Waste Glass Research Articles

Optimizing mix design methods for using slag, ceramic, and glass waste powders in eco-friendly geopolymer mortars

Optimizing mix design methods for using slag, ceramic, and glass waste powders in eco-friendly geopolymer mortars

Recycling and optimum utilization of CRT glass as building materials: An application of low CO2 based circular economy for sustainable construction

The construction industry is the major contributor of CO2 emission around the globe. The rapid advances in the electronics industry have transformed the disposal of cathode ray tube glass waste (CRT-WG) into a prominent environmental concern. Recycling of CRT glasses as building materials can help in the production of sustainable construction. Numerous previous studies have documented that CRT-WG can be utilized either as a component of fine aggregate or binder material as it provides a cleaner solution and reduce carbon emission. Under this cleaner production and low CO2 emission perspective, this paper provides a thorough review of the previous studies on the utilization of CRT glass as a partially and fully substitute of sand and cementitious material in mortar production and propose an application of CO2 based circular economy model for reduce carbon emissions. This paper summarized the fresh, mechanical and durability properties of mortar incorporating treated and un-treated CRT-WG with different mineral additives and w/b ratios. Furthermore, this research explores the optimal proportions of CRT glass that can be use as replacements for sand and cement powder to make eco-friendly and sustainable low carbon mortar suitable for both structural and non-structural applications. More particularly, this review emphasizes the benefits, the need for additional research, and the drawbacks of CRT-WG use in construction building. Overall, this study proposes that incorporating CRT glass into building materials through a low CO2 based circular economy offers significant potential advantages. This study will help in optimization of CRT glass in concrete mix design in combination with waste materials for sustainable construction.

Optimizing Glass Foam Production from Recycled Sources: Influence of Variation in Cullet Color and Spent Alkaline Battery Components

Glass foams present a compelling opportunity for upcycling glass waste, offering a favorable combination of low weight, thermal insulation, and mechanical strength. Prior works demonstrated the feasibility of producing glass foams from glass waste and foaming agents sourced from synthetic textile waste, manganese oxides, and spent alkaline battery cathodes. This work explores the optimization of the process, investigating the impact of glass composition of differently colored glasses on final properties and incorporating entire alkaline batteries, encompassing both cathode and anode components. By carefully adjusting the composition, foaming agent content, and process temperature, customizable properties are achieved. Increasing foaming agent content or utilizing transparent glass improves insulation but lowers density and mechanical properties. Lowering foaming agent content or using brown/green glass enhances density and strength at the expense of insulation. Temperatures beyond 900 °C increase crystalline content, boosting mechanical performance without affecting density. This innovative approach not only offers a pathway to sustainable insulation materials but also underscores the potential for minimizing environmental impact through the efficient upcycling of glass waste.

Extraction of nickel ions using nanoporous adsorbent material from waste glass

This study aims to create a porous glass adsorbent from waste glass to extraction nickel ions from its aqueous solution. The process involves converting waste glass to porous glass using 1:1:1:1 lime, sodium chloride, and sodium bicarbonate, followed by reacting with waste glass at 800 ˚C. The porous glass surface morphology, elemental composition, and functional groups, were analyzed using SEM, EDS, and FT-IR techniques.The outcome parameters used in this study are adsorbent dosage (10 g), contact time (150 min), heavy metal ion concentration (100 mg/l), and pH of 6. The adsorption capacity resulting from these parameters is 9.28 mg/g using the porous extract adsorbent for the extraction of nickel ions from its solutions. According to the findings. The proportion of Ni (II) ions extracted increased, coupled with a rise in the adsorbent dosage, heavy metal ion concentration, contact time, and pH. In addition, the Langmuir isotherm (R2 = 0.98,KL=0.072) has shown better performance than the Freundlich adsorption isotherm (R2 = 0.93,N=1.598) for the adsorption of the Ni(II) in this study.

The synergistic sintering of ultra-lightweight ceramsite from molybdenum ore tailings, iron ore tailings and waste glass powders: Properties and formation mechanism

Molybdenum ore tailings, iron ore tailings and waste glass powders are important industrial solid wastes, mainly composed of silicate minerals and quartz, which are expected to become alternative resources for inorganic non-metal industrial materials. In this paper, the ultra-lightweight ceramsite was prepared by the synergistic sintering of molybdenum ore tailings, iron ore tailings and waste glass powders according to their characteristics of silicate minerals. The physical and mechanical properties were investigated when the sintering temperature was between 1100 and 1140 °C. The evolution of mineral phases and formation mechanism of pore structure during sintering were studied by XRD, FT-IR, SEM, TG-DSC and HSM. The results showed that in the sintering process, the waste glass powders and the pargasite in iron ore tailings first melted to produce the initial liquid phases. Then the anorthoclase and the quartz in molybdenum ore tailings melted to produce a large amount of liquid phases. These liquid phases covered the gas generated by the oxidation of SiC, thus forming a rich pore structure. At the same time, the [Si2O64−] and Ca2+, Mg2+ in the liquid phases derived from quartz and pargasite melting recrystallized to form diopside, which was conducive to the improvement of mechanical properties of ceramsite. When the raw material ratio of molybdenum ore tailings, iron ore tailings and waste glass powders was 6:2:2 and the sintering temperature was 1120 °C, the pore structure of the ceramsite as prepared was uniform and rich and mostly closed. The density was low and the mechanical propertities were excellent. It has a good application prospect in the field of building thermal insulation and sound insulation.

Enhancing thermo-mechanical and moisture properties of 3D-Printed concrete through recycled ultra-fine waste glass powder

This paper presents a novel approach to enhancing 3D printed concrete (3DPC) by incorporating ultra-fine glass powder (UFGP), focusing on its mechanical properties and high-temperature resistance. Investigation like fresh properties, basic physical properties, residual compressive strength after exposure to 400 °C and 800 °C, hygric properties such as water vapor diffusion resistance, liquid water transport, and moisture buffering capacity were performed the observe the effect of UFGP replacement ratio on 3DPC, which demonstrates significant improvements, highlighting the potential of UFGP to elevate 3DPCs’ performance. Results showed significant improvements, particularly with a 20% UFGP mix, which showed the lowest compressive strength loss (9.0% at 400 °C and 53.7% at 800 °C). Additionally, the water vapor diffusion resistance factor for the 20% UFGP mix was measured at 65.03. These results suggest that incorporating UFGP in 3DPC enhances thermal resilience and mechanical properties, offering a solution for high-temperature construction. This study contributes to sustainable construction by emphasizing the importance of mechanical resilience for structural integrity under extreme temperatures.

Developing alkali-activated controlled low-strength material (CLSM) using urban waste glass and red mud for sustainable construction

Using industrial waste in controlled low-strength material (CLSM) offers many benefits and addresses waste management issues. However, identifying optimal CLSM design while balancing environmental impacts and engineering properties poses a notable challenge. Herein, new alkali-activated CLSM formulations based on urban waste glass and red mud (RM) are proposed for the first time with systematic investigations into the material properties and sustainability. The formulations involve the ternary blends of slag, glass powder (GP) and RM as the binders and crushed glass as aggregate. Our observations show RM has a clay-like texture with complex crystalline phases rich in Al and Fe. Increasing the proportion of RM to GP notably decreases the flowability, extends the setting time and impairs the mechanical properties. Nevertheless, red mud demonstrates a crucial role of reducing bleeding level especially for the mixtures with high proportions of glass aggregate. The standard leachate tests as per toxicity characteristic leaching procedure (TCLP) show the heavy metals leached from the CLSM are below the concentration limits and exhibit low mobility. The microstructural and thermodynamic analyses reveal the precipitation of calcium-(sodium-)aluminosilicate hydrate (C-(N-)A-S-H) as the major binding material. The reactive Fe and Al in red mud most probably contribute to the formation of hydrogarnet phases. Moreover, the suggested CLSM formations typically exhibit reduced carbon emissions and lower costs compared to the traditional CLSM produced with cement and fly ash, underlining their environmental sustainability and cost-effectiveness. This study provides a potential guideline for the flowable fill construction in the regions with bauxite producers.

Production of Autoclaved Cementitious Composites Using Recycled Waste Glass

ABSTRACTOne of the major negative environmental implications of economic growth and the advancement of information technology is the large quantity of electronic waste dumped in landfills. Cathode ray tubes (CRTs) from outdated televisions and computer monitors are a significant source of electrical waste. The CRT funnel primarily consists of silica, significant alkalis (Na2O‐K2O), and heavy metals like barium‐strontium, along with a substantial lead (Pb) content that may contaminate the soil. Owing to its heavy metal content, CRT is considered hazardous waste, and regulations require its glass to be recycled or repurposed instead of landfill disposal. The low pozzolanic activity of CRT silica suggests that its high content, when paired with an optimized particle size and specific curing conditions, can enhance the mechanical properties of cement‐based products. Hydrothermal treatment has been found to speed up both the hydration of ordinary Portland cement (OPC) and the pozzolanic reactions. Since the main objective was to safely recycle large amounts of CRT, three mixes were proposed with 10%, 20%, and 30% OPC + 90%, 80%, and 70% CRT, respectively, and the effect of hydrothermal curing conditions on mechanical properties and durability of these blends was investigated. CRT‐70, a blend containing 70% CRT glass waste, showed enhanced strength due to the formation of zeolitic phases and calcium silicate hydrate (CSH). These phases also provided CRT‐70 with notable fire resistance, ensuring its structural stability under elevated temperatures. These results demonstrate the possibility of production of precast building products via high‐volume recycling of hazardous CRT waste.

Effect of Waste Glass Powder Replacement of Hydraulic Lime on Properties of Natural Hydraulic Lime Mortars.

This paper investigates the effects of the partial replacement of natural hydraulic lime (NHL) with waste glass powder (GP) on the physical, mechanical, and microstructural properties of NHL mortars. In the experimental study, five mixtures containing up to 50% GP were prepared to evaluate its effect on the flow, carbonation, unit weight, water absorption, porosity, ultrasonic pulse velocity, capillary water absorption, compressive strength, and microstructure of NHL mortars. The experimental results suggest that the partial replacement of NHL with GP significantly affects the properties of NHL mortars. A reduction in compressive strength was observed with increasing GP content in mortars at both early and later stages. Nevertheless, the compressive strength difference between samples containing 50% GP and the reference was found to be relatively minor at 91 days, implying an enhanced pozzolanic reaction over time. The incorporation of GP improved the consistency and capillary water absorption of mortars, while the opposite was observed for ultrasonic pulse velocity, porosity, and water absorption. The microstructural analysis revealed distinct changes in the structure of samples incorporating GP. The partial substitution of hydraulic lime with GP could be beneficial in reducing the CO2 emissions of NHL mortars.

Preparation of C-S-H seeds from waste glass powder and its effect on early performance of cement paste

This study investigates the hydrothermal synthesis of calcium silicate hydrate (C-S-H) seeds using nano-size glass powder (NGP) derived from siliceous raw materials and CaO as the calcareous precursor. The influence of varying NGP concentrations on the particle size, microstructure, and phase composition of the C-S-H seeds was systematically analyzed. The synthesized C-S-H seeds were subsequently employed as additives to evaluate their effects on the early hydration process and compressive strength development of cement paste. The results indicate that increasing the NGP concentration from 0.2 mol/L to 0.8 mol/L leads to an exponential increase in the median particle size of the C-S-H seeds from 147 nm to 1328 nm and a corresponding morphological transformation from flocculent to granular structures. Additionally, the purity of the C-S-H sample decreased from 74.8% to 54.5% as the NGP concentration increased. The addition of C-S-H seeds can increase the 12h compressive strength of cement pastes by 15.5%–53.5%. This improvement is due to the accelerated early hydration kinetics induced by the C-S-H seeds, which act as nucleation sites, thereby increasing the nucleation and growth rates by 31.4% and 53.2%, respectively.

Response tests on the effects of particle size of waste glass sand and glass powder on the mechanical and durability performance of concrete

To investigate the effect of waste glass material particle sizes on the mechanical and durability properties of concrete, a two-phase experimental approach was conducted. First, comprehensive tests were performed to examine the effects of glass sand and glass powder of different particle sizes on concrete performance. Subsequently, based on the experimental results, an orthogonal test was designed to optimize the replacement amounts of composite particle sizes. The results indicated that an appropriate amount of glass sand can enhance the mechanical properties and durability of concrete, while excessive amounts or larger particle sizes may have adverse effects. The pozzolanic effect of glass powder also contributes to performance improvement, but the replacement rate should be limited to 20%. Under composite particle size conditions, the compressive, tensile, and shear strengths of concrete increased by 35.56%, 21.74%, and 13.79%, respectively, while durability significantly improved, with water absorption reduced by 20.73% and chloride ion permeability decreased by 63.10%. At a total replacement rate of 20%, the optimal proportions were determined to be 2.86% for 0.6 mm glass sand, 1.43% for 1.18 mm glass sand, 8.57% for 50–60 μm glass powder, and 7.14% for 60–70 μm glass powder. The incorporation of composite particle sizes improved the microstructure of concrete, thereby enhancing its mechanical and durability properties.

Cold Consolidation of Pharmaceutical Waste Glass Powders Through Alkali Activation and Binder Jet 3D Printing.

The recent COVID-19 emergency has led to an impressive increase in the production of pharmaceutical vials. This has led to a parallel increase in the amounts of waste glass; manufacturers typically recover material from faulty containers by crushing, giving origin to an unrecyclable fraction. Coarse fragments are effectively reused as feedstock for glass melting; on the contrary, fine powders (<100 microns), contaminated by metal and ceramic particles due to the same crushing operations, are landfilled. Landfilling is also suggested for pharmaceutical containers after medical use. This study aims at proposing new opportunities for the recycling of fine glass particles, according to recent findings concerning alkali activation of pharmaceutical glass, combined with novel processing, i.e., binder jetting printing. It has already been shown that pharmaceutical glass, immersed in low-molarity alkaline solution (not exceeding 2.5 M NaOH), undergoes surface dissolution and hydration; cold consolidation is later achieved, upon drying at 40-60 °C, by a condensation reaction occurring at hydrated layers of adjacent particles. Binder jetting printing does not realize a full liquid immersion of the glass powders, as the attacking solution is selectively sprayed on a powder bed. Here, we discuss the tuning of key parameters, such as the molarity of the attacking solution (from 2.5 to 10 M) and the granulometry of the waste glass, to obtain stable printed blocks. In particular, the stability depends on the formation of bridges between adjacent particles consisting of strong T-O bonds (Si-O-Si, Al-O-Si, B-O-Si), while degradation products (concentrating Na ions) remain as a secondary phase, solubilized by immersion in boiling water. Such stability is achieved by operating at 5 M NaOH.

Comparative LCA-MCDA of high-strength eco-pervious concrete by using recycled waste glass materials

Sustainable management of construction and demolition (C&D) waste and waste glass (WG) presents a significant challenge in densely populated regions like Hong Kong. While the potential for using WG in concrete is acknowledged, there is limited research on how to optimally use these materials to achieve sustainability, cost-effectiveness, and mechanical integrity. This study addresses these challenges by employing an integrated life cycle assessment and multi-criteria decision analysis (LCA-MCDA) within a cradle-to-gate scope, utilizing site-specific data. The VIKOR method, known for its robust decision-making capabilities in complex environmental assessments, was used to identify optimal concrete mixtures based on environmental, economic, and mechanical performance. The results indicate that replacing 25% of natural aggregate with recycled WG materials provides the best balance across the evaluated criteria. Furthermore, additional environmental benefits can be achieved by substituting natural aggregates with recycled waste concrete aggregates. This research underscores the importance of life cycle thinking in construction materials decision-making, demonstrating that significant use of recycled WG reduces energy consumption and greenhouse gas emissions, offering a sustainable alternative to conventional concrete.

Production of lightweight geopolymer concrete with foam glass aggregate derived from cathode-ray glass waste

This work focused on producing an eco-friendly lightweight structure by recycling the cathode ray tube glass waste (CRT-GW)to prepare a foam glass aggregate (FGA) and using metakaolin to prepare a geopolymer binder (GP). The geopolymer binder replaces cement to decrease the release of gas generated during cement production. The silicon carbide (SiC) was used as a foaming agent at 1 wt% to prepare the FGA. The foaming temperature effect was investigated for the FGA characterization included: bulk density, volume expansion, apparent porosity, uniaxial compressive strength, and leaching tests for lead and barium. The foam glass aggregate was sintered at different temperatures 725 °C, 750 °C, 775 °C, and 800 °C. These temperatures were selected depending on heating microscopy analysis results, where the maximum expansion height was 119 % at 800 °C. The main characterization ranges of foam glass were: bulk density 0.58–1.26 g/cm3, volume expansion 8–77 (vol%), uniaxial compressive strengths 1.55–9.98 MPa, and thermal conductivity 0.063–0.097 W/m.K.The lightweight geopolymer (LWGP) was prepared with 30 vol% of FGA sintered at different temperatures and 70 vol% of GP. These samples hardened at room temperature. The bulk density and compressive strength were measured for the lightweight geopolymer samples after a curing time of 28 days. A higher compressive strength was 9.11 MPa with a bulk density of 1.21 g/cm3 for lightweight geopolymer-containing foam glass aggregate sintered at 775 °C.

Assessment of Various Mitigation Strategies of Alkali-Silica Reactions in Concrete Using Accelerated Mortar Test.

The widespread use of reinforced concrete continues to face challenges, particularly in mitigating alkali-silica reaction (ASR), due to its detrimental effects on concrete strength and durability. This paper investigates the effectiveness of using binary supplementary cementitious materials (SCMs) in mitigating ASR by incorporating metakaolin (MK) and waste glass powder (GP) as partial replacements for cement. Additionally, the potential of a new cement product, "NewCem Plus" (NCM), along with the use of basalt fibers and lithium, was evaluated through a 14-day accelerated mortar bar test following the ASTM C1260. This study also assessed concrete's properties such as its compressive strength and workability using the flow test. The results indicated that MK was effective, reducing expansion by 79%, 84%, and 88% with 10%, 20%, and 30% cement replacement, respectively, compared to the control mixture. On the other hand, GP showed a more modest reduction in expansion, with 10%, 20%, and 30% replacement levels reducing expansion by 20%, 43%, and 75%, respectively. Furthermore, the addition of lithium to MK significantly mitigated ASR, reducing expansion below the ASTM threshold. However, mixtures containing NewCem Plus, lithium, and basalt fibers showed minimal impact on ASR reduction. These findings underscore the viability of using binary or ternary blends of SCMs to mitigate ASR in concrete, encouraging their adoption in future concrete applications.

Analysis of waste glass as a partial substitute for coarse aggregate in self-compacting concrete: An experimental and machine learning study

With the growing environmental burden to minimize debris and recycle, the concrete industry has replaced wasted glass with concrete composition elements in multiple ways. This study provides a comprehensive analysis of integrating waste glass aggregate (WGA) at various proportions (0 %, 5 %, 10 %, 15 %, and 20 %) as substitutes for coarse aggregates along with a consistent 20 % silica fume (SF) as cement replacement in self-compacting concrete (SCC). In addition to determining the mechanical, durability and microstructural properties of SCC, this research also uses advanced machine learning (ML) techniques to predict the mechanical properties accurately. By employing slump flow, j-ring flow and v-funnel time the rheology of fresh SCC was evaluated. Mechanical properties were assessed through the evaluation of compressive, splitting tensile, and flexural strength, whereas electrical resistivity, water permeability, rapid chloride permeability (RCPT), and accelerated mortar bar test (AMBT) were employed to evaluate durability. The microstructure was further examined using scanning electron microscopic (SEM) and energy-dispersive X-ray spectroscopy (EDS) analysis. The replacement of WGA with a constant SF in SCC improved flowability while lessening its passing ability. Furthermore, the study indicated that adding 5 % WGA along with 20 % SF to SCC resulted in a slight decrease of 4.53 % in compressive strength and 3.61 % in flexural strength compared to the reference mix containing 0 % WGA and 20 % SF after 28 days, which yields a favorable outcome. Findings from further assessments revealed that SCC's durability characteristics were enhanced by adding WGA and SF. Expansion of the Ca/Si ratio observed in EDS analysis significantly impacts the strength, while voids and cracks patterns detected in SEM analysis, result in an inferior microstructural performance with the incorporation of WGA. Notwithstanding both the ML models exhibiting excellent regression coefficients (R2), the random forest model showed superior accuracy and reliability in its results.

Recent Progress on the Synthesis and Applications of Zeolites from Industrial Solid Wastes

Zeolites have been increasingly applied in various fields such as energy conversion, environmental remediation, chemical production, and so on, being used as membranes, catalysts, and supports due to their large specific areas and strong gas adsorption. And, developing low-cost strategies for the preparation of zeolites has attracted the extensive attention of researchers. Coal fly ash, waste glass, discard zeolites, and slags are typical industrial wastes and rich in Si and Al, indicating that these industrial wastes can be utilized as alternative raw materials of zeolite synthesis. Firstly, the chemical composition and properties of these industrial wastes are summarized. Then, the strategies involved in synthesizing different zeolites from various industrial wastes are discussed. In addition, the applications of these zeolites are comprehensively reviewed.

Improving mechanical and thermal properties of unsaturated polyester resin by adding automotive glass waste

Improving mechanical and thermal properties of unsaturated polyester resin by adding automotive glass waste

Concrete's fire resistance improvement with waste glass and ceramic aggregates

AbstractEven though concrete structures are safer than steel structures in terms of fire resistance, the risk exists in concrete structures by spalling or exploding, especially in high-strength concrete. This study aims to produce a particular type of concrete using waste ceramics as fine aggregate and waste glass as coarse aggregate and compare data with normal aggregate concrete. Studies show that using waste ceramic and glass increases the fire resistance of concrete. After fire exposure in the control mix, the residual compressive strength was 10 MPa. The waste aggregate concrete was found to be 26.9 MPa after 800 centigrade exposures, which was an excellent result. Waste materials decreased construction costs and led to a clean environment.

The factors influencing waste management for economic development—the perspective of Nelson Mandela bay municipality residents

The rapid increase in volume and variety of solid waste as a result of continuous economic growth, urbanization, and industrialization has become an intractable problem for the public and private sectors, making it difficult to ensure effective and sustainable waste management. The study sought to understand the perspective of Nelson Mandela Bay Municipal residents on their perceived influence of municipal waste management on economic development. The study used a quantitative techniques approach, with a structured questionnaire. Data was collected from 255 respondents. The quantitative question aimed to determine if the influence was positive or negative, and the Likert scale question had a scale of 1 to 5. This research identified various types of waste, assessed challenges, and evaluated waste's potential for resource creation. The study concluded that municipal waste includes organic, paper, plastic, metal, glass, food, garden, hazardous, construction, demolition, and non-recyclable waste. Environmental pollution is a major challenge, and 26 factors positively influence waste to wealth. Waste to wealth can be achieved through social behavior, education/knowledge, MSWM governance, and economic feasibility for MSWM. The research also highlighted the importance of land attributes, budget allocation, trained personnel, and government regulations. The framework proposed aims to minimize urban poverty while preserving the environment and supporting the present urban economy. Urban communities can utilize solid waste management as a mechanism to foster economic development. The fundamental question is whether stakeholders will continue to ignore waste's potential demands and benefits for urban economic growth.