Glass Resin Research Articles

Tribological Research of Resin Composites with the Fillers of Glass Powder and Micro-Bubbles.

This study investigates the tribological properties of resin composites reinforced with the fillers of glass powder and micro-bubbles. Resin composites were prepared with varying concentrations from 1% to 5% wt of fillers. Tribological tests were conducted using a block-on-ring scheme under dry friction conditions. The measurements of friction coefficient and wear values were performed under variable rotation speeds and loading conditions. The study showed that resin composites with 2-3% glass powder fillers and resin composites with 3-4% micro-bubbles exhibited optimal tribological properties. The resin glass powder modifications reduce the wear by 63% and resin micro-bubbles reduce wear by 32%. SEM analysis of the surfaces revealed surface imperfections and structural damage mechanisms, including abrasive and fatigue wear. The study concludes that specific filler concentrations improve the friction and wear resistance of resin composites, highlighting the importance of material preparation and surface quality in tribological performance. The increased wear resistance on both composites would hopefully expand the usage of additive manufactured composite, namely industrial moving components such as polymer gear, wheel, pulley, etc.

A systematic investigation of the transfer of polyphosphate/inorganic silicate flame retardants from epoxy resins to layered glass fiber‐reinforced composites and their post‐furnace flexural properties

AbstractThe systematic transfer of solvent‐free, additive flame retardant (FR) formulations from epoxy resins to glass fiber‐reinforced epoxy composites (GFRECs) through prepregs is difficult. Additionally, obtaining data on their post‐fire mechanics is often challenging. Utilizing melamine polyphosphate (MPP), ammonium polyphosphate (APP), and silane‐coated ammonium polyphosphate (SiAPP) FRs with low‐melting inorganic silicates (InSi) in an 8:2 proportion and 10% loading by weight in a diglycidyl ether of bisphenol A (DGEBA) resin, a systematic investigation of the processing properties, room‐temperature mechanics, and temperature‐based mechanics of the systems was performed. The resin was cured with a dicyandiamide hardener (DICY) and a urone accelerator. The results revealed no substantial impact of these FRs at the current loading on the resin's glass transition temperature or processability. However, the fire residues from cone calorimetry tests of the composites containing FRs were found to be only 15‐20% of the thickness of the resins, implying a suppression of intumescence upon transfer. At room temperature, the decrease in the flexural modulus for the composites containing FRs was negligible. Exposure of the composites in a furnace at 400°C as a preliminary study before ignition tests was shown to cause significant flexural moduli reductions after 2.5 min of exposure and complete delamination after 3 min making further testing unviable. This study emphasizes the need for future research on recovering modes of action upon transfer of FR formulations from resins to composites. Based on the challenges outlined in this investigation, sample adaptation methods for post‐fire analysis will be developed in a future study.Highlights Processibility of resins for prepreg production unaffected by polyphosphate/inorganic silicate flame retardants (FRs). FR formulations had a negligible effect on the mechanics of the composites. 15%–25% increase in the fracture toughness of the DGEBA‐based resin matrix with FRs. Suppression of intumescent behavior in the composites verified quantitatively. Significant reduction in flexural moduli of the composites post‐400°C exposure in a furnace.

Comparative study of physical-chemical properties of bioactive glass ionomer cement.

This study analyzed the physical-chemical properties of bioactive ionomer materials. Cention N bioactive materials were evaluated chemically activated (CN) and light-cured (CN-LC), Equia Forte Fill (EQUI); conventional resin composite Filtek Z350 XT (Z350); resin glass ionomer cement Riva light Cure (RIVA) and flowable resin composite Filtek Bulk Fill Flow (BULK-F) were evaluated. Sixty specimens (n=10) were prepared for sorption (SR), solubility (SL), flexural strength (FS), shrinkage stress (SS), conversion degree (CD), microhardness (MI), and surface roughness (SR) tests. Non-cured and light-cured materials were assessed on FTIR. 30 human molar teeth were used in the bond strength test (BS). Data were subjected to ANOVA and post-hoc Tukey's test (5% of significance). EQUI showed more sorption in SR and no statistical difference from RIVA and CN-LC. CN group showed more solubility and EQUI presented less (p<0.05). BULK-F showed higher FS (MPa), without differences from CN and Z350, whereas EQUI presented the lowest FS not differing from RIVA. BULK-F and CN-LC showed more shrinkage stress differing from EQUI. CN-LC and CN showed higher CD differing from the other which showed no differences (p>0.05) between them. EQUI showed the highest hardness (p<0.05) in MI. There were no differences (p>0.05) in SR (µm). Z350 and BULK-F presented higher BS, whereas CN-LC showed the lowest, although not differing from EQUI and RIVA. Equia Forte's solubility and microhardness make it a good alternative as a restorative material. Cention N degree of conversion and flexural strength making it an esthetic option to amalgam.

Tree-based machine learning approach to modelling tensile strength retention of Fibre Reinforced Polymer composites exposed to elevated temperatures

Fibre Reinforced Polymer (FRP) composites are susceptible to degradation at elevated temperatures. Accurate modelling of the tensile performance of FRP composites under high-temperature exposure is crucial for their structural integrity. In this study, tree-based models, namely, decision tree, M5P, and random forest methods, are utilised to model the impact of elevated temperatures on the tensile strength of composite materials. A database of 787 experimental results is established and processed to train and test the regression tree models. The exposure temperature, resin glass transition temperature, sample thickness/diameter, exposure duration, ambient cooling, fibre-to-resin ratio, fibre orientation, resin type, fibre type, and manufacturing process were considered as the main parameters affecting the tensile strength retention (TSR) of FRP composites after exposure to elevated temperatures. To improve the prediction performance of machine learning, Bayesian optimisation and 10-fold cross validation (CV) technique were used to train regression tree methods. The results demonstrated the accuracy of the developed models in predicting the TSR of the composites under elevated temperatures. Feature contribution analysis showed that the exposure temperature exerts the most significant impact on the TSR, with the glass transition temperature coming next in importance. These were followed by sample thickness, exposure duration, ambient cooling, fibre-to-resin ratio, and fibre orientation, respectively. Resin type, fibre type, and the manufacturing process had the least contributions to the observed variations in TSR. Examining the tensile strength retention of FRP composites at high temperatures enables the development of precise predictive models and design guidelines for their optimal use across industries.

Analysis of the mechanical properties of the single layered braid reinforced thermoplastic pipe (BRTP) for oil & gas industries

Reinforced thermoplastic pipes (RTPs) are instantly being broadly scrutinized as a feasible surrogate for metallic pipes due to their superior corrosion resistance, low weight, and low maintenance worth, they have three primary layers inner, outer, and reinforcement. Process parameters for manufacturing reinforced layers are critically essential to enhancing the mechanical performance of RTPs. However, limited comparative research on the impact of braiding parameters on RTP’s mechanical characteristics appears to be publicly available. Therefore, this study examines how these variables affect the mechanical characteristics of braid RTP. This new class of braid RTP is constructed of an HDPE liner pipe, over-wrapped with a single braid layer of resin glass fiber. L9 Taguchi orthogonal array design for experiments was used to create specimens. Furthermore, specimens were subjected to tensile and compression to assess their mechanical properties. Epoxy and ±75 were the most promising parameters in achieving the highest number of tensile and compression properties among choices of thermoplastic polymer matrices and braid angles, respectively. ANOVA suggested that both parameters are significant and significantly impact the mechanical properties of the prototype braid RTP. Also, A1B3 is considered the best combination for producing braid RTP with higher mechanical performance; no notable interaction among factors was found.

Influence of the cervical margin relocation on stress distribution -

Aim: Evaluate the influence of the cervical margin relocation (CMR) on stress distribution in the lower first molar restored with direct nano-ceramic composite (zenit). Methods: A 3D model of the lower first molar was modeled and used. Standardized mesio-occluso-distal (MOD) preparation consisted in two models used in this study with mesial subgingival margin in model II. (CMR) was applied in model II using flowable composite or resin glass ionomer (Riva). Both models were restored with nanoceramic composite and then subjected to six runs (2 for the model I and 4 for model II) with load (100N) as two load cases, one at (11º) and other at (45º) from the vertical axis. The stress distributions (FEA) in the final restoration and (CMR) material were analyzed using 3D models. Results: The two models recorded an equivalent Von Mises stress and Total deformation in the final restoration, regardless of the difference in the oblique angle incidence from (11º to 45º) or the type of the material used for (CMR) there was no significant difference in the (FEA) between the model with CMR (model II) and the model without CMR (model I). Conclusions: (CMR) technique seems to be biomechanically beneficial with high eccentric applied stress, (CMR) with resin glass ionomer or flowable composite resin in combination with nanoceramic composite improved the biomechanical behavior of (MOD) cavities extended below cement enamel junction (CMR) with high modulus elasticity material like (Riva) exhibits a more uniform stress distribution.

Effect of citric acid erosion on enamel and dentin and possible protection by a novel bioactive borate adhesive system

ObjectivesThis study examined the ability of a borate adhesive to protect enamel/dentin surfaces from acidic erosion and its effect on the shear bond strength (SBS) of enamel/dentin to resin composite. Materials and methods180 human enamel/dentin specimens were utilized. Enamel buccal surfaces were etched with phosphoric-acid then divided into: (EBG) borate glass adhesive group; (ERS) resin-adhesive system group; (EF) fluoride gel 1.23% group, and enamel control (EC) group; followed by bonding to orthodontic-buttons. The dentin specimens were conditioned by EDTA (Ethylene-diamine-tetra-acetic acid) and divided into: (DBG) borate glass resin, (DRS) resin adhesive; (DDA) group had a dentin-desensitizing agent VivaSens (VivaDent, Liechtenstein) and (DC) control group. The treated enamel/dentin specimens had their SBS to composite. The enamel/dentin specimens were exposed to 1% citric acid (18 min). Enamel/dentin specimens were examined by (SEM/EDS) scanning-electron-microscope equipped with electron-dispersive-spectroscopy and (FTIR/ATR). Analysis-of-Variance (ANOVA) was used to compare the SBS and Wilcoxon-signed-rank test was used to compare the enamel/dentin areas protected by the applied agents before/after erosion (p = 0.05). ResultsThere was no significance difference in SBS among all groups except for (DDA) group that showed significant decrease p < 0.05. (EBG) and (DBG) groups were the only groups significantly protected enamel and dentin from erosion p < 0.05. FTIR/ATR showed that erosion altered the chemical structure of (DRS), (DDA), and (DC) groups but did not affect the other enamel/dentin groups. Degree of conversion of the borate-adhesive system was acceptable. ConclusionThe Borate adhesive system released calcium and phosphate compounds that decreased the erosive activity of the citric acid resulting in protecting simulated dentin-hypersensitive areas and enamel from erosion without affecting the SBS to resin-composite. Clinical significanceA Borate adhesive system can be adopted as a therapeutic agent in a fully integrated program for protecting dentin-hypersensitive areas and in enamel next to orthodontic fixed appliances.

Oligonucleotide Synthesis on Porous Glass Resins Containing Activators.

For the advancement of nucleic acid-related research, high-efficiency, low-cost synthesis of high-purity oligonucleotides is necessary. Herein, we introduced hydroxybenzotriazole (HOBt) activators on controlled pore glass resins to improve the efficiency of chain elongation (the synthesis efficiency increased from 48% without an activator to 92% with an activator). In particular, the use of the resin containing 6-trifluoromethyl HOBt with a linker of lauric acid and succinic acid significantly improved the synthesis efficiency for both DNA and RNA syntheses.

Investigation of Accelerated Degradation Methods to Cause Blisters for Non-Defective Vinyl Ester Resin Glass Flake Organic Coatings

Organic coatings are applied as a corrosion prevention measure, but their effectiveness may degrade over time. In this study, the acceleration effects of typical degradation methods in non-defective vinyl ester resin organic coatings containing glass flakes such as high-temperature immersion and immersion in chemical accelerators are clarified using physiochemical techniques. Immersion in an acetic acid (AcOH) aqueous solution causes resin swelling, and the behaviors are quantitatively evaluated through gravimetric, thickness, and electrochemical impedance spectroscopy (EIS) measurements. Furthermore, a combined process of immersion in hydrofluoric acid and an AcOH aqueous solution reduces the electrical properties and eventually blisters the thick coating surface. This result suggests that an appropriate combination of the resin swelling and the glass degradation (glass dissolution and/or formation of the gap between glass and resin) decrease mechanical properties of the glass flake coating and causes blisters. In order to help the health diagnosis of the visually non-defective aged glass flake coating, the relationship between the electrical characteristic values and the invisible degradation by accelerated tests is finally indicated.

Accurate predictions of thermoset resin glass transition temperatures from all-atom molecular dynamics simulation.

To enable the design and development of the next generation of high-performance composite materials, there is a need to establish improved computational simulation protocols for accurate and efficient prediction of physical, mechanical, and thermal properties of thermoset resins. This is especially true for the prediction of glass transition temperature (Tg), as there are many discrepancies in the literature regarding simulation protocols and the use of cooling rate correction factors for predicting values using molecular dynamics (MD) simulation. The objectives of this study are to demonstrate accurate prediction the Tg with MD without the use of cooling rate correction factors and to establish the influence of simulated conformational state and heating/cooling cycles on physical, mechanical, and thermal properties predicted with MD. The experimentally-validated MD results indicate that accurate predictions of Tg, elastic modulus, strength, and coefficient of thermal expansion are highly reliant upon establishing MD models with mass densities that match experiment within 2%. The results also indicate the cooling rate correction factors, model building within different conformational states, and the choice of heating/cooling simulation runs do not provide statistically significant differences in the accurate prediction of Tg values, given the typical scatter observed in MD predictions of amorphous polymer properties.

Retention of cemented zirconia copings on TiBase abutments.

This study evaluated the influence of resin cements and glass ionomers on tensile strength and types of failure of zirconia copings cemented on titanium base abutments. Forty-two samples were prepared, which were formed by a Cone Morse implant, a titanium abutment with the fixing screw, and a zirconia structure made using a CAD/CAM system. The samples (n = 42) were randomly distributed according to the cementing agent: resin-modified glass ionomer cement (RelyX Luting 2), self-adhesive resin cement (RelyX U200), and self-curing resin cement (Multilink N). After cementation of the copings, half of the samples from each group (n = 7) were randomly selected and subjected to thermocycling (5000 cycles). A tensile load test was performed on a universal testing machine until failure occurred (1 mm). In addition, the type of failure was analyzed using the two-way analysis of variance test and Tukey's post-hoc test (α = 0.05). Lower tensile load was observed for the glass ionomer cement (p < 0.001) regardless of the evaluation period. After thermocycling, a significant reduction in tensile load values was verified for both evaluated cements (p = 0.047). For the resin cements, failures were predominantly of the screw fracture type (82.1%) already with the use of glass ionomer cement, and 28.5% of the failures were of an adhesive type between the zirconia coping and the cement. Resin cements have better stability under tensile load compared to resin glass ionomers when cementing zirconia copings on titanium base abutments.

Fracture Resistance and Strain Analysis of Zirconia Copings With Vertical Knife Edge and Three Horizontal Finish Line Designs; Chamfer, Deep Chamfer and Shoulder With Two Cementation Techniques

Objective: The purpose of this in vitro study is to evaluate the effect of four finish line configurations and two cement types on the fracture resistance of zirconia copings. Material and Methods: Forty yttrium tetragonal zirconia polycrystals copings were manufactured on epoxy resin dies with four preparation designs: knife edge, chamfer, deep chamfer 0.5, 1 mm and shoulder 1 mm. The copings were cemented with two cement types (glass ionomer and resin cement); (n = 5). Two strain gauges were attached on each coping before they were vertically loaded till fracture with a universal testing machine. Data were analyzed by 2-way analysis of variance ANOVA (p &lt; .05). Fractured specimens were examined for mode of failure with digital microscope. Results: Knife edge showed the highest mean fracture resistance (987.04 ± 94.18) followed by Chamfer (883.28 ± 205.42) followed by Shoulder (828.64 ± 227.79) and finally Deep chamfer finish line (767.66 ± 207.09) with no statistically significant difference. Resin cemented copings had higher mean Fracture resistance (911.76 ± 167.95) than glass ionomer cemented copings (821.55 ± 224.24) with no statistically significant difference. Knife edge had the highest strain mean values on the buccal (374.04 ± 195.43) and lingual (235.80 ± 103.46) surface. Shoulder finish line showed the lowest mean strain values on the buccal (127.47 ± 40.32) and lingual (68.35 ± 80.68) with no statistically significant difference. Resin cemented copings had higher buccal (295.05 ± 167.92) and lingual (197.38 ± 99.85) mean strain values than glass ionomer copings (149.14 ± 60.94) and (90.27 ± 55.62) with no statistically significant difference. Conclusion: Vertical knife edge finish line is a promising alternative and either adhesive or conventional cementation can be used with zirconia copings. KEYWORDS Cementation; Flexural strength; Prosthodontics; Tooth preparation; Zirconium.

WITHDRAWN: Impact of riboflavin and curcumin mediated photodynamic therapy and Er,Cr:YSGG on microleakage of class V resin glass ionomer restorations in permanent molar teeth

The present study aimed to evaluate the impact of PDT using curcumin and riboflavin as photosensitizers and Er,Cr:YSGG on microleakage in class V RMGIC restorations in permanent teeth. Eighty permanent molars were investigated and randomly divided into 4 groups: control group: resin-modified glass ionomer restoration with no treatment, R-PDT: PDT with riboflavin, Cu-PDT: PDT with curcumin (Cu) and, Er,Cr:YSGG: laser application. All the teeth in each group were restored with the help of RMGIC. The samples were dipped for 24 h in 0.5 % Fuchsine solution, and subsequently fixed in acrylic resin-based molds. Microleakage scores were estimated considering both cervical and occlusal boundaries. Intergroup comparisons were made at each margin, and intragroup comparisons made at the cervical and occlusal margins. The Shapiro Wilk test was used to check the normality of the values. Whereas, the analysis of data was conducted using SPSS version 25 via the Kruskal-Wallis and Wilcoxon tests. P < 0.05 was contemplated to be statistically important. A high frequency (95%) of the enamel walls were not penetrated when subjected to treatment with R-PDT, followed by Cu-PDT and Er,Cr:YSGG. The highest amount of microleakage was observed (55%) Cu-PDT at the site of the cavity near the cementum. The least amount of microleakage was observed in the control group. A statistically significant difference in microleakage was noted at the cervical wall (p=0.015), while no significant difference was seen at the occlusal wall (p=0.789) between the groups. A significant difference was noted at the cervical wall between the control and R-PDT group (p=0.021) and Cu-PDT group (p=0.005), respectively. A significant difference in microleakage was observed when occlusal was compared with cervical walls within each group (p<0.05). Photosensitizers using riboflavin and curcumin may reduce the microleakage within the enamel surface restored with RMGIC in class V lesions that may not interfere with bonding. However, extreme caution should be taken while considering riboflavin and curcumin for class V RMGIC restorations extending to cementum surface.

Perceptions of dental therapy students regarding the teaching and training with dental amalgam, in a dental school in KwaZulu-Natal, South Africa

Dental amalgam has been used as a restorative material in dentistry for the past 150 years. This material has been used to restore posterior teeth throughout the world and is also used in South Africa. Dental amalgam has been the material of choice for patients presenting with large tooth decay areas, including the loss of cuspal areas. The reason for this is that dental amalgam was always considered strong and durable. Compared to alternate dental materials, this material could also withstand the significant forces associated with chewing and biting. Dental amalgam is also considered more cost-effective than alternate dental materials such as conventional glass ionomers, resin-modified glass ionomers, resin composite and ceramic restorations, making it more feasible and material of choice in lower economic countries, including South Africa.

Bond strength and Weibull analysis of fiber posts luted with different cement types and mechanically aged

This study aimed to evaluate the influence of cement type and mechanical cycling on the push-out bond strength (σ) of fiber posts luted to root canals. Eighty bovine single-root teeth were prepared and the roots were included with chemically cured acrylic resin. The specimens were allocated into 8 groups (n = 10) considering the factors ‘cement’ (glass ionomer cement – GIC, resin reinforced glass ionomer cement – RRGIC, conventional dual-cure resin cement – CRC, and self-adhesive resin cement – SARC) and ‘mechanical cycling’ (non-aged and aged – mc). The fiber posts and roots dentin were treated according to the cement type and luted to root canals. Composite-cores were made for the groups submitted to mechanical cycling (1,000,000 cycles, 84 N, 4 Hz). Each root were cut into 4 disk-samples of 1.8 mm (thickness) and submitted to push-out testing. Data (MPa) were analyzed using two-way ANOVA, Tukey test (5%), and Weibull analysis. ANOVA revealed that cement (p < 0.001) was significant; however, the mechanical cycling had no effect on bond strength (p = 0.895). The CRC (4.36 ± 1.15 MPa), CRCmc (4.13 ± 0.75 MPa), GIC (4.29 ± 2.14 MPa), and GICmc (4.04 ± 1.18 MPa) groups showed higher (σ) than RRGIC (2.36 ± 1.00 MPa). Weibull Characteristic strength of the CRC and CRCmc were significantly higher than RRGICmc, and RRGIC. The mixed type of failure was the most common. Conventional dual-cure resin cement and glass ionomer cement presented higher push-out bond strength to root dentin regardless of mechanical cycling.

Reinforcement effect of intra-orifice barrier materials in teeth treated with regenerative endodontic procedure: Research article.

Background. Regenerative endodontic treatment (RET) is a clinically advanced procedure for necrotic immature teeth. However, root canal walls of these teeth are brittle especially in the cervical region and need reinforcement. This in vitro study is conducted to evaluate the effect of intra-orifice barrier materials on the fracture resistance of immature teeth treated with regenerative procedure. Methods. Forty-eight maxillary central incisors were used. Twelve intact teeth were selected for the control group. Remained teeth were prepared using peeso drills to simulate immature teeth and assigned into three groups according to the intra-orifice barrier material placed over MTA (n = 12); Composite resin (CR), ProRoot MTA and Resin-modified glass ionomer cement (RMGIC). Fracture strength test was applied using a universal testing machine. One-way ANOVA and Tukey post hoc tests were used at P = 0.05. Results. A significant difference was obtained among groups (P < 0.05). MTA showed the lowest fracture resistance (P < 0.05). However, no significant difference was found among RMGIC, CR, and control groups (P > 0.05). Conclusion. Intra-orifice restorative materials have reinforcement affect in immature teeth treated with regenerative endodontic procedure. RMGIC or CR can be regarded as a viable choice to reduce the occurrence of cervical root fracture of immature teeth treated with a regenerative therapy.

A study of the optical transmission spectra of polyester resin-based glass fabricated by open mold cast technique

Polyester resin is a thermoset resin commonly used in the production of polymer composites. Polyester resin is a polymer matrix that is easily available and widely used by the general public and industry. Besides, this resin is cheap, has unique characteristics, namely that it can be made rigid and flexible. This research aimed to investigate the optical transmission spectra of polyester resin-based glass fabricated by open mold casting technique with different MEKPO or methyl ethyl ketone peroxide concentrations in the visible region. This research used Yukalac C 108B polyester resin. Catalyst MEKPO was added with three variations, 1%, 2%, and 5%. The prepared mixture was then set at 30 Celsius degree and 1000 RPM for five minutes by a magnetic stirrer. The optical transmission spectra of the glass were measured using optical emission spectroscopy. The result shows that the optical spectra of this polyester resin-based glass possess higher transmission in the region at 650 nm to 700 nm and the amount of catalyst that can produce polyester resin glass material by open mold cast technique with higher optical properties at 1% catalyst composition.

Mechanical Properties of Fibre Reinforced Polymers under Elevated Temperatures: An Overview

Fibre-reinforced polymer (FRP) composite is one of the most applicable materials used in civil infrastructures, as it has been proven advantageous in terms of high strength and stiffness to weight ratio and anti-corrosion. The performance of FRP under elevated temperatures has gained significant attention among academia and industry. A comprehensive review on experimental and numerical studies investigating the mechanical performance of FRP composites subjected to elevated temperatures, ranging from ambient to fire condition, is presented in this paper. Over 100 research papers on the mechanical properties of FRP materials including tensile, compressive, flexural and shear strengths and moduli are reviewed. Although they report dispersed data, several interesting conclusions can be drawn from these studies. In general, exposure to elevated temperatures near and above the resin glass transition temperature, Tg, has detrimental effects on the mechanical characteristics of FRP materials. On the other hand, elevated temperatures below Tg can cause low levels of degradation. Discussions are made on degradation mechanisms of different FRP members. This review outlines recommendations for future works. The behaviour of FRP composites under elevated temperatures provides a comprehensive understanding based on the database presented. In addition, a foundation for determining predictive models for FRP materials exposed to elevated temperatures could be laid using the finding that this review presents.

The effects of modified zinc oxide nanoparticles on the mechanical/thermal properties of epoxy resin

AbstractCharacterized by its strength, durability, and thermal properties, epoxy resin has been widely used as an adhesive, paint, and coating in many applications in the aerospace, civil and automotive industries. Despite this, the thermoset polymer resin has been known for its brittleness and low fracture resistance. This study focuses on the reinforcement of an epoxy resin system (diglycidyl ether of bisphenol A) with zinc oxide (ZnO) nanoparticles in their pristine form and a further modified form. The modification took place in two ways: coating with polydopamine (PDA) and covalently functionalizing them with (3‐aminopropyl)triethoxysilane (APTES) and (3‐glycidoxypropyl)trimethoxysilane (GPTMS). Therefore, four different types of nanoparticles were used: pristine ZnO, ZnO/PDA, ZnO/GPTMS, and ZnO/APTES aiming to improve the interfacial bonding between the polymeric matrix and the reinforcement. Thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy, and scanning electron microscopy characterization and imaging techniques were used to prove that the ZnO nanoparticles were successfully modified prior to manufacturing the epoxy composites. While tensile testing showed that using pristine ZnO increases the composite's strength by 32.14%, the fracture toughness of the resin was improved by 9.40% when reinforced with ZnO functionalized with APTES. TGA showed that the addition of functionalized nanoparticles increases the material's degradation temperature by at most 7.31 ± 4.9°C using ZnO/APTES. Differential scanning calorimetry and dynamic mechanical analysis testing proved that the addition of any type of nanoparticles increases the resin's glass transition temperature by as much as 7.83°C (ZnO/APTES).

Study on Effect of Abrasive Water Jet Machining Process Parameter on Taper Angle during Machining of Epoxy Resin Glass Fibre

Abrasive Water Jet Machining (AWJM) is one of the most advanced machining processes, which has the ability to machine various materials. In this paper, experiment was performed on cutting of epoxy fibre glass by AWJM. Epoxy fibre glass is a composite which consists of fibre glass cloth and epoxy resin as binder, achieved under specific heat and pressure. There are various process parameters such as water pressure, standoff distance, abrasive flow rate, traverse rate, abrasive etc. The water pressure and standoff distance was varied while performing the experiment and rest all parameters were kept constant. From this experiment taper angle was measured and it was observed that taper angle increases as the standoff distance increases, this is because the shape of the jet diverges with larger standoff distance. Minimum taper angle was observed as 0.34° at 32 ksi pressure, having 2 mm standoff distance. It was also observed that width of cut has significant effect on taper angle. From further calculations, the deviation of the cut slot for top width was observed as +1% to 5% and for bottom width it was -1% to 2%.