Glass Fiber Reinforced Polymer Research Articles

Improving mode I fracture response of glass fiber-epoxy composite adhesive joints using sanding treatment and MWCNTs inclusion

This study investigates the enhancement of fracture behavior in laminated composites using a combination of surface treatments and nanomaterial incorporation. The adherent material used is glass fiber-reinforced polymer (GFRP), and the surface treatment was applied to the GFRP surface. The adhesive used in the joints is an epoxy-based adhesive, which was reinforced with Multi-Walled Carbon Nanotubes (MWCNTs) to improve its mechanical properties. Initially, mechanical sanding techniques were explored, revealing significant improvements of 55% in fracture energy and 38% in load-bearing capacity with optimal 240-grit sanding. Subsequently, MWCNTs were introduced at varying weight percentages (0.1%, 0.3%, and 0.5%) into the adhesive. This combined approach aimed to synergistically examine the impact of surface pretreatments and nanoparticle integration on the fracture behavior of the GFRP joints. Results highlight the potential for fracture resistance and enhanced load-carrying capabilities in reinforced specimens, with maximum load and fracture energy improvements of up to 92% and 50%, respectively, compared to unreinforced specimens and those subjected solely to sanding treatments. Moreover, the shift in failure mode from adhesive failure to cohesive substrate failure was observed and is attributed to the enhanced bonding area created by the 240-grit sanding and the increased fracture resistance from the incorporation of 0.3 wt% MWCNTs. The inclusion of MWCNTs provides additional toughening mechanisms such as crack bridging and pull-out, which significantly increase the fracture energy. This comprehensive investigation underscores the intricate interplay between mechanical preparation and nanomaterial incorporation in significantly improving the performance of laminated composites.

Mathematical Morphology on Directional Data

AbstractWe define morphological operators and filters for directional images whose pixel values are unit vectors. This requires an ordering relation for unit vectors which is obtained by using depth functions. They provide a centre-outward ordering with respect to a specified centre vector. We apply our operators on synthetic directional images and compare them with classical morphological operators for grey-scale images. As application examples, we enhance the fault region in a compressed glass foam and segment misaligned fibre regions of glass fibre-reinforced polymers.

Mechanical properties of GFRP bars exposed to natural erosion environment: A case study

Unlike traditional steel bars, the long-term performance of GFRP (glass fiber reinforced plastic) bars in natural erosion environments remains unclear. This study simulated the water environment at the entrance of the Chai River, a tributary to Dianchi Lake in China, and investigated the mechanical properties of GFRP bars under varying corrosion concentrations. Microstructural analysis using SEM (scanning electronic microscopy) was also conducted to uncover the degradation mechanism. The results showed that after 180 days of immersion in natural water and exposure to environmental concentrations of 5 times, 10 times, and 20 times, the tensile strength of GFRP bars exhibited reductions of 2.8 %, 4.2 %, 7.2 %, and 9.5 %, respectively. However, the compressive strength decreased by 38.0 %, 48.6 %, 50.2 %, and 53.2 % under the same condition. As the number of corrosion cycles increased, the rate of strength decline decreased gradually. The combined action of hydroxyl ions generated through bicarbonate hydrolysis and water molecules in the solution led to the breakdown and swelling of the resin matrix, ultimately causing detachment at the fiber-resin interface. An analysis was conducted on the time-shifted regression equation of the accelerated conversion factor (ASF) under different concentrations, based on the correlation between natural erosion and acceleration testing. It was observed that a strong correlation exists between the strength retention rate and the natural erosion environment at 5 times the concentration. Finally, an improved time-shift method based on the Arrhenius theory was proposed to predict the tensile strength of GFRP bars in a natural erosion environment.

Rubber concrete reinforced with macro fibers recycled from waste GFRP composites: Mechanical properties and environmental impact analysis

With the rapid growth of the automotive industry, a huge amount of tires have been produced, which inevitably led to the accumulation of scrap tires. A typical disposal routine is using scrap tires as a partial substitute for fine aggregate in concrete, producing so-called rubber concrete. However, the detrimental effects of rubber particles on concrete properties have been identified, which, to some content, hinders their broader application. The discrete fiber addition is shown to be effective in minimizing this detrimental effect, and this paper has therefore attempted to introduce macro fiber produced from waste glass fiber reinforced polymer (GFRP) into the rubber concrete system. Three series of specimens for compression, splitting, and flexural testing were tested. The test variables include concrete type (i.e., normal concrete, rubber concrete, and modified rubber concrete); and macro fiber content (i.e., 0–2 %). In addition, the inverse analysis is performed to transform the flexural test response into the tensile constitutive law of the fiber-reinforced concrete (FRC). The test results revealed macro fibers have little effect on the compressive strength of normal concrete and rubber concrete and a detrimental effect on that of modified rubber concrete. Incorporated fibers notably improve the splitting and flexural performance of normal concrete and rubber concrete. In addition, the cost and environmental impact analysis revealed that the addition of recycling products increases the concrete cost and results in a maximum reduction of carbon emissions by 17.3 % and embodied energy emissions by 80 %.

Sandwich-structured electrospun polyvinylidene difluoride sensor for structural health monitoring of glass fiber reinforced polymer composites

Stress monitoring and interlaminar failure detection attract much attention in glass fiber reinforced polymer (GFRP) structural health monitoring area. However, due to limitations of sensing or electrode materials, existing embedding sensors cannot be designed to have both of the abilities without sacrificing mechanical properties. This work fabricated a sandwich-structured sensor, which is composed of three layers of electrospun polyvinylidene difluoride membranes. The upper and lower electrodes are flexible membranes that ensure stable signal collection in the rigid GFRP material system. The sensor can quantitatively monitor the stress based on piezoelectric effect, and interlaminar crack propagation based on parallel plate capacitors. The voltage and capacitance values have a linear relationship with the stress level and crack length (R-square of the functions is 0.999 and 0.933), respectively. Due to the porous microstructure of electrospun membranes, polymer matric can well infiltrate the polyvinylidene difluoride nanofibers while preparing the sensor embedded GFRP. Thus, the perfect bonding of the sensor within GFRP ensures the effective sensing abilities until sample failure and negligible effect (< -7%) on the mechanical properties of GFRP.

Strengthening of RC Beam with GFRP Composites in Shear N. B. Bhopale

The rehabilitation, repair and strengthening of existing reinforced concrete (RC) structures is essential due to factors such as aging, steel reinforcement corrosion, construction/design defects, increased service loads demand, seismic events, and advancements in design guidelines. Fiber-reinforced polymers (FRP) are now being recognized as a promising material for the rehabilitation of such structures, through strengthening or repairing. In buildings and bridges, RC sections are commonly found in the form of beams and girders. Shear failure of RC beams is particularly due to its sudden occurrence without warning. Therefore, the utilization of externally bonded (EB) FRP composites for shear strengthening of RC beams has gathered popularity as a structural enhancement technique, primarily due to advantages of FRP composites, such as high strength-to- weight ratio and exceptional corrosion resistance. In addition, FRP repair systems give a cost-saving choice to traditional repair methods and materials. A study was performed to analyse the shear characteristics of RC beams enhanced with continuous glass fiber-reinforced polymer (GFRP) sheets. Reinforced concrete beams externally bonded GFRP sheets subjected to failure using a symmetrical two-point concentrated static loading system. The experimental data obtained included load, deflection, and failure modes of each beam, along with the effect of the number of GFRP layers on the beams The failures observed in strengthened beams typically commence with the debonding of the FRP sheets, followed by brittle shear failure. The shear capacities of these beams were higher than that of the control beam.

Recovery and restoration of glass fibers from end‐of‐life composite waste through pyrolysis and partial oxidation processes combined with hot alkaline surface treatments

AbstractEnvironmental hazards caused by the ever‐increasing end‐of‐life (EoL) glass fiber reinforced polymer (GFRPs) composite waste is of major concern for the sustainable development of the industry. Compared to land filling or incineration, pyrolysis is one of the most promising environmentally friendly methods of disposal of EoL GFRPs. Pyrolysis not only results in recovery of clean glass fibers but other valuable products, such as oils. However, long processing time at elevated temperature leads to aggravation of already existed surface flaws along with the structural changes. Therefore, thermal conditioning of glass fibers results in severe deterioration of the strength in recovered fibers and hence limiting the use of recovered fibers to low end‐products. In this study, a new strategy was adopted where instead of complete cleaning of the fibers at pyrolysis stage, the fibers were partially oxidized and the complete removal of char from the surface of glass was done during hot alkaline etching. This strategy was opted to enhance the quality of the required fibers while reducing the processing time. The results showed ~200% increase in strength of fibers after the combined treatment of pyrolysis and post etching compared to the just pyrolyzed samples with etching time of just 1 min.Highlights End‐of‐life panels of GFRPs were pyrolyzed under inert environment of Argon. Residual char was partially removed through post oxidation under flowing air. Hot alkaline etching resulted in complete removal of char and surface defects. Partial oxidation and short etching cycles resulted in improved strength of recovered glass fibers.

Predicting shear strength of fiber-reinforced concrete beams reinforced with longitudinal FRP bars with machine learning techniques

ABSTRACT This study investigates the shear strength prediction of Fibre-Reinforced Concrete (FRC) beams reinforced with Fibre-Reinforced Polymer (FRP) bars and without stirrups through the application of Machine Learning (ML) techniques. The utilisation of FRP bars, particularly Glass Fibre-Reinforced Polymer (GFRP) and Basalt Fibre-Reinforced Polymer (BFRP) bars, has emerged as a promising alternative to traditional steel reinforcement due to their superior mechanical properties and corrosion resistance. Moreover, the incorporation of macro- and micro-discrete fibres into concrete compositions enhances both shear and flexural behaviour while reducing crack propagation induced by tensile stresses. The primary objective of this research is to develop accurate predictive models for the shear capacity of FRP-reinforced concrete beams, considering various influential parameters. Six different ML techniques, namely Multiple Linear Regression (MLR), Gaussian Process Regression (GPR), k-Nearest Neighbors (KNN), Support Vector Machines (SVMs), Artificial Neural Networks (ANNs) and Random Forest Regression (RFR), are employed to analyse the complex interactions between input variables, such as fibre type, bar diameter, concrete compressive strength, beam dimensions and the resulting shear strength. By leveraging these computational approaches, we aim to overcome the limitations of conventional analytical methods and provide robust predictions for structural design and optimisation.

Comparison of mechanical behavior of slabs reinforced with GFRP and steel

The objective of this study is to evaluate the mechanical behavior of GRFP in massive concrete slabs. The use of glass fiber reinforced polymer (GFRP) rebars in construction design has been an alternative technique to provide more durable structures. However, there is a need to evaluate the behavior of GFRP reinforced slabs under flexure and to compare the service state (SS) and ultimate service state (USS) of the loaded element. Thus, reinforced concrete slabs of varying thicknesses were constructed with steel and GFRP rebars. Results show that the applied load for maximum span deflection of the GFRP slab under SS was 50% lower than for the one with steel reinforcement. The maximum span deflection of the GFRP slab under USS was also 282% larger than for steel rebars reinforcement.

The impact of various curing methods on the curing process of polymer-fiber composites analyzed using analytical approach

Ti/Gf/Cf represents a novel form of hybrid fiber metal laminates (HFMLs) that successfully blend the benefits of titanium alloy, glass fiber reinforced plastic (GFRP), and carbon fiber reinforced plastic (CFRP). These materials have garnered attention in the field of engineering due to their exceptional levels of stiffness, strength, and shear resistance. The quality of HFMLs during the curing process was significantly impacted by the chosen curing method. Moreover, the use of multiple types of fibers complicated the optimization of curing parameters in HFMLs. A comprehensive study was conducted using a multi-physics field coupling finite element method to investigate the impact of various curing methods on the development of temperature distribution, curing degree, and curing stress in HFMLs during the curing process. By integrating thermal transmission equations, curing kinetics, and viscoelastic mechanical models, a detailed curing simulation model was established. Increasing the cooling rate from 1 °C to 5 °C was shown to raise the maximum curing stress by 4.7 MPa. Additionally, higher curing temperatures were found to induce internal curing stress due to variations in thermal properties. Insufficient insulation times were observed to exacerbate non-uniform temperature distribution and curing degree fields in HFMLs, potentially leading to increased internal stress. To mitigate the generation of large residual stress, it is recommended to lower the heating and cooling rates, reduce curing temperatures, and extend the insulation time appropriately during the curing process of HFMLs. The primary goal of this research was to accurately predict the evolution of curing parameters in HFMLs under different curing regimes, which were impacted by the chosen curing method. The results of the study demonstrated that rapid changes in temperature during heating and cooling stages can lead to uneven curing, resulting in the accumulation of residual stress within the laminates.

Effect of the Glass Fiber Orientation on Mechanical Performance of Epoxy based Composites

Composites are one of the most advanced and adaptable engineering materials. The strength of any composite depends upon volume/weight fraction of reinforcement, orientation angle and other factors. The present work focuses on the determination of the mechanical properties of pure epoxy and unidirectional glass fiber reinforced epoxy. Nowadays, glass fibers are being used in several engineering applications like electronics, aviation, automobile, sport industry etc. Glass fibers are having excellent properties like high strength, flexibility, stiffness, and resistance to chemical attack. With an increase in the content of unidirectional glass fiber volume the properties of unidirectional glass Fiber Reinforcement Polymer (GFRP) composite were improved. It may be used in different forms like chopped, woven mat, short fibers and long fibers etc. Each type of glass fiber has unique properties and is used for different applications. The mechanical and thermal properties of various polymer composites reinforced with glass fibers when subjected to mechanical loading have been studied and reported.

Understanding Impact Resistance of Hollow Core Slabs Using FRP Retrofitting. A Comparative Analysis of GFRP And CFRP

Abstract Sudden Impact of structural events poses a significant threat to life safety and structural stability. In other words, the local failure(s) of structures can lead to the collapse of other members and eventually a partial or total collapse. Impact load is one of the extreme loads that are not usually taken into design consideration because of its high cost to be prevented unless the usage of the building dictates this extra care. Hollow core slabs, while offering advantages in terms of weight and construction efficiency, are particularly vulnerable to localized damage in comparison with other slab systems to localized damage, which could lead to progressive collapse. This research investigates the effectiveness of Fiber Reinforced Polymer (FRP) retrofitting techniques in enhancing the impact of resistance of hollow core slabs, aiming to mitigate progressive collapse risks and improve structure resilience. In this paper, the significance of FRP retrofitting techniques and properties for different types have been discussed and compared, focusing on Glass Fiber-Reinforced Polymer (GFRP) and carbon Fiber-Reinforced Polymer (CFRP). By evaluating various case studies, experimental analyses, and numerical simulations, the effectiveness, durability, and performance of FRP retrofitting strategies are examined as well to show the most suitable material for resisting impact load. The findings of this study will provide valuable guidance for engineers and designers in selecting the most suitable FRP material for retrofitting hollow core slabs, enhancing structural integrity and safety against impact loading. Furthermore, this research identifies research gaps and potential areas for further investigation, contributing to the development of a more effective and resilient research orientation for enhanced structure systems.

Structural Behavior of Reinforced Concrete Columns Fully and Partially Reinforced with GFRP Bars Tested Under Concentric or Eccentric Compressive Loads

Concrete columns reinforced with glass fiber-reinforced polymer (GFRP) bars have been greatly interesting recently. The distinct properties of GFRP bars, such as high tensile strength and low modulus of elasticity compared to steel bars, as well as the linear stress-strain behavior, make the study of GFRP-reinforced concrete (FRP-RC) columns important. This paper investigates the structural behavior of column specimens reinforced by fully and partially GFRP bars subjected to concentric and eccentrically applied Compressive loads. 12 columns were reinforced by (36%, 64%, and 100%) of the GFRP bars ratio, and the control specimen was reinforced by conventional steel rebars; all specimens were tested under different eccentric ratios (e/h) 0, 0.66, and 1. The failure mode, the relation between the axial load and the average axial displacement, and a comparison between the experimental results and the theoretical interaction diagram for columns were presented and discussed. The results show that most of the failure in specimens occurs as a compressive failure, and it fails in the weakest region by crushing concrete, as well as kinking in GFRP bars. Using GFRP bars significantly increases the axial displacement values compared to the steel rebars in longitudinal reinforcement and decreases the failure load for specimens with an increase in the ratio of GFRP bars. The average axial displacement value for columns specimens tested under eccentric load at e/h equal to 0.66 and 1 decreases by 75% and 94.4% compared with the control specimen.

Finite Element Analysis of Reinforced Concrete Beams Strengthened with Hybrid Fiber Reinforced Polymer Systems using ANSYS

Background: Existing reinforced concrete (RC) structures can deteriorate over time due to aging, poor construction design, natural disasters, etc. In recent years, fiber-reinforced polymer (FRP) composite materials are becoming a preferred choice for concrete construction repair due to their durability, high strength, and corrosion resistance. This study aimed to study and analyze the properties of the constituent materials to identify any weaknesses and potential improvements. Methods: The present study investigated the effectiveness of flexural strengthening of RC beams using a hybrid grouping of glass-FRP (GFRP) and carbon-FRP (CFRP) unidirectional laminates. ANSYS finite element analysis (FE) software was used to investigate the failure modes of the beams and the stress-strain parameters. The impact of adopting two different grades of reinforcing bars in RC beam modeling was also contrasted in the study. Results: Comparisons between the finite element analysis and experimental literature results were made. Based on the test findings, it could be concluded that retrofitted beams perform better than non-retrofitted beams. According to experimental results, the HY14 sheet enhanced beam had a 188.46% higher ultimate load than the unenhanced beams. Conclusion: Comparing experimental findings to the conclusions of the numerical analysis, a maximum difference of ultimate load and deflection at mid-span of 3.40% and 4.91%, respectively, were used to assess the accuracy of the results.

Experimental and numerical investigation of bias performance of steel fiber-reinforced GRC-CFFT columns

Geopolymer concrete-filled glass fiber-reinforced polymer (GFRP) tube columns show significant potential in marine engineering due to their excellent durability and mechanical properties. This study investigated the bias performance of steel fiber-reinforced geopolymer recycled aggregate concrete-filled GFRP tube (SGRC-CFFT) columns, considering variables such as load eccentricity, GFRP tube thickness, fiber winding angle, and recycled coarse aggregate (RCA) replacement rate. The failure modes, load-displacement behaviors, and strain distribution were analyzed and discussed. Furthermore, a high-precision finite element model was established based on the test data. The test results indicated that increasing load eccentricity significantly reduced both the load-bearing and axial deformation capacity of CFFT columns. When the load eccentricity reached 0.40, the peak load of the specimen was only 39 % of that of the corresponding axial compression specimen. A higher RCA replacement rate would cause a more pronounced reduction in bias-bearing capacity, with a maximum decrease of 24.6 %. Before 80 % of the peak load, the axial deformation of the column mid-span section accorded to the plane section assumption. Due to the eccentric load, the hoop deformation of the CFFT column was concentrated on the compression side. The fiber winding angle was the critical factor influencing both the peak load and the peak moment of the biased SGRC-CFFT column.

Experimental and analytical investigations on debonding response of embedded through-section ribbed GFRP bar-to-concrete joints at elevated temperatures

Embedded Through-Section (ETS) technique has gained a great deal of increasing interest in the shear strengthening of existing reinforced concrete members, which is based on using fibre-reinforced polymer (FRP) bars installed through predrilled holes into concrete via adhesive. One of the key issues associated with the bonding of ETS FRP bars to concrete is the debonding of FRP bar-to-concrete interfaces which leads to premature and brittle failure of strengthened members, particularly under elevated temperatures. However, little research has been conducted on the influence of elevated temperatures on the bond behavior between ETS FRP bars and concrete. This paper presents experimental and analytical evaluations of the bond response of ETS-ribbed glass FRP (GFRP) bar-to-concrete joints subjected to elevated temperatures. A total of 90 pullout specimens were tested to quantify the influences of the temperature, bar diameter, and concrete strength on the failure mode, load response and bond strength. An analytical model to reproduce the full-range debonding process of ETS-GFRP bar-to-concrete interfaces was presented, which allowed simultaneously considering both long and short embedded lengths, interfacial friction, and snap-back behavior. The load-slip response, stress field, and peak load were solved analytically, resulting in a closed-form solution for the critical length for snap-back and a non-closed-form solution for the effective embedment length. After an inverse analysis procedure was proposed for determining the bond parameters, the accuracy of the analytical solution was verified through comparisons with the self-conducted test results and existing experimental data. A new temperature-dependent bond strength model was also developed. The findings revealed a remarkable decline in the bond strength of up to 92.3 % as the temperature increased from 20 °C to 160 °C, with about 60–70 % of this degradation occurring close to the glass transition temperature (Tg) of the adhesive. At temperatures well above Tg, the bond strength decreased with the bar diameter and displayed insignificant improvement with higher concrete strength. The results also demonstrated that the proposed analytical approach and bond strength model can predict the bond response of ETS ribbed GFRP bars embedded in concrete with reasonable accuracy.

The performance of waste glass aggregate concrete GFRP-steel double-skin tubular columns under axial compression: Experimental study

In an attempt to alleviate the problem of growing waste glass and fully utilize the excellent material properties of fiber-reinforced polymer (FRP), a novel composite structure, waste glass aggregate concrete glass fiber reinforced polymer (GFRP)-steel double-skin tubular column (WGAC-DSTC), was proposed based on the FRP-concrete-steel double-skin tubular column (DSTC). In the present research, eight WGAC-DSTCs and four waste glass aggregate concrete-filled GFRP tubular columns (WGAC-CFFTs) were investigated to explore their mechanical performance under axial compression. Effects of diverse replacement ratio of waste glass aggregate, GFRP tube thickness, and hollow ratio of column on the mechanical performance of twelve columns were investigated. Meanwhile, this research analyzed and discussed the failure characteristics of columns, load-displacement relationship, ductility coefficient, stiffness coefficient, parameter analysis, ultimate bearing capacity, load-strain relationship and constraint factor. Besides, predicted formulae for estimating the ultimate bearing capacity of WGAC-CFFTs and WGAC-DSTCs were proposed. The research results indicated that (1) Failure mode of the WGAC-DSTCs displayed axial compression failure or shear failure and failure mode of WGAC-CFFTs exhibited mainly axial compression failure; (2) WGAC-DSTCs with 10 % replacement ratio of waste glass aggregate and hollow ratio of 0.4 indicated an increase in the ultimate bearing capacity by 17.24 % and 45.78 %, respectively, as the GFRP tube thickness increased from 1.5 mm to 2 mm and 3 mm. As the column's hollow ratio enhanced from 0.27 to 0.68, the column's ultimate bearing capacity significantly decreased by 7.08 %-60.55 %. The ultimate bearing capacity of WGAC-CFFTs showed a trend of first increasing by 8.33 %-9.41 % but then decreasing by 1.52 % when the replacement ratio of waste glass aggregate rose from 0 % to 30 %; (3) WGAC could replace natural aggregate concrete in traditional DSTC and the bearing capacity could be guaranteed. Besides, it's recommended to utilize 20 % replacement ratio of waste glass aggregate for the WGAC-DSTC whose ultimate bearing capacity enhanced by 15.17 % and possessing optimal mechanical performance; (4) The results calculated utilizing predicted formulae matched well with results of experiment. The application of waste glass aggregate concrete in DSTC can contribute to economic growth and environmental protection and meet the concept of sustainable development.

Effect of MICP-recycled GFRP fiber on the self-repairing properties of concrete

The recycling of waste glass fiber-reinforced polymer (GFRP) holds paramount importance in realizing sustainability goals. This study aims to enhance the efficacy of fiber-reinforced self-healing concrete by employing recycled GFRP (rGFRP) fibers as carriers for Microbiologically Induced Calcite Precipitation (MICP). Preparations involved the development of pretreatment of rGFRP using microbial mineralization. Examination encompassed the assessment of interactions between microorganisms and fibers, microstructural characterization of self-healing specimens, and the strength of repaired specimens. This was conducted through the quantification of CaCO3 precipitation, strength tests, scanning electron microscopy (SEM), X-ray computed topography (CT) analysis, and mercury intrusion porosimetry (MIP). The results revealed that mineralized rGFRP fibers had little impact on the flexural and compressive strength of the reinforced mortar, while increased the tensile strength by up to 34.1 %. The mineralized rGFRP fiber-reinforced mortar achieved a repair rate of 84.5 % for cracks within 0.3 mm after 28 days of water curing. Comparatively, the mineralized rGFRP fiber bacterial mortar exhibited higher water absorption than its non-mineralized counterpart. Using untreated rGFRP fibers for self-healing can reduce the porosity and water absorption of the mortar to some extent, while adding mineralized rGFRP fibers for self-healing increased the crack area repair rate and also increased the porosity of the mortar. Therefore, using untreated rGFRP fibers as a carrier for microorganisms to repair mortar may present a more favorable choice. The results of this study will contribute to further improvement in the application of fiber-reinforced self-healing concrete in the engineering field.

Analysis of factors influencing GFRP shredding energy consumption and the physical properties of the resulting recyclates

Glass fibre reinforced polymer (GFRP) remains the dominant composite produced globally due to its low cost, high specific mechanical properties and chemical resistance performances. These unique features, however, impose significant recycling challenges for their end-of-life parts. Although there are various recycling technologies available, all of them require the waste GFRP to be reduced in size in order to enhance the recycling process efficiency. In this work, a full factorial design analysis was conducted to identify factors that influenced specific shredding energy consumption, average physical size and resin content of shredded GFRP recyclates. Factors investigated were glass fibre fabric architecture in GFRP wastes (non-crimp and nonwoven), GFRP waste feed rate (10–60 kg/h) and screen aperture of the shredding process (6–20 mm). It was observed that specific shredding energy was not significantly affected by the fabric architecture but could be reduced by opting for larger screen aperture and/or lower feed rate. However, improvement to shredding energy efficiency was achieved if 6 mm diameter screen was selected together with 60 kg/h feed rate. The 60 kg/h feed rate was found to be ideal in reducing oversize recyclates content but did not affect the median particle size of the remaining recyclates, which was found to be influenced by screen aperture and fabric architecture. Resin-rich and fibre-rich fractions were identified from the recyclates. The resin content of the former was found to be sensitive to all the studied factors.

Comparing tensile, bending and interlaminar shear performance of GFRP composites fabricated using recovered and virgin glass fibers: Optimization of the microwave assisted chemical recycling technique

AbstractGlobal glass fiber reinforced plastic (GFRP) recycling provides an effective solution to the end‐of‐life wastes and industrial scrap, by which we can construct a closed‐loop system that reduces environmental impact while increasing sustainability. This study reports the tensile, flexural and shear properties of GFRP composites fabricated from reclaimed fibers from the waste GFRP. A hybrid recycling technique that is, microwave assisted chemical recycling has been used for recovering the glass fiber fabrics. The quantity of solvents (a mixture of 30% H2O2 and CH3COOH in 1:1 ratio) required (in mL/g) for degrading the polymer is optimized with respect to the amount of microwave irradiation time. The microwave irradiation duration was varied at constant power of 900 W for optimizing the quantity of solvent used. SEM analysis of both virgin and reclaimed fiber surfaces indicate an almost complete degradation of polymer from the waste composites. RGFE laminates, fabricated from reclaimed glass fiber fabrics, exhibited marginally higher tensile strength (7%–8%) and significant lower tensile modulus (~29%). On the other hand, RGFE composites demonstrated a greater strain to failure of ~44% compared to VGFE composites during tensile testing, consequently leading to a subsequent increase in tensile toughness by ~28%. The ILSS values obtained from SBS tests and storage modulus and loss factor curves from DMA tests showed almost similar values. SEM studies revealed the probable causes of failures of the samples for tensile and flexural tests.Highlights Hybrid recycling technique using microwave irradiation is optimized. Amount of solvent used is optimized by varying the irradiation times. Tensile and flexural strengths exhibit a marginal increase of 7%–8%. Significant rise in strain at failure by 44% and tensile toughness by 28%. Fractography studies have been performed for analyzing failures.