Good Agreement Research Articles

Dual-polarized angle-selective surface based on double-layer frequency selective surface

In this Letter, we propose a dual-polarized angle-selective surface (ASS) based on a double-layer frequency selective surface (FSS) to achieve angular selectivity. By appropriately constructing the structure of the single-layer FSS, bandpass and band-stop are produced by the ASS under normal and oblique incidences, respectively, resulting in exceptional angular selectivity. Simulated results show that the proposed low-pass ASS achieves a bandpass (|S21| > −1 dB) from 0° to 10° and a band-stop (|S21| < −20 dB) from 31° to 85° with a profile thickness of 0.6 λ. A low-pass ASS prototype with an operating frequency of 10 GHz is fabricated to demonstrate the design concept. The measured results of the transmission coefficients are in good agreement with the simulated results. The proposed ASS can play an important role in many applications, as in minimizing the side lobes of the antenna.

Stability of a Multi-Span Current-Carrying Beam Resting on Periodic Supports and Exposed to an External Magnetic Field

Abstract The stability of a current-carrying beam in an external magnetic field is studied in this paper. The beam rests on periodic supports and is modeled as an Euler–Bernoulli elastic beam. Based on the linearized stability equation and propagator transfer matrix approach for a multi-span finite-length beam, the stability equation and solutions of the several boundary value problems are obtained. While the Floquet–Bloch theory is widely used in the dynamic problem of phononic and photonic structure conditions, its application to the solution of infinite length beam static stability problem is novel. The stability values of the periodic infinite beam model are in very good agreement with one of the finite-length multi-span beams.

Correction for the calculated XANES spectra of 1,4,7,10-alkyltetracenes considering the total electron yield (TEY) efficiency of sp2- and sp3-carbon atoms.

The calculated X-ray-absorption-near-edge-structure (XANES) spectra in the CK region of 1,4,7,10-alkyltetracenes, which are composed of both sp2-C atoms in the tetracene ring and sp3-C atoms in the alkyl-chains, can be corrected by considering the total electron yield (TEY) efficiency of sp3-C relative to sp2-C. In the correction, the previously measured TEY efficiency of k = 0.51 is applied to the calculated transition probabilities for sp3-C atoms. Then the calculated CK-XANES obtained from density functional theory (DFT) calculations can well reproduce the measured TEY-CK-XANES. Especially, the calculated π*/σ* peak intensity ratios are in good agreement with the measured ones. This suggests that a similar correction for the calculated XANES is necessary for compounds composed of multi-components with different TEY efficiencies.

Nonreciprocal magnonic directional coupler based on metal-coated YIG adjacent stripes

Unidirectional information transport is often realized in magnonic application using the filters, isolators, and circulators. In this Letter, we propose the simple design of the unidirectional magnonic coupler, which is realized as a laterally coupled yttrium–iron–garnet waveguide coated with a metal layer. We experimentally discover and numerically confirm that the proposed structure can exhibit unidirectional coupling, which can be easily controlled by the direction of the external magnetic field. At the same time, we show how the dynamic magnetization profile of the spin wave is varied with the change in the propagation direction to the opposite along the coupler. Brillouin light scattering reveals the variation of the spatial spin-wave profile, which is then used to extract the value of the coupling length. The experimental results are in good agreement with the results of the coupling length estimation from two methods: eingenmode analysis and Landau–Lifshits–Gilbert solution in parallel with the Maxwell equations. This opens up alternative ways to fabricate the non-reciprocal magnonic devices. In particular, we consider the operation of the unidirectional magnonic coupler as a multi-regime logic device.

Assessing Contributions of Synthetic Musk Compounds from Wastewater Treatment Plants to Atmospheric and Aquatic Environments.

The high environmental concentrations, persistence, and toxicity of synthetic musk compounds (SMCs) necessitate a better grasp of their fate in wastewater treatment plants (WWTPs). To investigate the importance of WWTPs as pathways of SMCs to the environment, air and wastewater samples were collected at four WWTPs in Ontario, Canada. Polycyclic musks (PCMs) were present at higher concentrations than nitro musks (NMs) and macrocyclic musks (MCMs). Three PCMs [galaxolide (HHCB), tonalide (AHTN), and iso-E super (OTNE)] were the most abundant compounds (0.30-680 ng/m3 in air, 0.40-15 μg/L in influent, and 0.007-6.0 μg/L in effluent). Analyses of multiyear data suggest that risk management measures put in place have been effective in reducing the release of many SMCs into the environment. The highest removal efficiency, up to almost 100% of some SMCs, was observed for the plant with the longest solid retention time. A fugacity-based model was established to simulate the transport and fate of SMCs in the WWTP, and good agreement was obtained between the measured and modeled values. These findings indicate that the levels of certain SMCs discharged into the atmospheric and aquatic environments were substantial, potentially resulting in exposure to both humans and wildlife.

Photoelastic Properties of Stoichiometric Lithium Niobate from First‐Principles Calculations

The linear optical response of lithium niobate under compressive as well as tensile stress is calculated from first principles. For this purpose, the elastic constants are computed with different exchange‐correlation functionals and compared with available experimental values. A good agreement with the measured quantities is obtained. A full set of the piezo‐optic and photoelastic coefficients is determined from the dependence of the dielectric permeability in the linear regime on the considered stress. The calculated coefficients agree with the experimental values as well. In contrast to the numerous experimental investigations, the coefficients are not only given for a single excitation wavelength but also within the technically relevant optical range. From the dispersion of the piezo‐optic and photoelastic coefficients, conclusions can be drawn about the refractive indices and the birefringence under strain for different excitation energies. It can be concluded that the birefringence in the long wavelength range increases under stress in the z direction. For uniaxial stress in x and y directions, the lattice symmetry is broken and the crystal becomes biaxial in the x and y directions as well.

A Fractal-Based Quantitative Method for the Study of Fracture Evolution of Coal under Different Confining Pressures

To study the dynamic crack evolution process of loaded coal from the perspective of fractals, we carried out in situ industrial CT scanning tests of loaded coal under different confining pressures, visualizing loaded coal fracturing. Combined with fractal theory, the temporal and spatial evolution law of coal cracks is described quantitatively. The results provide two findings: (1) from the perspective of two-dimensional images and three-dimensional space, the evolution characteristics of cracks in coal under different confining pressures were basically the same in each loading stage. During the loading stages, the cracks exhibited a change rule of a slow reduction, initiation/development, rapid increase, expansion, and penetration. (2) The fractal dimension of coal was calculated by introducing fractal theory, and its change law was in good agreement with the dynamic changes of the cracks, which can explain the influence of the confining pressure on the loaded coal. The fractal dimension showed three stages: a slight decrease, a stable increase, and then a significant increase. The larger the confining pressure, the more obvious the limiting effect. Thus, our approach provides a more accurate method for evaluating the spatial and temporal evolution of cracks in loaded coal. This study can be used to predict the instability failure of loaded coal samples.

Cross-Validation of the Remarkably High Surface Oxygen Exchange Kinetics of PrBa0.5Sr0.5Co1.5Fe0.5O5+δ: A Combined Thin-Film Mass Relaxation and Bulk Electrical Conductivity Relaxation Study.

In this work, we measure the oxygen kinetic properties of double perovskite PrBa0.5Sr0.5Co1.5Fe0.5O5+δ (PBSCF), a material widely used as the air electrode in solid oxide electrochemical cells, by mass relaxation (MR) and electrical conductivity relaxation (ECR) experiments. MR studies are carried out using thin films deposited on a gallium phosphate piezocrystal microbalance, and ECR studies are performed using a bulk bar sample with 97% theoretical density. Measurements are performed at 600 °C over the temperature oxygen partial pressure range from 10-4 to 0.21 atm. Despite the differences in experimental formats and surface microstructural features, the ks values extracted from the two methods are found to be in good agreement with one another. The rate constant is found to increase with oxygen partial pressure with a power law dependence, rising from 1.0 × 10-6 cm/s at 3.2 × 10-4 atm to 1.2 × 10-4 cm/s at 0.24 atm, as averaged over the oxidation and reduction directions. The rates in the oxidation direction are observed to be slightly higher than those in the reduction direction for a given pair of pO2 values, suggesting that the final pO2 value controls the overall relaxation behavior. The power law exponent describing the dependence of ks on pO2 is found to be 0.74 ± 0.01. The ECR study of the bulk sample reveals that even with a diffusion length of 1.8 mm, the relaxation process is largely free of diffusion limitations, indicating that PBSCF has the high bulk transport properties required for a double-phase boundary oxidation/reduction pathway.

An Analytical Solution for the Bending of Anisotropic Rectangular Thin Plates with Elastic Rotation Supports

The mechanical analysis of thin-plate structures is a major challenge in the field of structural engineering, especially when they have nonclassical boundary conditions, such as those encountered in cement concrete road slabs connected by transfer bars. Conventional analytical solutions are usually limited to classical boundary conditions—clamped support, simple support, and free edges—and cannot adequately describe many engineering scenarios. In this study, an analytical solution to the bending problem of an anisotropic thin plate subjected to a pair of edges with free opposing elastic rotational constraints is found using a two-dimensional augmented Fourier series solution method. In the derivation process, the thin-plate problem can be transformed into a problem of solving a system of linear algebraic equations by applying Stoke’s transform method, which greatly reduces the mathematical difficulty of solving the problem. Complex boundary conditions can be optimally handled without the need for large computational resources. The paper addresses the exact analytical solutions for bending problems with multiple combinations of boundary conditions, such as contralateral free–contralateral simple support (SFSF), contralateral free–contralateral solid support–simple support (CFSF), and contralateral free–contralateral clamped support (CFCF). These solutions are realized by employing the Stoke transformation and adjusting the spring parameters in the analyzed solutions. The results of this method are also compared with the finite element method and analytical solutions from the literature, and good agreement is obtained, demonstrating the effectiveness of the method. The significance of the study findings lies in the simplification of complex nonclassical boundary condition problems using a simple and reliable analytical method applicable to a wide range of engineering thin-plate structures.

Construction of Oxygen Vacancy-Rich TiO2 Nanocrystals for Boosting the Ammonolysis of Caprolactam to 6-Aminocapronitrile.

Hexamethylene diamine, an important chemical intermediate for polyamides, can be synthesized through the two-step route of caprolactam (CPL) ammonolysis to 6-aminocapronitrile (ACN), followed by hydrogenation. This method has received increasing attention from academia and industry. However, studies on the catalyst structure-performance correlation in CPL ammonolysis are still sporadic. In this work, a series of anatase TiO2 with different oxygen vacancy concentrations was prepared by chemical reduction using NaBH4. The oxygen vacancy on TiO2 surface, presented as Ti3+ sites, substantially enhances the adsorption and activation of NH3, which are demonstrated as the key steps in ammonolysis. Owing to the synergistic effect of Ti3+ and Ti4+ species, the CPL conversion rate and ACN selectivity of 85 and 97%, respectively, are achieved within 250 h. Density functional theory calculations showed that the intermediates on oxygen vacancy-rich TiO2 had a more favorable adsorption energy compared to those on intact TiO2, which is in good agreement with the experimental results.

Parametric Study of Die Sinking EDM of H13 Steel using Taguchi Techniques

As for H13 die steel, it is distinguished by a high hardness and a unique surface characteristics that must be created during machining using non-standard methods. One of such non conventional manufacturing techniques involving the use of Electrical Discharge Machining (EDM) for machining complex or hard material parts. It indicates that EDM has progressed from a series of a tool and die process to an alternative micro-scale application machining process. The paper is aimed at elaborating mathematical models defining the link between the MRR and SR to measured input parameters (current, pulse-on time, pulse-off time, and Reference voltage) in hot work steel EDM. With a L9 orthogonal involving four variables at three levels were used. The values of the model quality factors analyzed by the ANOVA procedure show that the selected mathematical models describe the process performance within successfully studied range with high level of precision. To determine the optimal condition, Taguchi method was used to measure the performance impact of different process parameters and find out best mixing. Minitab V 21 software has been used for the analysis and explanations. A good agreement between experimental value and the predicted one was found.

Quantifying riming from airborne data during the HALO-(AC)3 campaign

Abstract. Riming is a key precipitation formation process in mixed-phase clouds which efficiently converts cloud liquid to ice water. Here, we present two methods to quantify riming of ice particles from airborne observations with the normalized rime mass, which is the ratio of rime mass to the mass of a size-equivalent spherical graupel particle. We use data obtained during the HALO-(AC)3 aircraft campaign, where two aircraft collected radar and in situ measurements that were closely spatially and temporally collocated over the Fram Strait west of Svalbard in spring 2022. The first method is based on an inverse optimal estimation algorithm for the retrieval of the normalized rime mass from a closure between cloud radar and in situ measurements during these collocated flight segments (combined method). The second method relies on in situ observations only, relating the normalized rime mass to optical particle shape measurements (in situ method). We find good agreement between both methods during collocated flight segments with median normalized rime masses of 0.024 and 0.021 (mean values of 0.035 and 0.033) for the combined and in situ method, respectively. Assuming that particles with a normalized rime mass smaller than 0.01 are unrimed, we obtain average rimed fractions of 88 % and 87 % over all collocated flight segments. Although in situ measurement volumes are in the range of a few cubic centimeters and are therefore much smaller than the radar volume (about 45 m footprint diameter at an altitude of 500 m above ground, with a vertical resolution of 5 m), we assume they are representative of the radar volume. When this assumption is not met due to less homogeneous conditions, discrepancies between the two methods result. We show the performance of the methods in a case study of a collocated segment of cold-air outbreak conditions and compare normalized rime mass results with meteorological and cloud parameters. We find that higher normalized rime masses correlate with streaks of higher radar reflectivity. The methods presented improve our ability to quantify riming from aircraft observations.

Technical note: Cryostat transmission characterization for MR linac - temporal stability, clinical impact and change implementation.

In the Unity MR linac (Elekta AB, Stockholm, Sweden), the radiation beam traverses the cryostat and the coil support structure. The resulting beam attenuation must be considered for output calibration and its variation with gantry angle must be characterized in the treatment planning system (TPS). The aim of this work was to investigate the impact of a change of the cryostat transmission characterization (CTC) curve, due to the helium level modification, on clinical treatment plan dosimetry and to report on the experience with the CTC curve update. Twenty stereotactic body radiotherapy (SBRT) treatment plans: 10 prostate and 10 oligo-metastatic cancer plans, prepared with a beam model incorporating the CTC curve acquired at installation time, were re-calculated using the model implementing CTC curve post helium top-up. To account for the CTC change as well as to align our system to the recent reference conditions recommendations, the new model was commissioned with the emphasis on the specifics associated with the treatment plan adaptation and the existence of the offline and online TPS components. Average CTV mean dose reduction by 0.45% in prostate cases and average GTV mean dose reduction by 0.22% in oligo-metastatic cases was observed. Updated model validation showcased good agreement between measurements and TPS calculations. The agreement between CTC measurements demonstrates its temporal constancy and robustness of the measurement method employed. A helium fill level change was shown to affect the CTC and led to a small but systematic dose calculation inaccuracy. Finally, model validation and end-to-end testing results presented, underscore the minimal impact of transitioning to the new beam model and new reference conditions.

Exact closed forms for the transfer matrix of free oscillations in finite periodic Timoshenko–Ehrenfest beams

In this work, we obtain closed-form expressions for the transfer matrix of free oscillations in finite periodic Timoshenko–Ehrenfest beams with an arbitrary number of cells. By invoking the Cayley–Hamilton theorem on the transfer matrix for free oscillations of a beam composed of N cells, we obtain a fourth-order recursive relation for the matrix coefficients, which defines the so-called Tetranacci Polynomials. Such recursive relation provides an algorithm to compute the Nth power of the transfer matrix, avoiding the matrix product of the N matrices. Furthermore, in the symmetric case of free oscillations in finite periodic Timoshenko-Ehrenfest beams, closed-form expressions for the solutions to the recursive relation have recently been derived, which we use to write the transfer matrix of a finite beam composed of N cells in a closed form. We find a good agreement between the natural frequencies calculated with the obtained expressions and finite element simulations. These expressions are very useful for studying the interaction of evanescent oscillations and find application, for instance, in the development of phononic topological insulators. Our formalism can be applied to waves propagating in finite periodic layers described by a 4 × 4-transfer matrix, such as electromagnetic waves in anisotropic optical media.

Stratocumulus Precipitation Properties Over the Southern Ocean Observed From Aircraft During the SOCRATES Campaign

AbstractPrecipitation plays an important role in cloud and aerosol processes over the Southern Ocean (SO). The main objective of this study is to characterize SO precipitation properties associated with SO stratocumulus clouds. We use data from the Southern Ocean Clouds Radiation Aerosol Transport Experimental Study (SOCRATES), and leverage observations from airborne radar, lidar, and in situ probes. We find that for the cold‐topped clouds (cloud‐top‐temperature <0°C), the phase of precipitation with reflectivity >0 dBZ is predominantly ice, while reflectivity < −10 dBZ is predominantly liquid. Liquid‐phase precipitation properties are retrieved where radar and lidar are zenith‐pointing. Power‐law relationships between reflectivity (Z) and rain rate (R) are developed, and the derived Z–R relationships show vertical dependence and sensitivity to the presence of droplets with diameters between 10 and 40 μm. Using derived Z–R relationships, a reflectivity‐velocity (ZV) retrieval method, and a radar‐lidar retrieval method, we derive rain rate and other precipitation properties. The retrieved rain rate from all three methods shows good agreement with in‐situ aircraft estimates, with rain rates typically being quite light (<0.1 mm hr−1). We examine the vertical distribution of precipitation properties, and find that rain rate, precipitation number concentration, and precipitation liquid water all decrease as one gets closer to the surface, while precipitation size and distribution width increases. We also examine how cloud base rain rate (RCB) depends on cloud depth (H) and aerosol concentration (Na) for particles with a diameter greater than 70 nm, and find that RCB is proportional to .

Backbone and Side Group Interchain Correlations Govern Wide-Angle X-ray Scattering of Poly(3-hexylthiophene).

Identifying the origin of scattering from polymer materials is crucial to infer structural features that can relate to functional properties. Here, we use our recently developed virtual-site coarse graining to accelerate atomistic simulations and show how various molecular features govern wide-angle X-ray scattering from a conjugated polymer, poly(3-hexylthiophene) (P3HT). The efficient molecular dynamics simulations can represent the structure and capture the emergence of crystalline order from amorphous melts upon cooling while retaining atomistic details of chain configurations. The scattering extracted from simulations shows good agreement with wide-angle X-ray scattering experiments. Amorphous P3HT exhibits broad scattering peaks: a high-q peak from interchain side-group correlations and a low-q peak from interchain backbone-backbone correlations. During amorphous to crystalline phase transitions, the distance between backbones along the side-group direction increases because of lack of interdigitation in the crystalline phase. Scattering from π-π stacking emerges only after crystallization takes place. Intrachain correlations contribute negligibly to the scattering from the amorphous and crystalline phases.

Numerical simulation on the MHD time-dependent Williamson nanofluid flow with cross diffusion and heat generation/absorption over a stretching plate

This novel study unfolds the heat and mass transfer investigation of Williamson nanofluid (WNF) through a porous medium past a stretching plate, along with considering heat generation/absorption. Nanoparticles hold significant significance in thermal engineering, industrial operations, and biomedical advancements, contributing to enhanced heat transfer, cooling mechanisms, thermal extrusion processes, and applications in cancer treatment, particularly in addressing brain tumors. The coupled ordinary differential equations (ODEs) are gained from governing partial differential equations (PDEs) by applying sufficient transformations. Then the ODEs of a nonlinear nature, along with boundary conditions, are solved through bvp4c, a built-in MATLAB program. A good agreement has been found in comparing the present study with already published papers. Numerical values for skin friction, mass transfer, and heat transfer are shown through a table against involved physical parameters, especially for both injection [Formula: see text] and suction [Formula: see text] cases, by varying the values of unsteadiness parameter A and Weissenberg number [Formula: see text]. The effects of the physical parameters on velocity, temperature, and mass profile are graphically depicted and illustrated minutely. It is noted that both the magnetic and Williamson parameters cause the thickness of the boundary layer to be reduced. It can be deduced from these findings that the rate of heat transfer over the surface of the plate decreases as the unsteadiness parameter increases. Furthermore, it is observed that an increase in the parameters of thermophoresis and Brownian motion leads to a higher temperature of the nanofluid.

A miniaturized airplane blade antenna for radio navigation and communication systems

Blade antennas are preferred antenna structures for airborne applications due to their compact size, lightweight and drag-reducing aerodynamic shape. In this paper, we present the design, simulation and realization of a miniaturized blade antenna requiring a small ground plane and covering the frequency band 0.8–1.1 GHz. To reduce air drag, the proposed antenna is placed inside an aerodynamically optimized airborne radome. The return loss, the radiation patterns and the realized gain of the proposed antenna are studied using HFSS simulations. The comparison of the simulated return loss and radiation patterns to their measured counterpart demonstrates a good agreement. A minimum realized gain of 3.6 dB was achieved at the frequency of 0.9 GHz.

Numerical Evaluation of Aircraft Aerodynamic Static and Dynamic Stability Derivatives by a Mid-Fidelity Approach

The present study aimed to investigate the capability of mid-fidelity aerodynamic solvers in performing a preliminary evaluation of the static and dynamic stability derivatives of aircraft configurations in their design phase. In this work, the mid-fidelity aerodynamic solver DUST, which is based on the novel vortex particle method (VPM), was used to perform simulations of the static and dynamic motion conditions of the Stability And Control CONfiguration (SACCON): an unmanned combat aerial vehicle geometry developed by NATO’s Research and Technology Organisation (RTO), which is used as a benchmark test case in the literature for the evaluation of aircraft stability derivatives. Two different methods were exploited to extract the dynamic stability derivative values from the aerodynamic coefficient time histories that were calculated with DUST. The results for the mid-fidelity approach were in good agreement with the obtained experimental data, as well as with the results obtained using more demanding high-fidelity CFD simulations. This demonstrates its suitability when implemented in DUST for predicting the static and dynamic behavior of airloads in different conditions, as well as in reliably predicting the values of stability derivatives, with the advantage of requiring limited computational effort with respect to classical high-fidelity numerical approaches and the use of wind tunnel tests.

Validation of the Openwater wearable optical system: cerebral hemodynamic monitoring during a breath-hold maneuver.

Bedside cerebral blood flow (CBF) monitoring has the potential to inform and improve care for acute neurologic diseases, but technical challenges limit the use of existing techniques in clinical practice. Here, we validate the Openwater optical system, a novel wearable headset that uses laser speckle contrast to monitor microvascular hemodynamics. We monitored 25 healthy adults with the Openwater system and concurrent transcranial Doppler (TCD) while performing a breath-hold maneuver to increase CBF. Relative blood flow (rBF) was derived from changes in speckle contrast, and relative blood volume (rBV) was derived from changes in speckle average intensity. A strong correlation was observed between beat-to-beat optical rBF and TCD-measured cerebral blood flow velocity (CBFv), ; the slope of the linear fit indicates good agreement, 0.87 (95% CI: 0.83 ). Beat-to-beat rBV and CBFv were also strongly correlated, , but as expected the two variables were not proportional; changes in rBV were smaller than CBFv changes, with linear fit slope of 0.18 (95% CI: 0.17 to 0.19). Further, strong agreement was found between rBF and CBFv waveform morphology and related metrics. This first in vivo validation of the Openwater optical system highlights its potential as a cerebral hemodynamic monitor, but additional validation is needed in disease states.