Gold Mining Research Articles

Magma Degassing andGoldMineralizationinthe Alkaline Intrusion- HostedGiltEdgeGoldDeposit,NorthernBlackHills, SouthDakota,USA

Gold mineralization in the Gilt Edge deposit was closely associated with magmatic differentiation and the formation of a Tertiary alkaline intrusive complex within the Lead–Deadwood dome.. Fluid inclusions and trace element geochemistry were used to study fluid evolution and determine sources. Quartz disseminated in unaltered trachyte porphyry hosts two populations of primary inclusions: 1) hypersaline i S–L–V a red hematite crystal and 2) mixtures of L–V and V– L that record phase separation at ~700oC. Whereas samples of hydrothermal quartz collected from in ore zones within and beyond structures (e.g., fault and breccia zones) contain dominant populations of V–L and L–V inclusions, respectively. Mineralization in structures formed from complex fluids of magmatic origin based on inclusions containing five transparent salt crystals and opaque crystals with cubic and round habits that have homogenization temperatures (Th) 650oC and salinities 63 wt.% NaCl equiv. In contrast, broader areas of disseminated mineralization in argillized and propylitized rocks contain hydrothermal quartz hosting large populations of L–V inclusions with Th of 200o360oC and salinities of 10–30 wt.% NaCl equiv., which reflect fluid mixing. Trace element concentrations are significantly higher in samples from structures and define zones of near surface Ag–As–Zn–Pb and deep Au–W–Mo–Cu. Whereas low trace element concentrations characterize propylitized quartz trachyte porphyry, except for high concentrations of Sb and Hg that occur at depth and likely track the retreat of isotherms as the hydrothermal system collapsed. These data show that during differentiation in a deep magma chamber, volatile-rich low-density fluids were periodically degassed into preexisting structures that were reactivated. Gold deposition during four stages of mineralization likely occurred due to boiling, changes in oxygen fugacity, and fluid mixing.

Biomonitoring of Mercury and Lead Levels in the Blood of Children Living near a Tropical River Impacted by Artisanal and Small-Scale Gold Mining in Colombia.

(1) Background: Mercury and lead contamination resulting from various anthropogenic activities represents a global environmental problem and a considerable risk to the health of the human population. (2) Methods: The objective of this research was to evaluate the concentrations of mercury (Hg) and Lead (Pb) in the blood of the child population in the municipalities in the Atrato River basin using a direct Hg analyzer and graphite furnace atomic absorption spectrometry. (3) Results: In total, 171 children (5-14 years of age) were taken into account, and 18.71% (32) of the children had concentrations of Hg and Pb above the permissible values established by the WHO. In the municipality of UN, 19 children had blood Hg concentrations between 5.29 and 17.71 μg/L. In CA, two children had concentrations of 5.03 and 8.43 μg/L, separately. In the case of Pb, seven children showed concentrations between 3.60 and 4.83 μg/dL in the municipality of RQ, three in UN (3.59, 3.61, and 4.60 μg/dL), and one in Carmen de Atrato (5.47 μg/dL). (4) Conclusions: The levels of Hg and Pb in the blood of children living in the riparian areas of the Atrato River basin are related to gold mining activities in the basin and the consumption of contaminated fish.

Indoor/Outdoor particulate matter (respirable dust) and respirable crystalline silica source tracking in households located proximal to gold mine tailings in Johannesburg, South Africa

Introduction: This study aimed to investigate the concentration of Respirable Crystalline Silica (RCS) and respirable dust, Particulate matters (PM4) concentration in samples measured indoors and outdoors of the nine(9) selected households located proximal to gold mine tailings in Riverlea, Johannesburg. Materials and methods: Sampling locations were separated according to grids, based on distance from the tailings; A (<500 m from the dump), B (>500m<1 km) and C (1 km-3 km). Three households were selected from each grid zone to measure indoor and outdoor PM4 samples continuously over 24 h using GilAir constant sampling pumps. Samples were collected during dry and wet seasons, and respirable crystalline silica in PM4 samples were analysed by an X-ray diffraction method. Results: The mean indoor and outdoor PM4 mass concentrations ranged from 2.02±0.02 µg/m3 to 2.26±0.02 µg/m3, respectively. The dry season mean for PM4 mass concentrations were higher than the wet season PM4 mass concentrations in all zones. The pairwise comparison of PM4 mass concentration for dry and wet seasons revealed no statistically significant difference (p<0.05). The dry season means the indoor/outdoor ratio was greater than one across all zones, suggesting indoor activities as the primary source of PM. In both seasons, the mean indoor and outdoor RCS ranged from 0.02±0.01% to 0.06±0.03%. The mean indoor and outdoor 24 h RCS concentrations in both seasons were below the California Office of Environmental Health Hazard Assessment (OEHHA) defined 24 h ambient exposure threshold of 3 µg/m3. Conclusion: The study found that PM4 concentration was directly proportional to distance from the gold mine tailings. Using RCS as a signature chemical, we found a similar chemical composition in all samples collected in winter and dry season at varied distances. It is concluded that the gold mine tailings are the significant source of PM4 emissions. Therefore, further dust control measures needs to be implemented at the gold mine tailings.

Assessment of radiological contamination due to gold mining in soil and food crops of Babban Tsauni, Gwagwalada, Nigeria.

This work assessed the activity concentrations of 238U(226Ra), 232Th, and 40K and their associated radiological risks due to exposure to soil and consumption of food crops in Babban Tsauni artisanal gold mine, Gwagwalada, Nigeria, using the gamma spectrometry technique. The mean activity concentrations of 226Ra, 232Th, and 40K in the mine soil were 60.2±9.9, 161.4±16.2, and 664.6±138.2, while they were 46.4±4.9, 79.9±39.3, 266.4±185.4 for tubers and 46.9±15.7, 100.5±35.8, 311.4±132.7 (Bq/kg) for grains, respectively. The results reveal that the activity concentrations of radionuclides in all samples exceeded the recommended values set by United Nations Scientific Committee on the Effects of Atomic Radiation (33, 45, and 420 Bq/kg) except 40K, which fell within the acceptable limit in all food crop sample types. Estimated results for radiological hazard parameters, radium equivalent, annual effective dose due to ingestion, and excess life cancer risk were within safe limits, while the annual effective dose due to external gamma radiation in soil and annual gonadal equivalent dose were significantly high in all investigated samples; these call for constant radiological monitoring.

The role of an oxidized lithospheric mantle in gold mobilization.

Phanerozoic orogenic gold mineralization at craton margins is related to the metasomatism of the lithospheric mantle by crustal material. Slab subduction transfers Au from the crust to the metasomatized mantle and oxidizes the latter to facilitate the mobilization of Au into mantle melts. The role of volatiles in the mobilization of Au in the mantle is unclear because of the absence of direct geochemical evidence relating the mantle source of Au to Au mineralization in the overlying crust. This study uses lithium isotopes from a large suite of lamprophyres to characterize the mantle beneath the eastern North China Craton, which hosts giant Mesozoic gold deposits. Our results indicate a strong genetic link between carbonate metasomatism in the mantle and Au mineralization in the overlying crust. Although pre-enrichment of Au in the mantle is critical for forming giant Au provinces, the oxidation of the lithospheric mantle controls the mobilization of Au.

Penerapan Metode Enhanced Phytoremediation pada Lahan Bekas Tambang Emas Desa Tirta Kencana Kecamatan Bengkayang

Community gold mining activities using the amalgamation method cause soil pollution due to the use of mercury (Hg) to extract gold content which causes a decrease in soil quality and environmental damage. Enhanced phytoremediation is a method that can be applied to remove mercury levels with using the Cyperus kyllingia plant and adding supporting elements in the form of bacterial isolates that are resistant to mercury. This research aimed to determine the effectiveness of Cyperus kyllingia plants and bacterial isolates for removing mercury levels in mercury-contaminated soil, as well as observing the bacterial population and plant morphology during the research. Based on the research results, it is known that the best efficiency value for removing mercury levels is found in phytoremediation with the addition of bacterial isolates, namely 86.88%. The largest bacterial population was found in the phytoremediation reactor with the addition of bacterial isolates, namely 73.3 × 106 CFU/mL. The mercury content in polluted soil causes changes in plant morphology, namely the color of green plants changes to yellow, but plants can reproduce as indicated by an increase in the number of leaves and plant stems

Comparison of clustering methods in determining gold mineralization anomalies in Janja area, Iran

Comparison of clustering methods in determining gold mineralization anomalies in Janja area, Iran

Remote sensing and magnetic characterization of the Au mineralization and its structural implications: Meatiq dome, Eastern Desert, Egypt

This article examines hydrothermally altered ophiolitic ultramafic rocks (HAOU), specifically Listvenite, which are thrust over the Meatiq dome in the context of gold mineralization. These rocks represent gneissic complexes located in Egypt's eastern desert. The analyses presented herein are essential for understanding the distribution of sheared serpentinite on and beneath the surface and the underlying domal structure. This study offers critical insights into the distribution of serpentinite at Meatiq. It combines remote sensing, aerial and ground magnetic data with petrological, geochemical, and geological analyses to create precise geological maps of potential subsurface igneous structures commonly linked to gold mineralization. Remote sensing is used to test for rock differentiation; intensive field geological investigations were conducted along several traverses. Petrographic and geochemical analysis of selected samples confirmed Au content in some localities. Additionally, tomographic inversion of the collected magnetic land profiles has unveiled previously unidentified subsurface distributions of magnetic susceptibilities, which are essential for explaining the observed surface magnetic anomalies and for understanding the subsurface arrangement of various rock units. Results show that the HAOU rocks have a lower magnetic susceptibility signature relative to the adjacent serpentinites, the serpentinite from South Meatiq shows relatively high gold content, and the gold content decreases with carbonation and alteration of the serpentinite into talc-carbonate, as detected geochemically. The procedure followed in the present study can be regionally applied to studying HAOU rocks of similar geologic conditions. The novelty of this study, beyond the introduction of a novel workflow, lies in the revelation that the rocks forming the Meatiq dome are in thrust contact with steeply dipping suprastructure units.

Elevated total mercury (THg) levels in water sources under the influence of artisanal and small-scale gold mining (ASGM) in Tanzania.

This study investigated the presence and distribution of mercury in water bodies under the influence of artisanal and small-scale mining (ASGM) activities in Tanzania, which continue to predominantly rely on mercury for gold extraction. Various water bodies available for domestic and animal use in mining communities were sampled from surface water sources in ASGM settlements during the rainy and dry seasons. Water samples were analysed using cold vapour atomic fluorescence spectrophotometer (CVAFS). The results indicate that most of water sources had THg levels above the WHO guideline of 1.0µg/L (1000ng/L) for safe drinking water. The levels were significantly higher during the wet season ranging from 3.4 to 96.3µg/L, whereas the range was from 0.84 to 2.12µg/L during the dry period. The higher THg values during the wet season are likely a result of increased lateral transport (e.g. via enhanced runoff) and physical properties of the waterways. Transportation and resuspension of matrix-bound mercury from surface soils and inflow of contaminated water from unprotected tailings were also observed to be potential means of lateral mercury transport. The lowest concentrations (0.846µg/L) were observed in water samples from the Mabubi River, upstream of a mining village. Downstream of the mining village in the same river, higher concentrations were observed in the Nungwe Bay region of Lake Victoria. In other surveyed mining settlements where there were no nearby rivers, pool water indicated high concentrations of THg, including levels above thresholds for safe human use. Immediate stringent measures are needed in order to ensure human and animal safety at ASGM mining settlements. Future investigation is suggested to focus on the distribution of mercury in different media, assessing the prevalence of different mercury species, and investigating the influence of weather and hydrological conditions on the impacts of mercury to organisms as part of the strategies to mitigate mercury pollution.

Machine learning-assisted risk evaluation of heavy metals in the Hainan gold mining region, China.

This study employed machine learning (ML) to thoroughly investigate the impact of informal mining activities on the distribution and pollution status of heavy metals in soils near private gold mines in Hainan Province, southern China, a region known for its ecological sensitivity and economic importance. By systematically collecting surface soil samples and samples at depths of 0.5-1m from 175 drilling sites, a comprehensive quantitative analysis was conducted on major heavy metal elements, including lead (Pb), copper (Cu), cadmium (Cd), nickel (Ni), mercury (Hg), chromium (Cr), arsenic (As), and zinc (Zn). Combined with evaluation methods such as the Pollution Load Index (PLI), Normalized Pollution Index (NIPI), and Ecological Risk Index (ERI), the study revealed a high level of soil pollution at informal mining sites. The findings indicated that the average concentrations of Pb, Cd, Hg, As, and Zn in surface soils significantly exceeded the background values for soils in China, with a pronounced positive correlation observed between these heavy metal elements in both surface and deep soil profiles (r > 0.5). Furthermore, leveraging the heavy metal content in surface soils and the constructed environmental indicators, the predictive accuracy for metal content in deep soils was found to range from R2 = 0.27 to 0.68, suggesting that informal mining activities have led to substantial variations in metal content across different soil profiles. Through the application of a random forest model for predictive analysis of the PLI, NIPI, and ERI, high prediction accuracy was achieved (R2 = 0.78, 0.86, and 0.60, respectively). The study demonstrates that informal mining activities not only elevate the risk of soil pollution but also alter the distribution patterns of heavy metals. Also, this study provides a crucial foundation for the scientific assessment of soil quality and potential environmental hazards, while also affirming the efficacy of ML techniques in forecasting soil quality parameters.

Seismic imaging of deep‐seated gold deposit and host rocks through a reappraisal of legacy seismic data in the Fochville mining area, South Africa

AbstractReappraisal of legacy reflection seismic data has shown to deliver value in mineral exploration, particularly in brownfield settings. In this work, we demonstrate how the reappraisal and processing of legacy reflection seismic data can be advantageous in the mineral exploration industry. We use today's standard seismic processing tools to improve the imaging of deep and complex geological structures that host mineral deposits. The recovered and processed 25.3 km long legacy seismic profile in this study was acquired in 1983 by the Gold Division of Anglo‐American as part of the Witwatersrand Gold Fields exploration program. This study aims to improve the imaging of the Ventersdorp Contact Reef gold‐bearing horizon (termed reef), a world‐class gold deposit (2 m thick) situated at depths between ∼2400 and ∼4100 m below the ground surface near South Deep Gold Mine in Fochville, South Africa. The final processing results from the pre‐stack time and phase‐shift migration approaches clearly reveal a dipping reflection associated with the gold‐bearing horizon and major steeply dipping faults that crosscut and displace the deposit. The final results are integrated with borehole information, 1D synthetic modelling and aeromagnetic data to constrain the structural interpretation. In particular, 1D synthetic simulation and borehole data constrain the depth position of the gold deposit. The magnetic data provides additional constraints on the complex faulted blocks of the host rocks such as the intrusions that may have a direct impact on ore resources and evaluation. The mining companies, such as South Deep Gold Mine, operating closer to the seismic profiles can use this new structural information to update the current geological models and improve future mine planning and designs, thus providing some insight into the prospectivity of unmined ground.

Effective management of endangered Blanding’s Turtle (Emydoidea blandingii) populations in Nova Scotia, Canada, requires consideration of threats posed by legacy gold mine contamination

The Nova Scotia, Canada, Blanding’s turtle (Emydoidea blandingii) population is designated as endangered both federally and provincially. Currently, its range is confined to five disjunct sub-populations in the province’s southwestern interior. With fewer than 500 breeding adults in the wild, current recovery efforts are focused on reducing mortality risk to adult and juvenile turtles. However, little is being done to address the cumulative impacts of environmental contamination on species fitness and reproductive capacity. This paper focuses on legacy impacts of Nova Scotia’s gold mining industry within present-day Blanding’s turtle critical habitat, with a focus on mercury and arsenic contamination. To date, previous studies have not considered the impacts of legacy gold mining contaminants on Blanding’s turtle recovery and conservation. Three historical gold mining areas were identified as overlapping with Blanding’s turtle ranges (West Caledonia District, Brookfield District, and Pleasant River Barrens District). To address the current knowledge gap, site assessments for Blanding’s turtle presence, food web contamination surveys, turtle claw tissue sampling, and overall site remediation are recommended to complement existing recovery efforts. Keywords: Blanding’s turtle, critical habitat, environmental con-tamination, gold mine tailings

Static Correction of Passive-Source Seismic Reflection Exploration on Undulating Surfaces

Elevation static correction is an important step in seismic data processing used to eliminate distortions in events caused by surface fluctuations. There is a well-established processing sequence for active-source seismic data, with static correction applied first, followed by subsequent processing. For passive-source data, static correction can be carried out using two methods. The first method is similar to the static correction of active-source seismic data and involves performing static correction on virtual shot gathers. The second method involves directly applying static correction to ambient noise and then using the corrected ambient noise to retrieve the virtual shot gathers. In this study, we derived and compared these two methods to perform static correction on passive-source data. We compared the above two methods through the forward modeling of passive-source data and field data from the Daqiao Gold Mine. The results showed that applying static correction to ambient noise and virtual shot gathers can correct passive-source data from an undulating surface to a flat surface. The equivalence of static correction on virtual shot gathers, and ambient noise offers more choices for conducting static correction of passive-source seismic reflection exploration on undulating surfaces.

A systematic evaluation of alkaliphilic microbial consortia from a soda lake for the biodegradation of cyanide-rich wastewater

Alkaliphilic microorganisms are one option for the treatment of cyanide-polluted wastewater. This study reports the degradation of cyanide from simulated gold mine wastewater using alkaliphilic microbial consortia harvested from a soda lake, Lake Chitu, Ethiopia. A novel aerobic-anoxic integrated treatment setup was established for the treatment process. Colorimetry was used to measure residual cyanide concentration, and 16S rRNA amplicon gene sequencing was used to study microbial diversity. This treatment system was able to degrade 97.49 ± 0.12% of 200 mg/L sodium cyanide. However, changes were observed (p < 0.05) when the established consortia were stressed with heavy metals. About 28 % of the initial inoculum persisted until the end of the treatment days. Twenty-eight bacterial phyla were identified, with Firmicutes, Proteobacteria, and Bacteroidota being the most abundant. At the end of the treatment process, Alkalibacterium (74.43%), Exaguobacterium (6.6%), and Halomonas (3.89%) were dominant. These findings indicate that alkaliphilic microbial consortiums from Ethiopian Rift Valley soda lakes are effective for the treatment of cyanide-polluted wastewater.

Ecohydrological risk assessment model for the Pra River Basin using GIS and multi-criteria decision making

ABSTRACT The Pra River Basin in Ghana is a major source of ecological, cultural, and economic benefits. However, it has been experiencing degradation, and logistical constraints have limited the implementation of Integrated Water Resources Management. This study presents a GIS-based ecohydrological risk model that identifies ecohydrological units with the highest degradation risk. First, the PRB was divided into 25 eco-hydrological units. Second, seven drivers of degradation were identified and mapped. The drivers were reclassified into five categories with risk scores of 1–5, with 5 indicating higher risk scores. The variables were ranked using the Analytical Hierarchy Process, the degradation risk model was calculated using the weighted sum method, and the multi-criteria decision tool was used to identify the ecohydrological units with the highest degradation risk. Of the 25 ecohydrological units delineated, the Buama, Lower Offin, Ayensu, and Oda ecohydrological units were found to be at the highest risk of degradation due to high artisanal small-scale gold mining, high population density, low forest/vegetation cover, and high encroachment in waterways. The results can be used as a guide to prioritize management intervention, starting with the areas classified as high risk and moving down to those classified as moderate risk.

Evaluating Policy and Legal Challenges in the Legalisation of Artisanal Small Scale Gold Mining in West Kalimantan

Evaluating Policy and Legal Challenges in the Legalisation of Artisanal Small Scale Gold Mining in West Kalimantan

Physico-thermal and geochemical behavior and alteration of the Au indicator gangue hydrothermal quartz at the Kubi Gold ore deposits

Altered and gangue quartz in hydrothermal veins from the Kubi Gold deposit in Dunkwa on Offin in the central region of Ghana are investigated for possible Au-associated indicator minerals and to provide the understanding and increase the knowledge of the mineral hosting and alteration processes in quartz. X-ray diffraction, air annealing furnace, differential scanning calorimetry, energy dispersive X-ray spectroscopy, and transmission electron microscopy have been applied on different quartz types outcropping from surface and bedrocks at the Kubi Gold Mining to reveal the material properties at different temperatures. From the diffraction results of the fresh and annealed quartz samples, we find that the samples contain indicator and the impurity minerals iron disulfide, biotite, titanium oxide, and magnetite. These minerals, under oxidation process between 574 and 1400 °C temperatures experienced hematite alterations and a transformation from α-quartz to β-quartz and further to cristobalite as observed from the calorimetry scans for hydrothermally exposed materials. The energy dispersive spectroscopy revealed elemental components of Fe, S, Mg, K, Al, Ti, Na, Si, O, and Ca contained in the samples, and these are attributed to the impurity phase minerals observed in the diffraction. The findings also suggest that during the hydrothermal flow regime, impurity minerals and metals can be trapped by voids and faults. Under favorable temperature conditions, the trapped minerals can be altered to change color at different depositional stages by oxidation and reduction processes leading to hematite alteration which is a useful indicator minerals in mineral exploration.

The artisanal underground: gold, subsistence, and subsurface materiality in Colombia

AbstractThis article focuses on subsurface materiality to explore how small‐scale gold miners in Colombia navigate formal politics. In much critical research, the underground appears as a space of great developmentalist ambition, whose resources enable corporate expansion and bureaucratic rule. Here I take a slightly different route, as I demonstrate that subterranean matter makes possible ways of knowing and working that are anathema to a pro‐corporate legal regime. More specifically, I maintain that Colombian small‐scale miners experience the underground as invisible and unruly matter, and I show that this experience mediates their everyday criticism of, and resistance to, state governance.

Lattice defects and surface adsorption properties of gold-bearing chalcopyrite: A theoretical study based on DFT

Chalcopyrite (CuFeS2), as one of the carrier minerals of gold, undergoes significant alterations in lattice and surface properties upon doping with gold impurities. These changes markedly influence its separation and purification techniques, especially flotation. Using Density Functional Theory (DFT) based on first-principles, we analyze the influence of gold impurities on the lattice defects and surface properties of chalcopyrite. We developed an adsorption model using prop-2-yn-1-yl diethylcarbamodithioate (PDEC), a sulfur ester collector with an ethynyl group, on gold-infused chalcopyrite to elucidate the adsorption mechanism. Our findings indicate that the Au atom primarily occupies interstitial sites within the chalcopyrite lattice, resulting in an expanded lattice structure. Despite the doping, the lattice remains a p-type semiconductor with increased conductivity, facilitated by Au 6 s orbitals contributing to impurity levels within the conduction band from 2 to 4 eV. Additionally, there is a marked rise in spin-up electrons, with Integrated |Spin Density| results showing greater electron localization in Cu15Fe16S32Au and Cu16Fe16S32Au compared to ideal chalcopyrite crystal (Cu16Fe16S32). The Au atom exhibits maximum stability when adsorbed onto the S-Fe bonds on chalcopyrite surfaces, primarily forming covalent bonds through electron acceptance from Fe 3d orbitals. The presence of gold impurities decreases the collector's adsorption energy on the chalcopyrite (112) surface. However, PDEC exhibits enhanced adsorption performance relative to Al-DECDT and Z-200, primarily due to the chelation between thiocarbonyl and ethynyl groups of PDEC and the gold-bearing chalcopyrite (112) surface. Electron donation from Fe 4p orbitals of surface to the S 3 s and 3p orbitals of collector forms a sigma bond, while the ethynyl group undergoes hybridization with the Au 5d orbitals from −5 to −2.5 eV, fostering stable electron transfer.

Two-dimensional numerical analysis of seepage in an undersea mining area considering hydrochemical corrosion

The complex hydrogeological conditions and unique hydrochemical environment in the seabed rock often cause serious mine water inrush during undersea mining. With the exploitation of the undersea gold mining area in Sanshandao as the research background, a numerical analysis method for the seepage behavior of the surrounding rock in undersea gold mining considering the hydrochemical corrosion was put forward. A numerical simulation analysis of the undersea mining area in Sanshandao was conducted by the established method, and the results showed that mining the submarine ore body significantly changed the seepage field of the surrounding rock around the stope and water levels dropped obviously in the ore-controlling fault zone. Differences in the hydrochemical environment significantly influenced the distribution of the seepage field of the surrounding rock. The calculation results based on three fluids with different pH values show that the head variation range is the largest when pH = 2, followed by pH = 4, and pH = 7 has the smallest head variation range. The water inflow in the stope was also directly affected by the hydrochemical environment. With the change of pH, the water inflow at each boundary of the stope increases exponentially.