Grand Partition Function Research Articles

T-Matrix Approach to Strongly Coupled QGP

Based on a thermodynamic T-matrix approach we extract the potential V between two static charges in the quark-gluon plasma (QGP) from ts to the pertinent lattice-QCD free energy. With suitable relativistic corrections we utilize this new potential to compute heavy-quark transport coefficients and compare the results to previous calculations using either F or U as potential. We then discuss a generalization of the T-matrix re-summation to a “matrix log” re-summation of t-channel diagrams for the grand partition function of the QGP in the Luttinger-Ward skeleton diagram formalism. With V as a non-perturbative driving kernel in the light-parton sector, we obtain the QGP equation of state from ts to lattice-QCD data. The resulting light-parton spectral functions are characterized by large thermal widths at small momenta, indicating the dissolution of quasi-particles in a strongly coupled QGP.

Quantum statistics of classical particles derived from the condition of a free diffusion coefficient.

We derive an equation for the current of particles in energy space; particles are subject to a mean-field effective potential that may represent quantum effects. From the assumption that noninteracting particles imply a free diffusion coefficient in energy space, we derive Maxwell-Boltzmann, Fermi-Dirac, and Bose-Einstein statistics. Other new statistics are associated to a free diffusion coefficient; their thermodynamic properties are analyzed using the grand partition function. A negative relation between pressure and energy density for low temperatures can be derived, suggesting a possible connection with cosmological dark energy models.

General thermostatistical properties of a q-deformed fermion gas in two dimensions

Starting with a deformed fermionic grand partition function, we study the high and low temperature thermostatistical properties of a special q-deformed fermion gas in two spatial dimensions. Many of the deformed thermostatistical functions such as the specific heat and the entropy are derived in terms of the real deformation parameter q for the range q < 1. For high temperatures, we specifically focus on the behavior of both the entropy function and the deformed virial coefficients in the equation of state for the q-fermion gas in two dimensions. Possible physical applications of the present q-fermion gas are briefly discussed.

Thermodynamic signatures of an underlying quantum phase transition: A grand canonical approach

The grand canonical formalism is employed to study the thermodynamic structure of a model displaying a quantum phase transition when studied with respect to the canonical formalism. A numerical survey shows that the grand partition function diverges following a power law when the interaction parameter approaches a limiting constant. The power-law exponent takes a distinctive value when such limiting constant coincides with the critical point of the subjacent quantum phase transition. An approximated expression for the grand partition function is derived analytically implementing a mean field scheme and a number of thermodynamic observables are obtained. The system observables show signatures that can be used to track the critical point of the underlying transition. This result provides a simple fact that can be exploited to verify the existence of a quantum phase transition avoiding the zero temperature regime.

Exact relations between M2-brane theories with and without orientifolds

We study partition functions of low-energy effective theories of M2-branes, whose type IIB brane constructions include orientifolds. We mainly focus on circular quiver superconformal Chern-Simons theory on $S^3$, whose gauge group is $O(2N+1)\times USp(2N)\times \cdots \times O(2N+1)\times USp(2N)$. This theory is the natural generalization of the $\mathcal{N}=5$ ABJM theory with the gauge group $O(2N+1)_{2k} \times USp(2N)_{-k}$. We find that the partition function of this type of theory has a simple relation to the one of the M2-brane theory without the orientifolds, whose gauge group is $U(N)\times \cdots \times U(N)$. By using this relation, we determine an exact form of the grand partition function of the $O(2N+1)_{2} \times USp(2N)_{-1}$ ABJM theory, where its supersymmetry is expected to be enhanced to $\mathcal{N}=6$. As another interesting application, we discuss that our result gives a natural physical interpretation of a relation between the grand partition functions of the $U(N+1)_4 \times U(N)_{-4}$ ABJ theory and $U(N)_2 \times U(N)_{-2}$ ABJM theory, recently conjectured by Grassi-Hatsuda-Mari\~no. We also argue that partition functions of $\hat{A}_3$ quiver theories have representations in terms of an ideal Fermi gas systems associated with $\hat{D}$-type quiver theories and this leads an interesting relation between certain $U(N)$ and $USp(2N)$ supersymmetric gauge theories.

Thermodynamics of an exactly solvable confining quark model

The grand partition function of a model of confined quarks is exactly calculated at arbitrary temperatures and quark chemical potentials. The model is inspired by a version of QCD where the usual (perturbative) BRST symmetry is broken in the infrared, while possessing a quark mass function compatible with nonperturbative analyses of lattice simulations and Dyson-Schwinger equations. Even though the model is defined at tree level, we show that it produces a non-trivial and stable thermodynamic behaviour at any temperature or chemical potential. Results for the pressure, the entropy and the trace anomaly as a function of the temperature are qualitatively compatible with the effect of non-perturbative interactions as observed in lattice simulations. The finite density thermodynamics is also shown to contain non-trivial features, being far away from an ideal gas picture.

Orientifolding of the ABJ Fermi gas

The grand partition functions of ABJ theory can be factorized into even and odd parts under the reflection of fermion coordinate in the Fermi gas approach. In some cases, the even/odd part of ABJ grand partition function is equal to that of $\mathcal{N}=5$ $O(n)\times USp(n')$ theory, hence it is natural to think of the even/odd projection of grand partition function as an orientifolding of ABJ Fermi gas system. By a systematic WKB analysis, we determine the coefficients in the perturbative part of grand potential of such orientifold ABJ theory. We also find the exact form of the first few "half-instanton" corrections coming from the twisted sector of the reflection of fermion coordinate. For the Chern-Simons level $k=2,4,8$ we find closed form expressions of the grand partition functions of orientifold ABJ theory, and for $k=2,4$ we prove the functional relations among the grand partition functions conjectured in arXiv:1410.7658.

Representation of the grand partition function of the cell model: The state equation in the mean-field approximation

The method to calculate the grand partition function of a particle system, in which constituents interact with each other via potential, that include repulsive and attractive components, is proposed. The cell model, which was introduced to describe critical phenomena and phase transitions, is used to provide calculations. The exact procedure of integration over particle coordinates and summation over number of particles is proposed. As a result, an evident expression for the grand partition function of the fluid cell model is obtained in the form of multiple integral over collective variables. As it can be seen directly from the structure of the transition Jacobian, the present multiparticle model appeared to be different from the Ising model, which is widely used to describe fluid systems. The state equation, which is valid for wide temperature ranges both above and below the critical one, is derived in mean-field approximation. The pressure calculated for the cell model at temperatures above the critical one is found to be continuously increasing function of temperature and density. The isotherms of pressure as a function of density have horizontal parts at temperatures below the critical one.

Thermodynamics of an exactly solvable confining quark model

The grand partition function of a model of confined quarks is exactly calculated at arbitrary temperatures and quark chemical potentials. The model is inspired by a softly BRST-broken version of QCD and possesses a quark mass function compatible with nonperturbative analyses of lattice simulations and Dyson-Schwinger equations. Even though the model is defined at tree level, we show that it produces a nontrivial and stable thermodynamic behaviour at any temperature or chemical potential. Results for the pressure, the entropy and the trace anomaly as a function of the temperature are qualitatively compatible with the effect of nonperturbative interactions as observed in lattice simulations. The finite density thermodynamics is also shown to contain nontrivial features, being far away from an ideal gas picture.

Anyonic behavior of an intermediate-statistics fermion gas model.

We study the high-temperature behavior of an intermediate-statistics fermionic gas model whose quantum statistical properties enable us to effectively deduce the details about both the interaction among deformed (quasi)particles and their anyonic behavior. Starting with a deformed fermionic grand partition function, we calculate, in the thermodynamical limit, several thermostatistical functions of the model such as the internal energy and the entropy by means of a formalism of the fermionic q calculus. For high temperatures, a virial expansion of the equation of state for the system is obtained in two and three dimensions and the first five virial coefficients are derived in terms of the model deformation parameter q. From the results obtained by the effect of fermionic deformation, it is found that the model parameter q interpolates completely between bosonlike and fermionic systems via the behaviors of the third and fifth virial coefficients in both two and three spatial dimensions and in addition it characterizes effectively the interaction among quasifermions. Our results reveal that the present deformed (quasi)fermion model could be very efficient and effective in accounting for the nonlinear behaviors in interacting composite particle systems.

Steady-State Predictions from a Compact Cooperative Kinetic Model of Cardiac Sarcomere Dynamics

A compact model of cardiac sarcomere dynamics is useful when developing integrated models of whole ventricular function. Kinetic models can be simplified by separating slower from faster processes. The representation of faster processes can then be reduced to their equivalent equilibrium relationships. Analysis of cooperativity within a cardiac sarcomere is also aided by dealing with equilibria, which can be analyzed using statistical thermodynamics. These principles guided the formulation of a compact kinetic model of cardiac sarcomere dynamics. In this scheme there were three slower processes: (1) reversible transitions between weak and strong crossbridges, (2) detachment of strong crossbridges, (3) dissociation of calcium from regulatory units (RUs) having a strong crossbridge. In the overall kinetic scheme, an individual RU could exist in 6 states: 3 states of crossbridge binding (none, weak, strong) interacting with 2 states of calcium binding (yes, no). Exchanges between the 4 states without strong crossbridges occurred by rapid equilibria. Thus, in the reduced model only 3 kinetic states remained: (1) strong crossbridges attached to RUs where calcium was bound, (2) strong crossbridges remaining attached even after calcium had dissociated, (3) the equilibrium mixture of the 4 remaining states. Since strong crossbridges appear to act independently, rate constants between these 3 states were considered independent of neighboring RUs. However, cooperativity between neighboring RUs exerted major impacts on the mixture of 4 states interacting rapidly as equilibria. Applying the linear Ising Model of statistical thermodynamics, the grand partition function characterizing interactions between neighboring RUs included activating effects from strong crossbridges as well as free calcium ions. This model predicted steady-state relationships between force and pCa (given as Hill plots) that reproduced the experimentally observed bend toward less cooperative slope near half activation.

The phase transition of the first order in the critical region of the gas-liquid system

This is a summarising investigation of the events of the phase transition of the first order that occur in the critical region below the liquid-gas critical point. The grand partition function has been completely integrated in the phase-space of the collective variables. The basic density measure is the quartic one. It has the form of the exponent function with the first, second, third and fourth degree of the collective variables. The problem has been reduced to the Ising model in an external field, the role of which is played by the generalised chemical potential $\mu^*$. The line $\mu^*(\eta) =0$, where $\eta$ is the density, is the line of the phase transition. We consider the isothermal compression of the gas till the point where the phase transition on the line $\mu^*(\eta) =0$ is reached. When the path of the pressing reaches the line $\mu^* =0$ in the gas medium, a droplet of liquid springs up. The work for its formation is obtained, the surface-tension energy is calculated. On the line $\mu^* =0$ we have a two-phase system: the gas and the liquid (the droplet) one. The equality of the gas and of the liquid chemical potentials is proved. The process of pressing is going on. But the pressure inside the system has stopped, two fixed densities have arisen: one for the gas-phase $\eta_{g} = \eta_{c} ( 1 - {d}/{2})$ and the other for the liquid-phase $\eta_{l} = \eta_{c} (1 + {d}/{2} )$ (symmetrically to the rectlinear diameter), where $\eta_{c} = 0.13044$ is the critical density. Starting from that moment the external pressure works as a latent work of pressure. Its value is obtained. As a result, the gas-phase disappears and the whole system turns into liquid. The jump of the density is equal to $\eta_{c} d$, where $d = \sqrt{{D}/{2G}} \sim \tau^{\nu/2}$. $D$ and $G$ are coefficients of the Hamiltonian in the last cell connected with the renormalisation-group symmetry.

McMillan-Mayer theory of solutions revisited: simplifications and extensions.

McMillan and Mayer (MM) proved two remarkable theorems in their paper on the equilibrium statistical mechanics of liquid solutions. They first showed that the grand canonical partition function for a solution can be reduced to one with an effectively solute-only form, by integrating out the solvent degrees of freedom. The total effective solute potential in the effective solute grand partition function can be decomposed into components which are potentials of mean force for isolated groups of one, two, three, etc., solute molecules. Second, from the first result, now assuming low solute concentration, MM derived an expansion for the osmotic pressure in powers of the solute concentration, in complete analogy with the virial expansion of gas pressure in powers of the density at low density. The molecular expressions found for the osmotic virial coefficients have exactly the same form as the corresponding gas virial coefficients, with potentials of mean force replacing vacuum potentials. In this paper, we restrict ourselves to binary liquid solutions with solute species A and solvent species B and do three things: (a) By working with a semi-grand canonical ensemble (grand with respect to solvent only) instead of the grand canonical ensemble used by MM, and avoiding graphical methods, we have greatly simplified the derivation of the first MM result, (b) by using a simple nongraphical method developed by van Kampen for gases, we have greatly simplified the derivation of the second MM result, i.e., the osmotic pressure virial expansion; as a by-product, we show the precise relation between MM theory and Widom potential distribution theory, and (c) we have extended MM theory by deriving virial expansions for other solution properties such as the enthalpy of mixing. The latter expansion is proving useful in analyzing ongoing isothermal titration calorimetry experiments with which we are involved. For the enthalpy virial expansion, we have also changed independent variables from semi-grand canonical, i.e., fixed {N(A), μ(B), V, T}, to those relevant to the experiment, i.e., fixed {N(A), N(B), p, T}, where μ denotes chemical potential, N the number of molecules, V the volume, p the pressure, and T the temperature.

Diagrammatical methods within the path integral representation for quantum systems

The path integral representation has been successfully applied to the study of equilibrium properties of quantum systems for a long time. In particular, such a representation allowed Ginibre to prove the convergence of the low-fugacity expansions for systems with short-range interactions. First, I will show that the crucial trick underlying Ginibre's proof is the introduction of an equivalent classical system made with loops. Within the Feynman-Kac formula for the density matrix, such loops naturally emerge by collecting together the paths followed by particles exchanged in a given cyclic permutation. Two loops interact via an average of two- body genuine interactions between particles belonging to different loops, while the interactions between particles inside a given loop are accounted for in a loop fugacity. It turns out that the grand-partition function of the genuine quantum system exactly reduces to its classical counterpart for the gas of loops. The corresponding so-called magic formula can be combined with standard Mayer diagrammatics for the classical gas of loops. This provides low-density representations for the quantum correlations or thermodynamical functions, which are quite useful when collective effects must be taken into account properly. Indeed, resummations and or reorganizations of Mayer graphs can be performed by exploiting their remarkable topological and combinatorial properties, while statistical weights and bonds are purely c-numbers. The interest of that method will be illustrated through a brief description of its application to two long-standing problems, namely recombination in Coulomb systems and condensation in the interacting Bose gas.

Long-run growth rate in a random multiplicative model

We consider the long-run growth rate of the average value of a random multiplicative process xi + 1 = aixi where the multipliers \documentclass[12pt]{minimal}\begin{document}$a_i=1+\rho \exp (\sigma W_i - \frac{1}{2}\sigma ^2 t_i)$\end{document}ai=1+ρexp(σWi−12σ2ti) have Markovian dependence given by the exponential of a standard Brownian motion Wi. The average value ⟨xn⟩ is given by the grand partition function of a one-dimensional lattice gas with two-body linear attractive interactions placed in a uniform field. We study the Lyapunov exponent \documentclass[12pt]{minimal}\begin{document}$\lambda =\lim _{n\rightarrow \infty } \frac{1}{n}\log \langle x_n\rangle$\end{document}λ=limn→∞1nlog⟨xn⟩, at fixed \documentclass[12pt]{minimal}\begin{document}$\beta = \frac{1}{2} \sigma^2 t_n n$\end{document}β=12σ2tnn, and show that it is given by the equation of state of the lattice gas in thermodynamical equilibrium. The Lyapunov exponent has discontinuous partial derivatives along a curve in the (ρ, β) plane ending at a critical point (ρC, βC) which is related to a phase transition in the equivalent lattice gas. Using the equivalence of the lattice gas with a bosonic system, we obtain the exact solution for the equation of state in the thermodynamical limit n → ∞.

Binding polynomial in molecular self-assembly.

In the present work the concept of a binding polynomial is revisited for the most widely used case of self-assembly of identical molecular units and results in the re-construction of a link to the grand partition function of such a system. It is found that if the self-assembly process is not pronounced (i.e., the product of the equilibrium constant and the monomer concentration is close to zero), the binding polynomial has the meaning of a molecular partition function that is given by the summation over energy levels of any molecule in the system. In other cases the concept of a binding polynomial may be misleading.

Finite-temperature full configuration interaction

The exact basis-set values of various thermodynamic potentials of a molecule are evaluated by the finite-temperature full configuration-interaction (FCI) method using ab initio molecular integrals over Gaussiantype orbitals. The thermodynamic potentials considered are the grand partition function, grand potential, internal energy, entropy, and chemical potential in the grand canonical ensemble as well as the partition function, Helmholtz energy, internal energy, and entropy in canonical ensemble. Approximations to FCI that are accurate at low and high temperatures are proposed, implemented, and tested. The results of finite-temperature FCI and its approximations are compared with one another as well as with the results of finite-temperature zeroth-order manybody perturbation theory, in which the Fermi–Dirac statistics is exact. Analytical asymptotic properties in the lowor high-temperature limits of some of these thermodynamic potentials are also given.

Calculation of grand partition function (gpf) of the symmetric and asymmetric double well potential by using path-integral based thermal cluster cumulant (PI-TCC) method

Calculation of grand partition function (gpf) of the symmetric and asymmetric double well potential by using path-integral based thermal cluster cumulant (PI-TCC) method

CRITICAL SCALING OF TWO-COMPONENT SYSTEMS FROM QUANTUM FLUCTUATIONS

The thermodynamics of excited nuclear systems allows the exploration of a phase transition in a two-component quantum mixture. Temperatures and densities are derived from quantum fluctuations of fermions. The pressures are determined from the grand partition function of Fisher's model. Critical scaling of observables is found for the first time for fragmenting systems which differ in neutron to proton concentrations thus constraining the equation of state (EOS) of asymmetric nuclear material. The derived critical exponent, β = 0.35 ±0.01, belongs to the liquid–gas universality class. The critical compressibility factor Pc/ρcTc increases with increasing neutron concentration, which could be due to finite-size and/or Coulomb effects.

Emergence of Heavy-Tailed Distributions in a Random Multiplicative Model Driven by a Gaussian Stochastic Process

We consider a random multiplicative stochastic process with multipliers given by the exponential of a Brownian motion. The positive integer moments of the distribution function can be computed exactly, and can be represented as the grand partition function of an equivalent lattice gas with attractive 2-body interactions. The numerical results for the positive integer moments display a sharp transition at a critical value of the model parameters, which corresponds to a phase transition in the equivalent lattice gas model. The shape of the terminal distribution changes suddenly at the critical point to a heavy-tailed distribution. The transition can be related to the position of the complex zeros of the grand partition function of the lattice gas, in analogy with the Lee, Yang picture of phase transitions in statistical mechanics. We study the properties of the equivalent lattice gas in the thermodynamical limit, which corresponds to the continuous time limit of the random multiplicative model, and derive the asymptotics of the approach to the continuous time limit. The results can be generalized to a wider class of random multiplicative processes, driven by the exponential of a Gaussian stochastic process.