Glow Regime Research Articles

Numerical investigation of lean methane flame response to NRP discharges actuation

This study investigates the response of a laminar methane-air flame to Nanosecond Repetitively Pulsed (NRP) discharges in a canonical wall-stabilized burner using a combined experimental and numerical approach. The flow and flame behaviors were modeled using Direct Numerical Simulation (DNS) with an Analytically Reduced Chemistry for a precise chemical description. A phenomenological model incorporating detailed plasma kinetics and experimental observations was developed to simulate plasma effects. Zero-dimensional plasma reactor simulations were used to build up a reduced-order model describing discharge energy distribution in the specific conditions studied. Experimental measurements of electrical profiles identified two discharge regimes: a low-energy Corona discharge and a higher-energy Glow discharge, characterized by distinct spatial energy distributions. Experimental flame response analysis revealed three major phases: marginal response up to 100 pulses, a downstream shift of the flame tip, and stabilization after 400 pulses. Numerical simulations indicated that the Corona regime is crucial for explaining initial flame responses, while the Glow regime influences later stages. Adjustments in the Vibrational-Translational (VT) energy relaxation time and energy deposition ratios between fresh and burnt gases were necessary to match experimental observations. Additionally, an accurate modeling of the transient and steady-state flame responses requires integrating both the specificity of the Corona and the Glow discharge regimes. Future work should focus on measuring or theoretically calculating N2(v) relaxation times in CH4-H2O-CO2 mixtures and analyzing the spatial energy distribution of discharges interacting with flames to enhance plasma-combustion coupled models.Novelty and significanceIn this work, a phenomenological plasma-assisted combustion model has been developed, to investigate a laminar premixed stagnation plate burner, focusing on VT energy relaxation time and spatio-temporal energy distribution modeling. For the first time, not only O2, N2 and O but also the fuel and combustion intermediates and products have been considered in the VT relaxation model. It revealed their strong influence on the overall flame response in a case where the discharge crosses a flame front, highlighting the strong beneficial effect of energy deposited in vibrational form. The study questions and investigates the energy distribution from fresh to burnt gases, challenging the conventional uniform energy distribution assumption. The experimental identification of two specific plasma regimes was necessary to predict the transient flame response. Additionally, energy deposited downstream of the flame, in fresh gases, was found to more efficient than in hot gases to enhance combustion.

Hysteresis between gas breakdown and plasma discharge

In direct-current (DC) discharge, it is well known that hysteresis is observed between the Townsend (gas breakdown) and glow regimes. Forward and backward voltage sweep is performed using a one-dimensional particle-in-cell Monte Carlo collision (PIC-MCC) model considering a ballast resistor. When increasing the applied voltage after reaching the breakdown voltage (Vb), transition from Townsend to glow discharges is observed. When decreasing the applied voltage from the glow regime, the discharge voltage (Vd) between the anode–cathode gap can be smaller than the breakdown voltage, resulting in a hysteresis, which is consistent with experimental observations. Next, the PIC-MCC model is used to investigate the self-sustaining voltage (Vs) in the presence of finite initial plasma densities between the anode and cathode gap. It is observed that the self-sustaining voltage coincides with the discharge voltage obtained from the backward voltage sweep. In addition, the self-sustaining voltage decreases with increased initial plasma density and saturates above a certain initial plasma density, which indicates a change in plasma resistivity. The decrease in self-sustaining voltage is associated with the electron heat loss at the anode for the low pd (rarefied) regime. In the high pd (collisional) regime, the ion energy loss toward the cathode due to the cathode fall and the inelastic collision loss of electrons in the bulk discharge balance out. Finally, it is demonstrated that the self-sustaining voltage collapses to a singular value, despite the presence of a initial plasma, for microgaps when field emission is dominant, which is also consistent with experimental observations.

Computational study of a helium-propellant microwave electrothermal thruster

The microwave electrothermal thruster (MET) utilizes wave-exited microdischarges to heat gas flows, enhancing the specific impulse of the thruster. Our computational study investigates a 17.5 GHz helium-propellant MET, employing a two-dimensional, axisymmetric fluid model of plasma coupled with electromagnetic wave and gas flows. The discharges operate in the glow regime, remaining weakly ionized, and in thermal non-equilibrium. The plasma densities reach approximately 1020m−3, and the gas temperature is around 2000 K. Even a slight off-resonant frequency operation results in a significantly lower plasma density and gas temperature. Gas heating, primarily driven by electromagnetic Joule heating, plays a critical role in influencing the overall discharge behavior. The measured peak thrust and specific impulse are 8.24 mN and 292 s, respectively, at a mass flow rate of 3.2 mg/s with 30 W of power. Compared to a cold gas thruster, there is a significant increase in the specific impulse by a factor of approximately 1.7. The enhanced performance trades off with propulsive efficiency, which decreases by a factor of 1.5 from the peak 65% at 10 W. This is due to higher energy losses to cavity walls from heat conduction with increased power. These findings underscore the critical balance between the input power and mass flow rate to improve the MET performance, highlighting the importance of power management to maximize thrust and efficiency. Furthermore, the predicted thrust and specific impulse agree well with experimental values for nominally similar MET thruster studies in the literature.

Simulation of glow and arc discharges in nitrogen: effects of the cathode emission mechanisms

Experimental evidence in the literature has shown that low-current direct current nitrogen discharges can exist in both glow and arc regimes at atmospheric pressure. However, modelling investigations of the positive column that include the influence of the cathode phenomena are scarce. In this work we developed a 2D axisymmetric model of a plasma discharge in flowing nitrogen gas, studying the influence of the two cathode emission mechanisms—thermionic field emission and secondary electron emission—on the cathode region and the positive column. We show for an inlet gas flow velocity of 1 m s−1 in the current range of 80–160 mA, that the electron emission mechanism from the cathode greatly affects the size and temperature of the cathode region, but does not significantly influence the discharge column at atmospheric pressure. We also demonstrate that in the discharge column the electron density balance is local and the electron production and destruction is dominated by volume processes. With increasing flow velocity, the discharge contraction is enhanced due to the increased convective heat loss. The cross sectional area of the conductive region is strongly dependent on the gas velocity and heat conductivity of the gas.

Study on characteristics of acoustic signals generated by different DC discharge modes

Acoustic signals contain rich discharge information. In this study, the acoustic signal characteristics of transient glow, spark, and glow discharges generated through DC pin–pin discharge were investigated. The signals were analyzed in the time, frequency, and time–frequency domains, and the correlation between the electric and the acoustic signal was studied statistically. The results show that glow discharge does not produce measurable sound signals. For the other modes, with a decrease in the discharge gap, the amplitude of the acoustic signal increases sharply with mode transformation, the short-time average energy becomes higher, and the frequency components are more abundant. Meanwhile, the current pulse and sound pressure pulse have a one-to-one relationship in the transient glow and spark regimes, and they are positively correlated in amplitude. A brief theoretical analysis of the mechanism of plasma sound and the trends of signals in different modes is presented. Essentially, the change in the discharge energy is closely related to the sound generation of the plasma.

Longevity Demonstration of Methane to C2 via a Nonthermal Plasma Microreactor.

Hydrocarbon processing using plasmas has tremendous potential, yet there still exist many uncertainties pertaining to practical operation over long durations. Previously, it has been demonstrated that a nonthermal plasma operating in a DC glow regime can transform methane into C2 species (acetylene, ethylene, ethane) in a microreactor. Using a DC glow regime in a microchannel reactor allows for lower power consumption, at the expense of greater consequence of fouling. Since biogas can be a source of methane, a longevity study was undertaken to understand how the microreactor system would change over time with a feed mixture of simulated biogas (CO2, CH4) and air. Two different biogas mixtures were used, one of which contained 300 ppm H2S, while the other had no H2S. Potential difficulties observed from previous experiments included carbon deposition on the electrodes, which could interfere with the electrical characteristics of the plasma discharge as well as material deposition in the microchannel, which could affect gas flow. It was found that raising the temperature of the system to 120 °C helped prevent hydrocarbon deposition in the reactor. Purging the reactor periodically with dry air was also found to have positive effects as it removed carbon buildup on the electrodes themselves. Successful operation over a 50 h time period without any significant deterioration was demonstrated.

On the different regimes of positive DC corona discharges as a function of electrical and geometrical parameters

This experimental study aims to better understand the electrical and optical properties of a positive DC corona discharge and to highlight the influence of applied voltage and electrode gap on the discharge regime. When the high voltage is increased, three successive regimes have been observed, including one that has never been reported in the literature to the best of our knowledge. This is certainly due to the fact that the tungsten needle used in these experiments is a commercial needle, with a tip of perfect surface finish. In fact, after the ignition voltage, the mean current slowly increases, and it perfectly follows the theoretical Townsend's law; this is the glow regime. When the voltage reaches a first threshold, a few small current pulses appear. However, this is not the breakdown streamer regime because photographs and intensified camera visualizations highlight that the propagation of streamers toward the grounded plate is limited to half of the gap. In this regime, the time-averaged current becomes higher than that of Townsend's law. Each current pulse is composed of only one bump, and the pulse frequency is higher (approximately 20 kHz) than that of the breakdown streamers. When the voltage reaches a second threshold, the magnitude of current pulses suddenly increases, but their frequency decreases (a few kHz); this is the transition toward the breakdown streamer regime. In this regime, each current pulse is composed of two bumps: the first one corresponds to the arrival of a primary streamer at the plate and the second one corresponds to a secondary streamer. Finally, we investigated the effects of the electrode gap. The magnitude and frequency of the current pulses increase when the gap decreases. Consequently, the offset between Townsend's curve and the experimental I–V characteristics increases when the gap decreases, because the pulse component of the total discharge current increases.

Gliding arc/glow discharge for CO2 conversion: Comparing the performance of different discharge configurations

We studied the use of low current (hundreds of milliamperes) gliding arc/glow discharges for CO2 dissociation, at atmospheric pressure, in three different configurations. All of these are based on the gliding arc design with flat diverging electrodes. The discharge is mainly in the normal glow regime with contracted positive column. The CO2 gas is injected from a nozzle, at the closest separation between the electrodes. A pair of quartz glasses is placed on both sides of the electrodes, so that the gas flow is restricted to the active plasma area, between the electrodes. For two of the tested configurations, an external magnetic field was applied, to create a magnetic force, both in the direction of the gas flow, and opposite to the gas flow. In the first case, the arc is accelerated, shortening the period between ignition and extinction, while in the second case, it is stabilized (magnetically-stabilized). We studied two quantities, namely the CO2 conversion and the energy efficiency of the conversion. Generally, the CO2 conversion decreases with increasing flow rate and increases with power. The energy efficiency increases with the flow rate, for all configurations. The magnetically-stabilized configuration is more stable and efficient at low gas flow rates, but has poor performance at high flow rates, while the non-stabilized configurations exhibit good conversion for a larger range of flow rates, but they are generally more unstable and less efficient.

Evidence of near-the-limit energy cost NO formation in atmospheric spark discharge

We report a very low energy cost (EC) for nitric monoxide (NO) radical formation found in atmospheric spark discharge. For this purpose non-equilibrium air discharges working in spark and glow regimes were studied showing the optimum performance in the vicinity of the spark-to-glow transition. The minimum EC for NO production of about 80 eV/molecule (calculated based on the total direct current power applied to the discharge generator) is achieved in the spark regime before the transition, whereas the maximum NO yield (of about 104 part per million) corresponds to the glow regime. Based on the estimated power absorbed in plasma the EC below 4 eV/molecule is achievable in the spark regime, which is close to the Zeldovich reaction enthalpy of NO formation (about 3 eV/molecule). The result implies that the energetic efficiency of a single spark likely exceeds that of the modern Haber–Bosch cycle (with EC of about 5 eV/molecule in the case of ammonia, according to Patil et al (2015 Catal. Today 256 49). The found low EC is associated with the discharge non-equilibrium caused by short spark duration.

Enhanced electron density and plasma dynamics on nanosecond time scales in Helium plasma discharges

Enhanced electron density and plasma dynamics are investigated for Helium discharges on nanosecond timescales with Particle-In-Cell simulations. The plasma discharges are driven between planar electrodes with DC, single pulses, and dynamic frequency square waves. It is assumed that the DC and pulse discharges operate in the glow regime. It is shown that as pressure increases with narrowing gap distance, the peak transient electron density rises. This is in contrast to what is observed under a constant pressure-gap (pd ) and electric field reduced by neutral density (E /N ) values at saturation time. It is shown that although the pd and E /N values and therefore the breakdown voltage are the same across cases, the plasma kinetics are different due to a change in the energy relaxation lengths. The cross-points between the sheath length and energy relaxation length move to higher electron energies at higher pressure. This facilitates high-energy electrons to undergo inelastic collisions and produces different rates of increasing electron density and temperature at nanosecond timescales. Moreover, using a plasma frequency-dependent square wave, the electron density can be increased to 50 times higher over that of the DC case because of a reverse electric field. The electron kinetics on nanosecond time scales can be exploited for high electron density and fast ionization applications.

Semi-analytical investigation on plasma density and reduced electric field of glow discharge in a turnery gas cw-CO2 laser

The plasma density and the reduced-electric-field (REF) parameters of CO2 gas laser have been measured and calculated at the maximum and minimum discharge current in terms of the similarity variable in order to investigate the discharge regimes. These parameters have been obtained with various combinations of ratios of CO2: N2: He gases. The obtained results were based on a new definition of the reduced-mobility variable for each gas species. The REF values had reducing behavior and did not much differed at both maximum and minimum discharge currents. The electron density had ascending behavior at the maximum discharge current, while it remained almost constant at the minimum discharge current. These results show that the regime of normal glow predominates at the minimum current, while a sub-normal glow regime governs at the maximum discharge current

Transient processes during an initial stage of breakdown in saline solution

This paper deals with the investigation of the discharge in the solution of 0.9% NaCl in water for the conditions, when the voltage at the gap is in a vicinity of the so-called critical voltage at which the discharge in a thin vapor layer at the surface of active electrode appears. In the experiments, the critical voltage is at a level of (180–200) V. Most of the data correspond to powering the discharge by the bipolar voltage pulses of 5 s duration. The main attention is centered on the nonsteady (transient) processes and on the forms of the discharge operation. For the voltage pulses of negative polarity, when the metal electrode is the cathode, the discharge is sustained in the glow regime with the occasional glow-to-spark transitions. At the positive polarity of the voltage, the surface of liquid inside the vapor layer plays a role of cathode in the gas-discharge gap. In these conditions, the process of the glow-to-spark transition is suppressed and the discharge is sustained in the glow regime.

Distributed High Temperature Monitoring of SMF under Electrical Arc Discharges Based on OFDR.

The distributed high temperature measurement of an optical fiber subjected to electric arc discharges based on optical frequency-domain reflectometry is experimentally demonstrated. The distributed temperature profile is attained in an open glow regime of a few milliamps with maximum detectable temperature up to 2100 ± 20 °C. The discharge arc-induced softened length of the fiber and mechanical stress are measured and statistically analyzed in terms of the correlation of the Rayleigh spectra. The large wavelength scanning range of OFDR enables much higher accuracy for the delay time measurement with a minimum measured delay of 40 fs. The delay shift over the entire heating range for a single discharge duration is statistically calculated by using a temporal correlation method. The reliability of the thermal sensitivity coefficient as 10 pm/°C for telecom single mode fiber (SMF, @1550 nm) is quantitatively analyzed and evaluated by the correlation coefficient. Lastly, a spectral mapping method is employed in spectrum monitoring for discharge dynamic impact on the optical path length (OPL) and local Rayleigh scatter.

Generation and Diagnostics of Ambient Air Glow Discharge in Centimeter-Order Gaps

Re-pulsing glow discharges in gaps up to 2 cm were experimentally investigated in atmospheric pressure air. Discharge was ignited as a sequence of spark and glow discharge and sustained in a glow regime after ignition. It was confirmed that the discharge with defined parameters could be ignited without any adjustments after initiation of the discharge. The discharges were characterized by a high-speed camera, current and voltage measurements, and optical emission spectrometry (OES). Typical structure of the glow discharge consisting of cathode glow, dark faraday space, positive column, and anode glow was observed. Transition from subnormal to normal glow mode was confirmed by analysis of current and voltage waveforms. It was found by OES that the type of discharge strongly affects the ratio of produced reactive species. It was confirmed that with change of discharge from subnormal to normal glow regime, rotational temperature could vary across a wide range (from 1650 to 3500 K). The developed device allows glow discharge to be ignited with defined parameters, which makes the control of the gas temperature and ratio of reactive species possible by presetting the discharge parameters. Additionally, it was demonstrated that corona discharge or repeating spark discharges could also be generated using the developed device without additional manipulations of the experimental setup by adjusting the discharge parameters.

Control and Stabilization of Centimeter Scale Glow Discharge in Ambient Air Using Pulse-Width Modulation

Re-pulsing glow discharges in atmospheric-pressure air were experimentally investigated using a push-pull generator with pulse-width modulation. Discharges were ignited as a spark-glow discharge sequence and sustained in a glow regime after ignition in a gap of 2 cm and characterized by current and voltage measurements, as well as by optical emission spectroscopy. It was found that at a certain range of parameters, the discharge could be stabilized even in the presence of external airflow. It was demonstrated that the type of discharge and total power dissipated in the plasma volume could be precisely controlled by pulse-width modulation. Additionally, it was confirmed that the rotational temperature varied across a wide range (1640-2440 K) by using pulse-width modulation with gas-flow control, when vibrational temperature was around 4610 ± 770 K. The generation of stable glow discharge in the presence of gas flow with a wide range of parameters that could be precisely controlled by pulse-width modulation looks promising for use in energy-efficient gas conversion.

An atmospheric pressure non‐self‐sustained glow discharge in between metal/metal and metal/liquid electrodes

AbstractNon‐thermal plasmas operating at high pressure attract increasing attention for a variety of applications as an alternative to conventional chemical processes. In this study, an atmospheric pressure direct current non‐self‐sustained discharge in nitrogen is investigated as a source of non‐thermal plasma capable of operating in a glow regime. The discharge is sustained between an internal source of ionization and a metal or liquid electrode and studied by electrical diagnostics as well as by spectroscopy methods. The work is focused on the determination of the discharge properties including vibrational and gas temperature. The effect of the liquid electrode on the discharge properties is studied and analyzed. The mechanisms of the discharge sustaining and pathways of nitrogen state excitation are discussed.

Time-resolved mid-infrared dual-comb spectroscopy

Dual-comb spectroscopy can provide broad spectral bandwidth and high spectral resolution in a short acquisition time, enabling time-resolved measurements. Specifically, spectroscopy in the mid-infrared wavelength range is of particular interest, since most of the molecules have their strongest rotational-vibrational transitions in this “fingerprint” region. Here we report time-resolved mid-infrared dual-comb spectroscopy, covering ~300 nm bandwidth around 3.3 μm with 6 GHz spectral resolution and 20 μs temporal resolution. As a demonstration, we study a CH4/He gas mixture in an electric discharge, while the discharge is modulated between dark and glow regimes. We simultaneously monitor the production of C2H6 and the vibrational excitation of CH4 molecules, observing the dynamics of both processes. This approach to broadband, high-resolution, and time-resolved mid-infrared spectroscopy provides a new tool for monitoring the kinetics of fast chemical reactions, with potential applications in various fields such as physical chemistry and plasma/combustion analysis.

Parametric Study of Two Stable Forms of Discharge Burning in a Hall-Effect Thruster

In this paper, we experimentally studied the behavior of the integral operation parameters of a Hall-effect thruster (thrust and specific thrust impulse) in two stable discharge glow modes significantly different from each other in anodic efficiency. The studies were conducted using a laboratory model of a Hall-effect thruster with an extended layer with an average discharge channel diameter of 77 mm in the discharge voltage range of 500–900 V and in the gas-flow rate range from 2 to 5 mg/s. The most striking distinguishing features of the observed glow regimes are the plasma jet shape and the discharge current value at almost identical input parameters (gas flow, discharge voltage, and magnetic field). In the entire studied range of input parameters when changing from the optimal mode (in terms of efficiency) to suboptimal, the main integral characteristics of the engine are shown to undergo a stepwise change: the discharge current increases by 10‒30% with a simultaneous relative drop in thrust by 5–15% and in efficiency by 20–40%. A detailed study of the anodic efficiency structure showed that, at abrupt rebuilding, the efficiency of using the electron current (the ratio of the ion current to the discharge current) changes, i.e., the electron conductivity in the engine discharge channel.

Numerical modeling of a DBD in glow mode at atmospheric pressure

In this work, a fluid model of helium glow discharge at atmospheric pressure in a dielectric barrier discharge configuration has been developed and the discharge was numerically simulated. The transport equations for charged and excited species are self-consistent coupled to the Poisson equation for the electrical field calculation. A finite difference method technique is adopted; a detailed numerical procedure modeling is given. The addition of some nitrogen impurities to the helium successfully reproduced the discharge evolution during the breakdown. The numerical results showed that the discharge has a structure similar to DC low-pressure glow discharges and confirms the establishment of the glow regime at atmospheric pressure under very adequate conditions. The profiles of physical and electrical discharge parameters knowing that, particle densities, electric field, drift velocity, voltages and discharge current are presented and analyzed. A detailed study was made of the effect of nitrogen impurities on the stability of the glow mode of the discharge, and on the evolution of its parameters.

Comparison of deionized and tap water activated with an atmospheric pressure glow discharge

Liquid-cathode discharge at atmospheric pressure has been excited by a direct current voltage above the surfaces of deionized and tap water. Gap voltage decreases with increasing discharge current, which suggests that the discharges above both the liquids belong to a normal glow regime. For a given discharge current, gap and power voltages of the discharge above deionized water are higher than those above tap water. The optical spectrum obtained from the water surface reveals that there are abundant active species related to oxygen, nitrogen, and water vapor, which leads to changes in the pH value, conductivity, and concentrations of NO3−, NO2−, and H2O2 in liquid. Therefore, these parameters are investigated in the two liquids as functions of discharge current and plasma activation time. For both of them, the results show that the pH value decreases, while conductivity increment and concentrations of NO3−, NO2−, and H2O2 increase with increasing discharge current or activation time. Compared to activated tap water, deionized water has a lower pH value, while higher conductivity increment and concentrations of NO3−, NO2−, and H2O2 are observed after the same activation time and discharge current. Finally, these parameters are compared for different salt types and salt concentrations after plasma activation.