Abstract Based on industrial electricity consumption, we model industrial networks by Granger causality method and MST (minimum spanning tree), and then further stick onto an industrial coupling mechanism from energy-consumption perspective. First, we construct Granger causality networks of five provinces in South China of GD, GX, GZ, HN and YN based on their industrial electricity consumption data, and we demonstrate from a network-topology perspective: the distribution of weight of links of all industrial electricity-consumption Granger causality networks approximately follows power-law distribution, revealing a phenomenon that few industries may bring a tremendous influence on the rest. Moreover, correlation analysis between weight and degree of a node shows that in most Granger causality networks, both span and strength of influence of a given industry will significantly increase. Further, we analyze the relationship between the thresholds of Granger causality significance and density of corresponding networks. Results show GD and HN could be classified into a group with relatively greater global differentiation in industries and unbalanced industrial development, however, GX, GZ and YN are grouped as second cluster with relatively balanced industrial development. Furthermore, using Chu–Liu–Edmonds MST algorithm, we extract graphs of MSTs or maximal cliques from industrial electricity-consumption Granger causality networks, and research on energy transmission structure, feedback loop, and bootstrap reliability. By analyzing MSTs, we find that only GD, GX and YN can be extracted with MST graphs, and capture the probable transmission routes of key nodes. Besides we illustrate all three MST graphs are involved with feedback loops structures with various characteristics: GX has complete feed-forward section, feed-back section and feedback loop section; YN has only feed-forward section and feedback loop section; GD has multiple feedback loops section. Finally, we conduct bootstrap reliability tests on MSTs. Results show branches of reliability of GD, GX and YN are decentralized while those feedback loops sections are only concentrated on highly-reliable branches. As neither HN nor GZ can be extracted with MST graphs, we characterize them by maximal cliques. It is demonstrated that both industrial systems of HN and GZ are significantly grouped into two independent branches and those internal industries inside independent branches are highly correlated. However from perspectives of whole South China, the causal relationship is only converged on a few of industries. For regions without MST graphs like HN and GZ, the reliability of links is also greater than that of GD, GX and YN.