ABSTRACT Coal plays a crucial role in the energy structure of China. However, coal oxidation in goaf areas can lead to spontaneous combustion and the release of harmful substances, such as CO2 and As2O3, which pose environmental hazards. The transport patterns of CO2 and As2O3 from the mining area to the surface were investigated, and the environmental impacts of their transport were preliminarily investigated. This study aimed to obtain data on the relationship between the release of CO2 and As2O3 during spontaneous coal combustion and coal temperature, serving as baseline information for numerical models of spontaneous coal combustion. From a macro perspective, we explored the correlation between the simultaneous transport of CO2 and As2O3. Additionally, we constructed a multi-physics coupled model of spontaneous coal combustion in goaf areas using COMSOL software to analyze the transport patterns of CO2 and As2O3 released during spontaneous coal combustion in the three-zone overburden and their collaborative transport. The results indicated consistent release patterns of CO2 and As2O3, with CO2 released in much larger quantities than As2O3, thus providing conditions for CO2 to act as a carrier for As2O3 transport. During independent transport in the three-zone overburden, CO2 was transported to the surface, whereas a significant portion of As2O3 was enriched in the fracture zone. However, when CO2 and As2O3 were transported collaboratively, As2O3 reached the surface and the transport patterns of both substances in the overburden remained consistent, indicating that CO2 facilitated the transport of As2O3. This study provides an important theoretical basis for the remediation of spontaneous coal combustion in goaf areas, contributing to the effective control of CO2 and As2O3 emissions and the protection of mining environments. The surface concentration of CO2 peaked at 1560 mol/m3 at 45 d, and the surface concentration of As2O3 also peaked at 0.016 mol/m3.
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