Surface Gloss Research Articles

Influence of Printing Orientation on Surface Roughness and Gloss of 3D Printed Resins for Orthodontic Devices

The study aims to assess the effect of printing orientation on surface roughness and gloss of resins for 3D printing of aligners. Squared specimens (14 × 14 × 4 mm) were printed using Dental LT Clear (Formlabs, Somerville, MA, USA; LT) or Tera Harz TC-85 DAC (Graphy, Seoul, Republic of Korea; TC) with different orientations: 0° (horizontal), 90° (vertical), and as per the manufacturer’s recommendation (40° for LT, 60° for TC). A profilometer was used to measure roughness (Ra) in µm, while gloss was recorded in gloss units (GU) with a glossmeter. The collected data were statistically analyzed. Material type did not significantly influence roughness, while print orientation was an influential factor, with the orientation recommended by the manufacturer yielding the roughest specimens. Vertical printing resulted in significantly higher roughness than horizontal. Material type was a significant factor for gloss, with TC exhibiting significantly higher gloss than LT. Print direction significantly influenced gloss, with vertical printing resulting in the highest gloss. The finding of higher roughness for vertical prints can be explained by the presence of a greater number of layers. The superior gloss exhibited by TC regardless of print angulation could be related to the effective cleaning of uncured resin by centrifugation and to the high degree of monomer conversion in nitrogen atmosphere.

Organoleptic and Physicochemical Profile Comparison of Cow Milk Yogurt and 'Eggurt' Made from Different Egg Whites

Yogurt is a widely consumed fermented dairy product known for its distinctive flavor, nutritional value, and health benefits. To expand its nutritional profile and enhance textural qualities, this study explores the use of egg whites as an alternative ingredient in yogurt production. The research compares the sensory and physicochemical properties of traditional milk yogurt with "eggurt" a yogurt variant made using different egg white sources: free-range chicken, caged chicken, and duck eggs. Four samples were prepared, including one control (milk yogurt) and three “eggurt” variants. Sensory quality was evaluated through organoleptic testing using a structured Likert scale to assess attributes such as color, surface gloss, aroma, mouthfeel, and flavor. Physicochemical analysis included moisture content, total dissolved solids, viscosity, ash content, and acidity measurements. Results showed that free-range “eggurt” was most like milk yogurt in terms of texture and flavor, displaying balanced viscosity and minimal surface liquid separation. In contrast, caged “eggurt” exhibited increased surface liquid, higher ash content, and stronger acidity, while duck eggurt was noted for its excessive thickness, very high viscosity, and pronounced acidity. These textural and compositional differences, despite the higher production costs, suggest that free-range “eggurt” is the most promising alternative, offering a comparable sensory experience to traditional yogurt while enhancing texture and overall quality.

Composição química de revestimentos frios e a influência na refletância solar e emitância térmica

Abstract Cool materials have higher values of solar reflectance and lower values of thermal emittance, although still high when compared to conventional coatings, thus, their surfaces are less heated. In this regard, the goal was to identify the chemical elements present on cool surfaces that influence solar reflectance and thermal emittance. To this end, the spectral reflectance and the thermal emittance were measured with methods and equipment standardized by the Cool Roof Rating Council (CRRC) of 23 elastomeric cool coatings commercialized in the Brazilian market, and the chemical composition of the surfaces with EDS (Energy-dispersive X-ray detector) coupled to the field emission scanning electron microscope (FE-SEM) was analyzed. The presence of the metallic chemical element (titanium) in greater quantities on the surfaces was not decisive for lower thermal emittance values. The surfaces of materials with lower carbon and higher oxygen content have higher near infrared and solar reflectance. Therefore, surfaces with a matte finish have higher solar reflectance values because of the higher ratio of pigments in relation to resin than those with a glossy finish, which are mistakenly associated with higher reflectance due to its high surface gloss.

Effect of different polishing systems on surface roughness and gloss values of single-shade resin composites

BackgroundThe aim of this study was to evaluate variations in the surface roughness and gloss of different single-shade resin composites after polishing with a range of systems.MethodsIn total, 120 specimens were prepared from three different types of single-shade resin composites (supra-nanospherical—Omnichroma, nanohybrid—Charisma Diamond One, and microhybrid— Essentia Universal). The specimens were placed in distilled water and stored at 37 °C for 24 h. Each resin composite (n = 40) was divided into four groups (n = 10) according to the finishing/polishing (F/P) system: Mylar strip (control), Sof-Lex (multi-step), Twist Dia (two-step), and OneGloss (one-step). Surface roughness and gloss were measured. Surface characteristics were evaluated by atomic force microscopy (AFM) and a scanning electron microscope (SEM). A two-way analysis of variance (ANOVA) and Tukey’s honestly significant difference test were used for statistical analysis (p < 0.05).ResultsAmong all the composites, both the highest surface roughness and lowest gloss values were obtained in the groups treated with the OneGloss polishing system (p < 0.05). Compared with all the composites, Omnichroma had the lowest surface roughness and highest gloss values (except Twist Dia) both unpolished and after polishing with all the F/P systems (p < 0.05). All composites treated with the Twist Dia F/P system had similar gloss values. The results of the AFM and SEM analyses were consistent with the surface roughness measurements.ConclusionsThe gloss values of both the microhybrid and nanohybrid composites after F/P using the two-step system was superior to that of the traditional multistep system. The surface of the supra-nanofilled resin-based composite was smoother than that of both the microhybrid and nanohybrid composites.

Development and validation of polymer-based porphyrin-incorporated reference materials for calibration of quantitative light-induced fluorescence device

BackgroundThis study aimed at developing and validating polymer-based reference materials with varying amounts of porphyrin to accurately assess and calibrate quantitative light-induced fluorescence (QLF) device. MethodsReference materials with porphyrin concentrations ranging from 0 to 0.08 wt.% were prepared. The surface properties of the materials were analyzed via gloss and roughness measurements. Color analysis of the specimens was performed on black and white backgrounds with or without filters using a spectrophotometer. This approach revealed the correlations between fluorescence and color. The fluorescence emitted by the specimens was analyzed by measuring ΔR and ΔRmax values using a QLF-D Biluminator™. ResultsThe surface gloss and roughness of the reference materials were not affected by the porphyrin content (p > 0.005). Spectrophotometric measurements revealed significant color differences among most specimen groups depending on the background color and the presence of a filter. QLF-D imaging revealed significant differences in fluorescence (ΔR and ΔRmax) among all specimen groups regardless of the background. The fluorescence values observed on the black backgrounds were higher than those observed on the white backgrounds (p < 0.05). ConclusionsThe developed polymer-based porphyrin-incorporated materials serve as reliable reference standards for accurate assessment and calibration of QLF devices. This study demonstrates the importance of background conditions in fluorescence detection and highlights the potential of these materials as standards for QLF device calibration.

Effect of lubricated polishing and repolishing on gloss, roughness and material loss of nanoparticle resin composite

Aim: The study examined how different dry and lubricated polishing protocols impact the gloss, roughness, and material loss of nanoparticle resin composites, before and after simulated toothbrushing. Methods: One hundred cylindrical resin composite specimens were prepared and divided into an unpolished group and three test groups: Dimanto (DIM), Sof-Lex Pop-On (SOF), and Astrobrush (ASTRO). These groups underwent polishing dry, with water, or with or petroleum jelly. Surface parameters including gloss (Novo-Curve – Rhopoint TM, England), roughness, and material loss (MaxSurf XT 20, MahrGoettingen, Germany) were evaluated at four stages: baseline, polishing, simulated toothbrushing, and repolishing. Data were submitted to repeated measures ANOVA (P&lt;0.05). Results: Lubrication did not affect the studied parameters after polishing with DIM. SOF showed improved performance without lubricants, whereas ASTRO achieved higher gloss and lower roughness when lubricated. In terms of surface material loss, DIM exhibited less material loss when used with petroleum jelly, SOF had reduced material loss when used with water, and ASTRO showed the most material loss when lubricated with petroleum jelly. Conclusion: The gloss, roughness, and surface material loss of the nanoparticle resin composite are influenced by the type of polisher used and the choice of lubricant. However, none of the differences observed surpassed the established thresholds for roughness or gloss perception, suggesting that these protocols are potentially viable for clinical application. Despite detectable differences among the polishing systems and lubricant combinations, all tested options are clinically acceptable. None of them exceeded the thresholds for biofilm accumulation or perceptible differences in surface gloss.

Can wheel polishers improve surface properties and color stability of monochromatic resin composites?

BackgroundTo overcome the color layering procedure, monochromatic resin composites have been introduced. However, little is known about their polishability, gloss and color stability. This study aimed to investigate the surface roughness, gloss, and color change of monochromatic resin composites polished with wheel systems after being immersed in coffee.Materials and methodsOmnichroma, Zenchroma, Essentia Universal, Charisma Diamond One and NeoSpectra ST were used to obtain 120-disc samples of 8 × 2 mm. Only one side of the sample was polished with Twist Dia (TWD) or Nova Twist (NOV). The samples were examined for surface roughness, gloss, and color (ΔE and ΔE00) before and after 7 days of immersion in coffee and subsequent repolishing. The discs were examined via SEM. Surface roughness and gloss values were analyzed using ANOVA, Tukey and Pearson correlation tests. ΔE and ΔE00 values were evaluated using T tests, multivariate ANOVA, and Dunnett’s post-hoc tests.ResultsFor TWD groups, the smoothest material was Omnichroma (p < 0.05), while for NOV groups, it was Omnichroma and Zenchroma. Omnichroma was the glossiest, while Charisma Diamond One was the least glossy. In TWD groups, Charisma Diamond One and Essentia Universal were the most discolored, while Zenchroma and Omnichroma were the least. For NOV groups, Essentia Universal and Charisma Diamond One were the most discolored, while NeoSpectra ST, Omnichroma and Zenchroma were the least. After repolishing, Charisma Diamond One did not reach the level of ΔE < 2, while the other groups showed values below. Color evaluation with the CIELab and CIEDE2000 systems revealed similar results for the TWD groups after post-staining.ConclusionsSmooth and glossy surfaces could be achieved with the wheel system regardless of the composite resin. Repolishing after discoloration ensures that the color recovery is below the acceptable limit. Color evaluations with CIELab and CIEDE2000 yielded similar results.

Effect of toothbrushing on surface roughness and gloss of CAD-CAM versus conventional interim materials with different surface treatments

Characterizing interim restorations promotes esthetics. However, studies on the effects of characterization materials on the surface roughness and gloss of interim materials after toothbrushing are lacking. The purpose of this in vitro study was to evaluate the surface roughness and gloss of 5 different interim materials with different surface treatments after 1 year of simulated toothbrushing. Cuboid specimens (10×12×2 mm) were fabricated from each interim material: autopolymerized polymethyl methacrylate (UNIFAST Trad), autopolymerized bis-acryl composite resin (Protemp 4), light-activated composite resin (REVOTEK LC), milled polymethyl methacrylate block (DD provi P HI), and 3-dimensionally printed methacrylate oligomer (Nextdent C&B MFH). Each material was divided into 3 groups based on surface treatment (n=10): polishing, application of Lite Art and Resin Glaze, and application of OPTIGLAZE color. The specimens were subjected to 5000 and 10 000 cycles of toothbrushing. The surface roughness and gloss were measured and separately analyzed by using 3-way repeated measures ANOVA (α=.05). Significant interactions of the surface roughness and gloss among interim materials, surface treatments, and toothbrushing durations were found (P<.001). After 5000 and 10 000 cycles, each polished material showed no significant difference in surface roughness compared with baseline: Protemp 4 (P>.999), REVOTEK LC (P>.999, P=.922), and Nextdent C&B MFH (P>.999), except for UNIFAST Trad and DD provi P HI (P<.001). Coating with Lite Art and Resin Glaze, as well as OPTIGLAZE color, significantly reduced surface roughness after both 5000 and 10 000 cycles for all materials (application of Lite Art and Resin Glaze with UNIFAST TRAD (P<.001), Protemp 4 (P<.001), REVOTEK LC (P<.001), DD provi P HI (P<.001), and Nextdent C&B MFH (P<.001, P=.002), and application of OPTIGLAZE color with UNIFAST TRAD (P<.001), Protemp 4 (P<.001), REVOTEK LC (P<.001, P=.002), DD provi P HI (P<.001), and Nextdent C&B MFH (P<.001, P=.008)). Specimens with these treatments also exhibited significantly better gloss compared with the polished specimens (P<.001). After 5000 to 10 000 cycles of toothbrushing, Protemp 4, REVOTEK LC, and Nextdent C&B MFH, interim materials containing fillers, exhibited smoother surfaces compared with UNIFAST Trad and DD provi P HI, interim materials without fillers. Coating of all materials reduced surface roughness and increased gloss. After 5000 to 10 000 cycles of toothbrushing, the surface roughness of each material remained stable; while the gloss decreased slightly, it remained within clinically acceptable levels.

Influence of various cleaning solutions on the geometry, roughness, gloss, hardness, and flexural strength of 3D-printed zirconia

This study aimed to investigate the impact of various cleaning solutions on the geometry, roughness, gloss, hardness, and flexural strength of 3D-printed zirconia. Cleaning solutions, including isopropyl alcohol (IPA, 99.9%), ethyl alcohol (EtOH, 99.9%), and tripropylene glycol monomethyl ether (TPM, ≥ 97.5%), were diluted to a concentration of 70% and categorized into six groups: IPA99, EtOH99, TPM97, IPA70, EtOH70, and TPM70. Zirconia discs, printed via digital light processing, were sintered after cleaning. The geometry, roughness, gloss, hardness, and flexural strength were analyzed. Statistical analysis was performed using one-way ANOVA with Tukey’s post hoc test (p < 0.05). The thickness of TPM70 was the highest. The diameter of TPM70 was significantly larger than that of EtOH99 and IPA70 (p < 0.05). The weight of the TPM groups was significantly higher than that of IPA70 (p < 0.05). The roughness Ra of TPM70 was significantly greater than that of IPA99, EtOH99, and EtOH70 (p < 0.05). The differences in surface gloss, hardness, and flexural strength among the different groups were not statistically significant (p > 0.05). Different cleaning solutions did not affect the surface gloss, hardness, and flexural strength of 3D-printed zirconia. High and low concentrations of the same cleaning solution did not affect the surface gloss, hardness, and flexural strength. IPA70, TPM97, and EtOH can be considered viable post-printing cleaning alternatives to the traditional gold standard, IPA99.

Comparison of polishing methods for two types of monolithic all-ceramic crowns after occlusal adjustments: Polishing paste versus glazed porcelain.

This study compared the effects of two surface preparation methods on two types of zirconia. Immediately prior to the placement of a monolithic zirconia crown, its morphology may be modified using a rotary cutting instrument for occlusal adjustments. The crown surface is scratched during the grinding process and, thus, requires polishing. Simplified zirconia crowns of 3Y and 5Y were fabricated and used as specimens. The surface roughness and gloss of the occlusal surfaces of specimens were measured and compared when a polishing compound was used after polishing points and when a silica-based coating was sintered. No significant differences were observed in surface roughness between 3Y and 5Y zirconia. The use of polishing compounds was effective because polishing points alone only resulted in a level of surface roughness that may cause wear on antagonist teeth. Although the silica-based coating improved surface properties, the polishing compound more effectively improved surface roughness.

Sustainable engineering polymer composites fabricated using delignified bamboo fiber as reinforcement and walnut shell powder as filler

Developing sustainable engineering materials using renewable resources and agro-wastes represents an effective method for reducing carbon emissions and environmental pollution. In this study, a novel approach to fabricating high-performance biomass-based polymer composites was presented. Specifically, partially delignified bamboo fiber (DBF) and walnut shell powder (WSP) were incorporated into the matrix, namely melamine-hexamethylenediamine-urea (MHU) resin which was previously known for its excellent interfacial compatibility. Mechanical property investigations show that the DBF, acting as the reinforcement, provided the hybrid composites with high flexural and tensile strength up to 220 and 120 MPa, respectively, greatly surpassing those of commercial wood-plastic composites, wood-based composites, and natural wood, making them promising structural materials. As the filler, walnut shell powder endowed the composites with high hardness (Shore D > 90) and an appealing mirror-like surface gloss. Owing to the protection provided by the MHU matrix, the composite containing 38 % MHU exhibited outstanding flame retardancy (UL 94-V0 grade), which was further supported by cone calorimeter test (CCT) results. An unexpected and intriguing finding is that the composites exhibited fluorescence under UV irradiation. The rare silvery-grey fluorescence color imparted self-anticounterfeiting property to the composites. This study demonstrated the significant potential of bamboo fiber and walnut shell in the development of sustainable engineering materials.

Effect of Different Finishing Systems on Surface Roughness and Gloss of a 3D-Printed Material for Permanent Dental Use

The object of the study was to assess the effect of different finishing and polishing systems on the roughness and gloss of a 3D-printed permanent restorative material. One 3D printable Permanent material was selected for the study. Squared-shaped specimens (14 mm2; 5 mm thickness) were obtained by designing and printing. Eighty specimens were produced and randomly assigned (n = 10) to 8 finishing and polishing methods: Sof-Lex™ Spiral Wheels (SW), Sof-Lex™ XT Pop-on Disc (SD), Identoflex Lucent no paste (Ln), Identoflex Lucent + paste (Lp), Resin Nitrogen polymerized (NG), Optiglaze (OG), Opti1Step (OS), and HiLusterPLUS (HL). Surface roughness and gloss were then measured by a roughness meter and a glossmeter, respectively. For roughness, statistically significant differences were found (p &lt; 0.001), with NG(a) &gt; SD(b) = OG(b) = Lp(b); Lp(b) = Ln(bc); Ln(bc) = OS(cd); OS(cd) = SW(de); and SW(de) = HL(e). For gloss, statistically significant differences were also identified (p &lt; 0.001) with NG(a) &gt; SD(b) &gt; Lp(c) = OS(c) = OG(cd); OG(cd) = Ln(d) &gt; HL(e) = SW(e). The nitrogen chamber polymerization showed better results for both roughness and gloss. Multi-step finishing/polishing systems were able to produce smoother surfaces than 1-step and 2-step systems.

Influence of in-office whitening on the color matching and surface characteristics of single-shade resin composites.

The color matching of single-shade resin composites after in-office whitening was investigated. Four single-shade resin composites were used. A total of 35% hydrogen peroxide was used as the whitening agent. The resin composite was placed in a cavity of an artificially discolored bovine tooth. The color differences between the restoration and surrounding enamel before and after whitening were determined based on ΔE*ab, ΔE00, and ΔWID. The color stability, surface roughness (Sa), and surface gloss (GU) of the resin composite alone were also evaluated. Statistical analyses were performed using repeated-measures analysis of variance with the Tukey-Kramer test. Based on the 50:50% of perceptibility and acceptability thresholds of ΔE*ab and ΔE00, none of the resin composite restorations were clinically acceptable before or after whitening. Regarding ΔWID, although all resin composites showed "acceptable match" in the baseline, they showed "mismatch" after the third session of whitening. Most of the resin composites alone were stable in color against whitening. Although the single-shade resin composites failed to achieve the expected color matching on discolored teeth either before or after the whitening, the impact of the whitening on the color of the resin composite alone may be negligible.

Towards a zero-waste chemcycling of thermoset polymer composites: Catalyst assisted mild solvolysis for clean carbon fiber liberation and circular coating development

Thermoset materials and their reinforced composites are widely employed in the aircraft, wind energy and construction sectors. Their 3D-crosslinked network and their chemical and physical heterogeneity make them particularly difficult to be recycled. Nowadays, the management of composite scraps and end-of-life waste is still based on landfilling or incineration practices, which are clearly non-compliant with the principles of the circular economy. In this work, a catalysed solvolysis process in mild conditions (T = 180 °C, t = 1–3 h, catalyst 1–7 wt%) was applied for the chemical recycling (chemcycling) of anhydride-cured epoxy resins and their carbon fiber reinforced composites. The selection of the hydroxylated solvents followed thermodynamic considerations (Hansen solubility parameters) and green chemistry principles. The quality of the liberated fibers was studied through thermogravimetric analysis, scanning electron microscopy and single-fiber micromechanical testing, highlighting high surface purity and 100% retention of their pristine mechanical properties (Young's modulus, elongation at break and ultimate strength). The organic recyclates were characterized through gel permeation chromatography, Fourier-transform infrared spectroscopy and chemical titration, and directly reused as hydroxylated binders for the formulation and application of bicomponent polyurethane protective coatings. The resulting coatings were characterized by high chemical resistance (> 100 double rubs at methyl-ethyl ketone test), high surface scratch hardness (3H to 5H), good substrate adhesion (1.5–4 MPa), and excellent optical clarity and surface gloss. These results demonstrate the potential zero-waste reusability of all fractions derived from the chemical recycling of carbon fiber reinforced composites, in line with the principles of the circular economy.

Effect of Post-Printing Conditions on the Mechanical and Optical Properties of 3D-Printed Dental Resin.

This study aimed to evaluate the flexural strength (FS), surface wear, and optical properties of 3D-printed dental resins subjected to different post-printing conditions. A total of 240 specimens (2 × 2 × 25 mm³) were 3D-printed using resin materials for permanent (VaresoSmile Crown Plus) VSC and temporary (VaresoSmile Temp) VST restorations. Specimens underwent five post-printing conditions: no post-printing cure; post-cured in a Form Cure curing unit; Visio Beta Vacuum; Ivoclar Targis; or heat-cured (150 °C) for 30 min. Each group of specimens (n = 24) was tested either directly after post-curing, after 24 h of dry storage, or following hydrothermal accelerated aging in boiling water for 16 h. The three-point bending test was used to evaluate the FS. The two-body wear test was performed on 50 disc-shaped specimens (n = 5/group). Surface gloss and translucency were measured for permanent VSC specimens (n = 5/group). SEM/EDS and statistical analyses were performed. The Form Cure device yielded the highest FS and lowest wear depth (p < 0.05). Hydrothermal aging significantly reduced FS. There were no statistical differences in FS and wear values between materials subjected to same post-printing conditions. VSC groups exhibited similar optical properties across different post-printing treatments. Post-printing treatment conditions had a significant impact on the FS and wear of the 3D-printed resin, while optical properties remained unaffected.

Synthesis of palm oil-based bio-polyol by thiol-ene reaction: Preliminary study of its potential as cationic waterborne polyurethane for coating application

Thailand has the world's third-largest planting area for oil palm. Palm oil can be chemically modified to obtain bio-polyol instead of petroleum-based polyol. In this research, a new bio-polyol based on modified palm oil (MPO) was successfully synthesized by thiol-ene click reaction using Darocur1173 as a photoinitator. The molar ratios 2-Mercaptoethanol (ME) to carbon‑carbon double bonds for MPO synthesis was studied. The kinetics of the thiol-ene click reaction was investigated by monitoring with 1H NMR technique. The chemical structure of MPO was confirmed by 1HNMR and FTIR spectroscopy. In addition, the average molecular weight (Mn) of a series of MPO was determined by GPC. The influence of N-methyl diethanolamine (NMDEA) content as an internal emulsifier on cationic waterborne polyurethane (cWPU) was investigated. The resulting cWPU based on MPO showed well-dispersed particles with a shelf life of >6 months and the zeta potential increased with increasing NMDEA content ranging from 5.6 % to 9.6 %wt. Moreover, the plywood with cWPU coatings had a shiny gloss surface, with increasing NMDEA content. The cWPU coating with NMDEA content lower than 7.6 %wt protected the plywood surface against QUV accelerated weathering for 48 h without cracking the cWPU film. The cWPU showed a high gloss value, decreased contact angle, and increased water absorption behavior. The hydrophilicity of cWPU film increased with increasing NMDEA content. Also, increasing the NMDEA content led to a higher ratio of hard segment to soft segment in the PU chain which improved the tensile strength and thermal stability. These results demonstrated an efficient synthesis procedure which offers an opportunity to use palm oil as bio-polyol to develop green cWPU that can be used as a binder in coating applications.

Multiscale slope analysis and functional correlation with gloss reflectance from photographic papers

A novel multiscale 3D topographic characterization for slope is introduced. Slope is considered as a crucial parameter linking area-scale and 3D curvature analyses. Relationships between surface topography and gloss reflectance in photographic papers are used for an example application. Directional angles, characterizing slopes, are calculated two ways: normals to triangular facets (method 1), and eigenvectors of a covariance matrix based on nine points (method 2). Slope is the steepness of surface inclinations associated with the orientation of local surface features (facets). The impact of slope on gloss reflectance supports the use of pertinent geometric characterizations, i.e., alignment of geometric characterizations with the physical nature of the topographic interaction phenomena. Topographies of 24 photographic papers, were measured with a laser scanning confocal microscope and their gloss reflectance was measured with a micro-TRI-gloss gloss meter. Analyses of slope distributions with bivariate dispersion measures of directional angles and their trigonometric functions revealed strong correlations (R2 > 0.6) between slope distributions and gloss. Bivariate median deviation of secant or tangent of directional angles, demonstrated consistently high correlations across scales, magnifications, and filtrations. This study supports pertinent and useful characterizations grounded in the physics of topographic interaction phenomena to provide insights into relationships between surface topography, e.g., slope and gloss reflectance in photographic papers. This nuanced understanding has potential applications for other applications as well.

Preparation and characterization of hydrophobic waterborne polyurethane self‐matting coating

AbstractA green method to synthesize self‐matting waterborne polyurethane acrylic hybrid emulsion with hydrophobic function is introduced in this study. A reactive waterborne polyurethane (RWPU) dispersion containing unsaturated CC double bonds was prepared from epoxidized soybean oil. Subsequently, the RWPU dispersion was copolymerized with fluorinated monomers of different carbon chain lengths to prepare polyurethane acrylic hybrid emulsion (PUF). The results revealed the gloss levels of PUF films to be as low as 12.4 gloss units at 60°. The morphology of PUF films was observed by scanning electron microscope and three‐dimensional surface profilometer, and the relationship between surface roughness and gloss was discussed in detail. In addition, thermal gravimetric analysis was conducted to determine the thermal stability of the PUF films, and the results denoted that these PUF films exhibited excellent thermal stability. Comprehensive performance tests indicated that the RWPU dispersion, which was copolymerized with hexafluorobutyl methacrylate at a weight of 10%, exhibited a low gloss, a high contact angle of 120°, and a high elongation percentage of 423%. Furthermore, the dynamic light scattering results showed small average particle size, revealing the excellent storage stabilities.

Surface roughness and optical characteristics evaluations after chairside adjustment of different zirconia types.

Limited evidence is available for the effect of chairside adjustment using rotary cutting instruments on the surface roughness and optical properties of different zirconia types. To evaluate the effect of simulated adjustments on surface roughness and optical properties of different zirconia types. Three Partially Stabilized Zirconia (PSZ) types based on mole percent yttria (Y) concentration from the same manufacturer (Katana; Kuraray) were used: 3Y-PSZ, 4Y-PSZ, and 5Y-PSZ. Thirty disk-shaped specimens (Ø14 × 1.2 mm) from different zirconia types (N = 90) were prepared. Specimens were either left without adjustment (NA), adjusted with Dialite ZR finishing and polishing system (Brasseler) (APol), or adjusted with course diamond instruments only (ADia). The specimens were distributed into 9 groups (n = 10): Group 3Y-PSZ/NA, Group 3Y-PSZ/APol, Group 3Y-PSZ/ADia, Group 4Y-PSZ/NA, Group 4Y-PSZ/APol, Group 4Y-PSZ/ADia, Group 5Y-PSZ/NA, Group 5Y-PSZ/APol, and Group 5Y-PSZ/ADia. The surface roughness of specimen was analyzed using an Atomic Force Microscope (AFM) (Bruker's Dimension Icon, Bruker) and Root Means Square (RMS) were recorded (nm). Surface Gloss (SG), Translucency Parameter (TP), and Contrast Ratio (CR) values of all groups were recorded using an integrating sphere spectrophotometer. Statistical analysis was performed using analysis of variance (ANOVA) and Tukey's multiple comparison tests for pairwise comparisons at p < 0.05 and 95% confidence interval. APol had no effect on the surface roughness (p = 0.88) while ADia had a significant negative effect (p < 0.05) despite the type of zirconia. Out of the three testes optical properties, only SG was negatively affected by ADia for all types of zirconia (p < 0.05). The two adjustment types did not affect the TP of all the tested zirconia (p = 0.91). The CR was not affected by the tested adjustments for all zirconia types (p = 0.726). Proper zirconia adjustment following a sequence of burs and polishers can maintain acceptable roughness and optical properties. Adjustment of zirconia with rough diamond can lead to deleterious effects and should be avoided. Chairside adjustment of zirconia could lead to rougher surface and unpredictable changes of surface gloss. Therefore, zirconia adjustment should be minimized to the greatest extent possible and a proper protocol should be followed if had to be done.

Nanosized curing catalyst via nano-templated plasma PVD for attaining superior low-cure powder coating films

The addition of curing catalysts into powder coating is a key method to fabricate low-temperature curing powder coating for reducing energy consumption and expanding its applications to heat-sensitive substrates. However, the heterogeneous dispersion of the unmodified catalysts in powder coatings results in inconsistent catalysis of resin crosslinking, thus leading to compromised surface smoothness and gloss. Utilizing nanosized catalysts is an efficient solution to such problems. In this paper, we propose a nano-templated dielectric barrier discharge (DBD) plasma-assisted physical vapor deposition (PVD) strategy to fabricate the nanosized catalysts. The curing catalyst, 2-ethylimidazole (2-elm), is successfully vaporized and deposited on nano-carrier SiO2 (SiO2-NPs) in the DBD plasma reactor at atmospheric pressure, producing 2-elm@SiO2-NPs. The mechanical strength and chemical resistance of finishes of powder coating incorporated with the 2-elm@SiO2-NPs remained at low curing temperature (170 °C for 15 min) and fast curing condition (190 °C for 8 min). In addition, their surface qualities are comparable to that of the original powder coating, with up to 100 % gloss retention, successfully eliminating the issue of more than 25 % gloss attenuation of the powder coating with unmodified 2-elm. This study provides an effective, solvent-free strategy for fabricating nanosized curing catalysts and achieving high-quality film finishes.