With the development of energy efficient technologies for glass envelopes, using thermal storage techniques to improve their thermal inertia has become a trend in research. In the present study, the heat transfer and day-lighting models of a building with PCM glazing curtain wall (PGC) were developed. Multiple parameters such as glazing internal surface temperature, PCM liquid phase rate, indoor temperature, natural illumination, and daylighting coefficient were quantitatively analyzed to evaluate their indoor thermal environment and daylighting performance. The results show that the application of PGC can significantly improve indoor temperature uniformity and indoor thermal comfort compared to silica aerogel glass curtain wall (SGC) and hollow glass curtain wall (HGC). By filling 10 mm thick PCM, the temperature fluctuation of the inner surface of the glass and the midpoint temperature of the room can be reduced by 35 %, the peak temperature of the inner surface of the glass can be delayed by 0.89 h, and the average indoor natural light value and indoor daylight factor are satisfactory at 453.26 lx and 9.63 %, respectively. However, as the thickness of the PCM increases to 15 and 20 mm, the liquid fraction of the PCM and the energy storage performance of the PGC are greatly reduced, and natural daylighting does not meet the GB/t-50033-2013 limit.
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