AbstractSummary: Langevin molecular dynamics (LMD) simulations have been performed in order to understand the role of the short chain branches (SCB) on the formation of ordered domains by cooling ethylene/α‐olefins single chain models. Different long single‐chain models (C2000) with 0, 5 and 10 branches each 1000 carbons were selected. The branches were randomly distributed along the backbone chain. Furthermore, C1 (methyl) and C4 (butyl) branches were taken into account. These models mimic the molecular architecture of ethylene/1‐butene and ethylene/1‐hexene random copolymers. The simulations are performed according to the following protocol: 20 random chain conformations for each model were equilibrated at high temperature (T* = 13.3) and then they were cooled in steps of 0.45 until the final temperature (T* = 6.2) by running a total of 35 × 106 LMD steps. The distribution peaks of crystallization for each model were calculated by differentiating the global order parameter with respect to the temperature. The Tc* (crystallization temperature) decrease as the number of branches increases as it is experimentally observed. The formation of order in the copolymers is affected by the type and amount of the SCB in the backbone of the polymer chain. The stem lenght and crystallization fraction (α) were defined using the local‐bond order parameter. Both parameters decrease as the number of branches increase. In all cases here shown, the C4 branches are excluded from the ordered domains. However, we have observed that the methyl branch can be incorporated into the ordered regions. These facts satisfactorily agree with experimental data available in the literature.