrubs, which may result in increased infiltration. Based on geochemical and compositional analyses, we link vegetation differences to a relatively higher abundance of plant‐essential elements in the diorite bedrock. Additionally, the monzogranite's composition and crystal grain size supports more intense physical weathering and leads to a smaller observed hillslope grain size, which increases its erodibility. We conclude that subtle differences in composition and grain size can have a significant impact on stream erosivity and drainage density. Our results demonstrate the importance of taking lithology into account when interpreting fluvial networks and topographic metrics in slowly eroding landscapes.

Diverse intrusion modes during the construction of a high-silica magma reservoir: Evidence from La Obra–Cerro Blanco intrusive suite (central Chile)

Abstract Several conceptual models have been proposed for the amalgamation of granitoid plutons, which range from incremental growth to single-stage emplacement of these systems. This diversity of views has led to intense debate about the thermomechanical state of silicic intrusions and the magma differentiation paths within the crust. In this contribution, we present a comprehensive petrologic, geochronologic, and magnetic fabric data set from the La Obra–Cerro Blanco intrusive suite, which allows us to explore the petrogenesis and magma emplacement processes in the upper crust. This intrusive suite is composed of (1) a vertically zoned granitoid intrusion in spatial association with mafic layers and stocks and (2) a cupola-like high-silica granite. We interpret this intrusive suite as assembled by diverse but coexisting intrusion mechanisms over a time span of ~1.4 m.y. from 21.4 to 19.9 Ma. As indicated by the subhorizontal magnetic lineation, the first stage was dominated by horizontal emplacement of sheet-like intrusions of intermediate compositions, which became increasingly silicic after plagioclase and amphibole fractionation throughout the crustal column. The latest stage was instead dominated by cooling, crystallization, and differentiation of a thickened granitoid body and the formation of a high-silica magma chamber. The steep magnetic lineation and the abundance of aplite and rhyolitic dikes observed in the cupola-like, high-silica granites suggest that this portion acted as an evacuation channel of high-silica magma toward shallower levels, offering a rare opportunity to understand not only silicic magma accumulation and storage in the upper crust, but also the processes connecting the plutonic and volcanic environments.

Petrogenesis of early Paleozoic syn-collisional granitoids and enclaves in Western Kunlun, Northwest China: Implications for the growth of continental crust

The Western Kunlun Orogenic Belt (WKOB), along the northwestern margin of the Qinghai–Xizang Plateau, was formed by the collision of Gondwana-derived terranes to the south and the Tarim Block to the north and was closely associated with closure of the Proto-Tethys Ocean during the late Neoproterozoic to early Paleozoic. We present a combined zircon UPb geochronology, whole-rock composition, and Sr–Nd–Hf isotopic study of syn-collisional granitoid plutons and mafic microgranular enclaves (MMEs) in the region. Zircon UPb dating yields ages of 443.8 ± 4.4, 451.9 ± 4.2, 462.9 ± 3.5, and 456 ± 4.2 Ma for the Tongayoupuagezi, Shanjie, and Pishigai plutons and MMEs from the Pishigai pluton, respectively. The granitoids are metaluminous to weakly peraluminous (A/CNK = 1.00–1.17) and belong to the high-K calc-alkaline series. They have (87Sr/86Sr)i ratios of 0.7058–0.7154, εNd(t) values of −8.78 to −0.93, and εHf(t) values of −19.72 to +6.87. The MMEs have variable SiO2 contents (45.7–60.2 wt%) and are more mafic than the host granitoids, but have similar Sr–Nd–Hf isotopic compositions to the host granitoids [(87Sr/86Sr)i = 0.7102–0.7110; εNd(t) = −6.57 to −3.56; εHf(t) = −7.17 to −1.81]. The MMEs are fragments of cumulates formed during the early stages of magma evolution. The granitoids were produced by the partial melting of a mélange source. The new data support the view that the Middle–Late Ordovician syn-collisional granitoids with MMEs distributed along the WKOB represent a magmatic response to terrane collision. This suggests that juvenile crustal growth in older orogenic systems, which occurs by arc addition, also involves some vertical addition during the final stage of orogenic collision. Our study suggests that mélange diaper melting is a key mechanism of crustal growth during the syn-collision stage in continental collision zones, associated with slab breakoff.

Minerals of antimony: a newly found occurrence in the Karkonosze granitoid pluton and a review for Lower Silesia, Poland, with general background

The article describes assemblages of ore minerals of the size of tenths to a few millimetres, which occurred in small quartz veinlets and nests in 10 previously unknown sites. This mineralization was found in the north-eastern part of the Karkonosze granitoid pluton at the southern slope of the Wysoki Grzbiet (High Ridge) in Izera Mts. The studies concerned mainly 18 Sb minerals: antimony, Sb-bearing domeykite, getchellite, stibnite, willyamite, berthierite, boulangerite, bournonite, chalcostibite, falkmanite, famatinite, geocronite, robinsonite, semseyite, tetrahedrite-(Fe), cervantite, kermesite and schafarzikite; seven of them have been found in Poland for the first time. The parageneses, morphological features, XRD data and chemical composition of the Sb minerals are presented. Fluid inclusions in quartz adhering to the Sb minerals had generally homogenization temperature (Th) 108–341°C and total salinity ΣS 4.6–10.1 wt. %. The inclusion fluids were of the NaCO3- Ca(HCO3)2-NaCl-KCl type with minor F and S, and occasional CO2 presence. The parent granitoid contains Sb in trace amounts (0.18–0.36 ppm) and the rock was possibly a source of this (and other) element(s) for the ore minerals. Migration of meso-epithermal solutions with Sb etc. was probably stimulated by local reduction of pressure during the formation of fissures and cracks in granite, next filled by quartz with ore minerals. The features of the historical process of the recognition of Sb ores and previous studies of the minerals investigated in this research are included in the presentation and discussion. Special attention was paid to the listing of the occurreences of Sb minerals in Lower Silesia with appropriate references.

Compositional diversity of late Mesozoic granites rooting from the subducted crust in the Qinling–Dabie orogenic belt

Continental subduction has been identified in many orogens, such as the Alps, the Himalayas, and the Dabie; however, better understanding of the mechanism and outcome of different subduction processes remains desirable. The Qinling–Dabie orogen in Central China shows an asymmetric distribution of Triassic ultrahigh-pressure metamorphic rocks and syn- and post-tectonic granitoid plutons, thereby providing an excellent means by which to probe the diverse processes of continental subduction. Many late Mesozoic granitoid plutons that formed in post-orogenic or even anorogenic settings are widely distributed in both the Qinling and Dabie tectonic units and can be useful for studying the composition of materials beneath the crust because of their conspicuous compositional diversity. In the present study, we report zircon ages and NdHf isotopic compositions for the Shangcheng and Heyu granite plutons, which represent late Mesozoic plutons in Dabie and Qinling. When compared with those of the Shangcheng pluton, the wide range of Nd isotopic values and the slightly depleted Hf isotopic compositions of the Heyu pluton indicate that there may be juvenile crust beneath the Qinling tectonic unit that is not present beneath the southern margin of North China. The currently undetectable juvenile material in this region may be an important candidate source of the late Mesozoic magmatism and metal mineralization in the southern margin of North China. The compositional diversity of these granites, as indicated by the NdHf isotopic compositions, is attributed to the nature of the deep crust within the orogenic belt, and the magmatic origins of this region are discussed in the present study.

Protracted magmatism and crust–mantle interaction during continental collision: insights from the Variscan granitoids of the external western Alps

Variscan granitoids and associated mafic rocks exposed in the External Crystalline Massifs (ECM) of the Western Alps document the Variscan stages from the early Carboniferous collision to the early Permian post-collisional setting. Our study focuses on the Central part of the ECM, synthesizing newly acquired and existing geochronological, whole-rock geochemical and isotopic data. We identified two distinctive magmatic series: (i) high-K calc-alkaline granitoids, which range from magnesian (MgG) to ferro-magnesian (FeMgG) rocks; (ii) ultra-high-K metaluminous (UHKM) rocks (“durbachites”). These series were emplaced roughly simultaneously between ca. 350 and 300 Ma, with two main episodes during the Visean (ca. 348–335 Ma) and the late Carboniferous (305–299 Ma), with a more limited activity in between. A younger Permian event at ca. 280–275 Ma has also been identified in one granitoid pluton. Contemporaneous emplacement of these two series reflects concomitant crustal anatexis and melting of LILE–LREE-rich metasomatized lithospheric mantle. Trace elements and Nd–Sr isotopes reveal significant hybridization between these two magmatic end members, by magma mixing, or assimilation of crystallized mafic ultrapotassic enclaves in the high-K calc-alkaline granitoids. Granitoid composition evolves over time, especially SiO2, Mg#, Sr/Y, La/Yb and Nb/Ta, possibly explained by increasing differentiation of magmas over time, changes in the crust versus mantle sources mass-balance, and decrease in melting pressure due to the orogenic collapse. The εNdi values of both high-K calc-alkaline granitoids and durbachites decreases from [− 3.8; − 2.9] to [− 6.4; − 5.2] between 345 and 320 Ma, possibly indicating an increasing influence of subducted/relaminated crustal material contaminating the lithospheric mantle source. εNdi values then rise to [− 3.7; − 0.5] during the late Carboniferous, possibly due to progressive exhaustion of the enriched mantle source, or advection of the asthenosphere during the post-collisional stage.Graphic abstractPossible geodynamic scenario along the central-eastern segment of the Variscan Belt, which may account for the temporal evolution of Variscan magmatism in the External Western Alps.

Evolution of Silurian to Devonian magmatism associated with the Acadian orogenic cycle in eastern and southern Newfoundland Appalachians: Evidence for a three-stage evolution characterized by episodic hinterland- and foreland-directed migration of granitoid magmatism

Abstract The migration and character of magmatism over time can provide important insights into the tectonic evolution of an orogen. We present evidence for three separate stages of compositionally distinct granitoid magmatism associated with the Acadian orogenic cycle in the eastern and southern Newfoundland Appalachians. The interpretations are based on new zircon U-Pb ages, geochemical data, and Sr-Nd-Hf-O isotopic data for 18 samples from 15 Silurian and Devonian granitoid plutons, combined with previously published data. The three stages outline hinterland- and foreland-directed migration trends and represent subduction (435–420 Ma), syncollision (415–405 Ma), and postcollision (395–370 Ma) settings in the Acadian orogenic cycle. The Silurian plutons (435–420 Ma) of the first stage consist mainly of quartz diorite, tonalite, granodiorite, monzogranite, and syenogranite, with high-K calc-alkaline and enriched Sr-Nd-Hf-O isotopic compositions (e.g., εNd[t] = −5 to −2; εHf[t] = −3 to −1; δ18O = +6‰ to +8‰). They are interpreted to record the subduction of oceanic lithosphere of the Acadian seaway that separated the leading edge of composite Laurentia, represented by the Gander margin, and Avalonia. Early Devonian plutons (415–405 Ma) of the second stage contain more voluminous monzogranite and syenogranite; they have calc-alkaline to high-K calc-alkaline features, adakite-like compositions, and more depleted Sr-Nd-Hf-O isotopic compositions (e.g., εNd[t] = −6 to 0; εHf[t] = +1 to +3; δ18O = +5‰ to +6‰). Plutons of this stage occur mostly to the northwest of the Silurian granitoids, indicating a regional-scale northwestward (hinterland-directed) migration of magmatism with a rate of &amp;gt;9 km/m.y. The migration is interpreted to have been related to the progressive shallow underthrusting of Avalonia beneath the Gander margin (composite Laurentia) at least as far as 90 km inboard. The Middle to Late Devonian plutons of the third stage (395–370 Ma) consist mainly of monzogranite, syenogranite, and alkali-feldspar granite, which are silica- and alkali-rich granites with large negative Eu anomalies. These rocks are concentrated along both sides of the Dover–Hermitage Bay fault zone, which represents the boundary between Avalonia and composite Laurentia, to the southeast of the Silurian and Early Devonian igneous rocks. This stage of magmatism represents a foreland-directed (retreating) migration. The Early Devonian and Middle to Late Devonian episodes of magmatism were separated by a gap between 405 Ma and 395 Ma and recorded an evolution from (high-K) calc-alkaline to alkaline compositions, ascribed to partial delamination of Avalonian lithospheric mantle in a postcollisional setting.

Archean crustal growth and reworking in the Superior Province, Canada: Insights from whole-rock geochemistry and Nd isotopic data of the La Grande, Nemiscau and Opatica subprovinces

The southeastern Superior Province contains Meso- to Neoarchean (2952–2677 Ma) tonalite-trondhjemite-granodiorite (TTG) suites, volcanic (2773–2703 Ma) and sedimentary (<2724 Ma) supracrustal sequences, and granitoid intrusions (2708–2598 Ma). The region is a key crustal cross-section for understanding the growth, evolution, and stabilization of Archean cratons. Whole-rock geochemistry and Nd isotopic analyses have been performed on TTG suites, volcanic assemblages and granitoid plutons of the La Grande, Nemiscau and Opatica subprovinces. These analyses, combined with existing structural and U-Pb geochronological data, have been used to investigate the extend of the basement within the three subprovinces, their interaction, and the degree of crustal reworking in the southeastern Superior Province.Nd isotope data and zircon inheritance indicate that the TTG suites were generated from: (i) an old crustal domain with Nd model ages at 3.5–3.2 Ga that may represent the southern extension of the Langelier Complex, (ii) a ca. 3.0 Ga domain with isotopically juvenile signatures, and (iii) the reworking of < 3.0 Ga Nd model age TTG suites from the Opatica subprovince. The Nd juvenile signatures of the mafic to ultramafic volcanism at ca. 2773–2756 and ca. 2723–2703 Ma suggest continuous or multiple mantle plume events beneath the southeastern Superior Province, whereas interlayered felsic volcanic rocks were formed from anatectic melting at high pressure. Subsequent magmatism was related to sanukitoid suites (2704–2693 Ma) emplacement that record mantle-TTG melt interactions. Based on a common tectonometamorphic evolution of the three subprovinces from ca. 2756 Ma, previous studies argued that the Mesoarchean TTG suites exposed in the La Grande and Opatica subprovinces represent a single crustal block. The sedimentary belts of the area were deposited in sagduction-type basins formed at ca. 2724–2706 Ma and, within less than 15–20 myr, were buried and metamorphosed up to granulite facies at 2697–2685 Ma during dip-slip-dominated D2. The burial and the following exhumation of these rocks from ca. 2677 Ma may be attributed to the delamination of lower crustal residues, favoring interaction between mantle and TTG melts, and the formation of sanukitoids and anatectic S-type granites. Nd signatures of the 2646–2598 Ma I-type granitic intrusions indicate extensively reworking of TTGs due to crustal thickening during the D3-D4 events.Our study suggests that the Archean tectonic regime recorded in the southeastern Superior Province is the result of mantle plume tectonics. We conclude that the La Grande-Opatica boundary does not represent a major suture zone but rather but rather a fossil boundary within an older extensively reworked crustal block over which the metasedimentary rocks of the Nemiscau and La Grande subprovinces were deposited.

The Timescale and Carbon Flux Recorded by Skarn Garnet From Gangdese Arc, Southern Tibet

AbstractContact metamorphism of carbonate rocks in response to fluid infiltration releases carbon dioxide (CO2), potentially affecting Earth's carbon budget over geological timescales. This process was notably active in the Cretaceous when the closure of the Neo‐Tethys Ocean led to extensive arc magmatism in southern Tibet, coincident with a greenhouse climate interval. These arc plutons intersected carbonate sequences and formed widespread calcsilicate rocks. The mineral assemblages of these rocks record both the progression and duration of the CO2 release. In this study, we focus on a representative aureole in southern Tibet that was metamorphosed by a ∼64 Ma granitoid pluton of the Gangdese Batholith. The aureole presents lithologic zonation, with the inner garnet‐wollastonite zone indicating equilibrium with a water‐rich fluid at ∼525°C. Large garnet porphyroblasts feature cross‐cutting veins of secondary garnets that illustrate several stages of interface‐coupled dissolution‐reprecipitation processes facilitated by fluid infiltration. Diffusion modeling for Mg concentration profiles across vein‐host garnet yields a brief high‐temperature stage (25–150 kyr)—a duration still significantly overestimated considering factors that may accelerate diffusion in garnet, such as lattice parameters and hydration. Such short timescale aligns with conduction modeling of a cooling pluton, which, combined with the bulk‐rock mass balance analysis, indicates a local carbon flux comparable to fluxes at other modern tectonic settings. The metamorphic decarbonation, potentially episodic, in the continental arc may have been an important endogenic carbon source in the late Cretaceous.

Rapid switch in geodynamic setting revealed by episodic granitoid magmatism in the Lynn Lake greenstone belt of Paleoproterozoic Trans-Hudson Orogen, Manitoba, Canada

Bedrock geological mapping indicates that diverse granitoid intrusions occur closely in space and time in the Paleoproterozoic Lynn Lake greenstone belt of the Trans-Hudson Orogen, Manitoba, Canada. These intrusions display distinct geochemical characteristics of I-type, A-type and adakite-like granitoids as revealed by their respective alkalinity, alumina saturation state, and trace element concentrations and ratios. The ca. 1879 Ma I-type granitoid pluton intruded the 1892 to 1884 Ma supracrustal package of volcanic, volcaniclastic and minor sedimentary rocks that constitute the greenstone belt, which was cut by 1873 Ma A-type granite and then by 1854 Ma adakite-like quartz diorite intrusions. Why the geochemical affinities of these granitoids change so rapidly (within ∼25 Myr) in orogenic belts, however, is not as well understood. Here we propose using SmNd isotope data and trace element modeling that the compositional variety of the granitoid intrusions likely reflects the mineral assemblages of their source rocks rather than magmatic fractionation. They may have been formed by partial melting of the disparate sources at different depths to respond to the change in tectonic regimes. The timing of the granitoid intrusions tracks a rapid geodynamic transition from subduction to intra-arc extension and to slab break-off due to terrane accretion and collision. This records a crucial piece of history in geodynamic evolution of the Trans-Hudson Orogen, which to date has been overlooked largely in many other orogens.

Sulphur in apatite: a potential monitor of the magmatic redox state in the world-class gold fields of the North China Craton

ABSTRACT The redox condition, a key parameter of mineralization, is one of the most difficult parameters to constrain precisely. Here we employ electron probe and X-ray photoelectron spectroscopy (XPS) to analyse sulphur (S) in apatite grains from five granitoid plutons that are differentially related to gold mineralization in the world-class gold fields of Jiaodong, Xiaoqinling, and Wutai-Hengshan within the North China Craton (NCC) to constrain the redox condition of melt. The results show increasing order of the apatite S content and S6+/ΣS ratios in the Linglong (only spatially close the Jiaodong gold deposits), Sunzhuang (related with the Yixingzhai gold deposits), Huashan (weakly related with the Xiaoqinling gold deposits), Wenyu (closely related with the Xiaoqinling gold deposits) and Guojialing plutons (closely related with the world-class Jiaodong gold deposits), indicating that the oxidation state increased from the Linglong pluton to the Guojialing pluton. The S concentrations of Guojialing, Wenyu, Huashan and Sunzhuang plutons, are estimated using previous methods are, 120–208 ppm, 107–138 ppm, 72–77 ppm and 10–74 ppm, respectively. Combined with the regional differences in gold mineralization in the North China Craton, the gradual increase in mineralization scale is consistent with the trend of increasing oxidation state in the granitoid plutons from Wutai-Hengshan to Xiaoqinling to Jiaodong goldfields, thus also underpinning the contribution of Mesozoic granites to gold mineralization in the North China Craton through providing the thermal energy and medium for the activation and migration of ore-forming fluids.

Early uplift and exhumation of the Tanggula granitoid pluton since the Late Cretaceous: Implications for the stepwise topographic growth model in the eastern Qiangtang terrane

Abstract Reconstructing the uplift process of the eastern Qiangtang terrane is crucial for understanding the growth model of the central Tibetan Plateau. However, due to the limited amount of data available, it is not well constrained. The Tanggula granitoid pluton is an outstanding geological feature in the eastern Qiangtang terrane, and thus could provide crucial constraints on its uplift history. We applied multiple thermochronologic systems over a broad temperature range, including apatite U-Pb, biotite and K-feldspar 40Ar/39Ar, apatite and zircon fission-track, and zircon (U-Th)/He, to study samples from the Tanggula granitoid pluton. The results exhibit the expected relative age order of these thermochronologic systems, with 242–238 Ma apatite U-Pb ages, 218–204 Ma biotite 40Ar/39Ar ages, 197–191 Ma K-feldspar 40Ar/39Ar ages, 94–81 Ma zircon fission-track ages, 70–58 Ma zircon (U-Th)/He ages, and 61–39 Ma apatite fission-track ages. Using these thermochronologic ages and thermal history modeling results, we reconstructed a comprehensive thermal history for the pluton, from which three rapid cooling phases were revealed. The earliest rapid cooling phase (220–180 Ma; ~5.25 °C/m.y.) closely followed the emplacement of the Tanggula granitoid pluton, and thus is primarily an expression of natural cooling triggered by conduction with the surrounding rocks. In contrast, the rapid cooling during 100–60 Ma and since 20 Ma can be interpreted to represent intense exhumation, with corresponding exhumation of 5.0–6.0 km and 2.3–2.8 km, as well as an average exhumation rate of 0.125–0.150 mm/yr and 0.115–0.140 mm/yr, respectively. According to the thermal history, the earliest uplift in the Tanggula region could have been initiated as early as the Late Cretaceous. Using the published data, we determined that the onset of rapid uplift and exhumation in the entire eastern Qiangtang terrane had a northeastward, stepwise propagation process. The region within or around Anduo first experienced rapid uplift and exhumation that initiated during the late Early Cretaceous (ca. 130 Ma), the Tanggula region to the northeast experienced rapid uplift and exhumation that initiated during the Late Cretaceous (ca. 100 Ma), and the region farther to the northeast in Tuotuohe and Yushu–Nangqian experienced rapid uplift and exhumation that initiated in the late Paleocene (ca. 60 Ma). The northeastward stepwise uplift and exhumation in the eastern Qiangtang terrane was likely caused by the combined Lhasa–Qiangtang and India–Asia continental collisions.

The Late Cambrian to Neogene Evolution of the Khanom Core Complex (Peninsular Thailand)

Abstract The Khanom Core Complex in Peninsular Thailand is a part of the crystalline basement of Sundaland and plays a key role in our understanding of the evolution of Thailand and SE Asia. The complex comprises ortho- and paragneisses, schists, meta-volcanics, subordinate calcsilicate rocks, and postkinematic granitoids. New petrochronological data reveal that the sedimentation and metamorphism of the paragneiss precursors (Haad Nai Phlao complex, Khao Yoi paragneisses) occurred in the Late Cambrian at the latest. A syn- to postsedimentary andesitic intrusion/extrusion in the Haad Nai Phlao complex at 495 ± 10 Ma defines a minimum age for the former event(s). In the Early Ordovician (477 ± 7 Ma), the Haad Nai Phlao complex and the Khao Yoi paragneisses were intruded by the Khao Dat Fa granite. During the Indosinian orogenic events, the Laem Thong Yang (211 ± 2 Ma) and Haad Nai Phlao (210 ± 2 Ma) granitoid plutons were intruded. Immediately afterward (ca. 208–205 Ma), the first metamorphic overprinting of the Laem Thong Yang granite and the Haad Nai Phlao complex including the Khao Dat Fa granite occurred. A second metamorphic overprinting of all lithological units and the contemporaneous intrusion of the Khao Pret granite followed in the Late Cretaceous and Early Paleogene (ca. 80–68 Ma). The tectonic formation of the core complex took place in the Eocene (&amp;lt;42 Ma), followed by exhumation and regional cooling below ca. 450°C and the latest cooling to ca. 120°C in the Miocene (ca. 20 Ma). The evolutionary data show that the Khanom Core Complex is part of Sibumasu, and its Late Cretaceous-Neogene cooling pattern and exhumation history can be directly related to the northward drift of India.

The Harz Mountains (Germany) – Cadomia meets Avalonia and Baltica: U–Pb ages of detrital and magmatic zircon as a key for the decoding of Pangaea's central suture

Abstract U–Pb ages of detrital ( n = 2391) and magmatic ( n = 170) zircon grains from the Harz Mountains were obtained by LA-ICP-MS for provenance studies and absolute age dating. Results point to a complete closure of the Rheic Ocean at c. 419 Ma. A narrow Rhenish Seaway then re-opened in Emsian to mid-Devonian time ( c. 390–400 Ma). Devonian sedimentary rocks of the Harz Mountains were deposited on the northwestern (Rheno-Hercynian) and on the southeastern (Saxo-Thuringian) margins of the Rhenish Seaway. A new U–Pb zircon age from a plagiogranite (329 ± 2 Ma) within a harzburgite makes the existence of oceanic lithosphere in the Rhenish Seaway probable. The Rhenish Seaway was completely closed by Serpukhovian time ( c. 328 Ma). Existence of a terrane in the seaway is not supported by the new data. Provenance studies and spatial arrangement allow reconstruction of the thin- to thick-skinned obduction style of the Harz Mountains onto the southeastern margin of East Avalonia (Rheno-Hercynian Zone) during the Variscan orogeny. Detrital zircon populations define Rheno-Hercynian and Saxo-Thuringian nappes. Intrusion of the granitoid plutons of the Harz Mountains occurred in a time window of c. 300 to 295 Myr and constrained the termination of Variscan deformation.