Global Silicate Weathering Research Articles

The Role of Southeast Asian Island Topography on Indo‐Pacific Climate and Silicate Weathering

AbstractThe geography of the Southeast Asian Islands (SEAI) has changed over the last 15 million years, as a result of tectonic processes contributing to both increased land area and high topography. The presence of the additional land area has been postulated to enhance convective rainfall, facilitating both increased silicate weathering and the development of the modern‐day Walker circulation. Using an Earth System Model in conjunction with a climate‐silicate weathering model, we argue instead for a significant role of SEAI topography for both effects. SEAI topography increases orographic rainfall over land, through intercepting moist Asian‐Australian monsoon winds and enhancing land‐sea breezes. Large‐scale atmospheric uplift over the SEAI region increases by ∼14% as a consequence of increased rainfall over the SEAI and enhancement through dynamical ocean‐atmosphere feedback. The atmospheric zonal overturning circulation over the Indo‐Pacific increases modestly arising from dynamical ocean‐atmosphere feedback, more strongly over the tropical Indian Ocean. On the other hand, the effect of the SEAI topography on global silicate weathering is substantial, resulting in a ∼109 ppm reduction in equilibrium pCO2 and decrease in global mean temperature by ∼1.7ºC. The chemical weathering increase comes from both enhanced physical erosion rates and increased rainfall due to the presence of SEAI topography. The lowering of pCO2 by SEAI topography also enhances the Indo‐Pacific atmospheric zonal overturning circulation. Our results support a significant role for the progressive emergence of SEAI topography in global cooling over the last several million years.

Lithium isotope systematics and water/rock interactions in a shallow-water hydrothermal system at Milos Island, Greece

The active venting fluids of Milos Island, located within the southern Aegean Sea, belong to a shallow-water hydrothermal system (< 200 m depth) that shows chemical compositions and evolution processes comparable to those of mid-ocean ridges (MOR). In this study, we analyze Li and δ7Li in 69 vent water samples, grouped into two types based on their salt content. The low-Cl end-member (EM) Cave fluids show a relatively high Li content (0.39–0.54 mM) with MORB-like δ7Li (∼4.5 ‰, MORB = 3.7 ‰) compared to that of seawater, and the high-Cl brine fluids contain remarkably high Li (6.14–10.6 mM) and variable δ7Li (1.4–8.7 ‰). The latter fluids may have derived from metamorphic basement modified by seawater interactions at ∼300 °C. A scenario using a steady-state dissolution/precipitation model can generate consistent Li and δ7Li patterns, where linear correlations of Cl and Li suggest phase separation occurred after water/rock interaction at depth. On the contrary, no significant δ7Li variation in most Milos fluids suggests limited isotopic fractionation occurred during phase separation. More importantly, the detected Li enrichment in the high-Cl fluids implies a large Li flux, ∼3.4 × 107 mol/yr, to the ocean from the Milos system. Assuming that 10% of the world's shallow-water systems discovered to date have similar Li outputs to those of Milos, this Li flux would represent ∼1.8% of MOR hydrothermal fluxes which is on the order of ∼13 × 109 mol/yr. These results emphasize the importance of Li flux derived from shallow-water hydrothermal systems, which should not be excluded from the calculation of the marine Li budget and its impact on the global silicate weathering cycles.

Valanginian climate cooling and environmental change driven by Paraná-Etendeka basalt erosion

Abstract The Valanginian Weissert Event (ca. 134 Ma) has long been linked to emplacement of the Paraná-Etendeka large igneous province (LIP). Although several Mesozoic crises were triggered by volcanic CO2 emissions and global warming, causing oceanic oxygen depletion, the Weissert Event featured climate cooling and limited marine anoxia. Here, the impact of silicate weathering on environmental change during the Weissert Event is investigated by presenting the first osmium isotope (187Os/188Os) data sets for the late Berriasian–Valanginian interval. These records document a possible rise in weathering and nutrient runoff during the latest Berriasian, followed by a switch to Paraná-Etendeka basalt erosion during the Valanginian. The high weatherability of LIP basalts enhanced global silicate weathering despite limited coeval climate warming. This weathering triggered the documented cooling, with consequent micronutrient runoff potentially aiding ocean fertilization, highlighting a mechanism linking LIP formation with environmental change that was uniquely different than that of other Mesozoic crises.

High-temporal-resolution of lithium isotopes in Yangtze River headwater: Hydrological control on weathering in high-relief catchments

How climate change regulates silicate weathering in tectonically active areas remains clear. To evaluate the roles of temperature and hydrology in continental-scale silicate weathering in high-relief catchments, we applied a high temporal resolution of lithium isotopes in the Yalong River, which drains the high-relief borders of the eastern Tibetan Plateau. The dissolved δ7Li values range from +12.2‰ to +13.7‰ in the non-monsoon season and are higher and significantly vary from +13.5‰ to +19.4‰ in the monsoon season. The negative correlation between dissolved δ7Li and the Li/Na ratio is attributed to the formation of various proportions of δ7Li-low secondary minerals during weathering. From non-monsoon to monsoon season, the weathering intensity decreases with increasing secondary minerals formation and the weathering transforms from a supply limited to a kinetically limited weathering regime, indicated by a negative correlation between dissolved δ7Li value and SWR/D ratio (SWR = silicate weathering rate and D = total denudation rate). No correlations between temperature and dissolved δ7Li values were observed, and SWR suggested that temperature is not the direct control factor of silicate weathering in high-relief areas. The dissolved δ7Li values display positive correlations with discharge, physical erosion rates (PERs), and SWR. This positive correlations was attributed to an increase in the PER which caused the formation of more secondary minerals with increasing discharge. These results indicate the rapid temporal variability of riverine Li isotopes and chemical weathering process in response to changes in hydrology rather than temperature. Combined with the compiled PER, SWR, and Li isotopes at various altitudes, we further suggest that weathering in high-altitude catchments is more sensitive to hydrological changes than weathering in low-altitude catchments. These results highlight the key role of the hydrologic cycle (runoff and discharge) and the geomorphic regime in controlling global silicate weathering.

MUDDYING THE WATERS: MODELING THE EFFECTS OF EARLY LAND PLANTS IN PALEOZOIC ESTUARIES

ABSTRACT The Paleozoic evolution of vegetation transformed terrestrial landscapes, facilitating novel sedimentary processes and creating new habitats. This transformation left a permanent mark on the sedimentary record, perhaps most strikingly via an upsurge in preserved terrestrial mudrock. Whereas feedbacks between evolving vegetation and river structure have been widely studied, Paleozoic estuaries have so far received scant attention. Located at the interface between the land and sea, the co-adjustment of estuarine morphology and plant traits are fundamentally tied to a varied range of geochemical cycles, and determine how global silicate weathering patterns may have varied over time. Here we employ an eco-morphodynamic model with an in-built vegetation code to simulate estuarine morphology through five key stages in plant evolution. An abiotic model (early Precambrian?) saw mud deposition restricted to fortuitous instances of limited erosion along bar-flanks. Estuaries colonized by microbial mats (Precambrian onwards) facilitated mud accretion that sufficiently stabilized bar surfaces to promote extensive mudflat development. Small-stature, rootless vegetation (Silurian–Early Devonian) introduced novel above-ground baffling effects which led to notable mud accumulation in lower-energy environments. The incorporation of roots (Early Devonian) strengthened these trends, with root structures decreasing the mortality of the occupying plants. Once the full complement of modern vascular plant architectures had evolved (Middle Devonian), dense colonization promoted the formation of in-channel islands accompanied with system-wide mud accumulation. These simulations suggest estuaries underwent profound change during the Paleozoic, with the greening of the continents triggering processes and feedbacks which render all previous source-to-sink sediment pathways non-uniformitarian.

Global silicate weathering flux overestimated because of sediment–water cation exchange

Rivers carry the dissolved and solid products of silicate mineral weathering, a process that removes [Formula: see text] from the atmosphere and provides a key negative climate feedback over geological timescales. Here we show that, in some river systems, a reactive exchange pool on river suspended particulate matter, bonded weakly to mineral surfaces, increases the mobile cation flux by 50%. The chemistry of both river waters and the exchange pool demonstrates exchange equilibrium, confirmed by Sr isotopes. Global silicate weathering fluxes are calculated based on riverine dissolved sodium (Na+) from silicate minerals. The large exchange pool supplies Na+ of nonsilicate origin to the dissolved load, especially in catchments with widespread marine sediments, or where rocks have equilibrated with saline basement fluids. We quantify this by comparing the riverine sediment exchange pool and river water chemistry. In some basins, cation exchange could account for the majority of sodium in the river water, significantly reducing estimates of silicate weathering. At a global scale, we demonstrate that silicate weathering fluxes are overestimated by 12 to 28%. This overestimation is greatest in regions of high erosion and high sediment loads where the negative climate feedback has a maximum sensitivity to chemical weathering reactions. In the context of other recent findings that reduce the net [Formula: see text] consumption through chemical weathering, the magnitude of the continental silicate weathering fluxes and its implications for solid Earth [Formula: see text] degassing fluxes need to be further investigated.

Do degree and rate of silicate weathering depend on plant productivity?

Abstract. Plants and their associated below-ground microbiota possess the tools for rock weathering. Yet the quantitative evaluation of the impact of these biogenic weathering drivers relative to abiogenic parameters, such as the supply of primary minerals, water, and acids, is an open question in Critical Zone research. Here we present a novel strategy to decipher the relative impact of these drivers. We quantified the degree and rate of weathering and compared these to nutrient uptake along the “EarthShape” transect in the Chilean Coastal Cordillera. These sites define a major north–south gradient in precipitation and primary productivity but overlie granitoid rock throughout. We present a dataset of the chemistry of Critical Zone compartments (bedrock, regolith, soil, and vegetation) to quantify the relative loss of soluble elements (the “degree of weathering”) and the inventory of bioavailable elements. We use 87Sr∕86Sr isotope ratios to identify the sources of mineral nutrients to plants. With rates from cosmogenic nuclides and biomass growth we determined fluxes (“weathering rates”), meaning the rate of loss of elements out of the ecosystems, averaged over weathering timescales (millennia), and quantified mineral nutrient recycling between the bulk weathering zone and the bulk vegetation cover. We found that neither the degree of weathering nor the weathering rates increase systematically with precipitation from north to south along the climate and vegetation gradient. Instead, the increase in biomass nutrient demand is accommodated by faster nutrient recycling. In the absence of an increase in weathering rate despite a five-fold increase in precipitation and net primary productivity (NPP), we hypothesize that plant growth might in fact dampen weathering rates. Because plants are thought to be key players in the global silicate weathering–carbon feedback, this hypothesis merits further evaluation.

Physical controls and ENSO event influence on weathering in the Panama Canal Watershed

Recent empirical studies have documented the importance of tropical mountainous rivers on global silicate weathering and suspended sediment transport. Such field studies are typically based on limited temporal data, leaving uncertainty in the strength of observed relationships with controlling parameters over the long term. A deficiency of long-term data also prevents determination of the impact that multi-year or decadal climate patterns, such as the El Niño Southern Oscillation (ENSO), might have on weathering fluxes. Here we analyze an 18-year hydrochemical dataset for eight sub-basins of the Panama Canal Watershed of high-temporal frequency collected between 1998 and 2015 to address these knowledge gaps. We identified a strongly positive covariance of both cation (Ca2+, Mg2+, K+, Na+) and suspended sediment yields with precipitation and extent of forest cover, whereas we observed negative relationships with temperature and mosaic landcover. We also confirmed a statistical relationship between seasonality, ENSO, and river discharge, with significantly higher values occurring during La Niña events. These findings emphasize the importance that long-term datasets have on identifying short-term influences on chemical and physical weathering rates, especially, in ENSO-influenced regions.

Warm afterglow from the Toarcian Oceanic Anoxic Event drives the success of deep-adapted brachiopods

Many aspects of the supposed hyperthermal Toarcian Oceanic Anoxic Event (T-OAE, Early Jurassic, c. 182 Ma) are well understood but a lack of robust palaeotemperature data severely limits reconstruction of the processes that drove the T-OAE and associated environmental and biotic changes. New oxygen isotope data from calcite shells of the benthic fauna suggest that bottom water temperatures in the western Tethys were elevated by c. 3.5 °C through the entire T-OAE. Modelling supports the idea that widespread marine anoxia was induced by a greenhouse-driven weathering pulse, and is compatible with the OAE duration being extended by limitation of the global silicate weathering flux. In the western Tethys Ocean, the later part of the T-OAE is characterized by abundant occurrences of the brachiopod Soaresirhynchia, which exhibits characteristics of slow-growing, deep sea brachiopods. The unlikely success of Soaresirhynchia in a hyperthermal event is attributed here to low metabolic rate, which put it at an advantage over other species from shallow epicontinental environments with higher metabolic demand.

Weathering dynamics of Large Igneous Provinces (LIPs): A case study from the Lesotho Highlands

Basaltic terrains contribute a significant component to the global silicate weathering flux despite their limited areal coverage. A strong correlation between chemical weathering flux and climatic factors such as temperature in volcanically inactive basaltic fields implies that weathering of basalt might have played an important role in maintaining the habitability of the Earth and the balance of the geological carbon cycle. However, the low erosion rate of flood basalt provinces on tectonically quiescent cratons, where the clear climate dependence of weathering rate has been observed, implies a ‘supply-limited’ weathering regime so that weathering fluxes are expected to be controlled by physical erosion rather than climate. This work tests the weathering dynamics of flood basalts by investigating the weathering flux of the Karoo LIP on the Lesotho Highlands where an extremely low rate of denudation has been recorded through terrestrial cosmogenic nuclide dating and sediment flux. Stream chemistry of the rivers from the Lesotho Highlands shows typical characteristics of basalt weathering with Ca and Mg as the dominant cations and HCO3− as the dominant anion. Strong spatial and seasonal variability of solute concentration, possibly linked to a dilution effect, is observed. However, the giant Katse Reservoir of the Lesotho Highlands Water Project (LHWP) effectively averages the spatial and seasonal variability of the solute concentration. The average solution concentration and long-term runoff of the Katse Reservoir give an average atmospheric CO2 consumption rate of 0.26 ± 0.02 × 106 mol/km2/yr (mean ± standard deviation). The chemical weathering flux requires complete alteration of primary silicates and, therefore, a ‘supply-limited’ weathering regime is suggested given the low denudation rate. Nevertheless, the chemical weathering rate of the Lesotho Highlands, as well as other low-eroding basaltic plateaus, is still consistent with the global correlation between temperature and the rate of basalt weathering. A production-limited denudation rate, modulated by temperature, is suggested to reconcile the paradox between the observed temperature dependence of chemical weathering rates and ‘supply-limited’ weathering regimes.

A Capacitor‐Discharge Mechanism to Explain the Timing of Orogeny‐Related Global Glaciations

AbstractOver geological timescales, mountain building or orogenesis is associated with increased weathering, the drawdown of atmospheric CO2, and global cooling. However, a multimillion‐year delay appears to exist between peaks in low‐latitude mountain uplift and the maximum extent of Phanerozoic glaciation, implying a more complex causal relationship between the two. Here we show that global silicate weathering can be modulated by orogeny in three distinct phases. High, young mountain belts experience preferential precipitation and the highest erosion. As mountains are denuded, precipitation decreases, but runoff temperature rises, sharply increasing chemical weathering potential and CO2 drawdown. In the final phase, erosion and weathering are throttled by flatter topography. We conclude that orogeny acts as a capacitor in the climate system, granting the potential for intense transient CO2 drawdown when mountain ranges are denuded; the mechanism suggests such a scenario potentially happening 10–50 × 106 years in the future.

Neogene cooling driven by land surface reactivity rather than increased weathering fluxes.

The long-term cooling, decline in the partial pressure of carbon dioxide, and the establishment of permanent polar ice sheets during the Neogene period1,2 have frequently been attributed to increased uplift and erosion of mountains and consequent increases in silicate weathering, which removes atmospheric carbon dioxide3,4. However, geological records of erosion rates are potentially subject to averaging biases5,6, and the magnitude of the increase in weathering fluxes-and even its existence-remain debated7-9. Moreover, an increase in weathering scaled to the proposed erosional increase would have removed nearly all carbon from the atmosphere10, which has led to suggestions of compensatory carbon fluxes11-13 in order to preserve mass balance in the carbon cycle. Alternatively, an increase in land surface reactivity-resulting from greater fresh-mineral surface area or an increase in the supply of reactive minerals-rather than an increase in the weathering flux, has been proposed to reconcile these disparate views8,9. Here we use a parsimonious carbon cycle model that tracks two weathering-sensitive isotopic tracers (stable 7Li/6Li and cosmogenic 10Be/9Be) to show that an increase in land surface reactivity is necessary to simultaneously decrease atmospheric carbon dioxide, increase seawater 7Li/6Li and retain constant seawater 10Be/9Be over the past 16 million years. We find that the global silicate weathering flux remained constant, even as the global silicate weathering intensity-the fraction of the total denudation flux that is derived from silicate weathering-decreased, sustained by an increase in erosion. Long-term cooling during the Neogene thus reflects a change in the partitioning of denudation into weathering and erosion. Variable partitioning of denudation and consequent changes in silicate weathering intensity reconcile marine isotope and erosion records with the need to maintain mass balance in the carbon cycleand without requiring increases in the silicate weathering flux.

The silicate weathering feedback in the context of ophiolite emplacement: Insights from an inverse model of global weathering proxies

Silicate weathering provides a stabilizing feedback in the global carbon cycle and has played a key role in keeping surface environments clement for the majority of Earth9s history. It was recently proposed that ophiolite emplacement at low latitude at ∼90 to 70 Ma and ∼50 to 40 Ma enhanced the rate of silicate weathering and led to global cooling that terminated the Early Eocene Climatic Optimum. In this study, we revisit this proposal with a series of models of varying complexities to investigate the likelihood that Earth9s climate was driven largely by ophiolite emplacement in the Paleogene. Our models are constrained by either marine Os isotopic records or the combination of carbon cycle, Sr and Os isotopic records, and solid Earth degassing rates. The proposed changes in ophiolite weathering are inconsistent with our Os isotope mass balance model. With our coupled carbon cycle and weathering proxy model, total global silicate weathering fluxes (including ophiolite weathering) slightly decreased or remained relatively constant from 52 to 42 Ma. This constancy in global silicate weathering fluxes is inconsistent with the idea that enhanced ophiolite weathering directly led to global climate cooling. However, our model results support the idea that the strength of the silicate weathering feedback (weatherability) has played a significant role in regulating the pCO2 levels through the Cenozoic. Further, the modeling toolkit developed here can be used to explore the role of mafic rock weathering in driving climate change in other intervals through Earth9s history.

Lithium isotopic composition of benthic foraminifera: A new proxy for paleo-pH reconstruction

The lithium isotopic composition of foraminifera is an established tracer of long-term changes in the global silicate weathering cycle, following the assumption that foraminifera faithfully record the lithium isotopic composition (δ7Li) of seawater. In this study, we demonstrate by utilising benthic foraminifera (Amphistegina lessonii) that were cultured under decoupled pH-[CO32–] conditions, that foraminifera δ7Li is strongly dependent on pH. This is reinforced with δ7Li data from globally distributed core-top samples of Cibicidoides mundulus and Cibicidoides wuellerstorfi, which show the same negative correlation with pH. The dependency of δ7Li on pH is perhaps a surprising result given that lithium speciation in seawater is independent of both pH and carbonate ion speciation. The dependence of lithium incorporation on growth rate was assessed by measuring the calcium isotopic composition; no growth rate dependent incorporation was observed. Instead, we propose that the strength of the 6Li and 7Li hydration spheres (and hence their respective desolvation energy) is pH-dependent, resulting in a significant isotopic fractionation during the incorporation of lithium into foraminifer calcite. The core-top derived δ7Li-pH calibration is used to demonstrate the applicability of this δ11B-independent pH proxy in reconstructing deglacial variations in pH in the South Pacific. The use of foraminifera δ7Li to compliment δ11B-based pH reconstructions has the potential to provide insight into time-dependent variations in porewater/seawater δ11B, temperature and salinity, which were previously unresolvable.

Soils as pacemakers and limiters of global silicate weathering

The weathering and erosion processes that produce and destroy regolith are widely recognized to be positively correlated across diverse landscapes. However, conceptual and numerical models predict some limits to this relationship that remain largely untested. Using new global data compilations of soil production and weathering rates from cosmogenic nuclides and silicate weathering fluxes from global rivers, we show that the weathering-erosion relationship is capped by certain ‘speed limits’. We estimate a soil production speed limit of between 320 to 450tkm−2yr−1 and the associated weathering rate speed limit of roughly 150tkm−2yr−1. These limits appear to be valid for a range of lithologies, and also extend to mountain belts, where soil cover is not continuous and erosion rates outpace soil production. We argue that the presence of soil and regolith is a requirement for high weathering fluxes from a landscape, and that rapidly eroding, active mountain belts are not the most efficient sites for weathering.

Transport and exchange of U-series nuclides between suspended material, dissolved load and colloids in rivers draining basaltic terrains

This study presents uranium and thorium concentrations and activity ratios for all riverine phases (bedload, suspended load, dissolved load and colloids) from basaltic terrains in Iceland and the Azores. Small basaltic islands, such as these, are thought to account for ~25% of CO2 consumed by global silicate weathering, and for ~45% of the flux of suspended material to the oceans. These data indicate that [U] and [Th] in the dissolved and colloidal fractions are strongly controlled by pH, and to a much lesser extent by levels of dissolved organic carbon (which are low in these environments). At high pH, basalt glass dissolution is enhanced, and secondary mineral formation (e.g. Fe-oxyhydroxides and allophane) is suppressed, resulting in high dissolved [U], and low colloidal [U] and [Th], indicating a direct chemical weathering control on elemental abundances. When the dissolved (234U/238U) activity ratio is >~1.3 (i.e. when physical weathering, groundwater contribution or soil formation are high), there is little isotope exchange between dissolved and colloidal fractions. At lower activity ratios, the dissolved load and colloids have indistinguishable activity ratios, suggesting that when chemical weathering rates are high, secondary clay formation is also high, and colloids rapidly adsorb dissolved U. Many of the suspended sediment samples have (234U/238U) activity ratios of >1, which suggests that uptake of U onto the suspended load is important. Identical (230Th/232Th) in suspended, dissolved and colloidal samples suggests that Th, like U, is exchanged or sorbed rapidly between all riverine phases. This particle-reactivity, combined with poorly constrained contributions from groundwater and hydrothermal water, and short-term variations in input to soils (volcanic and glacial), suggests that U-series nuclides in riverine material from such basaltic terrains are unlikely to reflect steady state erosion processes.

Chemical weathering and associated CO 2 consumption in the Godavari river basin, India

The study gives insight into the source of major ions concentration and their seasonal variability, chemical weathering rates and associated CO 2 consumption in the Godavari River Basin (GRB). The results show that the Godavari river basin water was mildly alkaline, with a wide range of TDS (40 to 550 mgL − 1 ). The most dominant anion was HCO 3 − followed by Cl − and the most dominant cation was Ca 2+ followed by Na + for all three sampling seasons. The average molar ratio of Cl −/Na + was 0.59 in pre-monsoon, 0.51 for post-monsoon and 0.66 in monsoon, which is lower than the values, reported in earlier studies. The range of precipitation corrected molar ratio for (Ca 2+/Na +) was 0.20 to 1.84 in pre-monsoon, 0.59 to 1.59 in post-monsoon and 0.35 to 2.09 in monsoon season, (Mg 2+/Na +) was 0.26 to 1.18, 0.24 to 0.62 and 0.17 to 1.42 in pre-monsoon, post-monsoon and monsoon respectively, while (HCO 3 −/Na +) was 2.08 to 7.0 in pre-monsoon,1.98 to 4.05 in post-monsoon and 1.67 to 5.79 in monsoon, which indicated the influence of basalt weathering on river water chemistry. Factor analysis indicated the vital role of silicate and carbonate weathering along with atmospheric and anthropogenic input that govern the water chemistry of the GRB. The chemical weathering rate of GRB varied from 17.61 to 68.16 tkm − 2 y − 1 with an average of 39.49 tkm − 2 y − 1 in pre-monsoon, from 27.94 to 65.67 with the average of 42.02 tkm − 2 y − 1 in post-monsoon season and from 17.53 to 62.95 tkm − 2 y − 1 with an average value of 34.69 tkm − 2 y − 1 in monsoon. The associated CO 2 consumption rate due to chemical weathering in the GRB was ∼ 0.25 × 10 12 mol y − 1 which is ∼ 1.04% of the annual global CO 2 consumption (24 × 10 12 mol y − 1 ) by chemical weathering of silicate and carbonate rocks. The average annual CO 2 drawdown by Deccan trap (area 5 × 10 5 km 2) based on CO 2 consumption rate due to silicate weathering determined in this study was 0.29 × 10 12 mol y − 1 , ∼ 2.48% of the annual global CO 2 consumption (11.7 × 10 12 mol y − 1 ) by silicate weathering [Gaillardet, J., Dupre, B., Allegre, C.J., 1999. Global silicate weathering and CO 2 consumption rates deduced from the chemistry of large rivers. Chemical Geology 159, 3–30.]. The present study was the first attempt to calculate weathering rate of Deccan trap using major ion chemistry of the Godavari River water, the third largest river in India. The study further provides the inventory for CO 2 consumption on river basin scale, which is an important consideration from the point of view of global warming.

Hf and Nd isotopes in marine sediments: Constraints on global silicate weathering

The combined use of Lu–Hf and Sm–Nd isotope systems potentially offers a unique perspective for investigating continental erosion, but little is known about whether, and to what extent, the Hf–Nd isotope composition of sediments is related to silicate weathering intensity. In this study, Hf and Nd elemental and isotope data are reported for marine muds, leached Fe-oxide fractions and zircon-rich turbidite sands collected off the Congo River mouth, and from other parts of the SE Atlantic Ocean. All studied samples from the Congo fan (muds, Fe-hydroxides, sands) exhibit indistinguishable Nd isotopic composition (ε Nd ~ − 16), indicating that Fe-hydroxides leached from these sediments correspond to continental oxides precipitated within the Congo basin. In marked contrast, Hf isotope compositions for the same samples exhibit significant variations. Leached Fe-hydroxide fractions are characterized by ε Hf values (from − 1.1 to + 1.3) far more radiogenic than associated sediments (from − 7.1 to − 12.0) and turbidite sands (from − 27.2 to − 31.6). ε Hf values for Congo fan sediments correlate very well with Al/K (i.e. a well-known index for the intensity of chemical weathering in Central Africa). Taken together, these results indicate that (1) silicate weathering on continents leads to erosion products having very distinctive Hf isotope signatures, and (2) a direct relationship exists between ε Hf of secondary clay minerals and chemical weathering intensity. These results combined with data from the literature have global implications for understanding the Hf–Nd isotope variability in marine precipitates and sediments. Leached Fe-hydroxides from Congo fan sediments plot remarkably well on an extension of the ‘seawater array’ (i.e. the correlation defined by deep-sea Fe–Mn precipitates), providing additional support to the suggestion that the ocean Hf budget is dominated by continental inputs. Fine-grained sediments define a diffuse trend, between that for igneous rocks and the ‘seawater array’, which we refer to as the ‘zircon-free sediment array’ (ε Hf = 0.91 ε Nd + 3.10). Finally, we show that the Hf–Nd arrays for seawater, unweathered igneous rocks, zircon-free and zircon-bearing sediments (ε Hf = 1.80 ε Nd + 2.35) can all be reconciled, using Monte Carlo simulations, with a simple weathering model of the continental crust.

A framework for predicting global silicate weathering and CO2 drawdown rates over geologic time-scales.

Global silicate weathering drives long-time-scale fluctuations in atmospheric CO(2). While tectonics, climate, and rock-type influence silicate weathering, it is unclear how these factors combine to drive global rates. Here, we explore whether local erosion rates, GCM-derived dust fluxes, temperature, and water balance can capture global variation in silicate weathering. Our spatially explicit approach predicts 1.9-4.6 x 10(13) mols of Si weathered globally per year, within a factor of 4-10 of estimates of global silicate fluxes derived from riverine measurements. Similarly, our watershed-based estimates are within a factor of 4-18 (mean of 5.3) of the silica fluxes measured in the world's ten largest rivers. Eighty percent of total global silicate weathering product traveling as dissolved load occurs within a narrow range (0.01-0.5 mm/year) of erosion rates. Assuming each mol of Mg or Ca reacts with 1 mol of CO(2), 1.5-3.3 x 10(8) tons/year of CO(2) is consumed by silicate weathering, consistent with previously published estimates. Approximately 50% of this drawdown occurs in the world's active mountain belts, emphasizing the importance of tectonic regulation of global climate over geologic timescales.

Silicate weathering and CO 2 consumption deduced from the seven Chinese rivers originating in the Qinghai-Tibet Plateau

We present river chemical data for the seven Chinese rivers (the Jinsha Jiang, Yalong Jiang, Min Jiang, Dadu He, Lancang Jiang, Nu Jiang and Huang He) originating in the Qinghai–Tibet Plateau. Our sampling locations are near sites where the seven rivers flow down the plateau. Water samples were collected in both high-water periods (summer) and low-water periods (winter). Our study shows that most of the Ca, Mg and HCO 3 in the seven rivers are derived from the carbonate weathering and only small fractions (10%) of the cations are derived from silicate weathering. The chemical erosion rates of silicate and carbonate range from 1.1 mm ka − 1 to 3.4 mm ka − 1 and from 7.5 mm ka − 1 to 29.9 mm ka − 1 respectively. The long term CO 2 consumption by silicate weathering in the seven Chinese river basins ranges from 0.7 × 10 5 mol km − 2 a − 1 to 3.7 × 10 5 mol km − 2 a − 1 . Based on our analysis of chemical data from the seven Chinese rivers and the previously published data of the Ganges, Brahmaputra and Indus, the main ten rivers originating in the Himalaya and Qinghai–Tibet Plateau consume 328 × 10 9 mol a − 1 of atmospheric CO 2. This is only 3.8% of the CO 2 consumption derived from global silicate weathering (8700 × 10 9 mol a − 1 ), indicating that the chemical weathering of the Himalaya and Qinghai–Tibet Plateau makes a very small contribution to the reduction of the global atmospheric CO 2 concentration.