Global Ozone Research Articles

Static wind imaging Michelson interferometer for the measurement of stratospheric wind fields.

The stratospheric wind field provides significant information on the dynamics, constituent, and energy transport in the Earth's atmosphere. The measurement of the atmospheric wind field on a global basis at these heights is still lacking because few wind imaging interferometers have been developed that can measure wind in this region. In this paper, we describe an advanced compact static wind imaging Michelson interferometer (SWIMI) developed to measure the stratospheric wind field using near-infrared airglow emissions. The instrument contains a field widened and thermal compensated interferometer with a segmented reflective mirror in one arm, which replace the moving mirror in a conventional Michelson interferometer, to provide interference phase steps. The field widened, achromatic, temperature compensated scheme has been designed and manufactured. The characterization, calibration, inversion software, and test of the instrument have been completed. The capacity of two-dimensional wind, temperature, and ozone measurement of the instrument has been verified in the lab experiment and model simulation. What we believe to be the novel principle, modeling, design, and experiment demonstrated in this paper will offer a significant reference to the static, simultaneous and real-time detection and inversion of the global wind field, temperature, and ozone.

Design and Fabrication of Vapour Compression Refrigeration Cycle Based On Storage Type Domestic Water Heater

In present scenario, generally VCR (Vapour Compression Refrigeration) cycle is used for heating and cooling. The adverse effect of release of refrigerant like global warming and ozone depletion in the atmosphere is known to all. Electric heaters use electricity which is obtained from thermal power plant run on fossil fuels. The aim of the project is to demonstrate the economic benefit of using heat rejected in the condenser of Vapour Compression Refrigeration (VCR) system and to check the feasibility of the apparatus for mass production. The main aim of the project is to develop economically viable VCR cycle based domestic water heater (Heat pump) which has a good payback period and low energy consumption compare to electric-resistance heater. To develop storage type water heater, helical coil shaped condenser brazed inside the water storage tank has been designed. Since the capacity of the VCR system is less, capillary tube has been used as an expansion device. The VCR cycle based DWH has been tested extensively and heating capacity of about 725 W has been obtained. This may be due to under sizing of evaporator or condenser or may be due to larger capillary length. The VCR cycle based DWH can save up to Rs. 4770 compared to electric resistance water heater. The simple payback period for DWH is 3 year and 1 month.

Research Progress and Trends in the Field of Satellite Ozone from 2005 to 2023: A Bibliometric Review

Ozone, an important atmospheric constituent, affects various processes in the troposphere–stratosphere region and significantly contributes to climate and environmental change. The advancement of meteorological satellite technology has enabled the deployment of ozone detection instruments in space, providing accurate and global satellite ozone data in all weather conditions. This study employs scientometric methods, such as collaboration analysis, co-citation analysis, and keyword co-occurrence analysis to investigate the current status, trends, and future directions of satellite ozone research, with a broader search scope and more objective results compared with a manual review. Analyzing a dataset of 5320 bibliographic records from the WoS core collection database reveals the key intellectual frameworks shaping this field during the period from 2005 to 2023. The findings indicate that leading nations, like the United States, Germany, France, and China, along with their respective institutions and authors, spearhead satellite ozone research. Collaborative partnerships between the United States and European countries play a crucial role in advancing research efforts. Moreover, 20 distinct co-citation clusters identify the knowledge framework within the field, demonstrating a consistent progression over time. The focus has expanded from satellite ozone observation instruments to encompass broader areas, such as atmospheric pollution and environmental conditions, with “air quality” emerging as a prominent research area and future trend. Based on these insights, four major research directions are proposed: understanding atmospheric pollution mechanisms, improving ozone detection technologies, utilizing satellite ozone data for weather, and climate phenomena. This study aims to assist scholars by providing a comprehensive understanding of the developmental trajectory of satellite ozone research. Its results can serve as a valuable reference for researchers to identify relevant publications and journals efficiently. Policymakers can also utilize this systematic review as a structured point of reference.

Investigative comparison of R134a, R290, R600a and R152a refrigerants in conventional vapor compression refrigeration system

This work represents the performance comparison of conventional vapour compression refrigeration system (VCRS) using various refrigerants such as R134a, R152a, R600a and R290. The theoretical model has been utilized for computing work input to the compressor, refrigerating effect and coefficient of performance (COP) for R134a, R290, R600a and R152a refrigerants. This investigation has been done for the evaporator temperature range of -30 °C to 10 °C and the condenser temperature range of 40 °C to 45 °C. In this performance analysis it is seen that R290 shows favourable properties and can serve as best refrigerant among all in the group. R290 shows almost equal COP to R600a in large operating temperature range and it has very high refrigerating capacity comparatively to R134a together with its low global warming potential and ozone depletion potential. R152a and R600a also show some satisfying properties.

Life Cycle Assessment of Bioenergy Production Using Wood Pellets: A Case Study of Remote Communities in Canada

In remote communities of Canada, diesel is the primary source of electricity and heat. Promoting sustainable and diverse means of heat and power generation is essential to providing reliable and less carbon-intensive energy supply to remote communities. Among renewable energy sources in Canada, biomass is a major source of energy, with wood pellets being a notable contributor. In this study, using wood pellets in a remote community of Canada is investigated using life cycle analysis (LCA). Furthermore, wood pellet combustion is compared with diesel combustion, the most common fossil fuel in these regions. SimaPro (version 8.4.0.0) was used with Ecoinvent 3 as the primary library because of the nature of the feedstock. Harvesting, transportation, sawmill operation, pelletization, and combustion stages are considered in LCA. In doing so, first, life cycle data related to each of these stages are collected with respect to eight impact categories of global warming, ozone depletion, carcinogenic, non-carcinogenic, smog, respiratory effects, acidification, eutrophication, ecotoxicity, and fossil fuel depletion. The results indicate that pelletization and combustion stages have the greatest environmental impact, specifically in terms of non-carcinogenic effects from pelletization and respiratory effects from pellet combustion. Additionally, when comparing wood pellets to diesel, wood pellet combustion exhibits superior performance across various impact categories, particularly in non-carcinogenic effects.

A 16-year global climate data record of total column water vapour generated from OMI observations in the visible blue spectral range

Abstract. We present a long-term data set of 1∘×1∘ monthly mean total column water vapour (TCWV) based on global measurements of the Ozone Monitoring Instrument (OMI) covering the time range from January 2005 to December 2020. In comparison to the retrieval algorithm of Borger et al. (2020), several modifications and filters have been applied accounting for instrumental issues (such as OMI's “row anomaly”) or the inferior quality of solar reference spectra. For instance, to overcome issues related to low-quality reference spectra, the daily solar irradiance spectrum is replaced by an annually varying mean earthshine radiance obtained in December over Antarctica. For the TCWV data set, we only consider measurements with an effective cloud fraction less than 20 %, an air mass factor (AMF) greater than 0.1, a snow- and ice-free ground pixel, and an OMI row that is not affected by the row anomaly over the complete time range of the data set. The individual TCWV measurements are then gridded to a regular 1∘×1∘ lattice, from which the monthly means are calculated. The investigation of sampling errors in the OMI TCWV data set shows that these are dominated by the clear-sky bias and cause on average deviations of around −10 %, which is consistent with the findings of previous studies. However, the spatiotemporal sampling errors and those due to the row-anomaly filter are negligible. In a comprehensive intercomparison study, we demonstrate that the OMI TCWV data set is in good agreement with the global reference data sets of ERA5 (fifth-generation ECMWF atmospheric reanalysis), RSS SSM/I (Remote Sensing Systems Special Sensor Microwave Imager), and CM SAF/CCI TCWV-global (COMBI): over ocean the orthogonal distance regressions indicate slopes close to unity with very small offsets and high coefficients of determination of around 0.96. However, over land, distinctive positive deviations of more than +10 kg m−2 are obtained for high TCWV values. These overestimations are mainly due to extreme overestimations of high TCWV values in the tropics, likely caused by uncertainties in the retrieval input data (surface albedo, cloud information) due to frequent cloud contamination in these regions. Similar results are found from intercomparisons with in situ radiosonde measurements from version 2 of the Integrated Global Radiosonde Archive (IGRA2) data set. Nevertheless, for TCWV values smaller than 25 kg m−2, the OMI TCWV data set shows very good agreement with the global reference data sets. Furthermore, a temporal stability analysis proves that the OMI TCWV data set is consistent with the temporal changes in the reference data sets and shows no significant deviation trends. As the TCWV retrieval can be easily applied to further satellite missions, additional TCWV data sets can be created from past missions, such as the Global Ozone Monitoring Experiment-1 (GOME-1) or the SCanning Imaging Absorption spectroMeter for Atmospheric CartograpHY (SCIAMACHY); under consideration of systematic differences (e.g. due to different observation times), these data sets can be combined with the OMI TCWV data set in order to create a data record that would cover a time span from 1995 to the present. Moreover, the TCWV retrieval will also work for all missions dedicated to NO2 in the future, such as Sentinel-5 on MetOp-SG. The Max Planck Institute for Chemistry (MPIC) OMI total column water vapour (TCWV) climate data record (CDR) is available at https://doi.org/10.5281/zenodo.7973889 (Borger et al., 2023).

Comparing the Effect of Anthropogenically Amplified Halogen Natural Emissions on Tropospheric Ozone Chemistry Between Pre‐Industrial and Present‐Day

AbstractReactive halogens (X + XO, X = I, Br or Cl) catalytically destroy a fraction of tropospheric ozone under present‐day (PD) conditions, however, their distribution and potential impact on tropospheric ozone under pre‐industrial (PI) conditions remain largely unexplored. This study uses the Community Atmosphere Model with Chemistry (CAM‐Chem) to investigate the effect of anthropogenically amplified natural emissions of halogenated species and their subsequent chemistry on tropospheric ozone under PI and PD atmospheric conditions. Model results show that the global tropospheric ozone depletion due to natural halogens is slightly more sensitive in PI than PD, with percentage changes in tropospheric ozone burden (TOB) of −14.1 ± 0.6% for PI and −12.9 ± 0.6% for PD. Individually, the role of iodine and chlorine in ozone depletion is equivalent in both periods (ΔTOBI: ∼−7% and ΔTOBCl: ∼−2.5%), while bromine plays a larger role in PI (ΔTOBBr: −5.5 ± 0.6%) versus PD (ΔTOBBr: −4.3 ± 0.7%). The increase in anthropogenic ozone precursor emissions from PI to PD has amplified the natural emission of inorganic halogens and led to a shift in the partitioning of inorganic halogens from reactive to reservoir species. Consequently, halogen‐driven ozone depletion from the surface to the free troposphere is larger in PI than PD. In contrast, in the upper troposphere, the ozone depletion is larger in PD influenced mainly by stratospheric intrusion of reactive halogens from long‐lived species. This study highlights the importance of including a complete chemical coupling of natural halogens and atmospheric pollutants in chemistry‐climate models to adequately assess their effects on tropospheric ozone in a changing climate.

Impact of different sources of precursors on an ozone pollution outbreak over Europe analysed with IASI+GOME2 multispectral satellite observations and model simulations

Abstract. We examine the impact of different sources of ozone precursors on the daily evolution of successive ozone pollution outbreaks across Europe in July 2017 by using a multispectral satellite approach called IASI+GOME2 and a tropospheric chemistry reanalysis named TCR-2. IASI+GOME2, combining IASI (Infrared Atmospheric Sounding Interferometer) and GOME-2 (Global Ozone Monitoring Experiment-2) measurements respectively in the infrared and the ultraviolet, allows the observation of the daily horizontal distribution of ozone in the lowermost troposphere (defined here as the atmospheric layer between the surface and 3 km above sea level). IASI+GOME2 observations show a fair capacity to depict near-surface ozone evolution as compared to surface measurements from 188 European stations for the period 15–27 July 2017. At the beginning of this event (on 16 July), an ozone outbreak is initially formed over the Iberian Peninsula likely linked with high temperature-induced enhancements of biogenic volatile organic compound concentrations and collocated anthropogenic emissions. In the following days, the ozone plume splits into two branches, one being transported eastward across the western Mediterranean and Italy and the other one over western and Central Europe. The southern branch encounters ozone precursors emitted over the Balkan Peninsula by wildfires along the coast of the Adriatic Sea and biogenic sources in the inland region of the peninsula. Ozone concentrations of the northern plume are enhanced by photochemical production associated with anthropogenic sources of ozone precursors over Central Europe and by mixing with an ozone plume arriving from the North Sea that was originally produced over North America. Finally, both ozone branches are transported eastwards and mix gradually as they reach the northern coast of the Black Sea. There, emissions from agricultural fires after harvesting clearly favour photochemical production of ozone within the pollution plume, which is advected eastwards in the following days. Based on satellite analysis, this paper shows the interplay of various ozone precursor sources to sustain a 2-week-long ozone pollution event over different parts of Europe.

Changes in Stratosphere‐Troposphere Exchange of Air Mass and Ozone Concentration in CCMI Models From 1960 to 2099

AbstractThis study investigates changes in stratosphere‐troposphere exchange (STE) of air masses and ozone concentrations from 1960 to 2099 using multiple model simulations from Chemistry Climate Model Initiative (CCMI) under climate change scenario RCP6.0. We employ a lowermost stratosphere mass budget approach with dynamic isentropic surfaces fitted to the tropical tropopause as the upper boundary of lowermost stratosphere. The multi‐model mean (MMM) trends of air mass STEs are all small over all regions, which are within 0.3 (0.1) % decade−1 for 1960–2000 (2000–2099). The MMM trends of ozone STE for 1960–2000 are 0.3%, −2.7%, 3.4%, −0.9%, and −2.7% decade−1 over the Northern hemisphere (NH) extratropics, Southern hemisphere (SH) extratropics, tropics, extratropics, and globe, respectively. The corresponding ozone STE trends for 2000–2099 are 3.0%, 4.3%, 0.8%, 3.5%, and 4.7% decade−1. Changes in ozone STEs are dominated by ozone concentration changes, driven by climate‐induced changes and ozone‐depleting substance (ODS) changes. For 1960–2000, small changes in ozone STEs in the NH extratropics are due to a cancellation between effects of climate‐induced changes and ODS increases, while the ODS effect dominates in the SH extratropics, leading to a large ozone STE magnitude decrease. Increased ozone transport from tropical troposphere to stratosphere for 1960–2000 is due to increased tropospheric ozone. A decreased global ozone STE magnitude for 1960–2000 was largely caused by ODS‐induced ozone loss that is partly compensated by climate‐induced ozone changes. For 2000–2099, about two‐thirds of global ozone STE magnitude increases are caused by ozone increases in the extratropical lower stratosphere due to climate‐induced changes. The remaining one‐third is caused by ozone recovery due to the phaseout of ODS.

Performance of Solar Adsorption Cooling System Using Methanol and Activated Carbon as a Working Pair

The need for renewable energy sources is higher than ever due to rising global warming, climate change, and ozone depletion. For refrigeration and air conditioning applications, adsorption refrigeration systems are viable alternatives cooling techniques. This study is a topic and part of the M.Sc. thesis. A field solar-powered ice maker unit was created, studied, tested, and evaluated on the 13th and 30th of May, 2022. Activated carbon and methanol pair was used to set up a refrigeration system in Baghdad (Al Dora). Experimental tests were carried out outdoors to determine the coefficient of performance COP and specific cooling power SCP of the system. The results showed that the lowest temperature obtained at the evaporative surface was (4 oC) and (3 oC) for the 13th and 30th of May, respectively, at the opening time of the valve between the evaporator and the generator at 9 pm. In addition, the amounts of methanol condensate were (0.340 kg) and (0.344 kg) for the 13th and 30th of May, respectively, while the maximum cycle coefficient of performance (COP) and specific cooling power SCP are about 0.57 and 0.14 kW/kga.c , respectively

Comparison of Satellite and Ground-Based Measurements of Tropospheric Ozone Columns in the Vicinity of St. Petersburg

The monitoring of tropospheric ozone in world science has recently received considerable attention since ozone in the troposphere is both a greenhouse and a pollutant gas. It also plays an important role in various chemical and photochemical processes. Ground-based measurements can be used to assess the quality and to validate satellite measurements of the global ozone distribution. The time series of ozone tropospheric columns in the 0-8 km layer derived from spectral measurements of the IASI satellite instrument using two different algorithms (IASI_LATMOS and IASI_LISA), as well as from joint measurements by the IASI and GOME-2 instruments (IASI-GOME2) were compared to ground-based measurements using the Bruker IFS 125HR Fourier spectrometer at the NDACC St. Petersburg site for 2009–2021. IASI_LISA and IASI-GOME2 on average overestimate ground-based ozone measurements by 9.8 and 5.1%, respectively, while there is no bias between the IASI_LATMOS and FTIR data. The standard deviations of the differences between ground measurements and the IASI_LISA and IASI_LATMOS data do not exceed 12–13%; for the IASI-GOME2 data they are 24.5%. Ground-based and satellite measurements agree better in spring and summer. Ground-based and IASI_LATMOS demonstrate a statistically significant negative trend in the ozone columns in the 0–8 km layer in the vicinity of St. Petersburg for the period 2012–2021, amounting to –0.71 ± 0.35% per year and –0.60 ± 0.21% per year, respectively.

Relationship between summer time near-surface ozone concentration and planetary boundary layer height in Beijing

The planetary boundary layer height (PBLH) is critical in affecting the concentration of air pollutants at surface. The relationship between PBLH and surface ozone concentration can be complicated but not entirely clear. In this study, by using observations and WRF-Chem simulations, we explore the relationship between the surface ozone and the PBLH in the summer daytime in Beijing, a major global ozone pollution hotspot. It is found that the surface ozone-PBLH relationship exhibits a three-stage evolution with ozone: first, increasing with PBLH, then keeping steady, and finally falling. The two turning points are around 1000 and 2000 m respectively. This process is likely controlled by the different contributions of chemical production and vertical mixing. Specifically, when PBLH is below ∼1000 m, as PBLH increases, chemical production increases owing to the light enhancement whereas the ozone contribution from vertical mixing remains weak due to the decreased ozone concentration gradient between the surface and the upper layer, resulting in a net gain of surface ozone concentration. When the PBL continues to rise, chemical production contributes less mainly due to the decrease of ozone precursors at the surface, whereas vertical mixing becomes more vigorous that further diluting surface ozone, resulting in a net loss of surface ozone concentration, especially when PBLH reaches above ∼2000 m. Our results contribute to understanding the variability of surface ozone in Beijing area and provide insights for local ozone air quality control.

Formulation of the cosmic ray–driven electron-induced reaction mechanism for quantitative understanding of global ozone depletion

This paper formulates the cosmic ray-driven electron-induced reaction as a universal mechanism to provide a quantitative understanding of global ozone depletion. Based on a proposed electrostatic bonding mechanism for charge-induced adsorption of molecules on surfaces and on the measured dissociative electron transfer (DET) cross sections of ozone-depleting substances (ODSs) adsorbed on ice, an analytical equation is derived to give atmospheric chlorine atom concentration: [Formula: see text] where Φe is the prehydrated electron (epre-) flux produced by cosmic ray ionization on atmospheric particle surfaces, [Formula: see text] is the surface coverage of an ODS, and ki is the ODS's effective DET coefficient that is the product of the DET cross section, the lifetimes of surface-trapped epre- and Cl-, and the particle surface area density. With concentrations of ODSs as the sole variable, our calculated results of time-series ozone depletion rates in global regions in the 1960s, 1980s, and 2000s show generally good agreement with observations, particularly with ground-based ozonesonde data and satellite-measured data over Antarctica and with satellite data in a narrow altitude band at 13 to 20 km of the tropics. Good agreements with satellite data in the Arctic and midlatitudes are also found. A previously unreported effect of denitrification on ozone loss is found and expressed quantitatively. But this equation overestimates tropospheric ozone loss at northern midlatitudes and the Arctic, likely due to increased ozone production by the halogen chemistry in polluted regions. The results render confidence in applying the equation to achieve a quantitative understanding of global ozone depletion.

Investigation on the environmental impact of R32, R152a and R41 refrigerant blends

The improper usage of refrigerants has a drastic impact on the environment, which is contributing to global warming and ozone layer depletion. The refrigerants which are being used currently have a very high GWP (Global Warming Potential) value that signifies an adverse impact on global warming. Refrigerant properties can be enhanced and modified by making refrigerant blends. This research uses GWP as a measure of refrigerant impact on global warming and provides alternative refrigerant blends for R32, R41, and R152a refrigerants. The results show 89.1% and 88.64% reduction in the GWP value of the R32 refrigerant blend and R152a refrigerant blend respectively. The R41 refrigerant blend has shown a reduction of 78.26%, with higher performance characteristics.

Analysis energy production design from grid connected 40 MW large PV power plant

Electricity is an important source of energy in everyday life. In recent decades, growing energy demand worldwide has significantly fueled energy production, leading to environmental impacts such as global warming and ozone depletion. it has also endangered the species. Hence, the whole world has started shifting towards green energy generation, eliminating all the negative impacts on the environment. Solar energy is the most CO2 emission save compared to non-renewable energy sources. A photovoltaic generator is useful in areas well exposed to the sun. This paper is aimed the total amount of energy generated by the solar system connected to the grid on the 230 kV transmission line. This result was conducted by comparing the energy generated with tilt angle of 15°,20°,25°,30°and 35°. The most energy generated is produced with 25° of tilt angle according to the simulation result in this paper. The result was simulated by using PVsyst. This paper presents energy production of a 40-MW grid connected photovoltaic system located at Minbu Township in Myanmar. The simulation is carried out in order to get maximum energy production and the incident radiation, performance ratio, energy into the grid and energy output at array and losses. Based on the simulation result, it is concluded that maximum energy production and performance ratio are 75730 MWh and 81% through the year. The CO2 emission was saved 424781.5 tons per year. The incident energy in collector plane is 5.220kWh/m2/day. This research is only conducted for analysis on existing grid connected utility scale solar PV system and not provided for advanced techniques.

Research on the diurnal variation characteristics of ozone formation sensitivity and the impact of ozone pollution control measures in “2 + 26” cities of Henan Province in summer

Near-surface ozone pollution is becoming an increasingly serious air quality issue in China, especially in “2 + 26” cities (Beijing-Tianjin-Hebei and nearby cities). HN2 + 26 cities (“2 + 26” cities of Henan Province) are located in the south of “2 + 26” cities, with frequent and severe ozone pollution events in recent years. This study investigated the diurnal evolution characteristics of ozone formation sensitivity (OFS) of HN2 + 26 cities from May to September in 2021 by the innovative combination of Global Ozone Monitoring Experiment (GOME-2B) and Ozone Monitoring Instrument (OMI) satellite data, and assessed the impact of ozone pollution control measures (OPCMs) implemented from June 26 to July 1, 2021. The localized FNR (ratio of formaldehyde to nitrogen dioxide of satellite measurement) threshold (1.4–2.55) was established, and it was found that OFS in May–September 2021 was mainly in VOCs-limited regime in the morning (∼10:00), while transitional/NOx-limited regime in the afternoon (∼14:00). Three periods (before, during and after the OPCMs) were divided to evaluate the impact of OPCMs on OFS. It was indicated that OPCMs had no impact on the morning OFS, but had a significant impact on the afternoon OFS. Specifically, the OFS in two industrial cities Xinxiang (XX) and Zhengzhou (ZZ) shifted from transitional regime to NOx-limited regime after the OPCMs. We further investigated OFS differences between urban and suburban areas and found that OFS shift of XX only existed in urban areas, while that of ZZ existed in both urban and suburban areas. We compared their measures and found that it is effective to take hierarchical control measures on different levels of ozone pollution days to alleviate ozone pollution. This study provides an improved understanding of diurnal evolution characteristics of OFS and the impacts of OPCMs on it, which will provide a theoretical basis for formulating more scientific ozone pollution control policies.

Working fluid selection for a high efficiency integrated power/cooling system combining an organic Rankine cycle and vapor compression-absorption cycles

This paper presents the performance evaluation of several combinations of working fluids for a new heat recovery cogeneration system which combines an Organic Rankine Cycle (ORC), a Vapor Absorption Cycle (VAC) and a Vapor Compression Cycle (VCC). NH3–NaSCN is chosen as the working fluid in the VAC. Seven different refrigerants in the ORC-VCC were studied to identify the fluid that would allow the overall system to achieve a high efficiency in the tropical region. These fluids were chosen because of their low Global Warming Potential and Ozone Depletion Potential. A thermodynamic simulation allowed to set the appropriate operating conditions of the VAC. Subsequently, energy and exergy analyses showed that R717 is the appropriate working fluid for system operation in the tropical region. For this fluid, the highest values of cooling capacity, net power output, thermal efficiency, exergy efficiency and exergy destruction of the system were respectively 1205 kW, 158.3 kW, 64.32%, 39.39% and 690.4 kW for VCC evaporation temperature of 15 °C, for ORC-VCC condensation temperature of 40 °C and for ORC steam generator outlet temperature of 219.7 °C. The most exergy-destroying components are the steam generator and the ORC/VCC condenser with 57.29% and 22.58%, respectively.

Effect of normal, blended and geopolymer concrete on ecosystem

Though cement concrete has an omnipresence its sustainability is a concerning subject due to the carbon dioxide emissions stemming from cement production resulting in research work to find lesser polluting alternatives. A blended concrete made with partial cement replacement by pozzolans as well as a geo-polymer concrete made with partial or full cement replacement is the choice at the current setting. However, there still exists a huge knowledge gap on the ecological benefits obtained by using these alternatives combining various materials for cement replacement for the production of concrete for paver blocks. The concrete used in preparing paver blocks are different from normal structural concretes reason being large quantity of fine aggregate requirement to satisfy codal provisions. Based on a comparative analysis of the life-cycle in a cradle-to-gate approach between traditional cement concrete (TCC), blended concrete (BC) and geo-polymer concrete with fly ash and sugarcane bagasse ash (GPCBA) this study compiles and presents results on Aquatic ecotoxicity (AEC), Aquatic acidification (AA), Aquatic eutrophication (AE), Terrestrial ecotoxicity (TE) and Terrestrial acid (TA) impact categories in addition to mostly reported traits like Global Warming (GW) and Ozone Layer Depletion (OLD). The study showed that a paver block of TCC is more detrimental as compared to other sustainable forms of concrete by almost 40%. The introduction of fly ash in BC reduced the burden of TCC but marginally. A numerical co-relationship showed that GW and OLD were directly inter linked.

Global Ozone Monitoring Experiment-2 (GOME-2) daily and monthly level-3 products of atmospheric trace gas columns

Abstract. We introduce the new Global Ozone Monitoring Experiment-2 (GOME-2) daily and monthly level-3 product of total column ozone (O3), total and tropospheric column nitrogen dioxide (NO2), total column water vapour, total column bromine oxide (BrO), total column formaldehyde (HCHO), and total column sulfur dioxide (SO2) (daily products https://doi.org/10.15770/EUM_SAF_AC_0048, AC SAF, 2023a; monthly products https://doi.org/10.15770/EUM_SAF_AC_0049, AC SAF, 2023b). The GOME-2 level-3 products aim to provide easily translatable and user-friendly data sets to the scientific community for scientific progress as well as to satisfy public interest. The purpose of this paper is to present the theoretical basis as well as the verification and validation of the GOME-2 daily and monthly level-3 products. The GOME-2 level-3 products are produced using the overlapping area-weighting method. Details of the gridding algorithm are presented. The spatial resolution of the GOME-2 level-3 products is selected based on the sensitivity study. The consistency of the resulting level-3 products among three GOME-2 sensors is investigated through time series of global averages, zonal averages, and bias. The accuracy of the products is validated by comparison to ground-based observations. The verification and validation results show that the GOME-2 level-3 products are consistent with the level-2 data. Small discrepancies are found among three GOME-2 sensors, which are mainly caused by the differences in the instrument characteristic and level-2 processor. The comparison of GOME-2 level-3 products to ground-based observations in general shows very good agreement, indicating that the products are consistent and fulfil the requirements to serve the scientific community and general public.

Implementation of trait-based ozone plant sensitivity in the Yale Interactive terrestrial Biosphere model v1.0 to assess global vegetation damage

Abstract. A major limitation in modeling global ozone (O3) vegetation damage has long been the reliance on empirical O3 sensitivity parameters derived from a limited number of species and applied at the level of plant functional types (PFTs), which ignore the large interspecific variations within the same PFT. Here, we present a major advance in large-scale assessments of O3 plant injury by linking the trait leaf mass per area (LMA) and plant O3 sensitivity in a broad and global perspective. Application of the new approach and a global LMA map in a dynamic global vegetation model reasonably represents the observed interspecific responses to O3 with a unified sensitivity parameter for all plant species. Simulations suggest a contemporary global mean reduction of 4.8 % in gross primary productivity by O3, with a range of 1.1 %–12.6 % for varied PFTs. Hotspots with damage >10 % are found in agricultural areas in the eastern US, western Europe, eastern China, and India, accompanied by moderate to high levels of surface O3. Furthermore, we simulate the distribution of plant sensitivity to O3, which is highly linked with the inherent leaf trait trade-off strategies of plants, revealing high risks for fast-growing species with low LMA, such as crops, grasses, and deciduous trees.